CN104334024A - Herbicidal compositions comprising N-(tetrazol-5-yl)- or N-(triazol-5-yl)arylcarboxamides - Google Patents

Herbicidal compositions comprising N-(tetrazol-5-yl)- or N-(triazol-5-yl)arylcarboxamides Download PDF

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CN104334024A
CN104334024A CN201380027135.0A CN201380027135A CN104334024A CN 104334024 A CN104334024 A CN 104334024A CN 201380027135 A CN201380027135 A CN 201380027135A CN 104334024 A CN104334024 A CN 104334024A
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alkyl
halo
methyl
cycloalkyl
alkoxyl
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CN104334024B (en
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A·范阿尔姆西克
E·加茨魏勒
E·哈克
R·布劳恩
H·曼内
K·特拉博尔德
C·沃尔德拉夫
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Bayer CropScience AG
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/713—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
    • A01N33/18—Nitro compounds
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    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/10—Aromatic or araliphatic carboxylic acids, or thio analogues thereof; Derivatives thereof
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    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/34—Nitriles
    • A—HUMAN NECESSITIES
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/10—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with sulfur as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S435/00—Chemistry: molecular biology and microbiology
    • Y10S435/8215—Microorganisms
    • Y10S435/822—Microorganisms using bacteria or actinomycetales
    • Y10S435/874—Pseudomonas

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  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
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  • Agronomy & Crop Science (AREA)
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Abstract

There are described herbicidal compositions which comprise active substances from the group of the N-(tetrazol-5-yl)- and N-(triazol-5-yl)arylcarboxamides and further herbicides and optionally safeners. These herbicidal compositions are particularly suited for use against harmful plants in crops of useful plants.

Description

Comprise the herbicidal composition of N-(tetrazolium-5-base) aryl carboxamides and N-(triazole-5-base) aryl carboxamides
The present invention relates to pesticide activity herbicidal composition, and preparation method thereof and relate to it for preventing and treating the purposes of noxious plant.
WO 2012/028579 A1 discloses some N-with weeding characteristic (tetrazolium-5 base)-and N-(triazole-5-base) aryl carboxamides compound with the non-formerly disclosed EP11176378 with comparatively early priority.But these reactive compounds always do not have the activity of enough anti-noxious plants and/or some in them to some important crop plants as cereals, and corn and paddy rice are not completely compatible.
Therefore, the object of this invention is to provide herbicidal composition, the activity of its removal noxious plant and/or the selectivity of above-mentioned weed killer herbicide to important crop plants have the activity of increase.This object is by the following stated and comprise the herbicidal composition realization of the present invention of some N-(tetrazolium-5-base)-and N-(triazole-5-base) aryl carboxamides and other weed killer herbicides and optionally safener.
Herbicidal composition provided by the invention comprises:
(A) compound (component A) of one or more formulas (I) or its salt
Symbol wherein and mark are defined as follows separately:
A represents N or CY,
B represents N or CH,
X represents nitro, halogen, cyano group, formoxyl, thiocyano (thiocyanato), (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, (C 2-C 6)-thiazolinyl, halo-(C 2-C 6)-thiazolinyl, (C 2-C 6)-alkynyl, halo-(C 3-C 6)-alkynyl, (C 3-C 6)-cycloalkyl, halo-(C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, halo-(C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, COR 1, COOR 1, OCOOR 1, NR 1cOOR 1, C (O) N (R 1) 2, NR 1c (O) N (R 1) 2, OC (O) N (R 1) 2, C (O) NR 1oR 1, OR 1, OCOR 1, OSO 2r 2, S (O) nr 2, SO 2oR 1, SO 2n (R 1) 2, NR 1sO 2r 2, NR 1cOR 1, (C 1-C 6)-alkyl-S (O) nr 2, (C 1-C 6)-alkyl-OR 1, (C 1-C 6)-alkyl-OCOR 1, (C 1-C 6)-alkyl-OSO 2r 2, (C 1-C 6)-alkyl-CO 2r 1, (C 1-C 6)-alkyl-SO 2oR 1, (C 1-C 6)-alkyl-CON (R 1) 2, (C 1-C 6)-alkyl-SO 2n (R 1) 2, (C 1-C 6)-alkyl-NR 1cOR 1, (C 1-C 6)-alkyl-NR 1sO 2r 2, NR 1r 2, P (O) (OR 5) 2, CH 2p (O) (OR 5) 2, (C 1-C 6)-miscellaneous alkyl aryl, (C 1-C 6)-alkyl heterocyclic, two groups wherein finally mentioned are selected from following group by s separately and replace: halogen, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, S (O) n-(C 1-C 6)-alkyl, (C 1-C 6)-alkoxyl and halo-(C 1-C 6)-alkoxyl, and wherein heterocyclic radical has n oxo group,
Y represents hydrogen, nitro, halogen, cyano group, thiocyano, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, (C 2-C 6)-thiazolinyl, halo-(C 2-C 6)-thiazolinyl, (C 2-C 6)-alkynyl, halo-(C 2-C 6)-alkynyl, (C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkenyl group, halo-(C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, halo-(C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, COR 1, COOR 1, OCOOR 1, NR 1cOOR 1, C (O) N (R 1) 2, NR 1c (O) N (R 1) 2, OC (O) N (R 1) 2, CO (NOR 1) R 1, NR 1sO 2r 2, NR 1cOR 1, OR 1, OSO 2r 2, S (O) nr 2, SO 2oR 1, SO 2n (R 1) 2, (C 1-C 6)-alkyl-S (O) nr 2, (C 1-C 6)-alkyl-OR 1, (C 1-C 6)-alkyl-OCOR 1, (C 1-C 6)-alkyl-OSO 2r 2, (C 1-C 6)-alkyl-CO 2r 1, (C 1-C 6)-alkyl-CN, (C 1-C 6)-alkyl-SO 2oR 1, (C 1-C 6)-alkyl-CON (R 1) 2, (C 1-C 6)-alkyl-SO 2n (R 1) 2, (C 1-C 6)-alkyl-NR 1cOR 1, (C 1-C 6)-alkyl-NR 1sO 2r 2, N (R 1) 2, P (O) (OR 5) 2, CH 2p (O) (OR 5) 2, (C 1-C 6)-alkyl phenyl, (C 1-C 6)-miscellaneous alkyl aryl, (C 1-C 6)-alkyl heterocyclic, phenyl, heteroaryl and heterocyclic radical, six groups wherein finally mentioned are selected from following group by s separately and replace: halogen, nitro, cyano group, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, (C 3-C 6)-cycloalkyl, S (O) n-(C 1-C 6)-alkyl, (C 1-C 6)-alkoxyl, halo-(C 1-C 6)-alkoxyl, (C 1-C 6)-alkoxyl-(C 1-C 4)-alkyl and cyano methyl, and wherein heterocyclic radical has n oxo group,
Z represents halogen, cyano group, thiocyanogen, halo-(C 1-C 6)-alkyl, (C 2-C 6)-thiazolinyl, halo-(C 2-C 6)-thiazolinyl, (C 2-C 6)-alkynyl, halo-(C 2-C 6)-alkynyl, (C 3-C 6)-cycloalkyl, halo-(C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, halo-(C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, COR 1, COOR 1, OCOOR 1, NR 1cOOR 1, C (O) N (R 1) 2, NR 1c (O) N (R 1) 2, OC (O) N (R 1) 2, C (O) NR 1oR 1, OSO 2r 2, S (O) nr 2, SO 2oR 1, SO 2n (R 1) 2, NR 1sO 2r 2, NR 1cOR 1, (C 1-C 6)-alkyl-S (O) nr 2, (C 1-C 6)-alkyl-OR 1, (C 1-C 6)-alkyl-OCOR 1, (C 1-C 6)-alkyl-OSO 2r 2, (C 1-C 6)-alkyl-CO 2r 1, (C 1-C 6)-alkyl-SO 2oR 1, (C 1-C 6)-alkyl-CON (R 1) 2, (C 1-C 6)-alkyl-SO 2n (R 1) 2, (C 1-C 6)-alkyl-NR 1cOR 1, (C 1-C 6)-alkyl-NR 1sO 2r 2, N (R 1) 2, P (O) (OR 5) 2, heteroaryl, heterocyclic radical or phenyl, three groups wherein finally mentioned are selected from following group by s separately and replace: halogen, nitro, cyano group, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, (C 3-C 6)-cycloalkyl, S (O) n-(C 1-C 6)-alkyl, (C 1-C 6)-alkoxyl or halo-(C 1-C 6)-alkoxyl, and wherein heterocyclic radical has n oxo group, or
Z also can represent hydrogen, (C 1-C 6)-alkyl or (C 1-C 6)-alkoxyl, if Y represents S (O) nr 2group,
W represents hydrogen, (C 1– C 6)-alkyl, halo-(C 1– C 6)-alkyl, (C 2– C 6)-thiazolinyl, halo-(C 2– C 6)-thiazolinyl, (C 2– C 6)-alkynyl, halo-(C 2– C 6)-alkynyl, (C 3– C 7)-cycloalkyl, (C 3– C 7)-halogenated cycloalkyl, (C 1-C 6)-alkoxyl, (C 1-C 6)-halogenated alkoxy, S (O) n-(C 1-C 6)-alkyl, S (O) n-(C 1-C 6)-haloalkyl, (C 1-C 6)-alkoxyl-(C 1-C 4)-alkyl, (C 1-C 6)-alkoxyl-(C 1-C 4)-haloalkyl, halogen, nitro, NR 3cOR 3or cyano group,
R represents (C 1– C 8)-alkyl, halo-(C 1– C 8)-alkyl, (C 2-C 8)-thiazolinyl, halo-(C 2-C 8)-thiazolinyl, (C 2-C 8)-alkynyl, halo-(C 2-C 8)-alkynyl, wherein these six groups above-mentioned are selected from following group by s separately and replace: hydroxyl, nitro, cyano group, SiR 5 3, PO (OR 5) 2, S (O) n-(C 1-C 6)-alkyl, S (O) n-(C 1-C 6)-haloalkyl, (C 1-C 6)-alkoxyl, halo-(C 1-C 6)-alkoxyl, N (R 3) 2, COR 3, COOR 3, OCOR 3, NR 3cOR 3, NR 3sO 2r 4, O (C 1-C 2)-alkyl-(C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkyl, heteroaryl, heterocyclic radical, phenyl, Q-heteroaryl, Q-heterocyclic radical, Q-phenyl and Q-benzyl, seven wherein finally mentioned groups are selected from following group by s separately and replace: methyl, ethyl, methoxyl group, trifluoromethyl, cyano group and halogen, and wherein heterocyclic radical has n oxo group, or
R represents (C 3– C 7)-cycloalkyl, heteroaryl, heterocyclic radical or phenyl, it is selected from following group by s separately and replaces: halogen, nitro, cyano group, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, (C 3-C 6)-cycloalkyl, S (O) n-(C 1-C 6)-alkyl, (C 1-C 6)-alkoxyl, halo-(C 1-C 6)-alkoxyl and (C 1-C 6)-alkoxyl-(C 1-C 4)-alkyl, wherein heterocyclic radical have n oxo group,
Q represents O, S or NR 3,
R 1represent hydrogen, (C 1-C 6)-alkyl, (C 1-C 6)-haloalkyl, (C 2-C 6)-thiazolinyl, (C 2-C 6)-haloalkenyl group, (C 2-C 6)-alkynyl, (C 2-C 6)-halo alkynyl, (C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkenyl group, (C 3-C 6)-halogenated cycloalkyl, (C 1-C 6)-alkyl-O-(C 1-C 6)-alkyl, (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, phenyl, phenyl-(C 1-C 6)-alkyl, heteroaryl, (C 1-C 6)-miscellaneous alkyl aryl, heterocyclic radical, (C 1-C 6)-alkyl heterocyclic, (C 1-C 6)-alkyl-O-heteroaryl, (C 1-C 6)-alkyl-O-heterocyclic radical, (C 1-C 6)-alkyl-NR 3-heteroaryl or (C 1-C 6)-alkyl-NR 3-heterocyclic radical, 21 groups wherein finally mentioned are selected from following group by s separately and replace: cyano group, halogen, nitro, thiocyano, OR 3, S (O) nr 4, N (R 3) 2, NR 3oR 3, COR 3, OCOR 3, SCOR 4, NR 3cOR 3, NR 3sO 2r 4, CO 2r 3, COSR 4, CON (R 3) 2(C 1-C 4)-alkoxyl-(C 2-C 6)-alkoxy carbonyl, and wherein heterocyclic radical has n oxo group,
R 2representative (C 1-C 6)-alkyl, (C 1-C 6)-haloalkyl, (C 2-C 6)-thiazolinyl, (C 2-C 6)-haloalkenyl group, (C 2-C 6)-alkynyl, (C 2-C 6)-halo alkynyl, (C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkenyl group, (C 3-C 6)-halogenated cycloalkyl, (C 1-C 6)-alkyl-O-(C 1-C 6)-alkyl, (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, phenyl, phenyl-(C 1-C 6)-alkyl, heteroaryl, (C 1-C 6)-miscellaneous alkyl aryl, heterocyclic radical, (C 1-C 6)-alkyl heterocyclic, (C 1-C 6)-alkyl-O-heteroaryl, (C 1-C 6)-alkyl-O-heterocyclic radical, (C 1-C 6)-alkyl-NR 3-heteroaryl or (C 1-C 6)-alkyl-NR 3-heterocyclic radical, 21 groups wherein finally mentioned are selected from following group by s separately and replace: cyano group, halogen, nitro, thiocyano, OR 3, S (O) nr 4, N (R 3) 2, NR 3oR 3, COR 3, OCOR 3, SCOR 4, NR 3cOR 3, NR 3sO 2r 4, CO 2r 3, COSR 4, CON (R 3) 2(C 1-C 4)-alkoxyl-(C 2-C 6)-alkoxy carbonyl, and wherein heterocyclic radical has n oxo group,
R 3represent hydrogen, (C 1-C 6)-alkyl, (C 2-C 6)-thiazolinyl, (C 2-C 6)-alkynyl, (C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl or phenyl,
R 4representative (C 1-C 6)-alkyl, (C 2-C 6)-thiazolinyl, (C 2-C 6)-alkynyl, (C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl or phenyl,
R 5representative (C 1-C 4)-alkyl,
N is 0,1 or 2,
S is 0,1,2 or 3, and
(B) one or more are selected from the weed killer herbicide (B component) of B1 to B11:
B11, 3-dione compounds, comprise: Prohexadione calcium (prohexadione-calcium), TrinexAN_SNacethyl (trinexapac-ethyl), alloxydimsodium (alloxydim), clethodim (clethodim), cycloxydim (cycloxydim), clefoxidim (profoxydim), sethoxydim (sethoxydim), obtain herbicide (tepraloxydim), tralkoxydim (tralkoxydim), mesotrione (mesotrione), sulphur humulone (sulcotrione), special furan triketone (tefuryltrione), ring sulphur ketone (tembotrione), fluorine benzofenap (bicyclopyrone), azoles quinoline grass ester (pinoxaden),
B2 (sulphur) acid amides, comprising:
Beflubutamide, bromobutide (bromobutide), dimethenamid (dimethenamid), essence cresols fenacet (dimethenamide-P), diphenamide (diphenamide), napropamide (napropamide), pethoxamid (pethoxamid), N-[the chloro-4-of 3-(1-Methylethyl)-phenyl]-2-methylpentanamide, quinclorac (naptalam), propyzamide (propyzamide), diflufenican (diflufenican), ethobenzanid (etobenzanid), flufenacet (flufenacet), mefenacet (mefenacet), chlorine sulphonyl grass amine (mefluidide), pentanochlor (pentanochlor), fluorine metazachlor (picolinafen), Stam F-34 (propanil), benzene peptide propylhomoserin (N-phenylphthalamic acid), Acetochlor (acetochlor), alachlor (alachlor), butachlor (butachlor), dimethachlor (dimethachlor), metazachlor (metazachlor), isopropyl methoxalamine (metolachlor), S-isopropyl methoxalamine (S-metolachlor), third careless amine (pretilachlor), propachlor (propachlor), propisochlor (propisochlor), (the chloro-6 '-ethyl of 2--N-i-propoxymethyl acetyl-o-toluidines), P DimethenamidP (thenylchlor), sulphur grass spirit (asulam), carbaryl (carbaryl), carbetamide (carbetamide), chlorpropham (chlorpropham), desmedipham (desmedipham), phenmedipham (phenmedipham), propham (propham), butylate (butylate), cycloate (cycloate), dimepiperate (dimepiperate), EPTC, esprocarb (esprocarb), methasulfocarb (methasulfocarb), molinate (molinate), orbencarb (orbencarb), pebulate (pebulate), prosulfocarb (prosulfocarb), pyributicarb (pyributicarb), benthiocarb (thiobencarb), triallate (tri-allate), vernolate (vernolate), amidosulfuron (amidosulfuron), azimsulfuron (azimsulfuron), bensulfuron-methyl (bensulfuron-methyl), chlorimuronethyl (chlorimuron-ethyl), chlorine sulphur grand (chlorsulfuron), cinosulfuron (cinosulfuron), AC322140 (cyclosulfamuron), ethametsulfuron (ethametsulfuron-methyl), ethoxysulfuron (ethoxysulfuron), flazasulfuron (flazasulfuron), flucetosulfuron (flucetosulfuron), flupyrsulfuron-methyl-sodium (flupyrsulfuron-methyl-sodium), formyl ammonia sulphur grand (foramsulfuron), halosulfuronmethyl (halosulfuron-methyl), imazosulfuron (imazosulfuron), iodosulfuron methyl sodium (iodosulfuron-methyl-sodium), mesosulfuronmethyl (mesosulfuron-methyl), metsulfuron-methyl (metsulfuron-methyl), monosulfmeturon (monosulfuron), nicosulfuron (nicosulfuron), phonetic aniline sulphur grand (orthosulfamuron), oxasulfuron (oxasulfuron), primisulfuronmethyl (primisulfuron-methyl), prosulfuron (prosulfuron), pyrazosulfuron (pyrazosulfuron-ethyl), rimsulfuron (rimsulfuron), sulfometuronmethyl (sulfometuron-methyl), Sulfosulfuron (sulfosulfuron), thifensulfuronmethyl methyl esters (thifensulfuron-methyl), triasulfuron (triasulfuron), tribenuron-methyl methyl esters (tribenuron-methyl), trifloxysulfuron (sodium) (trifloxysulfuron (sodium)), triflusulfuronmethyl (triflusulfuron-methyl), tritosulfuron (tritosulfuron), (benzoic acid, 2-[[[[[4-methoxyl group-6-(methyl mercapto)-2-pyrimidine radicals] is amino] carbonyl] is amino] sulfonyl] methyl esters), flucarbazonesodium (flucarbazone-sodium), procarbazone (propoxycarbazone-sodium), thiophene ketone sulphur grand (thiencarbazone-methyl), cloransulammethyl (cloransulam-methyl), diclosulam (diclosulam), florasulam (florasulam), Flumetsulam (flumetsulam), metosulam (metosulam), penoxsuam (penoxsulam), pyroxsulam (pyroxsulam),
B3 aromatic nitrile, comprising:
Brominal (bromoxynil), dichlobenil (dichlobenil), ioxynil (ioxynil), pyraclonil (pyraclonil),
B4 oxazole class, comprising:
Benzofenap (benzofenap), pyrazolate (pyrazolynate), pyrazoxyfen (pyrazoxyfen), send Roc herbicide sulfone (pyroxasulfone), benzene pyrazoles humulone (topramezone), sulphonyl grass pyrazoles (pyrasulfotole), 3-(the chloro-5-{ of 3-[1-methyl-3-(trifluoromethyl)-1H-pyrazoles-5-base] oxygen base } phenoxy group)-1-methyl-5-(trifluoromethyl)-1H-pyrazoles, 3-(the iodo-5-{ of 3-[1-methyl-3-(trifluoromethyl)-1H-pyrazoles-5-base] oxygen base } phenoxy group)-1-methyl-5-(trifluoromethyl)-1H-pyrazoles, 1-ethyl-3-(the fluoro-5-{ of 3-[1-methyl-3-(trifluoromethyl)-1H-pyrazoles-5-base] oxygen base } phenoxy group)-5-(trifluoromethyl)-1H-pyrazoles, pyrrole grass ether (pyraflufen-ethyl), fluazolate (fluazolate), isouron (isouron), Yi Evil acyl grass amine (isoxaben), isoxazole humulone (isoxaflutole), miaow methyl oxalate (imazamethabenz-methyl), imazamox (imazamox), AC 263222 (imazapic), imazapyr (imazapyr), imazaquin (imazaquin), imazethapyr (imazethapyr), methazole (methazole), oxadiargyl (oxadiargyl), oxadiazon (oxadiazon), amicarbazone (amicarbazone), carfentrazone (carfentrazone-ethyl), sulfentrazone (sulfentrazone), bencarbazone, Amrol (amitrole), paclobutrazol (paclobutrazole), uniconazole P (uniconazole), cafenstrole (cafenstrole), fentrazamide (fentrazamide),
Other weed killer herbicides of B5, comprising:
Ring third pyrimidine acid (aminocyclopyrachlor), N-acetyl thiazole quinoline-4-carboxylic acid (N-acetylthiazolidine-4-carboxylic acid), acrolein (acrolein), chlorine Fampridine acid (aminopyralid), n-nonanoic acid ammonium (ammonium pelargonate), Amcide Ammate (ammonium sulfamate), Ai Wei hormone (aviglycine), benazolin (benazolin), benfluralin (benfluralin), benfuresate (benfuresate), bentazone (bentazone), benzobicylon (benzobicyclon), 6-benzylaminopurine (6-benzylaminopurine), borax (borax), butralin (butralin), carvol (carvone), catechin (catechin), morphactin (chlorflurenol-methyl), Pynamin (chloridazon), chlormequat (chlormequat chloride), monoxone (chloroacetic acid), chlorine acid imide (chlorphthalim), chlorine dimethyl phthalate (chlorthal-dimethyl), cinidon-ethyl (cinidon-ethyl), cinmethylin (cinmethylin), clofencet (clofencet), clomazone (clomazone), cloxyfonac (cloxyfonac), cyanamide (cyanamide), ring malonamic acid (cyclanilide), 6-c purine (6-isopentylaminopurin), kinetin (kinetin), zeatin (zeatin), dalapon (dalapon), daminozide (daminozide), dazomet (dazomet), Decanol (n-decanol), difenzoquat methylsulfuric acid ester (difenzoquat metilsulfate), 2,6-DIPN (2,6-diisopropylnaphthalene), dikegulac (dikegulac), dimethipin (dimethipin), cacodylic acid (dimethylarsenic acid), dinitramine (dinitramine), dinoterb (dinoterb), diquat (diquat dibromide), dithiopyr (dithiopyr), DNOC, endothal (endothal), fourth fluchloralin (ethafluralin), ethofumesate (ethofumesate), ethylchlozate, ferrous sulfate (ferrous sulfate), flampropMmethyl (flamprop-M-methyl), flufenpyrethyl (flufenpyr-ethyl), flumetralim (flumetralin), Flumiclorac pentyl (flumiclorac-pentyl), flumioxazin (flumioxazin), tetrafluoro propionic acid (flupropanate), flurenol (flurenol), fluridone (fluridone), fluorochloridone (flurochloridone), flurtamone (flurtamone), gibberellin (gibberillic acid), indanofan (indanofan), isopropalin (isopropalin), Isoprothiolane (isoprothiolane), maleic hydrazide (maleic hydrazide), mepiquat chloride (mepiquat chloride), metham-sodium (metam), methanearsonic acid (methylarsonic acid), 1-methyl cyclopropene (1-methylcyclopropene), methyl-isorhodanate (methyl isothiocyanate), nitrophenol salt mixture (nitrophenolate mixture), n-nonanoic acid (nonanoic acid), norflurazon (norflurazon), oleic acid (oleic acid), oryzalin (oryzalin), oxaziclomefone (oxaziclomefone), PP-148 (paraquatdichloride), pendimethalin (pendimethalin), pentachlorophenol (pentachlorophenol), Huan Wu Evil humulone (pentoxazone), petroleum oil (petroleum oils), prodiamine (prodiamine), jasmone (n-propyl dihydrojasmonate), pyridate (pyridate), quinoclamine (quinoclamine), sintofen (sintofen), sodium chlorate (sodium chlorate), sulfuric acid (sulfuric acid), tar (tar oils), TCA sodium, tecnazene (tecnazene), thrizopyr (thiazopyr), triacontanol (triacontanol), trefanocide (trifluralin) and ureasulfuric acid (urea sulfate),
B6 (mixing) aryl carboxylic acid class, comprising:
Dicamba (dicamba), 2,3,6-TBA, clopyralid (clopyralid), fluroxypyr (fluroxypyr), inabenfide (inabenfide), picloram (picloram), trichlopyr (triclopyr), dichloro quinolinic acid (quinclorac), quinmerac (quinmerac), indoles-3 guanidine-acetic acid, 4-indol-3-yl butyric acid, 2-(1-naphthyl) acetamide, 1-naphthyl acetic acid, 2-naphthyl ethoxyacetic acid
B7 organic phosphine compound class, comprising:
Anilofos (anilofos), bensulide (bensulide), bilanafos (bilanafos), butimafos, ioxynil (fosamine), Glufosinate (glufosinate), phosphine oxamate salt (glufosinate salts), Glufosinate (glufosinate-ammonium), phosphine oxamate sodium salt (glufosinate-sodium), L-Glufosinate (L-glufosinate-ammonium), L-phosphine oxamate sodium salt (L-glufosinate-sodium), glyphosate (glyphosate), glyphosate isopropyl amine salt (glyphosate-isopropyl-ammonium), glyphosate (glyphosate-ammonium), sulphosate (glyphosate-trimesium) (=sulfosate), glyphosate two ammonium (glyphosate-diammonium), glyphosate potassium (glyphosate-potassium), piperophos (piperophos), ethrel (ethephon) and De-Green (tribufos),
B8 phenyl ether, comprising:
Acifluorfen (acifluorfen-sodium), aclonifen (aclonifen), fluoroglycofen-ethyl (fluoroglycofen-ethyl), fomesafen (fomesafen), lactofen (lactofen), Oxyfluorfen (oxyfluorfen), bifenox (bifenox), HC252 ethyl ester (ethoxyfen-ethyl), clomeprop (clomeprop), adjust tartaric acid (cloprop), 2,4-drips propionic acid (dichlorprop), essence 2,4-drips propionic acid (dichlorprop-P), 2-first-4-chloropropionic acid (mecoprop), essence 2-first-4-chloropropionic acid (mecoprop-P), 4-CPA, 2,4-D, MCPA, MCPA-sulphur ethyl (thioethyl), 2,4-DB, MCPB, clodinafop-propargyl (clodinafop-propargyl), cyhalofop-butyl (cyhalofop-butyl), diclofop-methyl (diclofop-methyl), essence diclofop-methyl (diclofop-P-methyl), fenoxaprop (fenoxaprop-P-ethyl), fluazifop-P-butyl (fluazifop-butyl), efficient fluazifop butyl ester (fluazifop-P-butyl), fluazifop-butyl (haloxyfop), essence fluazifop-butyl (haloxyfop-P), metamifop (metamifop), propaquizafop (propaquizafop), quizalafop, quizalafop-P,
B9 pyrimidines, comprising:
The phonetic alcohol of three ring benzene (ancymidol), flurprimidol (flurprimidol), Nylar (pyrimisulfan), two careless ether (bispyribac-sodium), pyribenzoxim (pyribenzoxim), KIH 6127 (pyriminobac-methyl), iso-propyl-ester nitrofen (pyribambenz-isopropyl), propyl-ester nitorfen (pyribambenz-propyl), pyriftalid (pyriftalid), pyrithiobac-sodium (pyrithiobac-sodium), benzfendizone (benzfendizone), bromacil (bromacil), butafenacil (butafenacil), lenacil (lenacil), terbacil (terbacil), the fluoro-5-of the chloro-4-of 2-[3-methyl-2, 6-dioxo-4-(trifluoromethyl)-3, 6-dihydroxy-pyrimidine-1 (2H)-Ji]-N-[methyl (1-Methylethyl)-sulfamoyl] benzamide
B10 (sulphur) urea, comprising:
Cumyluron (cumyluron), bromax (chlorbromuron), chlortoluron (chlorotoluron), chloroxifenidium (chloroxuron), daimuron (daimuron), diflufenzopyr (diflufenzopyr), oxazole grand (dimefuron), diuron (diuron), fluometuron (fluometuron), CPPU (forchlorfenuron), isoproturon (isoproturon), karbutilate (karbutilate), lorox (linuron), methyldymron (methyldymron), metobromuron (metobromuron), metoxuron (metoxuron), afesin (monolinuron), neburea (neburon), Tupersan (siduron), Thidiazuron (thidiazuron), methiuron (methiuron), tebuthiuron (tebuthiuron), methabenzthiazuron (methabenzthiazuron),
B11 triazines, comprising:
Triaziflam (triaziflam), iodine metsulfuron-methyl (indaziflam), atrazine (atrazine), cyanazine (cyanazine), propazine (propazine), Simanex (simazine), Garagard (terbuthylazine), trietazine (trietazine), prometryn (prometon), ametryn (ametryn), dimethametryn (dimethametryn), prometryn (prometryn), symetryne (simetryn), terbutryn (terbutryn), hexazinone (hexazinon), metamitron (metamitron), piperazine humulone (metribuzin).
In another embodiment, these herbicidal compositions comprise C)
One or more safeners (component C), be selected from: benoxacor (benoxacor) (C1), cloquitocet_mexyl (cloquintocet-mexyl) (C2), cyclopropyl-sulfonylamide (cyprosulfamide) (C3), dichlormide (dichlormid) (C4), fenclorim (fenclorim) (C5), fenchlorazole (fenchlorazole) (C6), Xie Cao oxazole (furilazole) (C7), Shuan Ben oxazole acid (isoxadifen-ethyl) (C8), mefenpyrdiethyl (mefenpyr-diethyl) (C9),
CAS is 4-(dichloro-acetyl)-1-oxa--4-azaspiro [4.5] decane (C10) of 71526-07-3,
CAS is 2,2, the 5-trimethyl-3-(dichloro-acetyl)-1,3-oxazolidine (C11) of 52836-31-4.
B component) and C) to be known in such as " The Pesticide Manual ", the 15th edition, Britain crop protection association (The British Crop Protection Council) and British royal chemistry meeting (the Royal Soc.of Chemistry) and network address http://www.alanwood.net/pesticides/.
Herbicidal composition of the present invention can comprise other other components or use together with other other components, and the active crop of such as other kinds protects composition and/or additive and/or routine to be used for the formulation auxiliary agents of crop protection.
Weed killer herbicide (A), (B) and optional safener (C) are used in known manner, such as, use (being such as total to preparation or bucket mix formulation) together or use (fast) at the different time at shorter interval, such as, being applied to plant, plant part, the seed of plant or the region of plant growth.Such as, reactive compound or herbicide-safener gradation can be used separately and combine and use (sequential use), such as, go out preemergence application and then go out postemergence application, or the centre of using in early days after emerging then after emerging or later stage use.Preferred combination (joint) or the reactive compound sequentially used immediately in each bond.Also the bond of independent reactive compound or herbicide-safener can be used for seed treatment.
Preferred use is according to those compositions of the present invention, and it comprises, those compounds of general formula (I) and its salt as weed killer herbicide (A), wherein,
A represents N or CY,
B represents N or CH,
X represents nitro, halogen, cyano group, thiocyano, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, (C 2-C 6)-thiazolinyl, halo-(C 2-C 6)-thiazolinyl, (C 2-C 6)-alkynyl, halo-(C 3-C 6)-alkynyl, (C 3-C 6)-cycloalkyl, halo-(C 3-C 6)-cycloalkyl, (C 1-C 6)-alkyl-O-(C 1-C 6)-alkyl, (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, halo-(C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, COR 1, OR 1, OCOR 1, OSO 2r 2, S (O) nr 2, SO 2oR 1, SO 2n (R 1) 2, NR 1sO 2r 2, NR 1cOR 1, (C 1-C 6)-alkyl-S (O) nr 2, (C 1-C 6)-alkyl-OR 1, (C 1-C 6)-alkyl-OCOR 1, (C 1-C 6)-alkyl-OSO 2r 2, (C 1-C 6)-alkyl-CO 2r 1, (C 1-C 6)-alkyl-SO 2oR 1, (C 1-C 6)-alkyl-CON (R 1) 2, (C 1-C 6)-alkyl-SO 2n (R 1) 2, (C 1-C 6)-alkyl-NR 1cOR 1or (C 1-C 6)-alkyl-NR 1sO 2r 2, (C 1-C 6)-miscellaneous alkyl aryl, (C 1-C 6)-alkyl heterocyclic, 2 groups wherein finally mentioned are selected from following group by s separately and replace: halogen, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, S (O) n-(C 1-C 6)-alkyl, (C 1-C 6)-alkoxyl and halo-(C 1-C 6)-alkoxyl, and wherein heterocyclic radical has n oxo base,
Y represents hydrogen, nitro, halogen, cyano group, thiocyano, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, (C 2-C 6)-thiazolinyl, halo-(C 2-C 6)-thiazolinyl, (C 2-C 6)-alkynyl, halo-(C 3-C 6)-alkynyl, (C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkenyl group, halo-(C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, halo-(C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, COR 1, OR 1, COOR 1, OSO 2r 2, S (O) nr 2, SO 2oR 1, SO 2n (R 1) 2, N (R 1) 2, NR 1sO 2r 2, NR 1cOR 1, (C 1-C 6)-alkyl-S (O) nr 2, (C 1-C 6)-alkyl-OR 1, (C 1-C 6)-alkyl-OCOR 1, (C 1-C 6)-alkyl-OSO 2r 2, (C 1-C 6)-alkyl-CO 2r 1, (C 1-C 6)-alkyl-SO 2oR 1, (C 1-C 6)-alkyl-CON (R 1) 2, (C 1-C 6)-alkyl-SO 2n (R 1) 2, (C 1-C 6)-alkyl-NR 1cOR 1, (C 1-C 6)-alkyl-NR 1sO 2r 2, (C 1-C 6)-alkyl phenyl, (C 1-C 6)-miscellaneous alkyl aryl, (C 1-C 6)-alkyl heterocyclic, phenyl, heteroaryl or heterocyclic radical, 6 groups wherein finally mentioned are selected from following group by s separately and replace: halogen, nitro, cyano group, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, (C 3-C 6)-cycloalkyl, S (O) n-(C 1-C 6)-alkyl, (C 1-C 6)-alkoxyl, halo-(C 1-C 6)-alkoxyl, (C 1-C 6)-alkoxyl-(C 1-C 4)-alkyl and cyanogen methyl, and wherein heterocyclic radical has n oxo base,
Z represents halogen, cyano group, thiocyano, halo-(C 1-C 6)-alkyl, (C 2-C 6)-thiazolinyl, halo-(C 2-C 6)-thiazolinyl, (C 2-C 6)-alkynyl, halo-(C 3-C 6)-alkynyl, (C 3-C 6)-cycloalkyl, halo-(C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, halo-(C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, COR 1, COOR 1, C (O) N (R 1) 2, C (O) NR 1oR 1, OSO 2r 2, S (O) nr 2, SO 2oR 1, SO 2n (R 1) 2, NR 1sO 2r 2, NR 1cOR 1, (C 1-C 6)-alkyl-S (O) nr 2, (C 1-C 6)-alkyl-OR 1, (C 1-C 6)-alkyl-OCOR 1, (C 1-C 6)-alkyl-OSO 2r 2, (C 1-C 6)-alkyl-CO 2r 1, (C 1-C 6)-alkyl-SO 2oR 1, (C 1-C 6)-alkyl-CON (R 1) 2, (C 1-C 6)-alkyl-SO 2n (R 1) 2, (C 1-C 6)-alkyl-NR 1cOR 1, (C 1-C 6)-alkyl-NR 1sO 2r 2, 1,2,4-triazol-1-yl, or
Z can also represent hydrogen, (C 1-C 6)-alkyl or (C 1-C 6)-alkoxyl, if Y is S (O) nr 2base,
W represents hydrogen, (C 1– C 6)-alkyl, halo-(C 1– C 6)-alkyl, (C 1-C 6)-alkoxyl, (C 1-C 6)-halogenated alkoxy, S (O) n-(C 1-C 6)-alkyl, S (O) n-(C 1-C 6)-haloalkyl, (C 1-C 6)-alkoxyl-(C 1-C 4)-alkyl, halogen, nitro or cyano group,
R represents (C 1– C 8)-alkyl, halo-(C 1– C 8)-alkyl, (C 2-C 8)-thiazolinyl, halo-(C 2-C 8)-thiazolinyl, (C 2-C 8)-alkynyl, halo-(C 2-C 8)-alkynyl, wherein these 6 groups above-mentioned are selected from following group by s separately and replace: nitro, cyano group, SiR 5 3, P (OR 5) 3, S (O) n-(C 1-C 6)-alkyl, (C 1-C 6)-alkoxyl, halo-(C 1-C 6)-alkoxyl, N (R 3) 2, COR 3, COOR 3, OCOR 3, NR 3cOR 3, NR 3sO 2r 4, (C 3-C 6)-cycloalkyl, heteroaryl, heterocyclic radical, phenyl, Q-heteroaryl, Q-heterocyclic radical, Q-phenyl and Q-benzyl, 7 groups wherein finally mentioned are selected from following group by s separately and replace: methyl, ethyl, methoxyl group, trifluoromethyl, cyano group and halogen, and wherein heterocyclic radical has n oxo base, or
R represents (C 3– C 7)-cycloalkyl, heteroaryl, heterocyclic radical or phenyl, be selected from following group by s separately and replace: halogen, nitro, cyano group, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, (C 3-C 6)-cycloalkyl, S (O) n-(C 1-C 6)-alkyl, (C 1-C 6)-alkoxyl, halo-(C 1-C 6)-alkoxyl and (C 1-C 6)-alkoxyl-(C 1-C 4)-alkyl,
Q represents O, S or NR 3,
R 1represent hydrogen, (C 1-C 6)-alkyl, (C 2-C 6)-thiazolinyl, (C 2-C 6)-alkynyl, (C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, (C 1-C 6)-alkyl-O-(C 1-C 6)-alkyl, phenyl, phenyl-(C 1-C 6)-alkyl, heteroaryl, (C 1-C 6)-miscellaneous alkyl aryl, heterocyclic radical, (C 1-C 6)-alkyl heterocyclic, (C 1-C 6)-alkyl-O-heteroaryl, (C 1-C 6)-alkyl-O-heterocyclic radical, (C 1-C 6)-alkyl-NR 3-heteroaryl or (C 1-C 6)-alkyl-NR 3-heterocyclic radical, 16 groups wherein finally mentioned are selected from following group by s separately and replace: cyano group, halogen, nitro, OR 3, S (O) nr 4, N (R 3) 2, NR 3oR 3, COR 3, OCOR 3, NR 3cOR 3, NR 3sO 2r 4, CO 2r 3, CON (R 3) 2(C 1-C 4)-alkoxyl-(C 2-C 6)-alkoxy carbonyl, and wherein heterocyclic radical has n oxo base,
R 2representative (C 1-C 6)-alkyl, (C 2-C 6)-thiazolinyl, (C 2-C 6)-alkynyl, (C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, (C 1-C 6)-alkyl-O-(C 1-C 6)-alkyl, phenyl, phenyl-(C 1-C 6)-alkyl, heteroaryl, (C 1-C 6)-miscellaneous alkyl aryl, heterocyclic radical, (C 1-C 6)-alkyl heterocyclic, (C 1-C 6)-alkyl-O-heteroaryl, (C 1-C 6)-alkyl-O-heterocyclic radical, (C 1-C 6)-alkyl-NR 3-heteroaryl or (C 1-C 6)-alkyl-NR 3-heterocyclic radical, 16 groups wherein finally mentioned are selected from following group by s separately and replace: cyano group, halogen, nitro, OR 3, S (O) nr 4, N (R 3) 2, NR 3oR 3, NR 3sO 2r 4, COR 3, OCOR 3, NR 3cOR 3, CO 2r 3, CON (R 3) 2(C 1-C 4)-alkoxyl-(C 2-C 6)-alkoxy carbonyl, and wherein heterocyclic radical has n oxo base,
R 3represent hydrogen, (C 1-C 6)-alkyl, (C 2-C 6)-thiazolinyl, (C 2-C 6)-alkynyl, (C 3-C 6)-cycloalkyl or (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl,
R 4representative (C 1-C 6)-alkyl, (C 2-C 6) thiazolinyl or (C 2-C 6)-alkynyl,
R 5represent methyl or ethyl,
N represents 0,1 or 2, and
Behalf 0,1,2 or 3.
The composition of the present invention be preferably as follows, it comprises the compound of general formula (I) and its salt as weed killer herbicide (A), wherein,
A represents N or CY,
B represents N or CH,
X represents nitro, halogen, cyano group, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, (C 3-C 6)-cycloalkyl, OR 1, S (O) nr 2, (C 1-C 6)-alkyl-S (O) nr 2, (C 1-C 6)-alkyl-OR 1, (C 1-C 6)-alkyl-CON (R 1) 2, (C 1-C 6)-alkyl-SO 2n (R 1) 2, (C 1-C 6)-alkyl-NR 1cOR 1, (C 1-C 6)-alkyl-NR 1sO 2r 2, (C 1-C 6)-miscellaneous alkyl aryl, (C 1-C 6)-alkyl heterocyclic, 2 groups wherein finally mentioned are selected from following group by s separately and replace: halogen, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, S (O) n-(C 1-C 6)-alkyl, (C 1-C 6)-alkoxyl and halo-(C 1-C 6)-alkoxyl, and wherein heterocyclic radical has n oxo base,
Y represents hydrogen, nitro, halogen, cyano group, (C 1-C 6)-alkyl, (C 1-C 6)-haloalkyl, OR 1, S (O) nr 2, SO 2n (R 1) 2, N (R 1) 2, NR 1sO 2r 2, NR 1cOR 1, (C 1-C 6)-alkyl-S (O) nr 2, (C 1-C 6)-alkyl-OR 1, (C 1-C 6)-alkyl-CON (R 1) 2, (C 1-C 6)-alkyl-SO 2n (R 1) 2, (C 1-C 6)-alkyl-NR 1cOR 1, (C 1-C 6)-alkyl-NR 1sO 2r 2, (C 1-C 6)-alkyl phenyl, (C 1-C 6)-miscellaneous alkyl aryl, (C 1-C 6)-alkyl heterocyclic, phenyl, heteroaryl or heterocyclic radical, 6 groups wherein finally mentioned are selected from following group by s separately and replace: halogen, nitro, cyano group, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, (C 3-C 6)-cycloalkyl, S (O) n-(C 1-C 6)-alkyl, (C 1-C 6)-alkoxyl, halo-(C 1-C 6)-alkoxyl, (C 1-C 6)-alkoxyl-(C 1-C 4)-alkyl and cyanogen methyl, wherein heterocyclic radical have n oxo base,
Z represents halogen, cyano group, halo-(C 1-C 6)-alkyl, (C 3-C 6)-cycloalkyl, S (O) nr 2, 1,2,4-triazol-1-yl, or
Z can also represent hydrogen, methyl, methoxy or ethoxy, if Y is S (O) nr 2base,
W represents hydrogen, methyl, ethyl, methoxy, methoxyl group, fluorine, chlorine or S (O) ncH 3,
R represents (C 1– C 8)-alkyl, halo-(C 1– C 8)-alkyl, (C 2-C 8)-thiazolinyl, halo-(C 2-C 8)-thiazolinyl, (C 2-C 8)-alkynyl, halo-(C 2-C 8)-alkynyl, wherein above-mentioned 6 groups are selected from following group by s separately and replace: cyano group, S (O) n-(C 1-C 6)-alkyl, (C 1-C 6)-alkoxyl, halo-(C 1-C 6)-alkoxyl, COR 3, COOR 3, OCOR 3, NR 3cOR 3, NR 3sO 2r 4, (C 3-C 6)-cycloalkyl, heteroaryl, heterocyclic radical and phenyl, 3 groups wherein finally mentioned are selected from following group by s separately and replace: methyl, ethyl, methoxyl group, trifluoromethyl, cyano group and halogen, and wherein heterocyclic radical has 0 to 2 oxo group, or
The phenyl that R representative is selected from following group replaces by s: halogen, nitro, cyano group, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, (C 3-C 6)-cycloalkyl, S (O) n-(C 1-C 6)-alkyl, (C 1-C 6)-alkoxyl, halo-(C 1-C 6)-alkoxyl, (C 1-C 6)-alkoxyl-(C 1-C 4)-alkyl,
R 1represent hydrogen, (C 1-C 6)-alkyl, (C 2-C 6)-thiazolinyl, (C 2-C 6)-alkynyl, (C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, (C 1-C 6)-alkyl-O-(C 1-C 6)-alkyl, phenyl, phenyl-(C 1-C 6)-alkyl, heteroaryl, (C 1-C 6)-miscellaneous alkyl aryl, heterocyclic radical, (C 1-C 6)-alkyl heterocyclic, (C 1-C 6)-alkyl-O-heteroaryl, (C 1-C 6)-alkyl-O-heterocyclic radical, (C 1-C 6)-alkyl-NR 3-heteroaryl or (C 1-C 6)-alkyl-NR 3-heterocyclic radical, 16 groups wherein finally mentioned are selected from following group by s separately and replace: cyano group, halogen, nitro, OR 3, S (O) nr 4, N (R 3) 2, NR 3oR 3, COR 3, OCOR 3, NR 3cOR 3, NR 3sO 2r 4, CO 2r 3, CON (R 3) 2(C 1-C 4)-alkoxyl-(C 2-C 6)-alkoxy carbonyl, and wherein heterocyclic radical has n oxo base,
R 2representative (C 1-C 6)-alkyl, (C 3-C 6)-cycloalkyl or (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, is selected from following group by s separately and replaces: halogen and OR 3,
R 3represent hydrogen or (C 1-C 6)-alkyl,
R 4representative (C 1-C 6)-alkyl,
R 5represent methyl or ethyl,
N represents 0,1 or 2, and
Behalf 0,1,2 or 3.
Particularly preferably following composition of the present invention, it comprises the compound of general formula (I) and its salt as weed killer herbicide (A), wherein,
A represents CY,
B represents N,
X represents chlorine, methyl, ethyl, propyl group, cyclopropyl, methoxyl group or SO 2cH 3,
Y represents hydrogen, CH 2oCH 3, CH 2oCH 2cF 3,cH 2oC 2h 4oCH 3, 4,5-dihydro-1,2-oxazole-3-bases, 5-methoxy-4,5-dihydro-1,2-oxazole-3-base, pyrazol-1-yl, OMe, OEt, OPr, OiBu, OCH 2cPr, OC 2h 4oCH 3, SO 2cH 3, S (O) CH 3or SCH 3, SO 2et, S (O) Et or SEt,
Z represents trifluoromethyl, SO 2cH 3, SO 2et, chlorine or bromine,
W represents hydrogen, and
R represents methyl, ethyl, propyl group or methoxy ethyl.
Very particularly preferably following composition of the present invention, it comprises the compound of general formula (I) and its salt as weed killer herbicide (A), wherein,
A represents CY,
B represents N,
X represents chlorine,
Y represents SO 2cH 3, SOCH 3or SO 2et,
Z represents hydrogen or methyl,
W represents hydrogen, and
R represents methyl.
Also very particularly preferably following composition of the present invention, it comprises the compound of general formula (I) and its salt as weed killer herbicide (A), wherein,
A represents CY,
B represents N,
X represents chlorine or bromine,
Y represents hydrogen, methyl, SO 2cH 3or SCH 3,
Z represents hydrogen, SO 2cH 3or SCH 3,
W represents methyl, and
R represents methyl or ethyl.
Also very particularly preferably following composition of the present invention, it comprises the compound of general formula (I) and its salt as weed killer herbicide (A), wherein,
A represents CY,
B represents CH,
X represents chlorine or methyl,
Y represents 4,5-dihydro-1,2-oxazole-3-base, pyrazol-1-yl, OC 2h 4oCH 3or SO 2cH 3,
Z represents trifluoromethyl, SO 2cH 3, SO 2et or chlorine,
W represents hydrogen, and
R represents methyl.
Also very particularly preferably following composition of the present invention, it comprises the compound of general formula (I) and its salt as weed killer herbicide (A), wherein,
A represents N,
B represents N,
X represents chlorine, bromine, SO 2cH 3, methoxy, OCH 2cPr, OC 2h 4oCH 3or methyl,
Z represents trifluoromethyl,
W represents hydrogen, and
R represents methyl or ethyl.
Formula (I) and below all formulas in, the alkyl had more than two carbon atoms can be straight or branched.Alkyl group is that such as methyl, ethyl, n-pro-pyl or isopropyl, normal-butyl, isobutyl group, the tert-butyl group or 2-butyl, amyl group, hexyl are as n-hexyl, isohesyl and 1,3-dimethylbutyl.Similarly, thiazolinyl typical example is as pi-allyl, 1-methyl-prop-2-alkene-1-base, 2-methyl-prop-2-alkene-1-base, but-2-ene-1-base, fourth-3-alkene-1-base, 1-methyl fourth-3-alkene-1-base and 1-methyl but-2-ene-1-base.Alkynyl typical example is as propargyl, fourth-2-alkynes-1-base, fourth-3-alkynes-1-base, 1-methyl fourth-3-alkynes-1-base.Multiple bond can be positioned at the optional position of unsaturated group in each case.Cycloalkyl typical example as having the saturated carbon ring system of 3 to 6 carbon atoms, such as cyclopropane, cyclobutane, pentamethylene or cyclohexane.Similarly, cycloalkenyl group representative has the monocyclic alkenyl group of 3 to 6 carbocyclic unit, and such as cyclopropanyl, cyclobutane base, cyclopentenyl, cyclohexenyl group, wherein double bond can be positioned at optional position.
Halogen represents fluorine, chlorine, bromine and iodine.
Saturated, the semi-saturation of heterocyclic radical representative containing 3 to 6 annular atomses or complete undersaturated cyclic group, 1 to 4 atom of heterocyclic radical is selected from oxygen, nitrogen and sulphur, and it can additionally be condensed by benzo ring.Such as heterocyclic radical represents piperidyl, pyrrolidinyl, tetrahydrofuran base, dihydrofuran base and oxetanyl.
The aromatics cyclic group of heteroaryl representative containing 3 to 6 annular atomses, 1 to 4 atom in heteroaryl is selected from oxygen, nitrogen and sulphur, and it can condense additionally by benzo ring.Heteroaryl represents, such as benzimidazolyl-2 radicals-Ji, furyl, imidazole radicals, isoxazolyl, isothiazolyl, oxazolyl, pyrazinyl, pyrimidine radicals, pyridazinyl, pyridine radicals, benzoisoxazole base, thiazolyl, pyrrole radicals, pyrazolyl, thienyl, 1, 2, 3-oxadiazolyl, 1, 2, 4-oxadiazolyl, 1, 2, 5-oxadiazolyl, 1, 3, 4-oxadiazolyl, 1, 2, 4-triazolyl, 1, 2, 3-triazolyl, 1, 2, 5-triazolyl, 1, 3, 4-triazolyl, 1, 2, 4-triazolyl, 1, 2, 4-thiadiazolyl group, 1, 3, 4-thiadiazolyl group, 1, 2, 3-thiadiazolyl group, 1, 2, 5-thiadiazolyl group, 2H-1, 2, 3, 4-tetrazole radical, 1H-1, 2, 3, 4-tetrazole radical, 1, 2, 3, 4-oxatriazole, 1, 2, 3, 5-oxatriazole, 1, 2, 3, 4-thiatriazole base and 1, 2, 3, 5-thiatriazole base.
When group (group) is polysubstituted by group (radical), this refer to this group by one or more identical or different mentioned by those groups replace.This is applicable to the member ring systems formed by various atom or element similarly.Meanwhile, the scope of claim should get rid of these those compounds that are well known by persons skilled in the art, chemically unstable at the standard conditions.
The present invention also provides following herbicidal composition, and it comprises or stereoisomer by the chemical formula of B component included by included by formula (I) and composition thereof.The compound of the chemical formula of these formulas (I) or B component comprises carbon atom or the sulfoxide of such as one or more Asymmetrical substitute.The possible stereoisomer such as enantiomter or the diastereoisomer that are defined by its specific 3D shape are all stereoisomers included by formula (I) or component (B) and (C); Especially also for racemic mixture and-wherein may be enantiomter-enantiomter and especially respective biologically active enantiomter.Independent stereoisomer can be obtained by the method for routine or be obtained by the Stereoselective reaction being combined the pure raw material of spatial chemistry or auxiliary agent from the mixture of stereoisomer.
Example as the compound of weed killer herbicide (A) is listed in the following table:
In these tables, the abbreviation of use means:
Et=ethyl Me=methyl n-Pr=n-pro-pyl i-Pr=isopropyl
C-Pr=cyclopropyl Ph=phenyl Ac=acetyl group i-Bu=isobutyl group
Table 1: the compound of general formula (I), wherein A represents CY and B represents N and W represents hydrogen
Embodiment is numbered R X Y Z
A1-1 Me Cl H SO 2Me
A1-2 Me SO 2Me H CF 3
A1-3 Me Me SMe CF 3
A1-4 MeOC 2H 4 Me SMe CF 3
A1-5 Me Me SOMe CF 3
A1-6 Et Me SOMe CF 3
A1-7 Me Me SO 2Me CF 3
A1-8 Et Me SO 2Me CF 3
A1-9 Pr Me SO 2Me CF 3
A1-10 MeOC 2H 4 Me SO 2Me CF 3
A1-11 Me Me SEt CF 3
A1-12 Et Me SEt CF 3
A1-13 Me Me SOEt CF 3
A1-14 Et Me SOEt CF 3
A1-15 Me Me SO 2Et CF 3
A1-16 Et Me SO 2Et CF 3
A1-17 Me Me SO 2Me Cl
A1-18 Me Me SEt Cl
A1-19 Me Me SOEt Cl
Embodiment is numbered R X Y Z
A1-20 Et Me SOEt Cl
A1-21 Me Me SO 2Et Cl
A1-22 Me Me SMe Br
A1-23 Me Me SEt Br
A1-24 Me Me 4,5-dihydro-1,2-oxazole-3-base SO 2Me
A1-25 Et Me 4,5-dihydro-1,2-oxazole-3-base SO 2Me
A1-26 Me Me Pyrazol-1-yl SO 2Me
A1-27 Et Me Pyrazol-1-yl SO 2Me
A1-28 Me Me SMe SO 2Me
A1-29 Me Me SO 2Me SO 2Me
A1-30 Et Me SO 2Me SO 2Me
A1-31 Me Me SO 2Et SO 2Me
A1-32 Et Me SO 2Et SO 2Me
A1-33 Me Et SMe CF 3
A1-34 Me Et SOMe CF 3
A1-35 Me Et SO 2Me CF 3
A1-36 Me Et SMe Cl
A1-37 Et Et SMe Cl
A1-38 Me Et SOMe Cl
A1-39 Me Et SMe Br
A1-40 Me Et SO 2Me Br
A1-41 Me Pr SMe CF 3
A1-42 Me Pr SOMe CF 3
A1-43 Me c-Pr SMe CF 3
A1-44 Me OMe SMe CF 3
A1-45 Me OMe SOMe CF 3
A1-46 Me OMe SO 2Me CF 3
A1-47 Me OMe SEt CF 3
A1-48 Me Cl SMe H
A1-49 Me Cl SO 2Me Me
A1-50 Me Cl SO 2Et Me
A1-51 Me Cl SO 2Me CF 3
A1-52 Me Cl OC 2H 4OMe Cl
A1-53 Me Cl SMe Cl
A1-54 Et Cl SMe Cl
A1-55 Me Cl SOMe Cl
A1-56 Et Cl SOMe Cl
A1-57 Me Cl SO 2Me Cl
A1-58 Et Cl SO 2Me Cl
A1-59 Me Cl SO 2Et Cl
A1-60 Me Cl CH 2OMe SO 2Me
A1-61 Me Cl CH 2OCH 2CF 3 SO 2Me
Embodiment is numbered R X Y Z
A1-62 Et Cl CH 2OCH 2CF 3 SO 2Me
A1-63 Me Cl CH 2OC 2H 4OMe SO 2Me
A1-64 Me Cl 4,5-dihydro-1,2-oxazole-3-base SO 2Me
A1-65 Me Cl 4,5-dihydro-1,2-oxazole-3-base SO 2Et
A1-66 Me Cl 5-methoxy-4,5-dihydro-1,2-oxazole-3-base SO 2Et
A1-67 Me Cl OMe SO 2Me
A1-68 Me Cl OMe SO 2Et
A1-69 Me Cl OEt SO 2Me
A1-70 Me Cl OEt SO 2Et
A1-71 Me Cl OPr SO 2Me
A1-72 Me Cl OPr SO 2Et
A1-73 Me Cl Oi-Bu SO 2Me
A1-74 Me Cl OCH 2c-Pr SO 2Me
A1-75 Me Cl OCH 2c-Pr SO 2Et
A1-76 Me Cl OC 2H 4OMe SO 2Me
A1-77 Me Cl SMe SO 2Me
A1-78 Me Me OMe SO 2Me
A1-79 Et OMe SMe CHF 2
A1-80 Me OMe SO 2Me CHF 2
A1-81 Me OMe SMe CHF 2
A1-82 Me OMe SOMe CHF 2
A1-83 Me Cl O(CH 2) 3OMe SO 2Et
A1-84 Et Cl SOMe Me
A1-85 Me Cl SMe CF 3
Table 2: the compound of general formula (I), wherein A represents CY and B represents CH and W represents hydrogen
Embodiment is numbered R X Y Z
A2-1 Me Me SO 2Me CF 3
A2-2 Me Me 4,5-dihydro-1,2-oxazole-3-base SO 2Me
A2-3 Me Me Pyrazol-1-yl SO 2Me
A2-4 Me Me SO 2Me SO 2Me
Embodiment is numbered R X Y Z
A2-5 Me Cl SO 2Me Cl
A2-6 Me Cl 4,5-dihydro-1,2-oxazole-3-base SO 2Me
A2-7 Me Cl 4,5-dihydro-1,2-oxazole-3-base SO 2Et
A2-8 Me Cl OC 2H 4OMe SO 2Me
A2-9 Me Cl SO 2Me CF 3
A2-10 Me Cl SO 2Et CF 3
Table 3: the compound of general formula (I), wherein A represents CY and B represents N
Embodiment is numbered R X Y Z W
A3-1 Me Cl H SMe Me
A3-2 Me Cl SMe H Me
A3-3 Me Cl SO 2Me H Me
A3-4 Et Cl SO 2Me H Me
A3-5 Me Cl Me SMe Me
A3-6 Et Cl Me SO 2Me Me
A3-7 Me Br SO 2Me H Me
Table 4: the compound of general formula (I), wherein A represents N and B represents N and W represents hydrogen
Embodiment is numbered R X Z
A4-1 Me Me CF 3
A4-2 Me CH 2OMe CF 3
A4-3 Et CH 2OMe CF 3
A4-4 Me CH 2OC 2H 4OMe CF 3
A4-5 Et CH 2OC 2H 4OMe CF 3
A4-6 Me CH 2OCH 2c-Pr CF 3
A4-7 Me Cl CF 3
A4-8 Me Br CF 3
A4-9 Me SO 2Me CF 3
Preferred B1 class weed killer herbicide is clethodim (clethodim), sethoxydim (sethoxydim), benzofenap (tepraloxydim), mesotrione (mesotrione), sulphur humulone (sulcotrione), special furan triketone (tefuryltrione), ring sulphur ketone (tembotrione), fluorine benzofenap (bicyclopyrone), azoles quinoline grass ester (pinoxaden), tralkoxydim (tralkoxydim).
The weed killer herbicide of particularly preferred B1 class is clethodim (clethodim), sulphur humulone (sulcotrione), special furan triketone (tefuryltrione), ring sulphur ketone (tembotrione), fluorine benzofenap (bicyclopyrone), azoles quinoline grass ester (pinoxaden).
The weed killer herbicide of preferred B2 class is dimethenamid (dimethenamid), cresols fenacet-P (dimethenamide-P), napropamide (napropamide), pethoxamid (pethoxamid), propyzamide (propyzamide), diflufenican (diflufenican), flufenacet (flufenacet), mefenacet (mefenacet), fluorine metazachlor (picolinafen), Stam F-34 (propanil), Acetochlor (acetochlor), alachlor (alachlor), butachlor (butachlor), metazachlor (metazachlor), isopropyl methoxalamine (metolachlor), S-isopropyl methoxalamine (S-metolachlor), third careless amine (pretilachlor), P DimethenamidP (thenylchlor), sulphur grass spirit (asulam), carbetamide (carbetamide), desmedipham (desmedipham), phenmedipham (phenmedipham), esprocarb (esprocarb), molinate (molinate), prosulfocarb (prosulfocarb), benthiocarb (thiobencarb), amidosulfuron (amidosulfuron), chlorimuronethyl (chlorimuron-ethyl), AC322140 (cyclosulfamuron), ethoxysulfuron (ethoxysulfuron), flupyrsulfuron-methyl-sodium (flupyrsulfuron-methyl-sodium), formyl ammonia sulphur grand (foramsulfuron), iodosulfuron methyl sodium (iodosulfuron-methyl-sodium), mesosulfuronmethyl (mesosulfuron-methyl), nicosulfuron (nicosulfuron), phonetic aniline sulphur grand (orthosulfamuron), prosulfuron (prosulfuron), pyrazosulfuron (pyrazosulfuron-ethyl), rimsulfuron (rimsulfuron), trifloxysulfuron (sodium) (trifloxysulfuron (sodium)), flucarbazonesodium (flucarbazone-sodium), procarbazone (propoxycarbazone-sodium), thiophene ketone sulphur grand (thiencarbazone-methyl), florasulam (florasulam), metosulam (metosulam), penoxsuam (penoxsulam), metsulfuron-methyl (metsulfuron-methyl), Sulfosulfuron (sulfosulfuron), thifensulfuronmethyl methyl esters (thifensulfuron-methyl), tribenuron-methyl methyl esters (tribenuron-methyl), tritosulfuron (tritosulfuron), pyroxsulam (pyroxsulam).
The weed killer herbicide of particularly preferred B2 class is cresols fenacet-P (dimethenamide-P), napropamide (napropamide), diflufenican (diflufenican), flufenacet (flufenacet), mefenacet (mefenacet), Acetochlor (acetochlor), metazachlor (metazachlor), S-isopropyl methoxalamine (S-metolachlor), sulphur grass spirit (asulam), desmedipham (desmedipham), phenmedipham (phenmedipham), molinate (molinate), prosulfocarb (prosulfocarb), amidosulfuron (amidosulfuron), ethoxysulfuron (ethoxysulfuron), formyl ammonia sulphur grand (foramsulfuron), iodosulfuron methyl sodium (iodosulfuron-methyl-sodium), mesosulfuronmethyl (mesosulfuron-methyl), flucarbazonesodium (flucarbazone-sodium)), procarbazone (propoxycarbazone-sodium), thiophene ketone sulphur grand (thiencarbazone-methyl), florasulam (florasulam), metosulam (metosulam), metsulfuron-methyl (metsulfuron-methyl), Sulfosulfuron (sulfosulfuron), thifensulfuronmethyl methyl esters (thifensulfuron-methyl), tribenuron-methyl methyl esters (tribenuron-methyl), tritosulfuron (tritosulfuron), pyroxsulam (pyroxsulam).
The weed killer herbicide of preferred B3 class is Brominal (bromoxynil) and ioxynil (ioxynil).
The weed killer herbicide of preferred B4 class is benzofenap (benzofenap), benzene pyrazoles humulone (topramezone), sulphonyl grass pyrazoles (pyrasulfotole), isoxazole humulone (isoxaflutole), imazamox (imazamox), imazapyr (imazapyr), oxadiargyl (oxadiargyl), oxadiazon (oxadiazon), amicarbazone (amicarbazone), carfentrazone (carfentrazone-ethyl), sulfentrazone (sulfentrazone), uniconazole P (uniconazole), cafenstrole (cafenstrole), fentrazamide (fentrazamide), 3-(the chloro-5-{ of 3-[1-methyl-3-(trifluoromethyl)-1H-pyrazoles-5-base] oxygen base } phenoxy group)-1-methyl-5-(trifluoromethyl)-1H-pyrazoles, 3-(the iodo-5-{ of 3-[1-methyl-3-(trifluoromethyl)-1H-pyrazoles-5-base] oxygen base } phenoxy group)-1-methyl-5-(trifluoromethyl)-1H-pyrazoles, 1-ethyl-3-(the fluoro-5-{ of 3-[1-methyl-3-(trifluoromethyl)-1H-pyrazoles-5-base] oxygen base } phenoxy group)-5-(trifluoromethyl)-1H-pyrazoles, pyrrole grass ether (pyraflufen-ethyl),
The weed killer herbicide of particularly preferred B4 class is sulphonyl grass pyrazoles (pyrasulfotole), isoxazole humulone (isoxaflutole), oxadiargyl (oxadiargyl), oxadiazon (oxadiazon), amicarbazone (amicarbazone), fentrazamide (fentrazamide), 3-(the chloro-5-{ of 3-[1-methyl-3-(trifluoromethyl)-1H-pyrazoles-5-base] oxygen base } phenoxy group)-1-methyl-5-(trifluoromethyl)-1H-pyrazoles, 3-(the iodo-5-{ of 3-[1-methyl-3-(trifluoromethyl)-1H-pyrazoles-5-base] oxygen base } phenoxy group)-1-methyl-5-(trifluoromethyl)-1H-pyrazoles, 1-ethyl-3-(the fluoro-5-{ of 3-[1-methyl-3-(trifluoromethyl)-1H-pyrazoles-5-base] oxygen base } phenoxy group)-5-(trifluoromethyl)-1H-pyrazoles, pyrrole grass ether (pyraflufen-ethyl), imazamox (imazamox).
The weed killer herbicide of preferred B5 class is chlorine Fampridine acid (aminopyralid), benazolin (benazolin), benfuresate (benfuresate), bentazone (bentazone), cinidon-ethyl (cinidon-ethyl), clomazone (clomazone), diquat (diquat dibromide), ethofumesate (ethofumesate), Flumiclorac pentyl (flumiclorac-pentyl), flumioxazin (flumioxazin), flurtamone (flurtamone), oxaziclomefone (oxaziclomefone), pendimethalin (pendimethalin), pyridate (pyridate) and trefanocide (trifluralin).
The weed killer herbicide of particularly preferred B5 class is chlorine Fampridine acid (aminopyralid), benfuresate (benfuresate), ethofumesate (ethofumesate), (flurtamone) is with oxaziclomefone (oxaziclomefone) for flurtamone.
The weed killer herbicide of preferred B6 class is dicamba (dicamba), clopyralid (clopyralid), fluroxypyr (fluroxypyr), picloram (picloram), trichlopyr (triclopyr), dichloro quinolinic acid (quinclorac).
The weed killer herbicide of preferred B7 class is anilofos (anilofos), Glufosinate (glufosinate-ammonium) and L-Glufosinate (L-glufosinate-ammonium), glyphosate (glyphosate), glyphosate isopropyl amine salt (glyphosate-isopropyl-ammonium), glyphosate (glyphosate-ammonium), sulphosate (glyphosate-trimesium) (=sulfosate), glyphosate two ammonium (glyphosate-diammonium), glyphosate potassium (glyphosate-potassium).
The weed killer herbicide of preferred B8 class is acifluorfen (acifluorfen-sodium), aclonifen (aclonifen), fluoroglycofen-ethyl (fluoroglycofen-ethyl), Oxyfluorfen (oxyfluorfen), bifenox (bifenox), high by 2, 4-drips propionic acid (dichlorprop-P), high 2-first-4-chloropropionic acid (mecoprop-P), 2, 4-D, MCPA, clodinafop-propargyl (clodinafop-propargyl), cyhalofop-butyl (cyhalofop-butyl), diclofop-methyl (diclofop-methyl), essence diclofop-methyl (diclofop-P-methyl), Gao oxazole diclofop-methyl (fenoxaprop-P-ethyl), efficient fluazifop butyl ester (fluazifop-P-butyl), quizalafop-P.
The weed killer herbicide of particularly preferred B8 class be aclonifen (aclonifen), diclofop-methyl (diclofop-methyl), high diclofop-methyl (diclofop-P-methyl), Gao oxazole diclofop-methyl (fenoxaprop-P-ethyl), MCPA, 2,4-D, clodinafop-ethyl.
The weed killer herbicide of particularly preferred B9 class is two careless ether (sodium) (bispyribac (sodium)), pyriftalid (pyriftalid), bromacil (bromacil), lenacil (lenacil), the fluoro-5-of the chloro-4-of 2-[3-methyl-2; 6-dioxo-4-(trifluoromethyl)-3,6-dihydro-pyrimidin-1 (2H)-Ji]-N-[methyl (1-Methylethyl)-sulfamoyl] benzamide.
The weed killer herbicide of preferred B9 class is two careless ether (sodium) (bispyribac (sodium)), bromacils (bromacil).
The weed killer herbicide of preferred B10 class is cumyluron (cumyluron), daimuron (daimuron), diuron (diuron), isoproturon (isoproturon), diflufenzopyr (diflufenzopyr).
The weed killer herbicide of preferred B11 class is atrazine (atrazine), Simanex (simazine), Garagard (terbuthylazine), ametryn (ametryn), terbutryn (terbutryn), metamitron (metamitron), piperazine humulone (metribuzin).
The weed killer herbicide of particularly preferred B11 class is metamitron (metamitron), piperazine humulone (metribuzin), Garagard (terbuthylazine).
In herbicidal composition of the present invention, the rate of application of the weed killer herbicide of general formula (I) (component A) is generally the active component (a.i.) of per hectare 1 to 500g, preferably a.i./the hectare of 2 to 300g, the particularly preferably a.i./hectare of 3 to 200g.The rate of application of the weed killer herbicide of B component is generally the active component of per hectare 1 to 5000g, preferably a.i./the hectare of 2 to 3000g, particularly preferably a.i./the hectare of 3 to 2000g.The rate of application of the safener of component C is generally the active component of per hectare 1 to 500g, preferably a.i./the hectare of 2 to 400g, particularly preferably a.i./the hectare of 3 to 300g.
By using herbicidal composition of the present invention, wide spectrum noxious plant such as annual or perennial unifacial leaf or broadleaf weed and undesired crop plants can be prevented and treated by the method before emerging and after emerging.Herbicidal composition of the present invention is particularly suitable for crop such as grain, corn, rice, soybean, rape, beet, cotton, sugarcane, and also for perennial crop, forest plantation (plantations) and non-crop soil.They are similarly highly suitable for corn, cereal, beet, rice, the genetically modified crops of cotton and soybean (Glycine max) (such as RR soybean or LL soybean) and their crossbreed, Phaseolus (Phaseolus), Pisum (Pisum), Vicia (Vicia) and Arachis (Arachis) or derive from the vegetable crop such as potato of each Plants group (botanical groups), leek, wild cabbage, carrot, tomato, onion and perennial crop and plantation crops such as a kind of fruit, such as apple, pear, etc. and drupe, berry, grape, para-caoutchouc, banana, sugarcane, coffee, tea, oranges and tangerines, nut planting plants, lawn, palm crops and forestry crop.For the purposes of herbicide-safener combination of the present invention (A)+(B), these crops are preferred equally, are particularly preferably applied in cereal (such as wheat, barley, rye, oat), rice, corn, broomcorn millet/Chinese sorghum, beet, sugarcane, sunflower, rape and cotton.Herbicide-safener combination (A)+(B) also can be used for resistance or non-resistance sudden change crop and resistance or non-resistance genetically modified crops, preferred corn, rice, cereal, cotton, beet and soybean, such as resistance to imidazolidinone weedicide, atrazine, Glufosinate, glyphosate, 2, the weed killer herbicide of 4D, dicamba and hydroxyphenylpyruvic acid dioxygenase inhibitor, such as those crops of sulphur humulone, mesotrione, ring sulphur ketone, special furan triketone, benzobicylon, fluorine benzofenap (bicyclopyrone) and ketospirdox.
In the sense of the present invention, herbicidally effective amount is the amount of one or more weed killer herbicides plant growth to adverse effect." detoxicating activity amount " means the amount of one or more safeners being suitable for the poisonous effect reducing reactive compound in the crop production compositions (such as weed killer herbicide) on crop plants in the context of the present invention.
According to their character, the often kind of safener (C) be present in herbicidal composition of the present invention also can be used for the pretreatment (such as dress seed) of crop plants seed or prior to seeding safener is incorporated into furrow or being used together with weed killer herbicide by safener before plant emergence or after emerging.Process before emerging comprises the process (comprising any water that cultural area exists, such as, when being applied to rice) of cultural area before planting, and has sowed seed but also do not had the process of the cultural area before grown vegetal cover.Preferably safener is used together with weed killer herbicide.For this reason, bucket can be used to mix or namely use preparation.
In a preferred embodiment,---be optionally combined with other active agrochemical compositions---with described safener (B) and pretreatment is carried out to seed (the germination position of such as grain, seed or nourish and generate organ such as stem tuber or bud) or seedling.For the pretreatment of seed, described reactive compound such as can be applied to seed by seed dressing, maybe described reactive compound and described seed can be joined in water or other solvents, and described reactive compound can such as absorb by the absorption in dipping process or diffusion or by swelling or vernalization.For the process of seedling, such as, by spraying, dipping or pouring, shoot and described safener---optionally in conjunction with other active agrochemical compositions---are contacted and also transplant subsequently and optionally use weed killer herbicide (A) to carry out post processing.
Seed and seedling can process with safener (C) separately or be incorporated into row relax with safener (C) and other active agrochemical compound (such as fungicide, insecticide or plant hardening agent, fertilizer or swelling and promoter of emerging).After pretreatment is used, subsequently can by the weed killer herbicide of described safener at one or more formulas (I)---also can in conjunction with other known weed killer herbicides---again use before, afterwards or together.The pretreatment of seed or seedling can realize the raising to safener long-acting.Therefore, the present invention further provides a kind of method for preventing and treating the undesired plant in plant crop, it is characterized in that by the component of herbicidal composition of the present invention (A), (B) and optionally (C) be applied to described plant (such as noxious plant respectively or jointly, as monocotyledon weed or broadleaf weed or undesired crop plants), seed (such as grain, seed or organ of nourishing and generating, the germination position as stem tuber or bud) or plant growth region (such as cultural area).One or more safeners (C) can be applied to described plant, seed or plant growth region (such as cultural area) before the weed killer herbicide of general formula (I) (A) and weed killer herbicide (B), afterwards or with it simultaneously.In a preferred embodiment, described safener (C) is for the process of seed.Undesired plant is interpreted as meaning to grow all plants in the place not wanting them to grow.These can be such as noxious plant (such as unifacial leaf or broadleaf weed or undesired crop plants), comprise those plants such as some weeding active compound (as glyphosate, atrazine, Glufosinate or imidazolidinone weedicide) to resistance.Carrying out such as with the classification of subordinate to monocotyledon weed, is such as Echinochloa (Echinochloa), setaria (Setaria), Panicum (Panicum), knotgrass (Digitaria), ladder forage spp (Phleum), Poa L. (Poa), Festuca (Festuca), yard grass belongs to (Eleusine), Brachiaria (Brachiaria), Lolium (Lolium), Brome (Bromus), Avena (Avena), Cyperus (Cyperus), sorghum (Sorghum), Agropyron (Agropyron), Cynodon (Cynodon), Monochoria (Monochoria), genus fimbristylis (Fimbristyslis), Sagittaria (Sagittaria), water chestnut belongs to together (Eleocharis), Scirpus (Scirpus), Paspalum (Paspalum), ischaemum (Ischaemum), cusp Pittosporum (Sphenoclea), talon eria (Dactyloctenium), Agrostis (Agrostis), amur foxtail belongs to (Alopecurus), Apera belongs to.Carry out the classification with subordinate to broadleaf weed, sinapsis alba belongs to (Sinapis), separate row Vegetable spp (Lepidium), galium (Galium), Stellaria (Stellaria), Matricaria (Matricaria), Anthemis (Anthemis), ox achyranthes chrysanthemum spp (Galinsoga), Chenopodium (Chenpodium), Urtica (Urtica), Senecio (Senecio), Amaranthus (Amaranthus), Portulaca (Portulaca), Xanthium (Xanthium), japanese bearbind belongs to (Convolvulus), Ipomoea (Ipomoea), Polygonum (Polygonum), Daubentonia (Sesbania), Ambrosia (Ambrosia), Cirsium (Cirsium), bristlethistle (Carduus), sonchus (Sonchus), Solanum (Solanum), Han Lepidium (Rorippa), joint joint Lepidium (Rotala), Vandellia (Lindernia), lamium (Lamium), Veronica (Veronica), abutilon (Abutilon), thorn Rumex (Emex), Datura (Datura), Viola (Viola), weasel hemp nettle belongs to (Galeopsis), papaver (Papaver), bachelor's-button (Centaurea), Clover (Trifolium), Ranunculus (Ranunculus), Dandelion (Taraxacum), Euphorbia (Euphorbia).
Present invention also offers herbicidal composition of the present invention for preferred purposes of preventing and treating undesired plant in plant crop.
Herbicidal composition of the present invention is prepared by known method, if such as with the mix preparation of each component with other reactive compounds suitable, additive and/or conventional formulation auxiliaries, then use after its in a usual manner dilute with water, or by prepare respectively or each component that part is prepared respectively and the so-called bucket that water dilutes altogether mix thing.Can also separate administration prepare respectively or each component of preparing respectively of part.Also such as can use each component or herbicidal composition (sequential application) with many parts, such as, go out preemergence application, then carrying out postemergence application, or going out postemergence application in early days, then carry out mid-term or the later stage goes out postemergence application.Preferably jointly use or reactive compound in each bond of sequential application.Herbicidal composition of the present invention also can be used for preventing and treating the noxious plant in known plants crop or gene-modified plant crop still leaved for development.
Usually, genetically modified plants with particularly advantageous character for feature, the resistance of---particularly some weed killer herbicide---such as to some insecticide, to plant disease or the resistance causing plant disease organism (such as some insect or microorganism are as fungi, bacterium or virus).Other concrete properties relate to, such as, and the quantity of harvested material, quality, depot, composition and concrete composition.Such as, known there is the content of starch of raising or the starch quality of change genetically modified plants or harvested material in there are the genetically modified plants of different fatty acid composition.Other concrete properties can be tolerance to abiotic stress factor such as heat, low temperature, arid, salt and ultraviolet radiation or resistance.
Preferably use herbicidal composition of the present invention useful plant and having in the genetically modified crops of Important Economic value of ornamental plants, described crop is cereal (as wheat, barley, rye, oat), broomcorn millet/Chinese sorghum, rice, cassava and corn such as, or beet, cotton, soybean, rape, potato, tomato, pea and other vegetables crop.
The conventional method that preparation has the new plant improving characteristic compared with existing plant comprises, and such as conventional breeding methods and mutant produce method.Or, can by recombination method preparation have improve characteristic new plant (see, such as EP-A-0221044, EP-A-0131624).Such as in multiple case, following situation has been described :-to crop plants carry out genetic modification with improved plant in the starch (such as WO 92/011376, WO 92/014827, WO 91/019806) that synthesizes,
-to some Glufosinate class weed killer herbicide (see such as, EP-A-0242236, EP-A-242246) or glyphosate-class herbicides (WO 92/00377) or sulfonylurea herbicide (EP-A-0257993, US-A-5013659) there is the transgenic crop plant of resistance
-thuringiensis bacillus toxin (Bt toxin) can be produced thus make plant have the transgenic crop plant of resistance to some insect, such as cotton (EP-A-0142924, EP-A-0193259),-have change fatty acid composition transgenic crop plant (WO 91/13972)
-there is the genetic modification crop plants of new plant component or secondary metabolite (secondary metabolites), described new plant component or secondary metabolite are the novel plant antitoxin (phytoalexins) (EPA 309862, EPA0464461) of the disease resistance such as producing enhancing
-there is the genetically modified plant of the photorespiration of minimizing, it has high yield and higher stress tolerance (EPA 0305398), the transgenic crop plant (" molecule farm (molecular pharming) ") of the important protein of-generation pharmacy or diagnosis aspect
-the transgenic crop plant that is feature with higher yield or better quality,
-the transgenic crop plant that is feature with the combination of such as above-mentioned new capability (" gene stacking ").
Many molecular biotechnologies that can be used for preparing the new transgenic plant with improvement character are known in principle; See, such as I.Potrykus and G.Spangenberg (volume) Gene Transfer to Plants, Springer Lab Manual (1995), Springer Verlag Berlin, or Christou, " Trends in Plant Science " 1 (1996) 423-431 Heidelberg..
For carrying out this type of reorganization operation, can will can produce sudden change or introduce plasmid by the nucleic acid molecules that recombinant DNA sequence generation sequence changes.By standard method, can such as carry out base replacement, remove partial sequence or add sequence that is natural or synthesis.In order to be connected to each other by DNA fragmentation, linker (adapter) or attachment (linker) can be added in fragment; For example, see people such as Sambrook, 1989, Molecular Cloning, A Laboratory Manual, the second edition, Cold Spring Harbor Laboratory Press, Cold Spring Harbor, NY; Or Winnacker " Gene und Klone " [Genes and Clones], the VCH Weinheim second edition, 1996.
Such as, the generation with the plant cell of the active gene outcome reduced can be realized by following method: by expressing the corresponding antisense RNA of at least one or the just RNA for realizing co-suppression effect, or has a ribozyme of suitable construction by the transcript of expressing at least one specificity cutting said gene product.
For this reason, first the DNA molecular of all coded sequences (comprising any flanking sequence that may exist) comprising gene outcome can be used, or use the DNA molecular only comprising partial coding sequence, wherein said partial coding sequence is sufficiently long, to produce antisense effect in cell.Can also use and there is high homology but not identical DNA sequence dna with the coded sequence of described gene outcome.When in plant, express nucleic acid divides the period of the day from 11 p.m. to 1 a.m, synthesized protein can be positioned in any compartment of plant cell.But, be realize location in specific compartment, can such as by code area with guarantee that the DNA sequence dna of locating in specific compartment is connected.This type of sequence be well known by persons skilled in the art (such as, see, people such as Braun, EMBO J.11 (1992), 3219-3227; The people such as Wolter, Proc.Natl.Acad.Sci.USA 85 (1988), 846-850; The people such as Sonnewald, Plant is (1991) J.1,95-106).Nucleic acid molecules also can be expressed in the organelle of plant cell.
Transgenic plant cells regenerates by known technology to obtain complete plant.In principle, genetically modified plants can be the plants of any plant variety, namely both can be monocotyledon and also can be dicotyledon.Therefore, by the process LAN to homology (natural) gene or gene order, check or suppress, or obtaining the genetically modified plants of character change by the expression of allos (i.e. external source) gene or gene order.
Preferably, composition of the present invention may be used in genetically modified crops, described genetically modified crops have resistance to growth regulator such as dicamba, such as, or suppress the weed killer herbicide of important phytoenzyme, acetolactate synthase (ALS), epsp synthase, glutamine synthelase (GS) or HPPA dioxygenase (HPPD) have resistance; Or to the weed killer herbicide being selected from sulfonylureas, glyphosate, Glufosinate or benzoyl isooxazole and similar reactive compound, there is resistance.When composition of the present invention is used for genetically modified crops, except can observe in other crops to except the effect of noxious plant, also often find the special effect being applied to specific genetically modified crops, such as change or the broadening especially weeds prevented and treated spectrum, improve use time spendable rate of application, with described genetically modified crops, it is had to the more excellent compatibility of the weed killer herbicide of resistance, with on the growth of transgenic crop plant and the impact of output.Therefore, the present invention also provides composition of the present invention for preventing and treating the purposes of noxious plant in transgenic crop plant.
Preferably use bond of the present invention or its salt having in the genetically modified crops that Important Economic is worth of useful plant and ornamental plant, the crop of described crop such as cereal (as wheat, barley, rye, oat), broomcorn millet/Chinese sorghum, rice, cassava and corn or sugar beet, cotton, soybean, rape, potato, tomato, pea and other vegetables.
Therefore the present invention also provide composition of the present invention for transgenic crop plant or be there is by selection breeding tolerance crop plants in prevent and treat the purposes of noxious plant.
Described weed killer herbicide (A), (B) and described safener (C) can be converted to conventional formulation together or respectively, such as by spraying, pouring, spray and the using of seed dressing, described conventional formulation is solution, emulsion, suspending agent, pulvis, foaming agent, paste, granule, aerosol, microcapsule formulations in the natural and synthetic, polymeric material of active component dipping such as.Described preparation can comprise conventional auxiliary agent and additive.These preparations are produced by known mode, such as by being mixed with filler (i.e. liquid flux, pressurized liquefied gas and/or solid carrier) by described reactive compound, optionally use surfactant (i.e. emulsifier and/or dispersant and/or blowing agent).
If use filler be water; can also use such as organic solvent as secondary solvent.Useful liquid flux is mainly: aromatic compounds, as dimethylbenzene, toluene, Fluhyzon; Chloroaromatic compounds or chlorinated aliphatic hydrocarbons, as chlorobenzene, vinyl chloride or carrene; Aliphatic hydrocarbon, as cyclohexane or paraffin, as mineral oil fractions, mineral oil and vegetable oil; Alcohols, as butanols or glycol, and ether and ester; Ketone, as acetone, methyl ethyl ketone, methyl iso-butyl ketone (MIBK) or cyclohexanone; Intensive polar solvent, as dimethyl formamide or methyl-sulfoxide; And water.Useful solid carrier comprises: the natural minerals (as kaolin, clay, talcum, chalk, quartz, attapulgite, montmorillonite or diatomite) of such as ammonium salt and pulverizing and the synthetic mineral (as finely divided silica, aluminium oxide and silicate) of pulverizing; Useful solid carrier for granule comprises: the natural rock (as calcite, marble, float stone, sepiolite and dolomite) of the also classification of such as pulverizing, and synthesis inorganic and and organic powder particles, and the particle of organic material (as sawdust, coconut husk, corncob and tobacco stem); Useful emulsifier and/or blowing agent comprise: such as nonionic and anion emulsifier are (as polyoxyethylene fatty acid ester, polyoxyethylene aliphatic alcohol ether, as alkylaryl polyglycol ether, alkylsulfonate, alkyl sulfate, arylsulphonate), and protein hydrolysate; Useful dispersant comprises: such as lignin sulfite (lignosulfite) waste liquid and methylcellulose.Tackifier can be used in described preparation; natural and the synthetic polymer (such as gum Arabic, polyvinyl alcohol and polyvinyl acetate) of such as carboxymethyl cellulose and powder, particle or latex form, and natural phospholipid (such as cephalin and lecithin) and synthetic phospholipid.Other additives can be mineral oil and vegetable oil.
Dyestuff can be used, as inorganic pigment (as iron oxide, titanium oxide and Prussian blue) and organic dyestuff (as alizarin dyes, azo dyes and metallized phthalocyanine dye); And micronutrient, such as molysite, manganese salt, boron salt, mantoquita, cobalt salt, molybdenum salt and zinc salt.Described preparation generally includes the active component of 0.1-95 % by weight, preferably 0.5-90 % by weight.
Described weed killer herbicide (A), (B) and described safener (C) can itself form or use with its dosage form mixed with other agricultural chemical activity compounds (such as known weed killer herbicide), for preventing and treating undesired plant, such as controlling weeds or prevent and treat undesired crop plants, described formulation example mixes the form of thing as can be final preparation or bucket.Also reactive compound that can be known with other mixes mutually; other known activity compounds described such as fungicide, insecticide, miticide, nematocide, bird repellent, plant nutrient agent and soil structure conditioner, and can mix mutually with additive in crop protection and formulation auxiliary agents equally.
Described weed killer herbicide (A), (B) and described safener (C) can use in a manner per se, use with its dosage form or use with the type of service by diluting preparation further, such as ready to use solution, suspension, emulsion, powder, paste and granule.Usually such as by watering, spraying, spray, broadcast sowing and use.Described reactive compound can be applied to plant, plant parts, seed or cultural area (farmland), preferably be applied to the position of seed or green plants and plant, and be optionally applied to farmland in addition.A kind of method of application is, described reactive compound is mixed thing form with bucket co-administered, is now mixed together with water in bucket by the concentrate formulation through optimization preparation of single reactive compound, and uses obtained spray liquid.
The advantage of the combination formulations of the bond of reactive compound of the present invention (A), (B) and (C) is that it is easy to use, because the amount of described component is with optimal proportion setting each other.In addition, the auxiliary agent in described preparation can optimization adjustment each other.
For using, if suitable, dilute in a usual manner with the preparation water that commercial form exists, described formulation example is as wetting powder, outstanding newborn concentrating agents, dispersant and water dispersible granular.What be applied to soil is pulvis, particle form or for sowing or the preparation of particle form of sprayable solution, usually dilutes further without other inert substances before administration.
Biological Examples:
Test condition in-greenhouse experiments
Weed seed is placed in the basin (diameter 8cm) that sandy loam is housed, and weed seed is emerged at optimum conditions.Be applied in the basin containing culture medium by the method for weed killer herbicide after emerging, sprayed volume is 300l/ hectare.Weed killer herbicide is used with the form of the form of itself and its bond.Experiment is carried out in the greenhouse under optimal growth condition.Herbicide effects is assessed by range estimation is more unprocessed and treated.To no effect, 100%=plant is completely dead for percentage implication: 0%=.According to S.R.Colby, Weeds 15 (1967) 20-22 page, percentage is used to calculate process separately and the interaction combined between process.
Acquired results sees the following form.
-experiment condition in field
Experiment is carried out out of doors, and (community is tested, every community 10m 2, repeat 2 times, spray application rate is per hectare 200-300 premium on currency).Crop and broad leaved weed/grassy weed is sowed under the field condition of routine.In addition, the ruderal plant group that same appearance is natural.With after the method for emerging use weed killer herbicide.The rate of application of weeding active compound itself or its bond is as shown in the table equally.Evaluated by more treated and undressed test mutation visual score (using the scope of 0-100%) after application.Result (mean value of all plants in each community repeats twice) is recorded in following table.
The process of seed
The seed grain of crop plants Homogeneous phase mixing rocking in the bottle of safener, described safener is the preparation of suspending agent or emulsion concentrating agents and water, with the preparation making seed grain evenly apply each safener.Then by seed grain or the plant after emerging by the method herbicide treatment before emerging or after emerging.Herein, many weed killer herbicide/safener combinations of the present invention show good compatibility to crop plants and have good activity of weeding to wide spectrum noxious plant simultaneously.
Abbreviation implication:
A.i.=active component
E c=according to the expected value (E of Colby c=A+B – AxB/100)
Difference (%) (measured value deducts expected value) of Δ=measured value and expected value (%)
Evaluate:
-measured value E is greater than E c:-> acts synergistically (+Δ)
-measured value E equals E c:-> additive effect
-measured value E is less than E c:-> antagonism (-Δ)
Form 5-01: greenhouse
Form 5-02: greenhouse
Reactive compound Dosage Anti-pansy (Viola tricolor) active [%]
[a.i./hectare in g]
A1-2 2 60
Fenoxaprop 25 0
A1-2+ fenoxaprop 2+25 80(E C＝60,Δ＝20)
Form 5-03: greenhouse
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Form 5-116: field

Claims (13)

1. a herbicidal composition, comprises
(A) compound or its salt of one or more formulas (I), and
(B) one or more are selected from the weed killer herbicide of B1 to B11 class,
(A) compound (component A) of one or more formulas (I) or its salt,
Wherein symbol and mark separately as defined below
A represents N or CY,
B represents N or CH,
X represents nitro, halogen, cyano group, formoxyl, thiocyano, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, (C 2-C 6)-thiazolinyl, halo-(C 2-C 6)-thiazolinyl, (C 2-C 6)-alkynyl, halo-(C 3-C 6)-alkynyl, (C 3-C 6)-cycloalkyl, halo-(C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, halo-(C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, COR 1, COOR 1, OCOOR 1, NR 1cOOR 1, C (O) N (R 1) 2, NR 1c (O) N (R 1) 2, OC (O) N (R 1) 2, C (O) NR 1oR 1, OR 1, OCOR 1, OSO 2r 2, S (O) nr 2, SO 2oR 1, SO 2n (R 1) 2, NR 1sO 2r 2, NR 1cOR 1, (C 1-C 6)-alkyl-S (O) nr 2, (C 1-C 6)-alkyl-OR 1, (C 1-C 6)-alkyl-OCOR 1, (C 1-C 6)-alkyl-OSO 2r 2, (C 1-C 6)-alkyl-CO 2r 1, (C 1-C 6)-alkyl-SO 2oR 1, (C 1-C 6)-alkyl-CON (R 1) 2, (C 1-C 6)-alkyl-SO 2n (R 1) 2, (C 1-C 6)-alkyl-NR 1cOR 1, (C 1-C 6)-alkyl-NR 1sO 2r 2, NR 1r 2, P (O) (OR 5) 2, CH 2p (O) (OR 5) 2, (C 1-C 6)-miscellaneous alkyl aryl, (C 1-C 6)-alkyl heterocyclic, two groups wherein finally mentioned are selected from following group by s separately and replace: halogen, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, S (O) n-(C 1-C 6)-alkyl, (C 1-C 6)-alkoxyl and halo-(C 1-C 6)-alkoxyl, and wherein heterocyclic radical has n oxo group,
Y represents hydrogen, nitro, halogen, cyano group, thiocyano, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, (C 2-C 6)-thiazolinyl, halo-(C 2-C 6)-thiazolinyl, (C 2-C 6)-alkynyl, halo-(C 2-C 6)-alkynyl, (C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkenyl group, halo-(C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, halo-(C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, COR 1, COOR 1, OCOOR 1, NR 1cOOR 1, C (O) N (R 1) 2, NR 1c (O) N (R 1) 2, OC (O) N (R 1) 2, CO (NOR 1) R 1, NR 1sO 2r 2, NR 1cOR 1, OR 1, OSO 2r 2, S (O) nr 2, SO 2oR 1, SO 2n (R 1) 2, (C 1-C 6)-alkyl-S (O) nr 2, (C 1-C 6)-alkyl-OR 1, (C 1-C 6)-alkyl-OCOR 1, (C 1-C 6)-alkyl-OSO 2r 2, (C 1-C 6)-alkyl-CO 2r 1, (C 1-C 6)-alkyl-CN, (C 1-C 6)-alkyl-SO 2oR 1, (C 1-C 6)-alkyl-CON (R 1) 2, (C 1-C 6)-alkyl-SO 2n (R 1) 2, (C 1-C 6)-alkyl-NR 1cOR 1, (C 1-C 6)-alkyl-NR 1sO 2r 2, N (R 1) 2, P (O) (OR 5) 2, CH 2p (O) (OR 5) 2, (C 1-C 6)-alkyl phenyl, (C 1-C 6)-miscellaneous alkyl aryl, (C 1-C 6)-alkyl heterocyclic, phenyl, heteroaryl and heterocyclic radical, six groups wherein finally mentioned are selected from following group by s separately and replace: halogen, nitro, cyano group, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, (C 3-C 6)-cycloalkyl, S (O) n-(C 1-C 6)-alkyl, (C 1-C 6)-alkoxyl, halo-(C 1-C 6)-alkoxyl, (C 1-C 6)-alkoxyl-(C 1-C 4)-alkyl and cyano methyl, and wherein heterocyclic radical has n oxo group,
Z represents halogen, cyano group, thiocyano, halo-(C 1-C 6)-alkyl, (C 2-C 6)-thiazolinyl, halo-(C 2-C 6)-thiazolinyl, (C 2-C 6)-alkynyl, halo-(C 2-C 6)-alkynyl, (C 3-C 6)-cycloalkyl, halo-(C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, halo-(C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, COR 1, COOR 1, OCOOR 1, NR 1cOOR 1, C (O) N (R 1) 2, NR 1c (O) N (R 1) 2, OC (O) N (R 1) 2, C (O) NR 1oR 1, OSO 2r 2, S (O) nr 2, SO 2oR 1, SO 2n (R 1) 2, NR 1sO 2r 2, NR 1cOR 1, (C 1-C 6)-alkyl-S (O) nr 2, (C 1-C 6)-alkyl-OR 1, (C 1-C 6)-alkyl-OCOR 1, (C 1-C 6)-alkyl-OSO 2r 2, (C 1-C 6)-alkyl-CO 2r 1, (C 1-C 6)-alkyl-SO 2oR 1, (C 1-C 6)-alkyl-CON (R 1) 2, (C 1-C 6)-alkyl-SO 2n (R 1) 2, (C 1-C 6)-alkyl-NR 1cOR 1, (C 1-C 6)-alkyl-NR 1sO 2r 2, N (R 1) 2, P (O) (OR 5) 2, heteroaryl, heterocyclic radical or phenyl, three groups wherein finally mentioned are selected from following group by s separately and replace: halogen, nitro, cyano group, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, (C 3-C 6)-cycloalkyl, S (O) n-(C 1-C 6)-alkyl, (C 1-C 6)-alkoxyl or halo-(C 1-C 6)-alkoxyl, and wherein heterocyclic radical has n oxo group, or
Z also can represent hydrogen, (C 1-C 6)-alkyl or (C 1-C 6)-alkoxyl, if Y represents S (O) nr 2group,
W represents hydrogen, (C 1– C 6)-alkyl, halo-(C 1– C 6)-alkyl, (C 2– C 6)-thiazolinyl, halo-(C 2– C 6)-thiazolinyl, (C 2– C 6)-alkynyl, halo-(C 2– C 6)-alkynyl, (C 3– C 7)-cycloalkyl, (C 3– C 7)-halogenated cycloalkyl, (C 1-C 6)-alkoxyl, (C 1-C 6)-halogenated alkoxy, S (O) n-(C 1-C 6)-alkyl, S (O) n-(C 1-C 6)-haloalkyl, (C 1-C 6)-alkoxyl-(C 1-C 4)-alkyl, (C 1-C 6)-alkoxyl-(C 1-C 4)-haloalkyl, halogen, nitro, NR 3cOR 3or cyano group,
R represents (C 1– C 8)-alkyl, halo-(C 1– C 8)-alkyl, (C 2-C 8)-thiazolinyl, halo-(C 2-C 8)-thiazolinyl, (C 2-C 8)-alkynyl, halo-(C 2-C 8)-alkynyl, wherein above-mentioned six groups are selected from following group by s separately and replace: hydroxyl, nitro, cyano group, SiR 5 3, PO (OR 5) 2, S (O) n-(C 1-C 6)-alkyl, S (O) n-(C 1-C 6)-haloalkyl, (C 1-C 6)-alkoxyl, halo-(C 1-C 6)-alkoxyl, N (R 3) 2, COR 3, COOR 3, OCOR 3, NR 3cOR 3, NR 3sO 2r 4, O (C 1-C 2)-alkyl-(C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkyl, heteroaryl, heterocyclic radical, phenyl, Q-heteroaryl, Q-heterocyclic radical, Q-phenyl and Q-benzyl, seven groups wherein finally mentioned are selected from following group by s separately and replace: methyl, ethyl, methoxyl group, trifluoromethyl, cyano group and halogen, and wherein heterocyclic radical has n oxo group, or
R represents (C 3– C 7)-cycloalkyl, heteroaryl, heterocyclic radical or phenyl, it is selected from following group by s separately and replaces: halogen, nitro, cyano group, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, (C 3-C 6)-cycloalkyl, S (O) n-(C 1-C 6)-alkyl, (C 1-C 6)-alkoxyl, halo-(C 1-C 6)-alkoxyl and (C 1-C 6)-alkoxyl-(C 1-C 4)-alkyl, wherein heterocyclic radical have n oxo group,
Q represents O, S or NR 3,
R 1represent hydrogen, (C 1-C 6)-alkyl, (C 1-C 6)-haloalkyl, (C 2-C 6)-thiazolinyl, (C 2-C 6)-haloalkenyl group, (C 2-C 6)-alkynyl, (C 2-C 6)-halo alkynyl, (C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkenyl group, (C 3-C 6)-halogenated cycloalkyl, (C 1-C 6)-alkyl-O-(C 1-C 6)-alkyl, (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, phenyl, phenyl-(C 1-C 6)-alkyl, heteroaryl, (C 1-C 6)-miscellaneous alkyl aryl, heterocyclic radical, (C 1-C 6)-alkyl heterocyclic, (C 1-C 6)-alkyl-O-heteroaryl, (C 1-C 6)-alkyl-O-heterocyclic radical, (C 1-C 6)-alkyl-NR 3-heteroaryl or (C 1-C 6)-alkyl-NR 3-heterocyclic radical, 21 groups wherein finally mentioned are selected from following group by s separately and replace: cyano group, halogen, nitro, thiocyano, OR 3, S (O) nr 4, N (R 3) 2, NR 3oR 3, COR 3, OCOR 3, SCOR 4, NR 3cOR 3, NR 3sO 2r 4, CO 2r 3, COSR 4, CON (R 3) 2(C 1-C 4)-alkoxyl-(C 2-C 6)-alkoxy carbonyl, and wherein heterocyclic radical has n oxo group,
R 2representative (C 1-C 6)-alkyl, (C 1-C 6)-haloalkyl, (C 2-C 6)-thiazolinyl, (C 2-C 6)-haloalkenyl group, (C 2-C 6)-alkynyl, (C 2-C 6)-halo alkynyl, (C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkenyl group, (C 3-C 6)-halogenated cycloalkyl, (C 1-C 6)-alkyl-O-(C 1-C 6)-alkyl, (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, phenyl, phenyl-(C 1-C 6)-alkyl, heteroaryl, (C 1-C 6)-miscellaneous alkyl aryl, heterocyclic radical, (C 1-C 6)-alkyl heterocyclic, (C 1-C 6)-alkyl-O-heteroaryl, (C 1-C 6)-alkyl-O-heterocyclic radical, (C 1-C 6)-alkyl-NR 3-heteroaryl or (C 1-C 6)-alkyl-NR 3-heterocyclic radical, 21 groups wherein finally mentioned are selected from following group by s separately and replace: cyano group, halogen, nitro, thiocyano, OR 3, S (O) nr 4, N (R 3) 2, NR 3oR 3, COR 3, OCOR 3, SCOR 4, NR 3cOR 3, NR 3sO 2r 4, CO 2r 3, COSR 4, CON (R 3) 2(C 1-C 4)-alkoxyl-(C 2-C 6)-alkoxy carbonyl, and wherein heterocyclic radical has n oxo group,
R 3represent hydrogen, (C 1-C 6)-alkyl, (C 2-C 6)-thiazolinyl, (C 2-C 6)-alkynyl, (C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl or phenyl,
R 4representative (C 1-C 6)-alkyl, (C 2-C 6)-thiazolinyl, (C 2-C 6)-alkynyl, (C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl or phenyl,
R 5representative (C 1-C 4)-alkyl,
N represents 0,1 or 2,
Behalf 0,1,2 or 3, and
(B) one or more are selected from the weed killer herbicide (B component) of B1 to B11:
B11,3-dione compounds, comprise: Prohexadione calcium, TrinexAN_SNacethyl, alloxydimsodium, clethodim, cycloxydim, clefoxidim, sethoxydim, herbicide, tralkoxydim, mesotrione, sulphur humulone, special furan triketone, ring sulphur ketone, fluorine benzofenap, azoles quinoline grass ester
B2 (sulphur) acid amides, comprising:
Beflubutamide, bromobutide, dimethenamid, essence cresols fenacet, , diphenamide, napropamide, pethoxamid, N-[the chloro-4-of 3-(1-Methylethyl)-phenyl]-2-methylpentanamide, quinclorac, propyzamide, diflufenican, ethobenzanid, flufenacet, mefenacet, chlorine sulphonyl grass amine, pentanochlor, fluorine metazachlor, Stam F-34, benzene peptide propylhomoserin, Acetochlor, alachlor, butachlor, dimethachlor, metazachlor, isopropyl methoxalamine, S-isopropyl methoxalamine, third careless amine, propachlor, propisochlor, the chloro-6 '-ethyl of 2--N-i-propoxymethyl acetyl-o-toluidines), P DimethenamidP, the spirit of sulphur grass, carbaryl, carbetamide, chlorpropham, desmedipham, phenmedipham, propham, butylate, cycloate, dimepiperate, EPTC, esprocarb, methasulfocarb, molinate, orbencarb, pebulate, prosulfocarb, pyributicarb, benthiocarb, triallate, vernolate, amidosulfuron, azimsulfuron, bensulfuron-methyl, chlorimuronethyl, chlorine sulphur is grand, cinosulfuron, AC322140, ethametsulfuron, ethoxysulfuron, flazasulfuron, flucetosulfuron, flupyrsulfuron-methyl-sodium, formyl ammonia sulphur is grand, halosulfuronmethyl, imazosulfuron, iodosulfuron methyl sodium, mesosulfuronmethyl, metsulfuron-methyl, monosulfmeturon, nicosulfuron, phonetic aniline sulphur is grand, oxasulfuron, primisulfuronmethyl, prosulfuron, pyrazosulfuron, rimsulfuron, sulfometuronmethyl, Sulfosulfuron, thifensulfuronmethyl methyl esters, triasulfuron, tribenuron-methyl methyl esters, trifloxysulfuron (sodium), triflusulfuronmethyl, tritosulfuron, (benzoic acid, 2-[[[[[4-methoxyl group-6-(methyl mercapto)-2-pyrimidine radicals] is amino] carbonyl] is amino] sulfonyl] methyl esters), flucarbazonesodium, procarbazone, thiophene ketone sulphur is grand, chlorine ester sulphur oxalic acid, diclosulam, florasulam, Flumetsulam, metosulam, penoxsuam, pyroxsulam, B3 aromatic nitrile, comprising:
Brominal, dichlobenil, ioxynil, pyraclonil,
B4 oxazole class, comprising:
Benzofenap, pyrazolate, pyrazoxyfen, send Roc herbicide sulfone, benzene pyrazoles humulone, sulphonyl grass pyrazoles, 3-(the chloro-5-{ of 3-[1-methyl-3-(trifluoromethyl)-1H-pyrazoles-5-base] oxygen base } phenoxy group)-1-methyl-5-(trifluoromethyl)-1H-pyrazoles, 3-(the iodo-5-{ of 3-[1-methyl-3-(trifluoromethyl)-1H-pyrazoles-5-base] oxygen base } phenoxy group)-1-methyl-5-(trifluoromethyl)-1H-pyrazoles, 1-ethyl-3-(the fluoro-5-{ of 3-[1-methyl-3-(trifluoromethyl)-1H-pyrazoles-5-base] oxygen base } phenoxy group)-5-(trifluoromethyl)-1H-pyrazoles, pyrrole grass ether, fluazolate, isouron, Yi Evil acyl grass amine, isoxazole humulone, miaow methyl oxalate, imazamox, AC 263222, imazapyr, imazaquin, imazethapyr, methazole, oxadiargyl, oxadiazon, amicarbazone, carfentrazone, sulfentrazone, bencarbazone, Amrol, paclobutrazol, uniconazole P, cafenstrole, fentrazamide,
Other weed killer herbicides of B5, comprising:
Ring third pyrimidine acid, N-acetyl thiazole quinoline-4-carboxylic acid, acrolein, the acid of chlorine Fampridine, n-nonanoic acid ammonium, Amcide Ammate, Ai Wei hormone, benazolin, benfluralin, benfuresate, bentazone, benzobicylon, 6-benzylaminopurine, borax, butralin, carvol, catechin, morphactin, Pynamin, chlormequat, monoxone, chlorine acid imide, chlorine dimethyl phthalate, cinidon-ethyl, cinmethylin, clofencet, clomazone, cloxyfonac, cyanamide, ring malonamic acid, 6-c purine, kinetin, zeatin, dalapon, daminozide, dazomet, Decanol, difenzoquat methylsulfuric acid ester, 2,6-DIPN, dikegulac, dimethipin, cacodylic acid, dinitramine, dinoterb, diquat, dithiopyr, DNOC, endothal, fourth fluchloralin, ethofumesate, ethylchlozate, ferrous sulfate, flampropMmethyl, flufenpyrethyl, flumetralim, Flumiclorac pentyl, flumioxazin, tetrafluoro propionic acid, flurenol, fluridone, fluorochloridone, flurtamone, gibberellin, indanofan, isopropalin, Isoprothiolane, maleic hydrazide, mepiquat chloride, metham-sodium, methanearsonic acid, 1-methyl cyclopropene, methyl-isorhodanate, nitrophenol salt mixture, n-nonanoic acid, norflurazon, oleic acid, oryzalin, oxaziclomefone, PP-148, pendimethalin, pentachlorophenol, Huan Wu Evil humulone, petroleum oil, prodiamine, jasmone, pyridate, quinoclamine, sintofen, sodium chlorate, sulfuric acid, tar, TCA sodium, tecnazene, thrizopyr, triacontanol, trefanocide and ureasulfuric acid,
B6 (mixing) aryl carboxylic acid class, comprising:
Dicamba, 2,3,6-TBA, clopyralid, fluroxypyr, inabenfide, picloram, trichlopyr, dichloro quinolinic acid, quinmerac, indoles-3 guanidine-acetic acid, 4-indol-3-yl butyric acid, 2-(1-naphthyl) acetamide, 1-naphthyl acetic acid, 2-naphthyl ethoxyacetic acid
B7 organic phosphine compound class, comprising:
Anilofos, bensulide, bilanafos, butimafos, ioxynil, Glufosinate, phosphine oxamate salt, Glufosinate, phosphine oxamate sodium salt, L-Glufosinate, L-phosphine oxamate sodium salt, glyphosate, glyphosate isopropyl amine salt, glyphosate, sulphosate, glyphosate two ammonium, glyphosate potassium, piperophos, ethrel and De-Green
B8 phenyl ether, comprising:
Acifluorfen, aclonifen, fluoroglycofen-ethyl, fomesafen, lactofen, Oxyfluorfen, bifenox, HC252 ethyl ester, clomeprop, adjust tartaric acid, 2, 4-drips propionic acid, essence 2, 4-drips propionic acid, 2-first-4-chloropropionic acid, essence 2-first-4-chloropropionic acid, 4-CPA, 2, 4-D, MCPA, MCPA-sulphur ethyl, 2, 4-DB, MCPB, clodinafop-propargyl, cyhalofop-butyl), diclofop-methyl, essence diclofop-methyl, fenoxaprop, fluazifop-P-butyl, efficient fluazifop butyl ester, fluazifop-butyl, essence fluazifop-butyl, metamifop, propaquizafop, quizalafop, quizalafop-P,
B9 pyrimidines, comprising:
The phonetic alcohol of three ring benzene, flurprimidol, Nylar, two careless ether, pyribenzoxim, KIH 6127, iso-propyl-ester nitrofen, propyl-ester nitorfen, pyriftalid, pyrithiobac-sodium, benzfendizone, bromacil, butafenacil, lenacil, terbacil, the fluoro-5-of the chloro-4-of 2-[3-methyl-2; 6-dioxo-4-(trifluoromethyl)-3; 6-dihydroxy-pyrimidine-1 (2H)-Ji]-N-[methyl (1-Methylethyl)-sulfamoyl] benzamide
B10 (sulphur) urea, comprising:
Cumyluron, bromax, chlortoluron, chloroxifenidium, daimuron, diflufenzopyr, oxazole are grand, diuron, fluometuron, CPPU, isoproturon, karbutilate, lorox, methyldymron, metobromuron, metoxuron, afesin, neburea, Tupersan, Thidiazuron, methiuron, tebuthiuron, methabenzthiazuron
B11 triazines, comprising:
Triaziflam, iodine metsulfuron-methyl, atrazine, cyanazine, propazine, Simanex, Garagard, trietazine, prometryn, ametryn, dimethametryn, prometryn, symetryne, terbutryn, hexazinone, metamitron, piperazine humulone.
2. the herbicidal composition of claim 1, wherein
A represents N or CY,
B represents N or CH,
X represents nitro, halogen, cyano group, thiocyano, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, (C 2-C 6)-thiazolinyl, halo-(C 2-C 6)-thiazolinyl, (C 2-C 6)-alkynyl, halo-(C 3-C 6)-alkynyl, (C 3-C 6)-cycloalkyl, halo-(C 3-C 6)-cycloalkyl, (C 1-C 6)-alkyl-O-(C 1-C 6)-alkyl, (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, halo-(C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, COR 1, OR 1, OCOR 1, OSO 2r 2, S (O) nr 2, SO 2oR 1, SO 2n (R 1) 2, NR 1sO 2r 2, NR 1cOR 1, (C 1-C 6)-alkyl-S (O) nr 2, (C 1-C 6)-alkyl-OR 1, (C 1-C 6)-alkyl-OCOR 1, (C 1-C 6)-alkyl-OSO 2r 2, (C 1-C 6)-alkyl-CO 2r 1, (C 1-C 6)-alkyl-SO 2oR 1, (C 1-C 6)-alkyl-CON (R 1) 2, (C 1-C 6)-alkyl-SO 2n (R 1) 2, (C 1-C 6)-alkyl-NR 1cOR 1or (C 1-C 6)-alkyl-NR 1sO 2r 2, (C 1-C 6)-miscellaneous alkyl aryl, (C 1-C 6)-alkyl heterocyclic, 2 groups wherein finally mentioned are selected from following group by s separately and replace: halogen, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, S (O) n-(C 1-C 6)-alkyl, (C 1-C 6)-alkoxyl and halo-(C 1-C 6)-alkoxyl, and wherein heterocyclic radical has n oxo base,
Y represents hydrogen, nitro, halogen, cyano group, thiocyano, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, (C 2-C 6)-thiazolinyl, halo-(C 2-C 6)-thiazolinyl, (C 2-C 6)-alkynyl, halo-(C 3-C 6)-alkynyl, (C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkenyl group, halo-(C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, halo-(C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, COR 1, OR 1, COOR 1, OSO 2r 2, S (O) nr 2, SO 2oR 1, SO 2n (R 1) 2, N (R 1) 2, NR 1sO 2r 2, NR 1cOR 1, (C 1-C 6)-alkyl-S (O) nr 2, (C 1-C 6)-alkyl-OR 1, (C 1-C 6)-alkyl-OCOR 1, (C 1-C 6)-alkyl-OSO 2r 2, (C 1-C 6)-alkyl-CO 2r 1, (C 1-C 6)-alkyl-SO 2oR 1, (C 1-C 6)-alkyl-CON (R 1) 2, (C 1-C 6)-alkyl-SO 2n (R 1) 2, (C 1-C 6)-alkyl-NR 1cOR 1, (C 1-C 6)-alkyl-NR 1sO 2r 2, (C 1-C 6)-alkyl phenyl, (C 1-C 6)-miscellaneous alkyl aryl, (C 1-C 6)-alkyl heterocyclic, phenyl, heteroaryl or heterocyclic radical, 6 groups wherein finally mentioned are selected from following group by s separately and replace: halogen, nitro, cyano group, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, (C 3-C 6)-cycloalkyl, S (O) n-(C 1-C 6)-alkyl, (C 1-C 6)-alkoxyl, halo-(C 1-C 6)-alkoxyl, (C 1-C 6)-alkoxyl-(C 1-C 4)-alkyl and cyanogen methyl, and wherein heterocyclic radical has n oxo base,
Z represents halogen, cyano group, thiocyano, halo-(C 1-C 6)-alkyl, (C 2-C 6)-thiazolinyl, halo-(C 2-C 6)-thiazolinyl, (C 2-C 6)-alkynyl, halo-(C 3-C 6)-alkynyl, (C 3-C 6)-cycloalkyl, halo-(C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, halo-(C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, COR 1, COOR 1, C (O) N (R 1) 2, C (O) NR 1oR 1, OSO 2r 2, S (O) nr 2, SO 2oR 1, SO 2n (R 1) 2, NR 1sO 2r 2, NR 1cOR 1, (C 1-C 6)-alkyl-S (O) nr 2, (C 1-C 6)-alkyl-OR 1, (C 1-C 6)-alkyl-OCOR 1, (C 1-C 6)-alkyl-OSO 2r 2, (C 1-C 6)-alkyl-CO 2r 1, (C 1-C 6)-alkyl-SO 2oR 1, (C 1-C 6)-alkyl-CON (R 1) 2, (C 1-C 6)-alkyl-SO 2n (R 1) 2, (C 1-C 6)-alkyl-NR 1cOR 1, (C 1-C 6)-alkyl-NR 1sO 2r 2, 1,2,4-triazol-1-yl, or
Z also can represent hydrogen, (C 1-C 6)-alkyl or (C 1-C 6)-alkoxyl, if Y represents S (O) nr 2base,
W represents hydrogen, (C 1– C 6)-alkyl, halo-(C 1– C 6)-alkyl, (C 1-C 6)-alkoxyl, (C 1-C 6)-halogenated alkoxy, S (O) n-(C 1-C 6)-alkyl, S (O) n-(C 1-C 6)-haloalkyl, (C 1-C 6)-alkoxyl-(C 1-C 4)-alkyl, halogen, nitro or cyano group,
R represents (C 1– C 8)-alkyl, halo-(C 1– C 8)-alkyl, (C 2-C 8)-thiazolinyl, halo-(C 2-C 8)-thiazolinyl, (C 2-C 8)-alkynyl, halo-(C 2-C 8)-alkynyl, wherein above-mentioned 6 groups are selected from following group by s separately and replace: nitro, cyano group, SiR 5 3, P (OR 5) 3, S (O) n-(C 1-C 6)-alkyl, (C 1-C 6)-alkoxyl, halo-(C 1-C 6)-alkoxyl, N (R 3) 2, COR 3, COOR 3, OCOR 3, NR 3cOR 3, NR 3sO 2r 4, (C 3-C 6)-cycloalkyl, heteroaryl, heterocyclic radical, phenyl, Q-heteroaryl, Q-heterocyclic radical, Q-phenyl and Q-benzyl, 7 groups wherein finally mentioned are selected from following group by s separately and replace: methyl, ethyl, methoxyl group, trifluoromethyl, cyano group and halogen, and wherein heterocyclic radical has n oxo base, or
R represents (C 3– C 7)-cycloalkyl, heteroaryl, heterocyclic radical or phenyl, be selected from following group by s separately and replace: halogen, nitro, cyano group, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, (C 3-C 6)-cycloalkyl, S (O) n-(C 1-C 6)-alkyl, (C 1-C 6)-alkoxyl, halo-(C 1-C 6)-alkoxyl and (C 1-C 6)-alkoxyl-(C 1-C 4)-alkyl,
Q represents O, S or NR 3,
R 1represent hydrogen, (C 1-C 6)-alkyl, (C 2-C 6)-thiazolinyl, (C 2-C 6)-alkynyl, (C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, (C 1-C 6)-alkyl-O-(C 1-C 6)-alkyl, phenyl, phenyl-(C 1-C 6)-alkyl, heteroaryl, (C 1-C 6)-miscellaneous alkyl aryl, heterocyclic radical, (C 1-C 6)-alkyl heterocyclic, (C 1-C 6)-alkyl-O-heteroaryl, (C 1-C 6)-alkyl-O-heterocyclic radical, (C 1-C 6)-alkyl-NR 3-heteroaryl or (C 1-C 6)-alkyl-NR 3-heterocyclic radical, 16 groups wherein finally mentioned are selected from following group by s separately and replace: cyano group, halogen, nitro, OR 3, S (O) nr 4, N (R 3) 2, NR 3oR 3, COR 3, OCOR 3, NR 3cOR 3, NR 3sO 2r 4, CO 2r 3, CON (R 3) 2(C 1-C 4)-alkoxyl-(C 2-C 6)-alkoxy carbonyl, wherein heterocyclic radical have n oxo base,
R 2representative (C 1-C 6)-alkyl, (C 2-C 6)-thiazolinyl, (C 2-C 6)-alkynyl, (C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, (C 1-C 6)-alkyl-O-(C 1-C 6)-alkyl, phenyl, phenyl-(C 1-C 6)-alkyl, heteroaryl, (C 1-C 6)-miscellaneous alkyl aryl, heterocyclic radical, (C 1-C 6)-alkyl heterocyclic, (C 1-C 6)-alkyl-O-heteroaryl, (C 1-C 6)-alkyl-O-heterocyclic radical, (C 1-C 6)-alkyl-NR 3-heteroaryl or (C 1-C 6)-alkyl-NR 3-heterocyclic radical, 16 groups wherein finally mentioned are selected from following group by s separately and replace: cyano group, halogen, nitro, OR 3, S (O) nr 4, N (R 3) 2, NR 3oR 3, NR 3sO 2r 4, COR 3, OCOR 3, NR 3cOR 3, CO 2r 3, CON (R 3) 2(C 1-C 4)-alkoxyl-(C 2-C 6)-alkoxy carbonyl, wherein heterocyclic radical has n oxo base,
R 3represent hydrogen, (C 1-C 6)-alkyl, (C 2-C 6)-thiazolinyl, (C 2-C 6)-alkynyl, (C 3-C 6)-cycloalkyl or (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl,
R 4representative (C 1-C 6)-alkyl, (C 2-C 6) thiazolinyl or (C 2-C 6)-alkynyl,
R 5represent methyl or ethyl,
N represents 0,1 or 2, and
Behalf 0,1,2 or 3.
3. the herbicidal composition of claim 1 or 2, wherein
A represents N or CY,
B represents N or CH,
X represents nitro, halogen, cyano group, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, (C 3-C 6)-cycloalkyl, OR 1, S (O) nr 2, (C 1-C 6)-alkyl-S (O) nr 2, (C 1-C 6)-alkyl-OR 1, (C 1-C 6)-alkyl-CON (R 1) 2, (C 1-C 6)-alkyl-SO 2n (R 1) 2, (C 1-C 6)-alkyl-NR 1cOR 1, (C 1-C 6)-alkyl-NR 1sO 2r 2, (C 1-C 6)-miscellaneous alkyl aryl, (C 1-C 6)-alkyl heterocyclic, 2 groups wherein finally mentioned are selected from following group by s separately and replace: halogen, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, S (O) n-(C 1-C 6)-alkyl, (C 1-C 6)-alkoxyl and halo-(C 1-C 6)-alkoxyl, and wherein heterocyclic radical has n oxo base,
Y represents hydrogen, nitro, halogen, cyano group, (C 1-C 6)-alkyl, (C 1-C 6)-haloalkyl, OR 1, S (O) nr 2, SO 2n (R 1) 2, N (R 1) 2, NR 1sO 2r 2, NR 1cOR 1, (C 1-C 6)-alkyl-S (O) nr 2, (C 1-C 6)-alkyl-OR 1, (C 1-C 6)-alkyl-CON (R 1) 2, (C 1-C 6)-alkyl-SO 2n (R 1) 2, (C 1-C 6)-alkyl-NR 1cOR 1, (C 1-C 6)-alkyl-NR 1sO 2r 2, (C 1-C 6)-alkyl phenyl, (C 1-C 6)-miscellaneous alkyl aryl, (C 1-C 6)-alkyl heterocyclic, phenyl, heteroaryl or heterocyclic radical, 6 groups wherein finally mentioned are selected from following group by s separately and replace: halogen, nitro, cyano group, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, (C 3-C 6)-cycloalkyl, S (O) n-(C 1-C 6)-alkyl, (C 1-C 6)-alkoxyl, halo-(C 1-C 6)-alkoxyl, (C 1-C 6)-alkoxyl-(C 1-C 4)-alkyl and cyanogen methyl, wherein heterocyclic radical have n oxo base,
Z represents halogen, cyano group, halo-(C 1-C 6)-alkyl, (C 3-C 6)-cycloalkyl, S (O) nr 2, 1,2,4-triazol-1-yl, or
Z also can represent hydrogen, methyl, methoxy or ethoxy, if Y is S (O) nr 2base,
W represents hydrogen, methyl, ethyl, methoxy, methoxyl group, fluorine, chlorine or S (O) ncH 3,
R represents (C 1– C 8)-alkyl, halo-(C 1– C 8)-alkyl, (C 2-C 8)-thiazolinyl, halo-(C 2-C 8)-thiazolinyl, (C 2-C 8)-alkynyl, halo-(C 2-C 8)-alkynyl, 6 groups wherein finally mentioned are selected from following group by s separately and replace: cyano group, S (O) n-(C 1-C 6)-alkyl, (C 1-C 6)-alkoxyl, halo-(C 1-C 6)-alkoxyl, COR 3, COOR 3, OCOR 3, NR 3cOR 3, NR 3sO 2r 4, (C 3-C 6)-cycloalkyl, heteroaryl, heterocyclic radical and phenyl, 3 groups wherein finally mentioned are selected from following group by s separately and replace: methyl, ethyl, methoxyl group, trifluoromethyl, cyano group and halogen, and wherein heterocyclic radical has 0 to 2 oxo group, or
The phenyl that R representative is selected from following group replaces by s: halogen, nitro, cyano group, (C 1-C 6)-alkyl, halo-(C 1-C 6)-alkyl, (C 3-C 6)-cycloalkyl, S (O) n-(C 1-C 6)-alkyl, (C 1-C 6)-alkoxyl, halo-(C 1-C 6)-alkoxyl, (C 1-C 6)-alkoxyl-(C 1-C 4)-alkyl,
R 1represent hydrogen, (C 1-C 6)-alkyl, (C 2-C 6)-thiazolinyl, (C 2-C 6)-alkynyl, (C 3-C 6)-cycloalkyl, (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, (C 1-C 6)-alkyl-O-(C 1-C 6)-alkyl, phenyl, phenyl-(C 1-C 6)-alkyl, heteroaryl, (C 1-C 6)-miscellaneous alkyl aryl, heterocyclic radical, (C 1-C 6)-alkyl heterocyclic, (C 1-C 6)-alkyl-O-heteroaryl, (C 1-C 6)-alkyl-O-heterocyclic radical, (C 1-C 6)-alkyl-NR 3-heteroaryl or (C 1-C 6)-alkyl-NR 3-heterocyclic radical, 16 groups wherein finally mentioned are selected from following group by s separately and replace: cyano group, halogen, nitro, OR 3, S (O) nr 4, N (R 3) 2, NR 3oR 3, COR 3, OCOR 3, NR 3cOR 3, NR 3sO 2r 4, CO 2r 3, CON (R 3) 2(C 1-C 4)-alkoxyl-(C 2-C 6)-alkoxy carbonyl, wherein heterocyclic radical has n oxo base,
R 2representative (C 1-C 6)-alkyl, (C 3-C 6)-cycloalkyl or (C 3-C 6)-cycloalkyl-(C 1-C 6)-alkyl, is selected from following group by s separately and replaces: halogen and OR 3,
R 3represent hydrogen or (C 1-C 6)-alkyl,
R 4representative (C 1-C 6)-alkyl,
R 5represent methyl or ethyl,
N represents 0,1 or 2, and
Behalf 0,1,2 or 3.
4. the herbicidal composition any one of claims 1 to 3, wherein
A represents CY,
B represents N,
X represents chlorine, methyl, ethyl, propyl group, cyclopropyl, methoxyl group or SO 2cH 3,
Y represents hydrogen, CH 2oCH 3, CH 2oCH 2cF 3, CH 2oC 2h 4oCH 3, 4,5-dihydro-1,2-oxazole-3-bases, 5-methoxy-4,5-dihydro-1,2-oxazole-3-base, pyrazol-1-yl, OMe, OEt, OPr, OiBu, OCH 2cPr, OC 2h 4oCH 3, SO 2cH 3, S (O) CH 3or SCH 3, SO 2et, S (O) Et or SEt,
Z represents trifluoromethyl, SO 2cH 3, SO 2et, chlorine or bromine,
W represents hydrogen, and
R represents methyl, ethyl, propyl group or methoxy ethyl.
5. the herbicidal composition any one of claim 1 to 5, wherein
A represents CY,
B represents N,
X represents chlorine,
Y represents SO 2cH 3, SOCH 3or SO 2et,
Z represents hydrogen or methyl,
W represents hydrogen, and
R represents methyl.
6. the herbicidal composition any one of claim 1 to 5, wherein
A represents CY,
B represents N,
X represents chlorine or bromine,
Y represents hydrogen, methyl, SO 2cH 3or SCH 3,
Z represents hydrogen, SO 2cH 3or SCH 3,
W represents methyl, and
R represents methyl or ethyl.
7. the herbicidal composition any one of claims 1 to 3, wherein
A represents N,
B represents N,
X represents chlorine, bromine, SO 2cH 3, methoxy, OCH 2cPr, OC 2h 4oCH 3or methyl,
Z represents trifluoromethyl,
W represents hydrogen, and
R represents methyl or ethyl.
8. the herbicidal composition in any one of claim 1 to 7, containing one or more weed killer herbicides being selected from B1 to B11 class as B component:
B1 comprises for clethodim, sethoxydim, obtain herbicide, mesotrione, sulphur humulone, special furan triketone, ring sulphur ketone, fluorine benzofenap, azoles quinoline grass ester, tralkoxydim, B2 comprises dimethenamid, essence cresols fenacet, napropamide, pethoxamid, propyzamide, diflufenican, flufenacet, mefenacet, fluorine metazachlor, Stam F-34, Acetochlor, alachlor, butachlor, metazachlor, isopropyl methoxalamine, S-isopropyl methoxalamine, third careless amine, P DimethenamidP, the spirit of sulphur grass, carbetamide, desmedipham, phenmedipham, esprocarb, molinate, prosulfocarb, benthiocarb, amidosulfuron, chlorimuronethyl, AC322140, ethoxysulfuron, flupyrsulfuron-methyl-sodium, formyl ammonia sulphur is grand, iodosulfuron methyl sodium, mesosulfuronmethyl, nicosulfuron, phonetic aniline sulphur is grand, prosulfuron, pyrazosulfuron, rimsulfuron, trifloxysulfuron (sodium), flucarbazonesodium, procarbazone, thiophene ketone sulphur is grand, florasulam, metosulam, penoxsuam, metsulfuron-methyl, Sulfosulfuron, thifensulfuronmethyl methyl esters, tribenuron-methyl methyl esters, tritosulfuron, pyroxsulam,
B3 comprises Brominal and ioxynil,
B4 comprises benzofenap, benzene pyrazoles humulone, sulphonyl grass pyrazoles, isoxazole humulone, imazamox, imazapyr, oxadiargyl, oxadiazon, amicarbazone, carfentrazone, sulfentrazone, uniconazole P, cafenstrole, fentrazamide, 3-(the chloro-5-{ of 3-[1-methyl-3-(trifluoromethyl)-1H-pyrazoles-5-base] oxygen base } phenoxy group)-1-methyl-5-(trifluoromethyl)-1H-pyrazoles, 3-(the iodo-5-{ of 3-[1-methyl-3-(trifluoromethyl)-1H-pyrazoles-5-base] oxygen base } phenoxy group)-1-methyl-5-(trifluoromethyl)-1H-pyrazoles, 1-ethyl-3-(the fluoro-5-{ of 3-[1-methyl-3-(trifluoromethyl)-1H-pyrazoles-5-base] oxygen base } phenoxy group)-5-(trifluoromethyl)-1H-pyrazoles, pyrrole grass ether,
B5 comprises the acid of chlorine Fampridine, benazolin, benfuresate, bentazone, cinidon-ethyl, clomazone, diquat, ethofumesate, Flumiclorac pentyl, flumioxazin, flurtamone, oxaziclomefone, pendimethalin, pyridate and trefanocide,
B6 comprises dicamba, clopyralid, fluroxypyr, picloram, trichlopyr, dichloro quinolinic acid,
B7 comprises anilofos, Glufosinate and L-Glufosinate, glyphosate, glyphosate isopropyl amine salt, glyphosate, sulphosate, glyphosate two ammonium, glyphosate potassium,
B8 comprises acifluorfen, aclonifen, fluoroglycofen-ethyl, Oxyfluorfen, bifenox, essence 2,4-drips propionic acid, 2-first-4-chloropropionic acid, 2,4-D, MCPA, clodinafop-propargyl, cyhalofop-butyl, diclofop-methyl, smart diclofop-methyl, fenoxaprop, efficient fluazifop butyl ester, quizalafop-P
B9 comprises two careless ether (sodium), pyriftalid, bromacil, lenacil, the fluoro-5-of the chloro-4-of 2-[3-methyl-2; 6-dioxo-4-(trifluoromethyl)-3; 6-dihydro-pyrimidin-1 (2H)-Ji]-N-[methyl (1-Methylethyl)-sulfamoyl] benzamide
B10 comprises cumyluron, daimuron, diuron, isoproturon, diflufenzopyr,
B11 comprises atrazine, Simanex, Garagard, ametryn, terbutryn, metamitron, piperazine humulone.
9. the herbicidal composition any one of claim 1 to 7, comprises one or more weed killer herbicides being selected from B1, B2, B4, B5, B8, B9 and B11 class as B component:
B1 comprises clethodim, sulphur humulone, special furan triketone, ring sulphur ketone, fluorine benzofenap, azoles quinoline grass ester,
B2 comprises smart cresols fenacet, napropamide, diflufenican, flufenacet, mefenacet, Acetochlor, metazachlor, S-isopropyl methoxalamine, sulphur grass spirit, desmedipham, phenmedipham, molinate, prosulfocarb, amidosulfuron, ethoxysulfuron, formyl ammonia sulphur is grand, iodosulfuron methyl sodium, mesosulfuronmethyl, flucarbazonesodium, procarbazone, thiophene ketone sulphur are grand, florasulam, metosulam, metsulfuron-methyl, Sulfosulfuron, thifensulfuronmethyl methyl esters, tribenuron-methyl methyl esters, tritosulfuron, pyroxsulam
B4 comprises sulphonyl grass pyrazoles, isoxazole humulone, oxadiargyl, oxadiazon, amicarbazone, fentrazamide, 3-(the chloro-5-{ of 3-[1-methyl-3-(trifluoromethyl)-1H-pyrazoles-5-base] oxygen base } phenoxy group)-1-methyl-5-(trifluoromethyl)-1H-pyrazoles, 3-(the iodo-5-{ of 3-[1-methyl-3-(trifluoromethyl)-1H-pyrazoles-5-base] oxygen base } phenoxy group)-1-methyl-5-(trifluoromethyl)-1H-pyrazoles, 1-ethyl-3-(the fluoro-5-{ of 3-[1-methyl-3-(trifluoromethyl)-1H-pyrazoles-5-base] oxygen base } phenoxy group)-5-(trifluoromethyl)-1H-pyrazoles, pyrrole grass ether, imazamox,
B5 comprises the acid of chlorine Fampridine, benfuresate, ethofumesate, flurtamone with oxaziclomefone,
B8 comprise aclonifen, diclofop-methyl, smart diclofop-methyl, fenoxaprop, MCPA, 2,4-D, clodinafop-ethyl,
B9 comprises two careless ether (sodium), bromacil,
B11 comprises metamitron, piperazine humulone, Garagard.
10. the herbicidal composition any one of claim 1 to 9, comprises one or more in addition and is selected from following safener as component C: benoxacor, cloquitocet_mexyl, cyclopropyl-sulfonylamide, dichlormide, fenclorim, fenchlorazole, Xie Cao oxazole, the acid of Shuan Ben oxazole, mefenpyrdiethyl,
4-(dichloro-acetyl)-1-oxa--4-azaspiro [4.5] decane,
2,2,5-trimethyl-3-(dichloro-acetyl)-1,3-oxazolidine.
11. 1 kinds for preventing and treating the method for noxious plant in crop, it is characterized in that, required herbicidal composition one or more in the claim 1 to 10 of herbicidally effective amount is applied to noxious plant, plant, plant parts, plant seed or plant growth region.
The method of 12. claims 11, is characterized in that, described plant is sugarcane, corn, wheat, rye, barley, oat, rice, Chinese sorghum, cotton and soybean.
The method of 13. claims 11 or 12, it is characterized in that, described plant is by genetic modification.
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