CN104332582A - Double-polarity lead-acid storage battery - Google Patents

Double-polarity lead-acid storage battery Download PDF

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Publication number
CN104332582A
CN104332582A CN201410626687.XA CN201410626687A CN104332582A CN 104332582 A CN104332582 A CN 104332582A CN 201410626687 A CN201410626687 A CN 201410626687A CN 104332582 A CN104332582 A CN 104332582A
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CN
China
Prior art keywords
acid accumulator
lead
bipolar lead
substrate
base plates
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410626687.XA
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Chinese (zh)
Inventor
刘春�
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Individual
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Individual
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Publication date
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Priority to CN201410626687.XA priority Critical patent/CN104332582A/en
Publication of CN104332582A publication Critical patent/CN104332582A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/531Electrode connections inside a battery casing
    • H01M50/54Connection of several leads or tabs of plate-like electrode stacks, e.g. electrode pole straps or bridges
    • H01M50/541Connection of several leads or tabs of plate-like electrode stacks, e.g. electrode pole straps or bridges for lead-acid accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409Separators, membranes or diaphragms characterised by the material
    • H01M50/44Fibrous material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Cell Electrode Carriers And Collectors (AREA)
  • Secondary Cells (AREA)

Abstract

The invention discloses a double-polarity lead-acid storage battery. The double-polarity lead-acid storage battery comprises a battery shell, a shell cover and base plates, wherein the plurality of base plates are arranged in the battery shell in parallel at intervals; the base plates arranged at the two ends are positive and negative electrodes of the battery; the base plates are mainly made of flexible graphite materials; positive electrode lead plaster and negative electrode lead plaster are arranged on the two sides of the base plates; an insulating frame is arranged between the adjacent base plates; and each insulating frame is internally filled with a separation membrane made of glass fibers, rubber or plastic separation plates. The double-polarity lead-acid storage battery is provided with the plurality of base plates and inner single cells are connected in series; the positive electrode and the negative electrode do not need to be welded together with a lead part so that the use amount of lead materials is saved and the cost is reduced; large-current charging and discharging performances are improved and the production process is simple; and the double-polarity lead-acid storage battery is suitable for popularization and application.

Description

Bipolar lead-acid accumulator
Technical field
The present invention relates to a kind of bipolar lead-acid accumulator, belong to technical field of electrochemistry.
Background technology
As everyone knows, lead acid accumulator can be used for back-up source and electrical source of power, purposes is widely had in fields such as communication, electric power, vehicle launch, vehicle traction, new forms of energy, the baseplate material of traditional lead acid accumulator uses rigid conductive material, its sealing technology is complicated, is difficult to produce in enormous quantities; The conduction of substrate and anticorrosion modification difficulty, battery life is generally shorter; Substrate weight is comparatively large, and cost is also higher, and the raising of specific capacity is less; Simultaneously, traditional lead acid accumulator needs to use plumbous part positive pole and negative pole to be welded respectively when making, the internal resistance of cell is larger, conductive area less, makes the performance of high current charge-discharge low, when the discharge and recharge of needs large discharge, need many group lead accumulators to work simultaneously, inconvenience is installed, also can increases installation footprint, unfavorable industrial production simultaneously.
Summary of the invention
For above-mentioned weak point of the prior art, the invention provides a kind of long service life, cost is lower, easy for installation, floor space is little bipolar lead-acid accumulator.
To achieve these goals, the invention provides following technical scheme: a kind of bipolar lead-acid accumulator, comprise battery case, cap and substrate, described substrate has polylith, spacing side by side is arranged in battery case, the substrate being positioned at two ends is set to battery plus-negative plate, described substrate is made primarily of flexible graphite material, positive and negative electrode lead plaster is provided with in described substrate both sides, between two adjacent substrate, be provided with insulation frame, in described insulation frame, be filled with the barrier film be made up of glass fibre, rubber or plastic septum.
As preferably, described substrate comprises flexible graphite material and is coated in the copper conductive layer on flexible graphite material surface, aluminium conductive layer, plumbous conductive layer or its composite conductive layers, is embedded in aluminium, copper, iron or fortifying fibre at described flexible graphite material.
As preferably, described bipolar lead-acid accumulator can be valve-control sealed bipolar lead-acid accumulator or open type bipolar lead-acid accumulator or colloid bipolar lead-acid accumulator.
As preferably, the barrier film that filled glass fiber or chemical fibre are made in described insulation frame is made as valve-control sealed bipolar lead-acid accumulator.
As preferably, the barrier film that filled plastics plate or rubber slab are made in described insulation frame is made as open type bipolar lead-acid accumulator or colloid bipolar lead-acid accumulator.
Can be found out by above technical scheme, the present invention contains multiple substrate, is together in series between inner single lattice, do not need to use plumbous part to be welded into respectively with negative pole by positive pole, thus save lead material consumption, simultaneously, because the internal resistance of cell reduces, the increasing of conductive area, the performance of high current charge-discharge is improved, and flexible graphite material selected by substrate in addition, its sealing technology is simpler, more easily produce in enormous quantities, simply, battery life is longer for the conduction of substrate and anticorrosion modification; Substrate weight is less, and the raising of specific capacity is comparatively large, and cost is lower, is suitable for applying.
Accompanying drawing explanation
In order to be illustrated more clearly in the embodiment of the present invention or technical scheme of the prior art, be briefly described to the accompanying drawing used required in embodiment or description of the prior art below, apparently, accompanying drawing in the following describes is only some embodiments of the present invention, for those of ordinary skill in the art, under the prerequisite not paying creative work, other accompanying drawing can also be obtained according to these accompanying drawings.
Fig. 1 is structural representation of the present invention.
Embodiment
The present invention is further described below in conjunction with specific embodiment and accompanying drawing.
A kind of bipolar lead-acid accumulator as Fig. 1, comprise battery case 1, cap 2 and substrate 3, described substrate 3 has polylith, spacing side by side is arranged in battery case 1, the substrate 3 being positioned at two ends is set to battery plus-negative plate, and described substrate 3 is made primarily of flexible graphite material, is provided with positive and negative electrode lead plaster 4,5 in described substrate 3 both sides, between two adjacent substrate 3, be provided with insulation frame, in described insulation frame, be filled with the barrier film 6 be made up of glass fibre, rubber or plastic septum.
Further, described substrate 3 comprises flexible graphite material and is coated in the copper conductive layer on flexible graphite material surface, aluminium conductive layer, plumbous conductive layer or its composite conductive layers, improve the useful life of battery, be embedded in aluminium, copper, iron or fortifying fibre at described flexible graphite material.
Further, described bipolar lead-acid accumulator can be valve-control sealed bipolar lead-acid accumulator or open type bipolar lead-acid accumulator or colloid bipolar lead-acid accumulator.
Further, the barrier film 6 that filled glass fiber or chemical fibre are made in above-mentioned insulation frame is made as valve-control sealed bipolar lead-acid accumulator.
Further, the barrier film 6 that filled plastics plate or rubber slab are made in above-mentioned insulation frame is made as open type bipolar lead-acid accumulator or colloid bipolar lead-acid accumulator.
Flexible graphite proportion is little, and the specific capacity of battery can improve more than 20%; Flexible graphite body can use aluminium, copper, iron, high-intensity fiber compound, improves its mechanical strength and conductive capability, reduces the internal resistance of cell; Flexible graphite surface can metal coating or its composite bed such as copper coated, aluminium, lead, and to improve its decay resistance, the adhesion between enhanced activity material and substrate, reduces internal resistance, improves battery life; Flexible graphite possesses compression recovery performance, the self sealss of battery cell can be carried out, simplify manufacturing process, the present invention contains multiple substrate, be together in series between inner single lattice, do not need to use plumbous part to be welded into respectively with negative pole by positive pole, thus save lead material consumption, the performance of high current charge-discharge improves, and is suitable for applying.
Above the technical scheme that the embodiment of the present invention provides is described in detail, apply specific case herein to set forth the principle of the embodiment of the present invention and execution mode, the explanation of above embodiment is only applicable to the principle helping to understand the embodiment of the present invention; Meanwhile, for one of ordinary skill in the art, according to the embodiment of the present invention, embodiment and range of application all will change, and in sum, this description should not be construed as limitation of the present invention.

Claims (5)

1. a bipolar lead-acid accumulator, comprise battery case, cap and substrate, it is characterized in that: described substrate has polylith, spacing side by side is arranged in battery case, the substrate being positioned at two ends is set to battery plus-negative plate, and described substrate is made primarily of flexible graphite material, is provided with positive and negative electrode lead plaster in described substrate both sides, between two adjacent substrate, be provided with insulation frame, in described insulation frame, be filled with the barrier film be made up of glass fibre, rubber or plastic septum.
2. bipolar lead-acid accumulator according to claim 1, it is characterized in that: described substrate comprises flexible graphite material and is coated in the copper conductive layer on flexible graphite material surface, aluminium conductive layer, plumbous conductive layer or its composite conductive layers, is embedded in aluminium, copper, iron or fortifying fibre at described flexible graphite material.
3. bipolar lead-acid accumulator according to claim 1, is characterized in that: described bipolar lead-acid accumulator can be valve-control sealed bipolar lead-acid accumulator or open type bipolar lead-acid accumulator or colloid bipolar lead-acid accumulator.
4. bipolar lead-acid accumulator according to claim 4, is characterized in that: the barrier film that filled glass fiber or chemical fibre are made in described insulation frame is made as valve-control sealed bipolar lead-acid accumulator.
5. bipolar lead-acid accumulator according to claim 4, is characterized in that: the barrier film that filled plastics plate or rubber slab are made in described insulation frame is made as open type bipolar lead-acid accumulator or colloid bipolar lead-acid accumulator.
CN201410626687.XA 2014-11-10 2014-11-10 Double-polarity lead-acid storage battery Pending CN104332582A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410626687.XA CN104332582A (en) 2014-11-10 2014-11-10 Double-polarity lead-acid storage battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410626687.XA CN104332582A (en) 2014-11-10 2014-11-10 Double-polarity lead-acid storage battery

Publications (1)

Publication Number Publication Date
CN104332582A true CN104332582A (en) 2015-02-04

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Family Applications (1)

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CN201410626687.XA Pending CN104332582A (en) 2014-11-10 2014-11-10 Double-polarity lead-acid storage battery

Country Status (1)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105390753A (en) * 2015-11-10 2016-03-09 山东圣阳电源股份有限公司 Bipolar battery
CN105514444A (en) * 2015-12-15 2016-04-20 常熟市万隆电源技术研发有限公司 Gel-lead acid storage battery grid with high thermal capacity

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1331500A (en) * 2000-06-27 2002-01-16 黄敏方 Flat lead-acid accumulator
CN101227011A (en) * 2008-01-04 2008-07-23 天津市豪升新能源技术研究所 High energy sealed lead sour accumulator for torpedo
CN101719565A (en) * 2009-12-08 2010-06-02 超威电源有限公司 Three-dimensional ambipolar high-power lead storage battery
CN103531820A (en) * 2013-10-09 2014-01-22 广东中商国通电子有限公司 Carbon-based bipolar plate used for lead-acid storage battery and preparation method of the carbon-based bipolar plate

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1331500A (en) * 2000-06-27 2002-01-16 黄敏方 Flat lead-acid accumulator
CN101227011A (en) * 2008-01-04 2008-07-23 天津市豪升新能源技术研究所 High energy sealed lead sour accumulator for torpedo
CN101719565A (en) * 2009-12-08 2010-06-02 超威电源有限公司 Three-dimensional ambipolar high-power lead storage battery
CN103531820A (en) * 2013-10-09 2014-01-22 广东中商国通电子有限公司 Carbon-based bipolar plate used for lead-acid storage battery and preparation method of the carbon-based bipolar plate

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105390753A (en) * 2015-11-10 2016-03-09 山东圣阳电源股份有限公司 Bipolar battery
CN105514444A (en) * 2015-12-15 2016-04-20 常熟市万隆电源技术研发有限公司 Gel-lead acid storage battery grid with high thermal capacity

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Application publication date: 20150204