CN104313601A - 水电解极板表面处理方法 - Google Patents
水电解极板表面处理方法 Download PDFInfo
- Publication number
- CN104313601A CN104313601A CN201410673324.1A CN201410673324A CN104313601A CN 104313601 A CN104313601 A CN 104313601A CN 201410673324 A CN201410673324 A CN 201410673324A CN 104313601 A CN104313601 A CN 104313601A
- Authority
- CN
- China
- Prior art keywords
- board surface
- polar board
- polar plate
- solution
- pole plate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 238000000034 method Methods 0.000 title claims abstract description 30
- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 17
- 238000004381 surface treatment Methods 0.000 title claims abstract description 14
- 238000005260 corrosion Methods 0.000 claims abstract description 34
- 230000007797 corrosion Effects 0.000 claims abstract description 34
- 239000002253 acid Substances 0.000 claims abstract description 26
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 20
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910000975 Carbon steel Inorganic materials 0.000 claims abstract description 14
- 239000010962 carbon steel Substances 0.000 claims abstract description 13
- 229910052742 iron Inorganic materials 0.000 claims abstract description 11
- 229910001431 copper ion Inorganic materials 0.000 claims abstract description 10
- 238000006243 chemical reaction Methods 0.000 claims abstract description 7
- 239000012535 impurity Substances 0.000 claims abstract description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052802 copper Inorganic materials 0.000 claims abstract description 5
- 239000010949 copper Substances 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims abstract description 5
- 239000003518 caustics Substances 0.000 claims description 16
- 230000001681 protective effect Effects 0.000 claims description 14
- 238000005530 etching Methods 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 10
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims description 8
- 238000005649 metathesis reaction Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 238000005342 ion exchange Methods 0.000 claims description 4
- 238000005554 pickling Methods 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 4
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 3
- 239000012964 benzotriazole Substances 0.000 claims description 3
- 239000001509 sodium citrate Substances 0.000 claims description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 3
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims description 3
- 229940038773 trisodium citrate Drugs 0.000 claims description 3
- 239000003513 alkali Substances 0.000 abstract description 3
- 150000002500 ions Chemical class 0.000 abstract description 3
- 239000012530 fluid Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 62
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 28
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 229910052759 nickel Inorganic materials 0.000 description 14
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 12
- 239000012528 membrane Substances 0.000 description 10
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 8
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 239000008139 complexing agent Substances 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 238000007747 plating Methods 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 4
- 239000013543 active substance Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000008151 electrolyte solution Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 229910017604 nitric acid Inorganic materials 0.000 description 4
- 235000006408 oxalic acid Nutrition 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 235000010344 sodium nitrate Nutrition 0.000 description 4
- 239000004317 sodium nitrate Substances 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 230000003628 erosive effect Effects 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 229960004418 trolamine Drugs 0.000 description 3
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- YLIMHFXLIKETBC-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCC[Na] YLIMHFXLIKETBC-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 229960003280 cupric chloride Drugs 0.000 description 2
- WPUMTJGUQUYPIV-JIZZDEOASA-L disodium (S)-malate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](O)CC([O-])=O WPUMTJGUQUYPIV-JIZZDEOASA-L 0.000 description 2
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 2
- -1 iron ion Chemical class 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000003002 pH adjusting agent Substances 0.000 description 2
- 229960004839 potassium iodide Drugs 0.000 description 2
- 235000007715 potassium iodide Nutrition 0.000 description 2
- 235000019265 sodium DL-malate Nutrition 0.000 description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 2
- 239000001394 sodium malate Substances 0.000 description 2
- NGSFWBMYFKHRBD-UHFFFAOYSA-N sodium;2-hydroxypropanoic acid Chemical compound [Na+].CC(O)C(O)=O NGSFWBMYFKHRBD-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000002481 rotproofing Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
Landscapes
- Electroplating Methods And Accessories (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
Description
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410673324.1A CN104313601B (zh) | 2012-12-13 | 2012-12-13 | 水电解极板表面处理方法 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210538399.XA CN103088350B (zh) | 2012-12-13 | 2012-12-13 | 水电解极板表面处理方法 |
CN201410673324.1A CN104313601B (zh) | 2012-12-13 | 2012-12-13 | 水电解极板表面处理方法 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201210538399.XA Division CN103088350B (zh) | 2012-12-13 | 2012-12-13 | 水电解极板表面处理方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104313601A true CN104313601A (zh) | 2015-01-28 |
CN104313601B CN104313601B (zh) | 2016-09-07 |
Family
ID=52368906
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201410673324.1A Active CN104313601B (zh) | 2012-12-13 | 2012-12-13 | 水电解极板表面处理方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN104313601B (zh) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06116734A (ja) * | 1992-10-02 | 1994-04-26 | Mitsui Mining & Smelting Co Ltd | マグネ基合金の高耐食性塗装方法 |
CN1712573A (zh) * | 2004-06-24 | 2005-12-28 | 侯文清 | 铁锰铝合金表面镀层处理方法 |
CN1793425A (zh) * | 2005-12-30 | 2006-06-28 | 东北大学 | 一种金属镁及镁合金表面复合防护的方法 |
CN101760767A (zh) * | 2009-12-03 | 2010-06-30 | 四川长虹电器股份有限公司 | 钢带电镀镍方法 |
CN102021552A (zh) * | 2009-09-21 | 2011-04-20 | 邵阳市创捷化工有限公司 | 一种用于黑色金属表面基体改性剂及其生产方法 |
-
2012
- 2012-12-13 CN CN201410673324.1A patent/CN104313601B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06116734A (ja) * | 1992-10-02 | 1994-04-26 | Mitsui Mining & Smelting Co Ltd | マグネ基合金の高耐食性塗装方法 |
CN1712573A (zh) * | 2004-06-24 | 2005-12-28 | 侯文清 | 铁锰铝合金表面镀层处理方法 |
CN1793425A (zh) * | 2005-12-30 | 2006-06-28 | 东北大学 | 一种金属镁及镁合金表面复合防护的方法 |
CN102021552A (zh) * | 2009-09-21 | 2011-04-20 | 邵阳市创捷化工有限公司 | 一种用于黑色金属表面基体改性剂及其生产方法 |
CN101760767A (zh) * | 2009-12-03 | 2010-06-30 | 四川长虹电器股份有限公司 | 钢带电镀镍方法 |
Also Published As
Publication number | Publication date |
---|---|
CN104313601B (zh) | 2016-09-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103088333B (zh) | 水电解极板表面处理液 | |
CN101638790A (zh) | 镁及镁合金的电镀方法 | |
CN108060442B (zh) | 一种铜铝复合排表面制备锌铜复合镀层的方法 | |
CN102452743A (zh) | 含络合物镀镍废水的处理方法 | |
CN103088358B (zh) | 水电解极板镀覆前的表面处理方法 | |
CN103088375B (zh) | 水电解极板镀镍添加剂 | |
CN102234833B (zh) | 电解退除碳化铬膜层的退镀液及方法 | |
CN103088332A (zh) | 水电解极板表面涂覆液 | |
CN104532267A (zh) | 一种极板表面处理方法 | |
CN103088350B (zh) | 水电解极板表面处理方法 | |
CN104451724B (zh) | 可提高极板镀镍后的耐腐蚀性的水电解极板表面处理方法 | |
CN104313601B (zh) | 水电解极板表面处理方法 | |
CN104313602B (zh) | 可在极板表面形成保护膜的水电解极板表面处理方法 | |
CN104404535B (zh) | 可提高耐腐蚀性的水电解极板表面处理方法 | |
CN104694937B (zh) | 一种循环冷却水微碱化过渡期换热器电化学诱导成膜方法 | |
CN104451707B (zh) | 可形成保护膜的水电解极板表面处理方法 | |
CN104451687B (zh) | 极板表面处理方法 | |
CN104451647B (zh) | 成本较低的水电解极板表面处理方法 | |
CN104532266A (zh) | 耐腐蚀的水电解极板表面处理方法 | |
CN103046051B (zh) | 水电解极板镀覆前的表面腐蚀处理方法 | |
CN100336143C (zh) | 铝电解电容器用负极铝腐蚀箔表面残留铜的去除方法 | |
CN102242367B (zh) | 多功能edta清洗缓蚀剂 | |
CN103498157A (zh) | 在4j34铁镍钴瓷封合金制备镀银层的方法 | |
CN1796616A (zh) | 铁器文物脱氯方法 | |
CN101880871A (zh) | 一种适用于镁合金直接化学镀镍溶液的补加方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C41 | Transfer of patent application or patent right or utility model | ||
CB03 | Change of inventor or designer information |
Inventor after: Lin Binbin Inventor before: The inventor has waived the right to be mentioned |
|
COR | Change of bibliographic data | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20160706 Address after: 325200 Zhejiang city of Wenzhou province Ruian City Feiyun street Ruian station logistics office building 710 Applicant after: Lin Binbin Address before: 213022 Jiangsu Province, Changzhou New District No. -701 26- Ding Long Jin Lu BaiCaoYuan Applicant before: Wu Xiaozai |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee | ||
CP02 | Change in the address of a patent holder |
Address after: 225400 Jiangsu Province, Taixing City Industrial Park Xiangrong Road No. 18 Patentee after: Lin Binbin Address before: 325200 Zhejiang city of Wenzhou province Ruian City Feiyun street Ruian station logistics office building 710 Patentee before: Lin Binbin |
|
TR01 | Transfer of patent right |
Effective date of registration: 20170918 Address after: 225321 Taizhou, Zhejiang Province, high port road, Port Road, Jin Nan Road, No. 2, No. Patentee after: Zhu Haiyan Address before: 225400 Jiangsu Province, Taixing City Industrial Park Xiangrong Road No. 18 Patentee before: Lin Binbin |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20180523 Address after: 737100 Xinhua East Road, Jinchuan District, Jinchang, Gansu Province, No. 38 Patentee after: Jinchang sailing Industry & Trade Co., Ltd. Address before: 225321 2 Port Jinggang Road, Taizhou port, Jiangsu Patentee before: Zhu Haiyan |