CN104312807B - A kind of acid wash bottle additive and application - Google Patents
A kind of acid wash bottle additive and application Download PDFInfo
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- CN104312807B CN104312807B CN201410568833.8A CN201410568833A CN104312807B CN 104312807 B CN104312807 B CN 104312807B CN 201410568833 A CN201410568833 A CN 201410568833A CN 104312807 B CN104312807 B CN 104312807B
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Abstract
The invention provides a kind of acid wash bottle additive and application, the main component of wash bottle additive is low foaming surfactant, chelating agent, antisludging agent, corrosion inhibiter, solubilizer and water composition.Preparation method is that above-mentioned each component is added to the water to be sufficiently mixed uniformly, obtains the homogeneous liquid additive of transparent and stable.Acidity wash bottle additive of the invention is easy to use, be easy to addition.This wash bottle additive is still during whole wash bottle simultaneously；The outer paper mark of bottle can be made to be come off by original state；Without glue trace outside body clear transparent, bottle, noresidue in bottle；Bottle is inside and outside not to be hung to drip in the globule, bottle and is dripped no more than 3 in 5 seconds；Phenolphthalein detection is dripped in bottle in neutrality, beer quality local flavor is not influenceed；De- mark rate is more than 99.5%, and white vase rate is more than 99%.There is special efficacy especially for the dirty bottle of weight, mildew bottle, weathering bottle.
Description
Technical field
The present invention relates to a kind of preparation method and application of wash bottle additive, belong to Beer bottle washing field.
Background technology
Quickly, there is over thousands of family in current domestic large-scale Beer Brewage producer to the industry development such as beer, beverage, produces beer per year in recent years
The kL of wine about 50,000,000, the indivedual breweries of depolarization all using new bottle outside, remaining most of manufacturing enterprise be all using returnable bottle come
It is filling.Therefore wash bottle additive consumption in wash bottle industry is huge.Bottle washing procedure is into the critical process in beer production
One of, cleaning performance directly affects the quality and outward appearance of beer product.Traditional Beer bottle washing uses liquid caustic soda, solid caustic soda or pure
Alkali etc., concentration of lye reaches more than 4%, and returnable bottle percentage of damage remains high, and clean bottle rate is no more than 94%, especially to band glue
The difficult wash bottle of weight dirt of the dirts such as matter, grease, protein, wine dirt is helpless, and there is bottle appearance after laundering and obscure, and washs expense
Height, transports, stores, using dangerous, perishable human body skin, easily make equipment scaling, tests bottle operative's labor intensity greatly,
The problems such as polluting environment.In order to solve the above problems, develop a efficient Detergent power and necessitate.Recent year
Wai Junyou producers develop and produce wash bottle additive, the Detergent power applied in the market, mostly with detergent for household use
Based on formula, it is slightly improved and formed, and it is in the majority with solid alkaline wash bottle additive.Solid alkaline wash bottle additive is used
When need to be first dissolved in working solution, it is impossible to adapt to high-speed automated cleaning line, producer's acceptance is just gradually reduced.Exploitation is a
Efficiently being easy to the liquid acidic wash bottle additive of addition turns into the task of top priority.
Patent CN92104136.5 provides a kind of powder industrial bottle-washing detergent, and patent CN200410077723.8 provides one
The alkaline bottle-washing agent of bi-component is planted, the induced by alkyl hydroxybenzene surface that this 2 patents use current more country to limit or prohibit the use of is lived
Property agent, it is big for environment pollution.And silicone oil defoamer has been used, easily cause cleaning agent residual.Patent CN92104639.1 is carried
A kind of powder bottle washing agent is supplied, the bottle-washing agent foam that the patent is provided is larger, can not meet existing bottle-washing.
The content of the invention
It is an object of the invention to many drawbacks for overcoming existing wash bottle additive, there is provided a kind of highly effective and safe, low bubble, height
The liquid acidic wash bottle additive of dirt-removing power.
The present invention includes wash bottle additive, bottle washing solution and wash bottle method.Bottle washing solution is actual to refer to addition in bottle washing machine
Alkaline solution, bottle washing solution is mixed by wash bottle additive, caustic alkali and water.
A certain amount of deionized water is typically filled in bottle washing machine, bottle washing solution is added thereto, that is, adds sodium hydroxide and this
Liquid acidic wash bottle additive in invention.Bottle washing solution generally comprises the sodium hydroxide and 0.1-1 parts by weight of 1-5 parts by weight
The water of liquid acidic wash bottle additive and 94-98 parts by weight.
A kind of acid wash bottle additive, mainly including following parts by weight raw material composition：Low foaming surfactant 10-20
Part, 5-25 parts of acidizer chelates 2-10 parts of anti-incrustation corrosion inhibitor, 5-20 parts of solubilizer, 25-80 parts of water.
In order to improve wash bottle efficiency and wash bottle cleanliness factor during wash bottle, permeability, the fissility of bottle washing solution need to be increased,
To be effectively improved the scattered removal ability of dirt.In addition to the conventional wash bottle auxiliary agent of addition, add appropriate surfactant to increase
Permeability and fissility are imitated, and accomplishes still to low bubble effect for a long time in the process.
Low foaming surfactant is fat alcohol ethoxyl compound, alcohol ethoxy propoxylated compounds, amino modified
Fat alcohol ethoxyl compound, amino modified alcohol ethoxy propoxylated compounds, low carbon chain APG, decynediol second
One or more mixtures in oxo-compound.
Low foaming surfactant is Triton DF-16, Plurafac LF-403, Plurafac LF-305, Plurafac
LF-221、Plurafac LF-431、Triton CF-32、ED 3060、SL4、NW342、Surfynol DF-110D、
Surfynol465, Skyin2445, Triton XL-100, more preferably Triton DF-16, Plurafac LF-431, SL4.
Wash bottle additive should also include other builders, and conventional builder known in the art is organic acid and/or nothing
Liquid wash bottle additive is directly prepared into using acidizer in the sodium salt of machine acid, the present invention, is added to during use in alkali lye, in
With the corresponding salt of reaction generation, building action is equally played.
Described acidizer is one kind and/or a variety of mixtures in organic acid, inorganic acid.
Described organic acid is specially malic acid, citric acid, fumaric acid, maleic acid, tartaric acid, oxalic acid, citric acid, benzene first
One kind and/or a variety of mixtures in acid, salicylic acid, sulfamic acid.More preferably citric acid, maleic acid, sulfamic acid, grape
Saccharic acid.
Described inorganic acid is specially one kind and/or a variety of mixtures in hydrochloric acid, sulfuric acid, phosphoric acid.More preferably sulphur
Acid and phosphoric acid.
In order to reduce calcium ions and magnesium ions fouling in bottle washing system during wash bottle in the present invention, prevent vial from being lost by alkali lye
Quarter and the precipitation of silica, the dirt produced during scattered wash bottle are not deposited, and the extension wash bottle working solution life-span is, it is necessary to add
Appropriate chelating anti-incrustation corrosion inhibitor.
Described chelating anti-incrustation corrosion inhibitor is in ATMP, HEDP, NTA, gluconic acid sodium salt, glucoheptose sodium, PAAS, AA/AMPS
One kind and/or a variety of mixtures.More preferably ATMP, gluconic acid sodium salt, glucoheptose sodium.
In order to promote the stabilization of wash bottle additive in the present invention, it should also include a certain amount of water-soluble growth regulator, i.e., it is solubilized
Agent.
Described solubilizer is p-methyl benzenesulfonic acid, paratoluenesulfonic acid sodium salt, sodium xylene sulfonate, isopropanol, Triton H-
66th, one kind and/or a variety of mixtures in Triton QS-44.More preferably p-methyl benzenesulfonic acid and Serdox NAL.
The invention provides a kind of preparation method of acid wash bottle additive, by low foaming surfactant, acidizer, chelating
Anti-incrustation corrosion inhibitor, solubilizer and water are uniformly mixed to get homogeneous phase transparent liquid according to a certain percentage.
Using application of the acid wash bottle additive on washing beer bottle made from above-mentioned formula and method.
By weight, 0.1-1 parts of liquid acidic wash bottle additive, 1-5 parts of sodium hydroxide, 94-98 parts of water, by the reagent
It is directly appended to be applied in bottle washing machine in alkaline working solution after mixing.
The present invention has following remarkable advantage as wash bottle additive compared with existing commercially available bottle-washing agent：
1. a wash bottle additive is liquid acidic wash bottle additive is easy to use, be easy to addition.
2. a wash bottle additive reaches still during whole wash bottle, foam is not had and spills over working site, effectively into
Divide to be present in working solution for a long time, there is the very long wash bottle life-span.
3. a wash bottle additive can make the outer paper mark of bottle be come off by original state, body clear transparent, bottle is outer without glue trace, and bottle is interior without residual
Stay, the globule is not hung inside and outside bottle, beer quality local flavor is not influenceed.
4. de- mark rate is more than 99.5%, white vase rate is more than 99%.There is spy especially for the dirty bottle of weight, mildew bottle, weathering bottle
Effect.
5. highly effective chelating agent can prevent alkali groove fouling, high active substance can make wash bottle temperature reduce 10-15 DEG C, and bottle-washing agent is changed
The groove cycle extends 5 days or so on the original basis, and energy conservation and consumption reduction effects are notable.As existing wash bottle producer preferred product.
Embodiment
The present invention is described further for following examples
Embodiment 1
| Sequence number | Raw material | Consumption/% |
| 1 | Triton DF-16 | 10 |
| 2 | Citric acid | 5 |
| 3 | 85% phosphoric acid | 20 |
| 4 | ATMP | 2 |
| 5 | Paratoluenesulfonic acid sodium salt | 5 |
| 6 | Deionized water | Surplus |
Embodiment 2
| Sequence number | Raw material | Consumption/% |
| 1 | Triton DF-16 | 15 |
| 2 | Plurafac LF-403 | 3 |
| 3 | Maleic acid | 2 |
| 4 | Sulfuric acid | 4 |
| 5 | 85% phosphoric acid | 15 |
| 6 | Gluconic acid sodium salt | 2 |
| 7 | HEDP | 1 |
| 8 | Paratoluenesulfonic acid sodium salt | 15 |
| 9 | Isopropanol | 3 |
| 10 | Deionized water | Surplus |
Embodiment 3
| Sequence number | Raw material | Consumption/% |
| 1 | Plurafac LF-221 | 8 |
| 2 | Plurafac LF-431 | 5 |
| 3 | Surfynol DF-110D | 2 |
| 4 | Sulfamic acid | 3 |
| 5 | 85% phosphoric acid | 15 |
| 6 | Glucoheptose sodium | 3 |
| 7 | PAAS | 6 |
| 8 | Triton H-66 | 10 |
| 8 | Deionized water | Surplus |
Embodiment 4
| Sequence number | Raw material | Consumption/% |
| 1 | ED 3060 | 15 |
| 2 | Skyin 2445 | 5 |
| 3 | Benzoic acid | 5 |
| 4 | 85% phosphoric acid | 20 |
| 5 | ATMP | 2 |
| 6 | Triton QS-44 | 10 |
| 7 | Deionized water | Surplus |
Embodiment 5
| Sequence number | Raw material | Consumption/% |
| 1 | SL4 | 5 |
| 2 | NW 342 | 13 |
| 3 | Citric acid | 5 |
| 4 | Sulfuric acid | 2 |
| 5 | ATMP | 3 |
| 6 | NTA | 2 |
| 7 | Triton H-55 | 12 |
| 8 | Deionized water | Surplus |
Embodiment 6
| Sequence number | Raw material | Consumption/% |
| 1 | Surfynol 465 | 5 |
| 2 | Triton CF-32 | 13 |
| 3 | Citric acid | 5 |
| 4 | Maleic acid | 2 |
| 5 | 85% phosphoric acid | 10 |
| 6 | Sulfuric acid | 2 |
| 7 | NTA | 3 |
| 8 | Sodium xylene sulfonate | 13 |
| 9 | Deionized water | Surplus |
Embodiment 7
| Sequence number | Raw material | Consumption/% |
| 1 | Plurafac LF-431 | 15 |
| 2 | SL4 | 2 |
| 3 | Octanoic acid | 2 |
| 4 | Capric acid | 3 |
| 5 | Citric acid | 5 |
| 6 | 85% phosphoric acid | 12 |
| 7 | Gluconic acid sodium salt | 6 |
| 8 | Serdox NHL | 14 |
| 9 | Deionized water | Surplus |
Embodiment 8
| Sequence number | Raw material | Consumption/% |
| 1 | Plurafac LF-305 | 12 |
| 2 | Plurafac LF-431 | 3 |
| 3 | Octanoic acid | 2 |
| 4 | Maleic acid | 3 |
| 5 | Sulfuric acid | 7 |
| 6 | 85% phosphoric acid | 13 |
| 7 | Glucoheptose sodium | 5 |
| 8 | AA/AMPS | 2 |
| 9 | Isopropanol | 10 |
| 10 | Deionized water | Surplus |
Embodiment 9
| Sequence number | Raw material | Consumption/% |
| 1 | Plurafac LF-221 | 3 |
| 2 | Plurafac LF-403 | 9 |
| 3 | Triton DF-16 | 5 |
| 4 | N-nonanoic acid | 2 |
| 5 | Laurate | 4 |
| 6 | 85% phosphoric acid | 11 |
| 7 | Gluconic acid sodium salt | 5 |
| 8 | Serdox NAL | 16 |
| 9 | Deionized water | Surplus |
Embodiment 10
| Sequence number | Raw material | Consumption/% |
| 1 | Triton XL-100 | 10 |
| 2 | Surfynol DF-110D | 2 |
| 3 | Citric acid | 5 |
| 4 | Octanoic acid | 3 |
| 5 | 85% phosphoric acid | 16 |
| 6 | Gluconic acid sodium salt | 3 |
| 7 | HEDP | 2 |
| 8 | P-methyl benzenesulfonic acid | 15 |
| 9 | Deionized water | Surplus |
In order to verify the actual effect of the present invention, above-described embodiment product is added in bottle washing machine and verified.Alkali
Liquid recommended density 2-3%, actual use concentration 2.5%, wash bottle additive recommended density 0.1%-1%, actual use concentration
0.3%.75-85 DEG C of wash bottle temperature.
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, although with reference to compared with
The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to skill of the invention
Art scheme is modified or equivalent substitution, and without departing from the objective and scope of technical solution of the present invention, it all should cover at this
Among the right of invention.
Claims (3)
1. a kind of acid wash bottle additive for washing beer bottle, it is characterised in that mainly the raw material including following parts by weight is constituted：
2. a kind of acid wash bottle additive for washing beer bottle, it is characterised in that mainly the raw material including following parts by weight is constituted：
3. a kind of acid wash bottle additive for washing beer bottle, it is characterised in that mainly the raw material including following parts by weight is constituted：
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410568833.8A CN104312807B (en) | 2014-10-23 | 2014-10-23 | A kind of acid wash bottle additive and application |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410568833.8A CN104312807B (en) | 2014-10-23 | 2014-10-23 | A kind of acid wash bottle additive and application |
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| CN104312807A CN104312807A (en) | 2015-01-28 |
| CN104312807B true CN104312807B (en) | 2017-09-05 |
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Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104946437A (en) * | 2015-05-18 | 2015-09-30 | 安徽省华凯轻工科技有限公司 | Cleaning agent special for beer bottles and preparation method of cleaning agent |
| CN105154246A (en) * | 2015-09-18 | 2015-12-16 | 上海升阶化工科技有限公司 | Environment-friendly public place heavy-dirt detergent |
| CN107652897A (en) * | 2016-07-26 | 2018-02-02 | 中万恩科技有限公司 | A kind of drying brightener |
| CN106995750A (en) * | 2017-04-11 | 2017-08-01 | 冯恩芳 | A kind of low alkaline Retrieve beer bottle special purpose detergent |
| CN108559653A (en) * | 2018-05-18 | 2018-09-21 | 北京安洁康生物科技有限公司 | A kind of liquid removes mould wash bottle additive and its methods for making and using same |
| CN109112002B (en) * | 2018-09-26 | 2020-12-22 | 蓝思科技（长沙）有限公司 | Cleaning agent for cleaning dirt after glass deplating electroplated layer, cleaning method and electronic product |
| CN110846143A (en) * | 2019-11-26 | 2020-02-28 | 河南昊化黎明智能清洗科技有限公司 | Bottle washing additive and preparation method thereof |
| CN111117800A (en) * | 2019-12-26 | 2020-05-08 | 南京巨鲨显示科技有限公司 | Biological membrane removing cleaning agent and preparation method thereof |
| CN112980593A (en) * | 2021-02-08 | 2021-06-18 | 辽宁大学 | Active descaling powder |
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| CN1224458A (en) * | 1996-04-09 | 1999-07-28 | 尤尼利弗公司 | Anti-etch bottle washing solution |
| CN1597893A (en) * | 2003-09-16 | 2005-03-23 | 刘仁豪 | Composition of detergent |
| CN103154221A (en) * | 2010-11-11 | 2013-06-12 | 艺康股份有限公司 | Process for cleaning and label removal for bottles |
| CN103849498A (en) * | 2012-11-29 | 2014-06-11 | 埃科莱布美国股份有限公司 | Cleaning additive and cleaning method adopting the cleaning additive |
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2014
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1224458A (en) * | 1996-04-09 | 1999-07-28 | 尤尼利弗公司 | Anti-etch bottle washing solution |
| CN1597893A (en) * | 2003-09-16 | 2005-03-23 | 刘仁豪 | Composition of detergent |
| CN103154221A (en) * | 2010-11-11 | 2013-06-12 | 艺康股份有限公司 | Process for cleaning and label removal for bottles |
| CN103849498A (en) * | 2012-11-29 | 2014-06-11 | 埃科莱布美国股份有限公司 | Cleaning additive and cleaning method adopting the cleaning additive |
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