CN104312053A - Green and environment-friendly PVC (polyvinyl chloride) wood-plastic composite material and preparation method thereof - Google Patents
Green and environment-friendly PVC (polyvinyl chloride) wood-plastic composite material and preparation method thereof Download PDFInfo
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- CN104312053A CN104312053A CN201410618291.0A CN201410618291A CN104312053A CN 104312053 A CN104312053 A CN 104312053A CN 201410618291 A CN201410618291 A CN 201410618291A CN 104312053 A CN104312053 A CN 104312053A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses a green and environment-friendly PVC (polyvinyl chloride) wood-plastic composite material. The green and environment-friendly PVC wood-plastic composite material is prepared from the following raw materials in parts by weight: 15-20 parts of pine needle meal, 5-10 parts of licorice powder, 10-15 parts of bamboo powder, 3-5 parts of cassava starch, 5-10 parts of turf, 60-80 parts of PVC SG-7, 8-10 parts of epoxidized soybean oil, 2-4 parts of liquid paraffin, 1-2 parts of decyl polyglucoside, 3-5 parts of camellia oil, 3-5 parts of barium-zinc compound stabilizer, 1-2 parts of AC foaming agent, 2-4 parts of a foaming modifier and 3-5 parts of a compound additive. The wood-plastic composite material disclosed by the invention adopts environment-friendly and nontoxic raw materials, and is safe and pollution-free; the product has good physical and mechanical properties, is pollution-free to the environment, and accords with the requirements of energy conservation, emission reduction and environmental protection.
Description
Technical field
The present invention relates to technical field of composite materials, be specifically related to a kind of environmental protection PVC wood plastic composite material and preparation method thereof.
Background technology
Wood plastic composite is a kind of emerging matrix material, for main raw material with xylon or vegetable fibre, fill, strengthen, through hot pressing compound, the modified thermoplastic material that different processing mode makes such as to melt extrude, be mainly used in the industries such as building materials, furniture, logistics packaging.Wood plastic composite has merged the two-fold advantage of " wood " and " moulding ", the use limitation that can overcome because strength of wood is low, the large and organic materials Young's modulus of variability is low etc. causes, discarded timber and plastics can be made full use of again, energy-saving and emission-reduction, reduce environmental pollution, promoting the value added of material, is a kind of type material having development prospect.Especially along with the increase of minimizing and the demand day by day of natural resource, the Application Areas of wood plastic composite constantly expands, and state of the art is upgraded thereupon, and market outlook are very wide.
Summary of the invention
The object of this invention is to provide a kind of environmental protection PVC wood plastic composite material.
The present invention is achieved by the following technical solutions:
A kind of environmental protection PVC wood plastic composite material, it is characterized in that, it is obtained by the raw material of following weight parts:
Pine needle powder 15-20, licorice powder 5-10, bamboo powder 10-15, tapioca (flour) 3-5, peat composed of rotten mosses 5-10, PVC SG-7 60-80, epoxy soybean oil 8-10, whiteruss 2-4, lauryl glucosyl 1-2, Camellia oil 3-5, barium zinc composite stabilizer 3-5, AC whipping agent 1-2, foaming control agent 2-4, composite assistant 3-5;
Wherein composite assistant is made up of the raw material of following weight part:
Nano zine oxide 8-10, nano aluminium oxide 4-6, nano silicon 3-5, antimonous oxide 3-5, trolamine 2-4, white mineral oil 4-6, sweet oil 6-10, Weibull 0.3-0.5, glyceryl monostearate 1-2, aluminate coupling agent 2-4;
Wherein the preparation method of composite assistant is:
Nano zine oxide, nano aluminium oxide, nano silicon and antimonous oxide are added ultrasonic disperse 10-15min in ethanol in proper amount, add Weibull, trolamine and aluminate coupling agent 200-400r/min again and stir 0.5-1h, filter and wash, add white mineral oil, sweet oil and glyceryl monostearate 80-90 DEG C after vacuum-drying, 800-1000r/min stirs 2-4h, wash drying after filtration, to obtain final product.
A preparation method for environmental protection PVC wood plastic composite material, it comprises the following steps:
(1) grinding of whiteruss, lauryl glucosyl and Camellia oil will be added after pine needle powder, licorice powder, bamboo powder, tapioca (flour) and the abundant drying of the peat composed of rotten mosses evenly, then in 80-90 DEG C, stir 0.5-1h under 800-1000r/min condition, obtain mixed fillers;
(2) jointly high mixer is added after being mixed with PVC SG-7, epoxy soybean oil and composite assistant by the mixed fillers obtained in (1), prior to 80-90 DEG C of high-speed mixing 20-30min, add all the other raw materials 120-140 DEG C of high-speed mixing 10-15min again, add extrusion moulding in screw extrusion press subsequently, finally carry out surface treatment, get product.
Advantage of the present invention is:
1. the present invention adopts the starting material of environment-protecting asepsis, safety nuisance free, and product has excellent physical and mechanical properties, and environmentally safe, meet the requirement of energy-saving and emission-reduction and environmental protection;
2., by adding composite assistant, make product have excellent germ resistance, resistance to deterioration and creep resistance, steady quality, long service life.
Embodiment
Non-limiting examples of the present invention is as follows:
A kind of environmental protection PVC wood plastic composite material, is prepared from by the component raw material of following weight (kg):
Pine needle powder 18, licorice powder 8, bamboo powder 12, tapioca (flour) 4, the peat composed of rotten mosses 6, PVC SG-7 70, epoxy soybean oil 9, whiteruss 3, lauryl glucosyl 1.5, Camellia oil 4, barium zinc composite stabilizer 4, AC whipping agent 1.5, foaming control agent 3, composite assistant 4;
Wherein, composite assistant is made up of the raw material of following weight (kg):
Nano zine oxide 9, nano aluminium oxide 5, nano silicon 4, antimonous oxide 4, trolamine 3, white mineral oil 5, sweet oil 8, Weibull 0.4, glyceryl monostearate 1.5, aluminate coupling agent 3;
The preparation method of composite assistant:
Nano zine oxide, nano aluminium oxide, nano silicon and antimonous oxide are added ultrasonic disperse 10min in ethanol in proper amount, add Weibull, trolamine and aluminate coupling agent 400r/min again and stir 0.5h, filter and wash, add white mineral oil, sweet oil and glyceryl monostearate 90 DEG C after vacuum-drying, 1000r/min stirs 3h, wash drying after filtration, to obtain final product.
The preparation method of environmental protection PVC wood plastic composite material comprises the following steps:
(1) grinding of whiteruss, lauryl glucosyl and Camellia oil will be added after pine needle powder, licorice powder, bamboo powder, tapioca (flour) and the abundant drying of the peat composed of rotten mosses evenly, then in 90 DEG C, stir 0.5h under 1000r/min condition, obtain mixed fillers;
(2) jointly high mixer is added after being mixed with PVC SG-7, epoxy soybean oil and composite assistant by the mixed fillers obtained in (1), prior to 90 DEG C of high-speed mixing 20min, add all the other raw materials 140 DEG C of high-speed mixing 15min again, add extrusion moulding in screw extrusion press subsequently, finally carry out surface treatment, get product.
It is as follows that the present embodiment product presses GB/T 29418-2012 standard detection performance index:
Tensile strength: 23.3MPa, flexural strength: 28.1MPa.
Claims (2)
1. an environmental protection PVC wood plastic composite material, is characterized in that, it is obtained by the raw material of following weight parts:
Pine needle powder 15-20, licorice powder 5-10, bamboo powder 10-15, tapioca (flour) 3-5, peat composed of rotten mosses 5-10, PVC SG-7 60-80, epoxy soybean oil 8-10, whiteruss 2-4, lauryl glucosyl 1-2, Camellia oil 3-5, barium zinc composite stabilizer 3-5, AC whipping agent 1-2, foaming control agent 2-4, composite assistant 3-5;
Described composite assistant is made up of the raw material of following weight part:
Nano zine oxide 8-10, nano aluminium oxide 4-6, nano silicon 3-5, antimonous oxide 3-5, trolamine 2-4, white mineral oil 4-6, sweet oil 6-10, Weibull 0.3-0.5, glyceryl monostearate 1-2, aluminate coupling agent 2-4;
The preparation method of described composite assistant is:
Nano zine oxide, nano aluminium oxide, nano silicon and antimonous oxide are added ultrasonic disperse 10-15min in ethanol in proper amount, add Weibull, trolamine and aluminate coupling agent 200-400r/min again and stir 0.5-1h, filter and wash, add white mineral oil, sweet oil and glyceryl monostearate 80-90 DEG C after vacuum-drying, 800-1000r/min stirs 2-4h, wash drying after filtration, to obtain final product.
2. the preparation method of a kind of environmental protection PVC wood plastic composite material according to claim 1, is characterized in that, comprise the following steps:
(1) grinding of whiteruss, lauryl glucosyl and Camellia oil will be added after pine needle powder, licorice powder, bamboo powder, tapioca (flour) and the abundant drying of the peat composed of rotten mosses evenly, then in 80-90 DEG C, stir 0.5-1h under 800-1000r/min condition, obtain mixed fillers;
(2) jointly high mixer is added after being mixed with PVC SG-7, epoxy soybean oil and composite assistant by the mixed fillers obtained in (1), prior to 80-90 DEG C of high-speed mixing 20-30min, add all the other raw materials 120-140 DEG C of high-speed mixing 10-15min again, add extrusion moulding in screw extrusion press subsequently, finally carry out surface treatment, get product.
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CN201410618291.0A CN104312053A (en) | 2014-11-06 | 2014-11-06 | Green and environment-friendly PVC (polyvinyl chloride) wood-plastic composite material and preparation method thereof |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107586463A (en) * | 2017-10-09 | 2018-01-16 | 泰力(安徽)电器股份有限公司 | A kind of preparation method of switch panel production base-material heating fumigating material |
CN108912541A (en) * | 2018-06-22 | 2018-11-30 | 安徽索亚装饰材料有限公司 | A kind of Wood-plastic foam material with good impact strength |
CN109370064A (en) * | 2018-10-15 | 2019-02-22 | 道高分子聚合物(宁波)有限公司 | A kind of plastic cement race track resin particle and preparation method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1475339A (en) * | 2002-08-15 | 2004-02-18 | 孙建宁 | Flame-retardant antistatic polyvinyl chloride composite pipe and preparation method thereof |
CN101955614A (en) * | 2010-02-22 | 2011-01-26 | 成都奥金希斯科技股份有限公司 | Novel wood plastic composite decorative building material and manufacturing method thereof |
RU2011154172A (en) * | 2011-12-29 | 2013-07-10 | ООО "Башпласт" | ELECTRIC INSULATION COMPOSITION |
CN103897262A (en) * | 2012-12-27 | 2014-07-02 | 浙江艾迪雅科技股份有限公司 | Low cost and high efficient soundproof material and manufacturing method thereof |
-
2014
- 2014-11-06 CN CN201410618291.0A patent/CN104312053A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1475339A (en) * | 2002-08-15 | 2004-02-18 | 孙建宁 | Flame-retardant antistatic polyvinyl chloride composite pipe and preparation method thereof |
CN101955614A (en) * | 2010-02-22 | 2011-01-26 | 成都奥金希斯科技股份有限公司 | Novel wood plastic composite decorative building material and manufacturing method thereof |
RU2011154172A (en) * | 2011-12-29 | 2013-07-10 | ООО "Башпласт" | ELECTRIC INSULATION COMPOSITION |
CN103897262A (en) * | 2012-12-27 | 2014-07-02 | 浙江艾迪雅科技股份有限公司 | Low cost and high efficient soundproof material and manufacturing method thereof |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107586463A (en) * | 2017-10-09 | 2018-01-16 | 泰力(安徽)电器股份有限公司 | A kind of preparation method of switch panel production base-material heating fumigating material |
CN108912541A (en) * | 2018-06-22 | 2018-11-30 | 安徽索亚装饰材料有限公司 | A kind of Wood-plastic foam material with good impact strength |
CN109370064A (en) * | 2018-10-15 | 2019-02-22 | 道高分子聚合物(宁波)有限公司 | A kind of plastic cement race track resin particle and preparation method thereof |
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Application publication date: 20150128 |