CN104311971A - Multi-metal anti-rusting master batch as well as preparation method and application thereof - Google Patents

Multi-metal anti-rusting master batch as well as preparation method and application thereof Download PDF

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CN104311971A
CN104311971A CN201410629005.0A CN201410629005A CN104311971A CN 104311971 A CN104311971 A CN 104311971A CN 201410629005 A CN201410629005 A CN 201410629005A CN 104311971 A CN104311971 A CN 104311971A
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rust
master batch
rusting
many metal
composite
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CN104311971B (en
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李文强
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QINGDAO XIN SURPLUS XIN PACKING MATERIAL CO., LTD.
Qingdao University of Science and Technology
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QINGDAO XIN SURPLUS XIN PACKING MATERIAL Co Ltd
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    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08K13/02—Organic and inorganic ingredients
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    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
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    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
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    • C08K5/00—Use of organic ingredients
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    • C08K5/20—Carboxylic acid amides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3472—Five-membered rings
    • C08K5/3475—Five-membered rings condensed with carbocyclic rings
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/55—Boron-containing compounds
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    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
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    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
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    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/08—Copolymers of ethene
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
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    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
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    • C08K2201/005—Additives being defined by their particle size in general
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    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films
    • C—CHEMISTRY; METALLURGY
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    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
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    • C08L2207/06—Properties of polyethylene
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  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

The invention discloses multi-metal anti-rusting master batch as well as a preparation method and application thereof. The anti-rusting master batch comprises the following components in percentage by mass: 30-50% of a compounded anti-rusting agent, 40-60% of carrier plastic and 10-20% of an additive, wherein the compounded anti-rusting agent is prepared by mixing sodium benzoate, sebacic acid, triethanolamine boric acid ester and benzotriazole in a mass ratio of (1-1.3):(1.1-1.5):(2.2-3.2):(0.8-1.2); the additive is prepared by mixing stearic acid amino, coarse whiting, sucrose fatty acid ester and an antioxidant 1076 in a mass ratio of (0.9-1.3):(4.8-6.5):(2.5-3.3):(0.8-1.1). When being used as an additive, the triethanolamine boric acid ester has both a dispersion function and an anti-rusting function, the compounded anti-rusting agent has certain polarity and can penetrate the carrier plastic to be volatilized to the surface of packaged metal to form a protecting film, so that corrosion of external corrosive substances is prevented, and the phenomenon that frost separation is generated as the compounded anti-rusting agent is not compatible with the carrier plastic because of the too high polarity is avoided. The multi-metal anti-rusting master batch is free of harmful component, is environment-friendly and safe to use, and has the anti-rusting function on multiple metals.

Description

Many metal anti-rust master batch and its preparation method and application
Technical field:
The present invention relates to and adapt to the nontoxic volatile rust prevention field of plastic products of various metals goods, refer to a kind of many metal anti-rust master batch and preparation method thereof and embody rule particularly.
Background technology:
Corrosion of metal relates to the common problem of national economy every field, it is because oxygen and water act on the electrochemical process that metallic surface generates oxide compound and hydroxide mixture, have high risks to the performance of metal and goods thereof and value, can cause a serious accident time serious causes equipment scrapping.Metal and goods thereof, in production, transport and storage process, in the overland transport process that transport especially at sea and high upsurge wet, inevitably meet with corrosion and corrosion occur.According to statistics, within 2005, the annual financial loss caused because of corrosion of China is more than 36,000,000,000 yuan, and its harm is very serious.It is at present conventional that to smear antirust grease owned by France antirust in contact; not only loaded down with trivial details, consuming time bothersome, the poor effect of technique; but also need to carry out cleaning by degreasing operation before unpacking; very easily cause the secondary pollution of environment; and those are not reached to turning, the position, gap of slushing oil; then can not form effective corrosion protection, this method more and more can not accept by people.Then cost is higher to adopt vacuum-packing method, and for extremely difficult reality large-scale workpiece.Although the antirust cost of siccative is lower, easy to use, affected by environment comparatively large, effect is difficult to ensure.
Vapor phase inhibitor technology (i.e. VCI technology, VCI is the abbreviation of English Volatile Corrosion Inhibitor) is one of current untouchable antirust important method.It utilizes vapour-phase inhibitor automatically to volatilize gas at normal temperatures and forms layer protecting film in metallic surface; inhibit the generation of electrochemical reaction; also block some simultaneously and accelerate metal eroding substance to the erosion of metallic surface, thus slow down or stop metallic surface corrosion.Vapor phase inhibitor technology has environmental friendliness, easy to use, the clean feature such as clean, is widely used in the rust protection of the links such as metal and production of articles, transport and storage in recent years.Domestic based on vapor phase inhibitor technology exploitation volatile rust prevention product also often have report, be particularly the gas-phase antirusting film that the carrier of vapor phase inhibitor is produced with plastics, have transparent, pliable and tough, can machine-shaping, barrier high.But gas-phase antirusting film conventional at present has blown film type and application type, but their equal existing defects, in the former gas-phase antirusting film disclosed in CN01128198.7, CN01127534.0, all containing the strong carcinogen nitrite forbidden in the world in vapour-phase inhibitor component, and in technique disclosed in CN01127534.0, vapour-phase inhibitor is directly joined blown film in resin, owing to not carrying out mixing pre-treatment, vapour-phase inhibitor size distribution is uneven, and gained membrane product there will be surface irregularity and analyses white phenomenon; Latter take plastic film as base material; to coat on plastics film after inhibiter and caking agent mixing; not only energy consumption is large for this; complex procedures; more can not cleaner production; also easily affect rust-proof effect because mixing uneven, the antirust film of this kind of technique gained only has rust inhibition to ferrous metal, and lacks coloured or many metallic combinations part and even do not have defencive function.
This shows, development and production one all has excellent rust-proof effect to multiple many metals, and with environmental friendliness, easy and simple to handle, rakish gas-phase antirusting film, seem particularly urgent to solving the corrosion of metal problem relating to national economy, developing high-quality and efficient gas-phase anti-rust master batch is then realize the most basic approach of these needs and key point.
Boric acid is combined with Sauerstoffatom with SP2 hydridization due to each boron atom, and boron is still electron deficiency, be easy to react with organic alcohols compound generate perborate tetrahydrate monoesters, dibasic acid esters, three esters and four replace spirane structure.Boric acid ester has the performances such as good lubrication, antirust, sterilization, and to the effect of human non-toxic's evil.But just at present, as a kind of desirable environmental type additive, boric acid ester is mainly used in water-base cutting fluid field (Li Wei, Ma Tao, Wang Sen, Tan Hailin. the application of boric acid ester in water-base cutting fluid. tool technique, 2010, 44 (5): 93-95.), play extreme pressure lubricant respectively, tensio-active agent, rust-preventive agent, the effect of anticorrosion and bactericidal agent, and they yet there are no as additive and relate in vapor phase inhibitor technology, especially yet there are no about with nontoxic inorganic salt, organic amine boric acid ester is the report of the gas-phase anti-rust master batch of compound corrosion inhibitor and its preparation method and application aspect.
Summary of the invention:
The object of the invention is to solve deficiency of the prior art, a kind of many metal gas-phase anti-rust master batch and its preparation method and application are provided.
For achieving the above object, the many metal anti-rust master batch of one provided by the invention, is characterized in that the percent mass accounting of each component in described anti-rust master batch is: 35 ~ 50% composite rust-preventive agent, 40 ~ 80% carrier plastics and 10 ~ 20% auxiliary agents; The ratio that described composite rust-preventive agent is 1 ~ 1.3:1.1 ~ 1.5:2.2 ~ 3.2:0.8 ~ 1.2 by Sodium Benzoate, sebacic acid sodium, triethanolamine borate, benzotriazole in mass ratio mixes; The ratio that described auxiliary agent is 0.9 ~ 1.3:4.8 ~ 6.5:2.5 ~ 3.3:0.8 ~ 1.1 by stearic acid amide, water-ground limestone, sucrose fatty ester, antioxidant 1076 in mass ratio mixes.
Further, the ratio that described composite rust-preventive agent is 1:1.2:3:0.9 by Sodium Benzoate, sebacic acid sodium, triethanolamine borate, benzotriazole in mass ratio mixes; The ratio that described auxiliary agent is 1:5.5:3:1 by stearic acid amide, water-ground limestone, sucrose fatty ester, antioxidant 1076 in mass ratio mixes.
Further, the polyethylene of described carrier plastics to be density be 0.90 ~ 0.96g/cm.
Further, described carrier plastics is one or both the mixture in Low Density Polyethylene, linear low density polyethylene.
Further, the particle diameter of described composite rust-preventive agent is 800 ~ 2800 orders.
Further, the particle diameter of described composite rust-preventive agent is 900 ~ 1100 orders.
Prepare a method for above-mentioned many metal anti-rust master batch, comprise the following steps: (a) by described quality proportioning by composite rust-preventive agent, carrier plastics and auxiliary agent high-speed mixing 4 ~ 5 minutes obtained compounds; B () mediates gained compound, melting treatment, and mixing under 150 ~ 180 DEG C of temperature condition, plasticizing is afterwards extruded, obtained described many metal anti-rust master batch.
An application for above-mentioned many metal anti-rust master batch, comprises the following steps: described anti-rust master batch adds in the raw material of thermoplastics according to the ratio that mass ratio is 1:25 ~ 50 by (a), fully stirs and makes composite grain; (b) again by described composite grain antirust plastic composite grain through blown film or film, be processed into gas-phase antirusting film wrapping material.
Beneficial effect of the present invention is mainly reflected in: provide a kind of many metal gas-phase anti-rust master batch, first by the composite rust-preventive agent of triethanolamine borate for the preparation of anti-rust master batch, it not only has dissemination but also play rust-proof effect, and produce synergistic effects between other three kinds of inhibiter components, strengthen rustless property.The compound corrosion inhibitor adopted is Sodium Benzoate, sebacic acid sodium, triethanolamine borate, benzotriazole mixture about powder particle diameter is 1000 orders.This mixed inhibitor had both had certain polarity; carrier plastics can be penetrated and evaporate into packaged metallic surface formation protective membrane; intercept the erosion of extraneous corrosive deposit; also can not cross strong and incompatible and analyse white phenomenon with carrier plastics because its polarity; and not containing nitrite unwanted component; enable the corresponding many metal anti-rust master batch of gained be applicable to more metal types, use Environmental Safety more.
Embodiment:
For understanding the present invention further, below in conjunction with embodiment, the invention will be further described, but and do not limit the present invention in any way.
The preparation method that many metal gas-phase anti-rust master batch in following embodiment adopt, comprise following concrete steps: composite rust-preventive agent, carrier plastics and auxiliary agent are poured in plastic high-speed mixer by described quality proportioning by (a), high-speed mixing 4 ~ 5 minutes obtained compounds; B () is mediated by Double-rotor continuous mixing tablets press gained compound, melting treatment, and mixing under 150 ~ 180 DEG C of temperature condition, plasticizing is afterwards extruded, obtained described many metal anti-rust master batch.
Embodiment 1:
Many metal anti-rust master batch a, wherein the percent mass accounting of each component is: 35% composite rust-preventive agent, 45% carrier plastics and 20% auxiliary agent; Described composite rust-preventive agent is by Sodium Benzoate, sebacic acid sodium, triethanolamine borate, benzotriazole in mass ratio for the ratio of 1:1.2:3:0.9 mixes, and the particle diameter of composite rust-preventive agent is 900 ~ 1100 orders; The ratio that described auxiliary agent is 1:5.5:3:1 by stearic acid amide, water-ground limestone, sucrose fatty ester, antioxidant 1076 in mass ratio mixes.
Embodiment 2:
Many metal anti-rust master batch b, wherein the percent mass accounting of each component is 40% composite rust-preventive agent, 45% carrier plastics and 15% auxiliary agent; Described composite rust-preventive agent is by Sodium Benzoate, sebacic acid sodium, triethanolamine borate, benzotriazole in mass ratio for the ratio of 1:1.2:3:0.9 mixes, and the particle diameter of composite rust-preventive agent is 900 ~ 1100 orders; The ratio that described auxiliary agent is 1:5.5:3:1 by stearic acid amide, water-ground limestone, sucrose fatty ester, antioxidant 1076 in mass ratio mixes.
Embodiment 3:
Many metal anti-rust master batch c, wherein the percent mass accounting of each component is: 42% composite rust-preventive agent, 46% carrier plastics and 12% auxiliary agent; Described composite rust-preventive agent is by Sodium Benzoate, sebacic acid sodium, triethanolamine borate, benzotriazole in mass ratio for the ratio of 1:1.2:3:0.9 mixes, and the particle diameter of composite rust-preventive agent is 900 ~ 1100 orders; The ratio that described auxiliary agent is 1:5.5:3:1 by stearic acid amide, water-ground limestone, sucrose fatty ester, antioxidant 1076 in mass ratio mixes.。
Embodiment 4:
Many metal anti-rust master batch d, wherein the percent mass accounting of each component is: 38% composite rust-preventive agent, 49% carrier plastics and 13% auxiliary agent; Described composite rust-preventive agent is by Sodium Benzoate, sebacic acid sodium, triethanolamine borate, benzotriazole in mass ratio for the ratio of 1:1.2:3:0.9 mixes, and the particle diameter of composite rust-preventive agent is 900 ~ 1100 orders; The ratio that described auxiliary agent is 1:5.5:3:1 by stearic acid amide, water-ground limestone, sucrose fatty ester, antioxidant 1076 in mass ratio mixes.
Embodiment 5 effect test example
By embodiment 1,2,3, the anti-rust master batch of 4 gained adds in the raw material of thermoplastics according to the ratio that mass ratio is 1:25 ~ 50, fully stirs and makes composite grain; Again by the composite grain antirust plastic composite grain of gained through blown film or film, be processed into gas-phase antirusting film wrapping material.
In the above embodiments 5, colour batch or the fire retardant of appropriate different colours can also be added when coextrusion film blowing, make gas-phase antirusting film present required color or have certain flame retardant properties, these additional characteristics do not produce any detrimentally affect to the rustless property of gas-phase antirusting film.
By embodiment 1,2,3, gas-phase antirusting film wrapping material corresponding to 4 carry out volatile rust prevention process to many metals together with multiple like product not containing organic amine Borated Ester Additives, and their rustless property is compared, touchstone is with reference to GB/T19532-2004, and test-results is in table 1:
In table 1, same kind of products at abroad selects the clean happy special market products of German Blanc promise and the U.S., and its market price is higher than antirust film of the present invention two to three times; Domestic like product selects Chinese grace east market products, and price is suitable with antirust film of the present invention.Comparative test result shows, gas-phase antirusting film of the present invention is all better than the selected external and domestic similar-type products not containing organic amine Borated Ester Additives to the rust-proof effect of various metal, the wherein best results of embodiment 2 is better embodiment of the present invention.Anti-rust master batch of the present invention and film price only have 1/2nd or 1/3rd of same kind of products at abroad, and have no side effect, free from environmental pollution, meet national environmental standard requirement, completely can substituting import one product.Think that their vapor phase corrosion inhibitor mechanism may be: the triethanolamine borate evaporateing into metallic surface, N and O atom in boric acid ester in its molecule and organic alcohol amine molecule is all containing lone-pair electron, coordinate bond can be formed with the d electronics unoccupied orbital of Fe, there occurs chemisorption; Add the corrosion inhibition of inorganic salt in compound corrosion inhibitor, make compound corrosion inhibitor form firmly adsorption film in metallic surface, to suppress oxygen and water to the contact of metallic surface, from having played good rust-proof effect.

Claims (8)

1. the anti-rust master batch of metal more than, is characterized in that the percent mass accounting of each component in described anti-rust master batch is: 30 ~ 50% composite rust-preventive agent, 40 ~ 60% carrier plastics and 10 ~ 20% auxiliary agents; The ratio that described composite rust-preventive agent is 1 ~ 1.3:1.1 ~ 1.5:2.2 ~ 3.2:0.8 ~ 1.2 by Sodium Benzoate, sebacic acid sodium, triethanolamine borate, benzotriazole in mass ratio mixes; The ratio that described auxiliary agent is 0.9 ~ 1.3:4.8 ~ 6.5:2.5 ~ 3.3:0.8 ~ 1.1 by stearic acid amide, water-ground limestone, sucrose fatty ester, antioxidant 1076 in mass ratio mixes.
2. the many metal anti-rust master batch of one according to claim 1, is characterized in that described composite rust-preventive agent by Sodium Benzoate, sebacic acid sodium, triethanolamine borate, benzotriazole in mass ratio for the ratio of 1:1.2:3:0.9 mixes; The ratio that described auxiliary agent is 1:5.5:3:1 by stearic acid amide, water-ground limestone, sucrose fatty ester, antioxidant 1076 in mass ratio mixes.
3. the many metal anti-rust master batch of one according to claim 1, is characterized in that described carrier plastics to be density are the polyethylene of 0.90 ~ 0.96g/cm.
4. the many metal anti-rust master batch of one according to claim 3, is characterized in that described carrier plastics is one or both the mixture in Low Density Polyethylene, linear low density polyethylene.
5. the many metal anti-rust master batch of one according to claim 1 and 2, is characterized in that the particle diameter of described composite rust-preventive agent is 800 ~ 2800 orders.
6. the many metal anti-rust master batch of one according to claim 5, is characterized in that the particle diameter of described composite rust-preventive agent is 900 ~ 1100 orders.
7. a preparation method for many metal anti-rust master batch according to claim 1, is characterized in that comprising the following steps: (a) by described quality proportioning by composite rust-preventive agent, carrier plastics and auxiliary agent high-speed mixing 4 ~ 5 minutes obtained compounds; B () mediates gained compound, melting treatment, and mixing under 150 ~ 180 DEG C of temperature condition, plasticizing is afterwards extruded, obtained described many metal anti-rust master batch.
8. the application of many metal anti-rust master batch according to claim 1, it is characterized in that this application comprises the following steps: described anti-rust master batch adds in the raw material of thermoplastics according to the ratio that mass ratio is 1:25 ~ 50 by (a), fully stir and make composite grain; (b) again by described composite grain antirust plastic composite grain through blown film or film, be processed into gas-phase antirusting film wrapping material.
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CN106037160A (en) * 2016-08-08 2016-10-26 道晟拉链科技（太仓）有限公司 Durable zipper
JP2018119201A (en) * 2017-01-27 2018-08-02 中部キレスト株式会社 Antirust film for metal
CN108586800A (en) * 2018-03-23 2018-09-28 上海电力学院 A kind of compounding vapor phase inhibitor and its preparation method and application
CN109732804A (en) * 2019-01-25 2019-05-10 维希艾防锈新材料(上海)有限公司 Environment-friendlyantirust antirust master batch production high degree of dispersion extrusion equipment and anti-rust master batch
CN110128864A (en) * 2019-05-10 2019-08-16 武汉疏能新材料有限公司 A kind of efficient permanent seal cooling vapor phase inhibitor and preparation method thereof
CN111206250A (en) * 2020-01-20 2020-05-29 青岛科技大学 Mixed amide type water-based gas-phase antirust concentrated solution and preparation and use methods thereof
CN111825921A (en) * 2020-08-07 2020-10-27 常州市天王塑业有限公司 Antirust master batch and preparation process thereof
CN112681007A (en) * 2020-12-21 2021-04-20 青岛鑫盈鑫包装材料有限公司 Special gas-phase environment-friendly antirust paper for nodular cast iron and preparation method thereof
KR20210069267A (en) * 2019-12-03 2021-06-11 주식회사 지러스트 Composite films for preventing discoloration of ferrous and non-ferrous metal
WO2022091991A1 (en) * 2020-10-26 2022-05-05 株式会社アイセロ Anti-corrosion film

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105199190A (en) * 2015-09-10 2015-12-30 上海贝达包装材料有限公司 Multifunctional environment-friendly gaseous-phase antirusting masterbatch and preparation method therefor and application thereof
CN105199190B (en) * 2015-09-10 2018-01-30 苏州贝达新材料科技有限公司 A kind of Mobyneb environment protection gas-phase rust-proofing master batch and its preparation method and application
CN106037160A (en) * 2016-08-08 2016-10-26 道晟拉链科技（太仓）有限公司 Durable zipper
JP2018119201A (en) * 2017-01-27 2018-08-02 中部キレスト株式会社 Antirust film for metal
CN108586800A (en) * 2018-03-23 2018-09-28 上海电力学院 A kind of compounding vapor phase inhibitor and its preparation method and application
CN109732804A (en) * 2019-01-25 2019-05-10 维希艾防锈新材料(上海)有限公司 Environment-friendlyantirust antirust master batch production high degree of dispersion extrusion equipment and anti-rust master batch
CN110128864A (en) * 2019-05-10 2019-08-16 武汉疏能新材料有限公司 A kind of efficient permanent seal cooling vapor phase inhibitor and preparation method thereof
KR20210069267A (en) * 2019-12-03 2021-06-11 주식회사 지러스트 Composite films for preventing discoloration of ferrous and non-ferrous metal
KR102319644B1 (en) * 2019-12-03 2021-11-02 주식회사 지러스트 Composite films for preventing discoloration of ferrous and non-ferrous metal
CN111206250A (en) * 2020-01-20 2020-05-29 青岛科技大学 Mixed amide type water-based gas-phase antirust concentrated solution and preparation and use methods thereof
CN111825921A (en) * 2020-08-07 2020-10-27 常州市天王塑业有限公司 Antirust master batch and preparation process thereof
WO2022091991A1 (en) * 2020-10-26 2022-05-05 株式会社アイセロ Anti-corrosion film
CN112681007A (en) * 2020-12-21 2021-04-20 青岛鑫盈鑫包装材料有限公司 Special gas-phase environment-friendly antirust paper for nodular cast iron and preparation method thereof

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