CN104311884A - Special filler for glass fiber reinforced plastic door and window and preparation method of filler - Google Patents
Special filler for glass fiber reinforced plastic door and window and preparation method of filler Download PDFInfo
- Publication number
- CN104311884A CN104311884A CN201410603906.2A CN201410603906A CN104311884A CN 104311884 A CN104311884 A CN 104311884A CN 201410603906 A CN201410603906 A CN 201410603906A CN 104311884 A CN104311884 A CN 104311884A
- Authority
- CN
- China
- Prior art keywords
- parts
- filler
- wood powder
- reinforced plastic
- fiber reinforced
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention provides a special filler for glass fiber reinforced plastic doors and windows. The filler is prepared from the following raw materials in parts by weight: 1-2 parts of a vinyl silane coupling agent, 0.5-0.8 part of butyl cellosolve, 2-4 parts of panthenol, 2-3 parts of crystalline flake graphite, 8-10 parts of sepiolite fibre, 1.6-1.9 parts of dibutyltin maleate, 0.5-0.8 part of 3-propanediol, 0.3-0.5 part of didecyl dimethyl ammonium chloride, 1-1.5 parts of emulsion rosin size, 20-30 parts of modified wood meal, 180-200 parts of light calcium carbonate, and 60-80 parts of water. According to the invention, as the sepiolite fibre is added into the filler to be matched with glass fibre, the impact strength, toughness and abrasion resistance of the glass fiber reinforced plastic are enhanced; through addition and usage of the modified wood meal, the compatibility of the filler with PVC is good, and heat preservation performance, shock resistance and pigmenting performance of the doors and windows are improved; the glass fiber reinforced plastic prepared from the filler is high in strength, and suitable for installation of large doors and windows.
Description
Technical field
The invention belongs to pearl filler field, particularly a kind of glass fiber reinforced plastic door and window filler special and preparation method thereof.
Background technology
Plastic door-window, namely adopts the door and window that U-PVC plastic material is made.Plastic door-window has the superperformances such as wind resistance, waterproof, insulation.
Current plastic door-window comprises PVC plastic door-window and glass filament reinforced plastics (glass reinforced plastic) door and window.In all kinds of building doors and windows, PVC plastic door and window repeats there is outstanding advantage in recycling and Energy in use at saving section bar production energy consumption, reclaimed materials, has the excellent ratio of performance to price in heat preservation energy-saving.
Need to use filler when making plastic door-window, the pearl filler that current is often, but the wetting ability of calcium carbonate is strong, need to improve its surface property, to increase the consistency of itself and plastics, increase reinforcing property, current modified calcium carbonate performance is good not enough; Also have single pearl filler can not meet the requirement of improvement in performance.
Wood powder can improve the toughness of plastics, insulation, the performance such as painted through modification while reducing costs, with calcium carbonate with the use of, synergy can be played, to enhance product performance.
Summary of the invention
The object of the present invention is to provide a kind of glass fiber reinforced plastic door and window filler special and preparation method thereof, this filler enhances the shock strength of glass reinforced plastic, toughness and wear resistance, is applicable to make large-scale door and window.
Technical scheme of the present invention is as follows:
A kind of glass fiber reinforced plastic door and window filler special, is characterized in that being made up of the raw material of following weight part: vinyl silicane coupling agent 1-2, butyl glycol ether 0.5-0.8, panthenol 2-4, crystalline flake graphite 2-3, sepiolite fibre 8-10, dibutyitin maleate 1.6-1.9, ammediol 0.5-0.8, Timbercote 2000 0.3-0.5, emulsion gum rosin 1-1.5, modified wood powder 20-30, light calcium carbonate 180-200, water 60-80;
Described modified wood powder is made up of the raw material of following weight part: wood powder 2-3,30% sodium hydroxide solution 20-30,30% ethanolic soln 20-30, nano titanium oxide 0.2-0.3, nano far infrared ceramic powder 0.2-0.3, polyoxyethylene glycol 0.1-0.2, Timbercote 2000 0.1-0.2, water are appropriate; Preparation method is: added by wood powder in 30% sodium hydroxide solution and soak 7-8 hour, suction filtration, dry, then adds in 30% ethanolic soln and soak 7-8 hour, and washing, to neutral, is dried to over dry; Nano titanium oxide, nano far infrared ceramic powder, Timbercote 2000, polyoxyethylene glycol are added in the water of 4-5 times of weight, stirs and add over dry wood powder again, stir, add in kneader again and mediate 20-30 minute, take out, dry, be ground into 40-100 order particle, obtain final product.
The preparation method of described glass fiber reinforced plastic door and window filler special, is characterized in that comprising the following steps:
(1) modified wood powder, panthenol, ammediol, Timbercote 2000 are added to the water, add vinyl silicane coupling agent, emulsion gum rosin while stirring, stir, ultrasonic vibration 8-10 minute, obtain wood powder slurry;
(2) send in high-speed mixer by light calcium carbonate, add (1) the wood powder slurry obtained, mixing 15-20 minute, is warming up to 60-65 DEG C, adds sepiolite fibre, crystalline flake graphite, and mixing 20-30 minute, obtains mixture;
(3) other remaining components mixed, add in the mixture that (2) step obtains, mixing 20-30 minute, is heated to 70-80 DEG C, and mixing 30-40 minute, vacuum-drying, is ground into 10-100 object particle, obtains final product.
Beneficial effect of the present invention
Filler of the present invention with the addition of sepiolite fibre, coordinates with glass fibre, enhances the shock strength of glass reinforced plastic, toughness and wear resistance; By adding by using modified wood powder, good with the consistency of PVC, add the heat-insulating property of door and window, impact resistance and tinctorial property; The glass reinforced plastic intensity that filler of the present invention makes is high, is applicable to the installation of large-scale door and window.
Embodiment
A kind of glass fiber reinforced plastic door and window filler special, is made up of the raw material of following weight part (kilogram): vinyl silicane coupling agent 1.5, butyl glycol ether 0.7, panthenol 3, crystalline flake graphite 2.5, sepiolite fibre 9, dibutyitin maleate 1.8, ammediol 0.7, Timbercote 2000 0.4, emulsion gum rosin 1.3, modified wood powder 25, light calcium carbonate 190, water 70;
Described modified wood powder is made up of the raw material of following weight part (kilogram): wood powder 2.5,30% sodium hydroxide solution 25,30% ethanolic soln 25, nano titanium oxide 0.2, nano far infrared ceramic powder 0.2, polyoxyethylene glycol 0.1, Timbercote 2000 0.1, water are appropriate; Preparation method is: added by wood powder in 30% sodium hydroxide solution and soak 7.5 hours, suction filtration, dry, then adds in 30% ethanolic soln and soak 7.5 hours, and washing, to neutral, is dried to over dry; Nano titanium oxide, nano far infrared ceramic powder, Timbercote 2000, polyoxyethylene glycol are added in the water of 4 times of weight, stirs and add over dry wood powder again, stir, add again in kneader and mediate 25 minutes, take out, dry, be ground into 40-100 order particle, obtain final product.
The preparation method of described glass fiber reinforced plastic door and window filler special, comprises the following steps:
(1) modified wood powder, panthenol, ammediol, Timbercote 2000 are added to the water, add vinyl silicane coupling agent, emulsion gum rosin while stirring, stir, ultrasonic vibration 9 minutes, obtains wood powder slurry;
(2) light calcium carbonate is sent in high-speed mixer, add (1) the wood powder slurry obtained, mix 18 minutes, be warming up to 63 DEG C, add sepiolite fibre, crystalline flake graphite, mix 25 minutes, obtain mixture;
(3) other remaining components are mixed, add in the mixture that (2) step obtains, mix 25 minutes, be heated to 75 DEG C, mix 35 minutes, vacuum-drying, be ground into 10-100 object particle, obtain final product.
Experimental data:
The oil-absorption(number) of the present embodiment filler is 37mL/100g, is 100 ° with the contact angle of water.Be used for producing hard PVC test piece by this filler, addition is 15%, and the performance test results is: yield strength 63.67Mpa, and breaking tenacity is 47.88Mpa, elongation at break 104%, Young's modulus 2707.49Mpa.
Claims (2)
1. a glass fiber reinforced plastic door and window filler special, is characterized in that being made up of the raw material of following weight part: vinyl silicane coupling agent 1-2, butyl glycol ether 0.5-0.8, panthenol 2-4, crystalline flake graphite 2-3, sepiolite fibre 8-10, dibutyitin maleate 1.6-1.9, ammediol 0.5-0.8, Timbercote 2000 0.3-0.5, emulsion gum rosin 1-1.5, modified wood powder 20-30, light calcium carbonate 180-200, water 60-80;
Described modified wood powder is made up of the raw material of following weight part: wood powder 2-3,30% sodium hydroxide solution 20-30,30% ethanolic soln 20-30, nano titanium oxide 0.2-0.3, nano far infrared ceramic powder 0.2-0.3, polyoxyethylene glycol 0.1-0.2, Timbercote 2000 0.1-0.2, water are appropriate; Preparation method is: added by wood powder in 30% sodium hydroxide solution and soak 7-8 hour, suction filtration, dry, then adds in 30% ethanolic soln and soak 7-8 hour, and washing, to neutral, is dried to over dry; Nano titanium oxide, nano far infrared ceramic powder, Timbercote 2000, polyoxyethylene glycol are added in the water of 4-5 times of weight, stirs and add over dry wood powder again, stir, add in kneader again and mediate 20-30 minute, take out, dry, be ground into 40-100 order particle, obtain final product.
2. the preparation method of glass fiber reinforced plastic door and window filler special according to claim 1, is characterized in that comprising the following steps:
(1) modified wood powder, panthenol, ammediol, Timbercote 2000 are added to the water, add vinyl silicane coupling agent, emulsion gum rosin while stirring, stir, ultrasonic vibration 8-10 minute, obtain wood powder slurry;
(2) send in high-speed mixer by light calcium carbonate, add (1) the wood powder slurry obtained, mixing 15-20 minute, is warming up to 60-65 DEG C, adds sepiolite fibre, crystalline flake graphite, and mixing 20-30 minute, obtains mixture;
(3) other remaining components mixed, add in the mixture that (2) step obtains, mixing 20-30 minute, is heated to 70-80 DEG C, and mixing 30-40 minute, vacuum-drying, is ground into 10-100 object particle, obtains final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410603906.2A CN104311884A (en) | 2014-10-31 | 2014-10-31 | Special filler for glass fiber reinforced plastic door and window and preparation method of filler |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410603906.2A CN104311884A (en) | 2014-10-31 | 2014-10-31 | Special filler for glass fiber reinforced plastic door and window and preparation method of filler |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104311884A true CN104311884A (en) | 2015-01-28 |
Family
ID=52367210
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410603906.2A Pending CN104311884A (en) | 2014-10-31 | 2014-10-31 | Special filler for glass fiber reinforced plastic door and window and preparation method of filler |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104311884A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107237430A (en) * | 2017-05-17 | 2017-10-10 | 南通德瑞森复合材料有限公司 | A kind of anti-dazzle heat-protecting glass steel curtain wall |
-
2014
- 2014-10-31 CN CN201410603906.2A patent/CN104311884A/en active Pending
Non-Patent Citations (1)
| Title |
|---|
| 冯孝中: "单机复色挤出木质塑料研究", 《郑州轻工业学院学报》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107237430A (en) * | 2017-05-17 | 2017-10-10 | 南通德瑞森复合材料有限公司 | A kind of anti-dazzle heat-protecting glass steel curtain wall |
| WO2018209798A1 (en) * | 2017-05-17 | 2018-11-22 | 南通德瑞森复合材料有限公司 | Anti-glare heat-insulating fiberglass curtain wall |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103497559B (en) | Weather resistant exterior wall putty powder | |
| CN109385130A (en) | A kind of external wall elastic water-proof putty powder and its preparation process | |
| CN103173076B (en) | A kind of exterior coating and preparation method thereof | |
| CN104292706A (en) | Flame retardant PVC plastic door and window filler and preparation method thereof | |
| CN104356543A (en) | Filler for plastic door window and preparation method of filler | |
| CN104086866B (en) | A kind of high-strength and ageing resistance capacitor film filler special and preparation method thereof | |
| CN104292704A (en) | Strengthening filler for plastic doors and windows and preparation method of strengthening filler | |
| CN104311884A (en) | Special filler for glass fiber reinforced plastic door and window and preparation method of filler | |
| CN109206948A (en) | Weather-proof inorganic exterior coating and preparation method thereof based on graphene and mullite | |
| CN109233539A (en) | A kind of preparation method of external wall special-purpose thermal insulation coating | |
| CN104311885A (en) | Plastic door and window filler containing nanometer corundum powder and preparation method of plastic door and window filler | |
| CN104194065A (en) | Thermally stable plastic filler and preparation method thereof | |
| CN104496319A (en) | Anti-compressive and anti-crack thermal mortar and preparation method thereof | |
| CN104312003A (en) | High-resistance polypropylene sheet | |
| CN104292705A (en) | Special calcium carbonate filler for PVC doors and windows, and preparation method thereof | |
| CN104292707A (en) | Oxidation resisting calcium carbonate filler and preparation method thereof | |
| CN103173077B (en) | Coating of a kind of washability and preparation method thereof | |
| CN105255062A (en) | PVC plastic door and window filler and preparing method thereof | |
| CN104277377A (en) | Heat-preservation plastic door and window filler and preparation method thereof | |
| CN104292869A (en) | Filling material for refrigerator plastic housing and preparation method of filling material | |
| CN102533031A (en) | External wall paint of building | |
| CN106281179A (en) | A kind of waterproof high bond strength resin adhesive | |
| CN104277376A (en) | Calcium carbonate filler for plastic doors and windows and preparation method of calcium carbonate filler | |
| CN104496317A (en) | Refractory finishing mortar and preparation method thereof | |
| CN104529291A (en) | Masonry mortar and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150128 |