CN104309184B - Red mud is in conjunction with the preparation method of expanded vermiculite multiaspect illuminated light wall material - Google Patents

Red mud is in conjunction with the preparation method of expanded vermiculite multiaspect illuminated light wall material Download PDF

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Publication number
CN104309184B
CN104309184B CN201410535329.8A CN201410535329A CN104309184B CN 104309184 B CN104309184 B CN 104309184B CN 201410535329 A CN201410535329 A CN 201410535329A CN 104309184 B CN104309184 B CN 104309184B
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raw material
red mud
expanded vermiculite
conjunction
preparation
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Expired - Fee Related
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CN201410535329.8A
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CN104309184A (en
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唐竹兴
刘敏
刘坤
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Shandong University of Technology
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Shandong University of Technology
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B30/00—Compositions for artificial stone, not containing binders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/10—Properties of the layers or laminate having particular acoustical properties
    • B32B2307/102—Insulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/304—Insulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/56—Damping, energy absorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2607/00—Walls, panels

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Road Paving Structures (AREA)

Abstract

Red mud, in conjunction with the preparation method of expanded vermiculite multiaspect illuminated light wall material, is characterized in that: red mud is made up of color coat (1), transition zone (2), heat-insulation layer (3) three part in conjunction with expanded vermiculite multiaspect illuminated light wall material.Red mud prepared by the present invention have employed once-firing in conjunction with expanded vermiculite multiaspect illuminated light wall material, transition zone is added in the middle of color coat and heat-insulation layer, efficiently solve the hole diameter caused because material melting point is inconsistent between color coat and heat-insulation layer excessive, the shortcoming that bond strength and thermal shock resistance reduce, monochrome is prepared into by adding ceramic toner, the interior and exterior decoration material of the colors such as tertiary colour and pattern, without the need to additional decoration, production technology is simple, cost is low, building heat preservation is effective, energy-conservation, waterproof, environmental protection, the illuminated red mud produced is decorated in conjunction with expanded vermiculite light wall material collection, insulation, heat insulation, sound insulation and shockproof etc. multi-functional.

Description

Red mud is in conjunction with the preparation method of expanded vermiculite multiaspect illuminated light wall material
Technical field
The present invention relates to the preparation method of red mud in conjunction with expanded vermiculite multiaspect illuminated light wall material, belong to field of ceramic preparation technology.
Background technology
Red mud, in conjunction with expanded vermiculite multiaspect illuminated light wall material collection decoration, heat insulation integrated New Type Light-weight Wall Material, is a kind of novel wall material with decoration, insulation, waterproof, sound insulation and the function integration such as shockproof.Current construction material generally adopts structural clay tile, cement hollow building blocks and air-entrained concrete building block etc., these construction material heat-insulating properties and decorate properties poor, needing when being applied to inner, external wall additionally to add tiling or wallpaper, is the building and ornament materials that manufacturing cost is high.
Summary of the invention
The object of this invention is to provide a kind of serviceability is excellent, production cost the is low red mud preparation method in conjunction with expanded vermiculite multiaspect illuminated light wall material, its technical scheme is:
Red mud is in conjunction with the preparation method of expanded vermiculite multiaspect illuminated light wall material, and red mud is made up of color coat (1), transition zone (2), heat-insulation layer (3) three part in conjunction with expanded vermiculite multiaspect illuminated light wall material, and concrete grammar comprises the following steps:
A. the preparation of color coat (1) raw material: by ceramic raw materials such as clay, quartz sand, borax, zircon sand, zinc oxide, albite, potassic feldspar, lithium feldspar, tin oxide, brium carbonates, by chemical composition be: SiO 2be 12 ~ 32%, B 2o 3be 10 ~ 25%, Al 2o 3be 3 ~ 6%, K 2o is 6 ~ 11%, Li 2o is 1 ~ 6%, Na 2o is 1 ~ 12%, ZnO be 11 ~ 21%, BaO is 6 ~ 11%, TiO 2be 4 ~ 11%, SnO be 0 ~ 5%, ZrO 2be 0 ~ 6% batching and frit raw material is made in fine grinding, then be 50 ~ 95% being 5 ~ 50% with ceramic pigment weight ratio by frit raw material with weight ratio, ratio uniform mixes, and makes 850 ~ 1000 DEG C of melt process the colored frit particle that granularity is 1 ~ 3mm;
B. the preparation of transition zone (2) raw material: be 50 ~ 95% make transition zone raw material with clay 5 ~ 50% Homogeneous phase mixing with weight ratio by the frit raw material of preparation in step (a);
C. the preparation of heat-insulation layer (3) raw material: red mud being added weight ratio is that red mud mud made by the water of 30 ~ 60% and the waterglass of 5 ~ 20%, be 10 ~ 40% Homogeneous phase mixing by red mud mud and expanded vermiculite particle with volume ratio again, after drying, make heat-insulation layer raw material;
D. red mud is in conjunction with the preparation of expanded vermiculite multiaspect illuminated light wall material: first adopt load bearing board (4) left, right, before, the cube that rear and bottom surface surrounds top-open burns mould, and apply releasing agent, then by the colored frit particle (1) of preparation in step (a) evenly plain cloth in holding the bottom of burning mould, and the medial surface being evenly distributed in and holding and burn mould is separated with external partition (5), thickness is 1 ~ 10mm, profile height is 25 ~ 35mm, use internal partition (6) that the transition zone raw material of preparation in step (b) is evenly distributed in the inner side of colored frit particle again, thickness is 1 ~ 5mm, then the even plain cloth of heat-insulation layer raw material step (c) prepared is inside transition zone raw material, the gross thickness of vertically holding the inner plane direction, bottom of burning mould is made to reach 25 ~ 35mm, then the external partition (5) of surrounding is taken out, internal partition (6), 1 ~ 5 hour is incubated at the temperature of 800 ~ 1100 DEG C, crystallization at the temperature of 400 ~ 750 DEG C, anneal 5 ~ 15 hours, through cooling, come out of the stove, cutting and surface grinding make red mud in conjunction with expanded vermiculite multiaspect illuminated light wall material.
Compared with prior art, its advantage is in the present invention:
1, technique is simple, and the red mud of production has stronger decoration, insulation, waterproof, heat insulation, sound insulation and antiknock quality in conjunction with expanded vermiculite multiaspect illuminated light wall material;
2, red mud provided by the invention can be prepared into the interior and exterior decoration material of the colors such as monochrome, tertiary colour and pattern by adding ceramic toner in conjunction with expanded vermiculite multiaspect illuminated light wall material;
3, in the middle of color coat and heat-insulation layer, add transition zone, efficiently solve that the hole diameter caused because material melting point is inconsistent between color coat and heat-insulation layer is excessive, shortcoming that bond strength and thermal shock resistance reduce;
4, the present invention is owing to have employed once-firing, and without the need to additional decoration, reduces cost significantly, and building heat preservation is effective, energy-saving and environmental protection.
Accompanying drawing explanation
Fig. 1 is that red mud burns mould and assembly structure schematic diagram in conjunction with holding of expanded vermiculite multiaspect illuminated light wall material;
1, color coat; 2, transition zone; 3, heat-insulation layer; 4, load bearing board; 5, external partition; 6, internal partition
Detailed description of the invention
embodiment 1
A. the preparation of color coat (1) raw material: by ceramic raw materials such as clay, quartz sand, borax, zircon sand, zinc oxide, albite, potassic feldspar, lithium feldspar, tin oxide, brium carbonates, by chemical composition be: SiO 2be 32%, B 2o 3be 25%, Al 2o 3be 3%, K 2o is 6%, Li 2o is 1%, Na 2o is 12%, ZnO be 11%, BaO is 6%, TiO 2be 4% batching and frit raw material is made in fine grinding, then be 50% being 50% with ceramic pigment weight ratio by frit raw material with weight ratio, ratio uniform mixes, and makes 850 DEG C of melt process the colored frit particle that granularity is 1mm;
B. the preparation of transition zone (2) raw material: be 50% make transition zone raw material with clay 50% Homogeneous phase mixing with weight ratio by the frit raw material of preparation in step (a);
C. the preparation of heat-insulation layer (3) raw material: red mud being added weight ratio is that red mud mud made by the water of 30% and the waterglass of 20%, then be 10% Homogeneous phase mixing by red mud mud and expanded vermiculite particle with volume ratio, make heat-insulation layer raw material after drying;
D. red mud is in conjunction with the preparation of expanded vermiculite multiaspect illuminated light wall material: first adopt load bearing board (4) left, right, before, the cube that rear and bottom surface surrounds top-open holds burning mould, and apply releasing agent, then by the colored frit particle (1) of preparation in step (a) evenly plain cloth in holding the bottom of burning mould, and the medial surface being evenly distributed in and holding and burn mould is separated with external partition (5), thickness is 1mm, profile height is 25mm, use internal partition (6) that the transition zone raw material of preparation in step (b) is evenly distributed in the inner side of colored frit particle again, thickness is 1mm, then the even plain cloth of heat-insulation layer raw material step (c) prepared is inside transition zone raw material, the gross thickness of vertically holding the inner plane direction, bottom of burning mould is made to reach 25mm, then the external partition (5) of surrounding is taken out, internal partition (6), 1 hour is incubated at the temperature of 800 DEG C, crystallization at the temperature of 400 DEG C, anneal 5 hours, through cooling, come out of the stove, cutting and surface grinding make red mud in conjunction with expanded vermiculite multiaspect illuminated light wall material.
The purity of testing proportion material used is technical pure.
embodiment 2
A. the preparation of color coat (1) raw material: by ceramic raw materials such as clay, quartz sand, borax, zircon sand, zinc oxide, albite, potassic feldspar, lithium feldspar, tin oxide, brium carbonates, by chemical composition be: SiO 2be 22%, B 2o 3be 17.5%, Al 2o 3be 4.5%, K 2o is 8.5%, Li 2o is 3.5%, Na 2o is 6.5%, ZnO be 16%, BaO is 8.5%, TiO 2be 7.5%, SnO be 2.5%, ZrO 2be 3% batching and frit raw material is made in fine grinding, then be 72% being 28% with ceramic pigment weight ratio by frit raw material with weight ratio, ratio uniform mixes, and makes 920 DEG C of melt process the colored frit particle that granularity is 2mm;
B. the preparation of transition zone (2) raw material: be 75% make transition zone raw material with clay 25% Homogeneous phase mixing with weight ratio by the frit raw material of preparation in step (a);
C. the preparation of heat-insulation layer (3) raw material: red mud being added weight ratio is that red mud mud made by the water of 45% and the waterglass of 13%, then be 25% Homogeneous phase mixing by red mud mud and expanded vermiculite particle with volume ratio, make heat-insulation layer raw material after drying;
D. red mud is in conjunction with the preparation of expanded vermiculite multiaspect illuminated light wall material: first adopt load bearing board (4) left, right, before, the cube that rear and bottom surface surrounds top-open burns mould, and apply releasing agent, then by the colored frit particle (1) of preparation in step (a) evenly plain cloth in holding the bottom of burning mould, and the medial surface being evenly distributed in and holding and burn mould is separated with external partition (5), thickness is 5mm, profile height is 30mm, use internal partition (6) that the transition zone raw material of preparation in step (b) is evenly distributed in the inner side of colored frit particle again, thickness is 3mm, then the even plain cloth of heat-insulation layer raw material step (c) prepared is inside transition zone raw material, the gross thickness of vertically holding the inner plane direction, bottom of burning mould is made to reach 30mm, then the external partition (5) of surrounding is taken out, internal partition (6), 3 hours are incubated at the temperature of 950 DEG C, crystallization at the temperature of 600 DEG C, anneal 10 hours, through cooling, come out of the stove, cutting and surface grinding make red mud in conjunction with expanded vermiculite multiaspect illuminated light wall material.
The purity of testing proportion material used is technical pure.
embodiment 3
A. the preparation of color coat (1) raw material: by ceramic raw materials such as clay, quartz sand, borax, zircon sand, zinc oxide, albite, potassic feldspar, lithium feldspar, tin oxide, brium carbonates, by chemical composition be: SiO 2be 12%, B 2o 3be 10%, Al 2o 3be 6%, K 2o is 11%, Li 2o is 6%, Na 2o is 1%, ZnO be 21%, BaO is 11%, TiO 2be 11%, SnO be 5%, ZrO 2be 6% batching and frit raw material is made in fine grinding, then be 95% being 5% with ceramic pigment weight ratio by frit raw material with weight ratio, ratio uniform mixes, and makes 1000 DEG C of melt process the colored frit particle that granularity is 3mm;
B. the preparation of transition zone (2) raw material: be 95% make transition zone raw material with clay 5% Homogeneous phase mixing with weight ratio by the frit raw material of preparation in step (a);
C. the preparation of heat-insulation layer (3) raw material: red mud being added weight ratio is that red mud mud made by the water of 60% and the waterglass of 5%, then be 40% Homogeneous phase mixing by red mud mud and expanded vermiculite particle with volume ratio, make heat-insulation layer raw material after drying;
D. red mud is in conjunction with the preparation of expanded vermiculite multiaspect illuminated light wall material: first adopt load bearing board (4) left, right, before, the cube that rear and bottom surface surrounds top-open holds burning mould, and apply releasing agent, then by the colored frit particle (1) of preparation in step (a) evenly plain cloth in holding the bottom of burning mould, and the medial surface being evenly distributed in and holding and burn mould is separated with external partition (5), thickness is 10mm, profile height is 35mm, use internal partition (6) that the transition zone raw material of preparation in step (b) is evenly distributed in the inner side of colored frit particle again, thickness is 5mm, then the even plain cloth of heat-insulation layer raw material step (c) prepared is inside transition zone raw material, the gross thickness of vertically holding the inner plane direction, bottom of burning mould is made to reach 35mm, then the external partition (5) of surrounding is taken out, internal partition (6), 5 hours are incubated at the temperature of 1100 DEG C, crystallization at the temperature of 750 DEG C, anneal 15 hours, through cooling, come out of the stove, cutting and surface grinding make red mud in conjunction with expanded vermiculite multiaspect illuminated light wall material.
The purity of testing proportion material used is technical pure.

Claims (1)

1. red mud is in conjunction with the preparation method of expanded vermiculite multiaspect illuminated light wall material, it is characterized in that: red mud is made up of color coat (1), transition zone (2), heat-insulation layer (3) three part in conjunction with expanded vermiculite multiaspect illuminated light wall material, and concrete grammar comprises the following steps:
A. the preparation of color coat (1) raw material: by clay, quartz sand, borax, zircon sand, zinc oxide, albite, potassic feldspar, lithium feldspar, tin oxide, brium carbonate, by chemical composition is: SiO 2be 12 ~ 32%, B 2o 3be 10 ~ 25%, Al 2o 3be 3 ~ 6%, K 2o is 6 ~ 11%, Li 2o is 1 ~ 6%, Na 2o is 1 ~ 12%, ZnO be 11 ~ 21%, BaO is 6 ~ 11%, TiO 2be 4 ~ 11%, SnO be 0 ~ 5%, ZrO 2be 0 ~ 6% batching and frit raw material is made in fine grinding, then be 50 ~ 95% being 5 ~ 50% with ceramic pigment percentage by weight by frit raw material with percentage by weight, ratio uniform mixes, and makes 850 ~ 1000 DEG C of melt process the colored frit particle that granularity is 1 ~ 3mm;
B. the preparation of transition zone (2) raw material: by the frit raw material prepared in step a with percentage by weight be 50 ~ 95% with clay 5 ~ 50% Homogeneous phase mixing make transition zone raw material;
C. the preparation of heat-insulation layer (3) raw material: red mud being added percentage by weight is that red mud mud made by the water of 30 ~ 60% and the waterglass of 5 ~ 20%, be 10 ~ 40% Homogeneous phase mixing by red mud mud and expanded vermiculite particle with percent by volume again, after drying, make heat-insulation layer raw material;
D. red mud is in conjunction with the preparation of expanded vermiculite multiaspect illuminated light wall material: first adopt load bearing board (4) left, right, before, the cube that rear and bottom surface surrounds top-open holds burning mould, and apply releasing agent, then the colored frit uniform particles plain cloth prepared in step a is burnt the bottom of mould in holding, and the medial surface being evenly distributed in and holding and burn mould is separated with external partition (5), thickness is 1 ~ 10mm, profile height is 25 ~ 35mm, use internal partition (6) that the transition zone raw material prepared in step b is evenly distributed in the inner side of colored frit particle again, thickness is 1 ~ 5mm, then the even plain cloth of heat-insulation layer raw material prepared by step c is inside transition zone raw material, the gross thickness of vertically holding the inner plane direction, bottom of burning mould is made to reach 25 ~ 35mm, then the external partition (5) of surrounding is taken out, internal partition (6), 1 ~ 5 hour is incubated at the temperature of 800 ~ 1100 DEG C, crystallization at the temperature of 400 ~ 750 DEG C, anneal 5 ~ 15 hours, through cooling, come out of the stove, cutting and surface grinding make red mud in conjunction with expanded vermiculite multiaspect illuminated light wall material.
CN201410535329.8A 2014-10-13 2014-10-13 Red mud is in conjunction with the preparation method of expanded vermiculite multiaspect illuminated light wall material Expired - Fee Related CN104309184B (en)

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CN105622169B (en) * 2015-12-30 2018-11-06 潮州三环（集团）股份有限公司 A kind of chromatic ceramics and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004072397A1 (en) * 2003-02-11 2004-08-26 Saint-Gobain Isover Double-shelled separating wall with a lining made of mineral wool
CN102503507A (en) * 2011-10-19 2012-06-20 山东理工大学 Novel preparation method of red mud light-weight wall material
CN102561630A (en) * 2012-01-13 2012-07-11 山东理工大学 Novel red mud decorating and heat-insulation integrated light wall material
CN103467022A (en) * 2013-09-02 2013-12-25 山东理工大学 Method for preparing waterproof and pollution-proof grade-A flame retardant and environment-friendly thermal mortar by expanded microbeads

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004072397A1 (en) * 2003-02-11 2004-08-26 Saint-Gobain Isover Double-shelled separating wall with a lining made of mineral wool
CN102503507A (en) * 2011-10-19 2012-06-20 山东理工大学 Novel preparation method of red mud light-weight wall material
CN102561630A (en) * 2012-01-13 2012-07-11 山东理工大学 Novel red mud decorating and heat-insulation integrated light wall material
CN103467022A (en) * 2013-09-02 2013-12-25 山东理工大学 Method for preparing waterproof and pollution-proof grade-A flame retardant and environment-friendly thermal mortar by expanded microbeads

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