CN1043048C - Linear low density polyethylene fire retardant sleeve and its method for mfg. - Google Patents

Linear low density polyethylene fire retardant sleeve and its method for mfg. Download PDF

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Publication number
CN1043048C
CN1043048C CN93109001A CN93109001A CN1043048C CN 1043048 C CN1043048 C CN 1043048C CN 93109001 A CN93109001 A CN 93109001A CN 93109001 A CN93109001 A CN 93109001A CN 1043048 C CN1043048 C CN 1043048C
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China
Prior art keywords
weight part
density polyethylene
linear low
low density
fire retardant
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Expired - Fee Related
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CN93109001A
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Chinese (zh)
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CN1085920A (en
Inventor
郝兰祥
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Miao Erchun
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Miao Erchun
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Priority to CN93109001A priority Critical patent/CN1043048C/en
Publication of CN1085920A publication Critical patent/CN1085920A/en
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Publication of CN1043048C publication Critical patent/CN1043048C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

The present invention relates to a linear low-density polyethylene fire-retardant sleeve pipe and a production method thereof. 100 of linear low-density polyethylene, 6% to 8% of chloroparaffin, 4.5% to 6% of antimonous oxide, 1% to 2% of antimony pentoxide, 0.5% to 1.5% of a resin acceptor, 0.3% to 0.6% of calcium bicarbonate and 5% to 8% of aluminium hydroxide are mixed together and are kneaded at the temperature of 90 to 110 DEG C, and then, after granulation, plasticization at the temperature of 120 to 150 DEG C, extrusion and coiling, are made into the pipe. With the characteristics of fire retardance, insulation, static electricity resistance, difficult ageing, good toughness, easy bending, convenient operation, etc., the linear low-density polyethylene fire-retardant sleeve pipe is suitable to be used as a conductor penetrating insulation sleeve pipe for construction, telecommunication, microcomputers, decoration, decoration construction and military engineering.

Description

Linear low density polyethylene fire retardant sleeve and method for making
The present invention relates to insulation thimble that conductor passes and preparation method thereof.
In recent years, the urban and rural buildings thing adopts plastic casings to replace conventional metals sleeve pipe in the fitting-out works such as dark power circuit that applies and telecommunication, microcomputer, decoration towards large-scale, high-rise, luxurious development in the buildings more.
But currently used plastic casing mainly is high-pressure polyethylene or polychloroethylene pipes.The high-pressure polyethylene sleeve pipe, resistance to compression, bending resistance all can reach the technical requirements of construction, but exist the shortcoming of inflammable, not antistatic and high-voltage breakdown, are the hidden danger that causes fire.PVC sleeve, though possess flame retardant resistance, material is crisp hard, and easy fracture is anti-aging, bending resistance is poor, uses inconvenience, and the construction waste wood is many.
The present invention is directed to the existing shortcoming of above-mentioned plastic casing and develop a kind of have resistance to compression, antistatic, anti-high pressure, difficult aging, particularly have high flame resistance, good toughness, convenient construction, as requested the linear low density polyethylene fire retardant sleeve of any scale.
The present invention is achieved in that
A kind of linear low density polyethylene fire retardant sleeve, its basic characteristics are: it is a main raw material with the linear low density polyethylene, is equipped with other industrial chemicals and makes fire retardant sleeve, and its proportioning raw materials is, the major ingredient linear low density polyethylene is 100 weight parts, adds: clorafin 6-8 weight part again; Antimonous oxide 4.5-6 weight part; Antimony peroxide 1-2 weight part; Coupling agent 0.5-1.5 weight part; Decabromodiphenyl oxide 0.3-0.6 weight part; Light calcium carbonate 3.5-5 weight part; Aluminium hydroxide 5-8 weight part.
The making method of aforesaid polyethylene fire retardant sleeve, be characterized in, above-mentioned various raw materials are prepared by described prescription, by operation manufacturings such as compound-kneading-granulations-plastify-extrude-coil, its processing parameter is: mediate temperature and be controlled at 90-110 ℃, plasticization temperature is controlled at 120-150 ℃, promptly can be made into linear low density polyethylene fire retardant sleeve.
The internal diameter size of product and cross-sectional shape can design according to customer requirements, realize that by changing the forcing machine mould performance index of this product are as follows:
Tensile strength>12MPa; Elongation at break>330%; Resistance to compression: be depressed into external diameter 1/2 place's non-cracking; Crooked 180 degree crack-frees, oxygen index>27.0%, insulation resistance>55000M Ω, withstand voltage 5000V/min does not puncture.
Can find out that by These parameters the linear low density polyethylene sleeve pipe of being made by the present invention has overcome the inflammable shortcoming of high-pressure polyethylene sleeve pipe.Overcome shortcoming such as inconvenient crooked break-in, scale and joint inconvenience in the hard fragility of PVC sleeve and the construction again, had concurrently simultaneously high-pressure polyethylene telescopic fracture resistance good, again can be arbitrarily crooked according to construction requirement, the advantage of intercepting scale and polyvinyl chloride high flame resistance.Its main flame retardant properties maintains the leading position.This product can be widely used in the urban and rural buildings thing and secretly apply the distribution line sleeve pipe, the aspects such as conveying of fire prevention such as engineering such as electronics, telecommunication, microcomputer, decoration, finishing and warehouse, military installations, inflammable gas, liquid.Linear low density polyethylene fire retardant sleeve is than low about 500 yuan of high-pressure polyethylene sleeve pipe cost of material per ton, can prevent effectively that fire from taking place, and is moulding the good material of Dai Gang, and its economic benefit is all more outstanding.
Embodiment 1: the major ingredient linear low density polyethylene is 100 weight parts, is equipped with clorafin 7 weight parts, antimonous oxide 5 weight parts, antimony peroxide 1.5 weight parts, coupling agent 1 weight part, decabromodiphenyl oxide 0.5 weight part, light calcium carbonate 4 weight parts; Aluminium hydroxide 6.5 weight parts by compound-mediate-make the technology of expecting-plastifying-extruding-coiling to process, are mediated temperature and are controlled at 100 ℃, and plasticization temperature is controlled at 120-150 ℃, promptly can be made into linear low density polyethylene fire retardant sleeve.
Embodiment 2: the major ingredient linear low density polyethylene is 100 weight parts, is equipped with clorafin 6 weight parts, antimonous oxide 4.5 weight parts; Antimony peroxide 1 weight part; Coupling agent 0.5 weight part, decabromodiphenyl oxide 0.3 weight part; Light calcium carbonate 3.5 weight parts; Aluminium hydroxide 6 weight parts promptly can be made into linear low density polyethylene fire retardant sleeve according to technology and the condition of embodiment 1.
Embodiment 3: the major ingredient linear low density polyethylene is 100 weight parts, is equipped with clorafin 8 weight parts, antimonous oxide 6 weight parts; Antimony peroxide 2 weight parts; Coupling agent 1.5 weight parts, decabromodiphenyl oxide 0.6 weight part; Light calcium carbonate 5 weight parts; Aluminium hydroxide 8 weight parts promptly can be made into linear low density polyethylene fire retardant sleeve by technology and the condition of embodiment 1.

Claims (2)

1. fire retardant sleeve that is used for urban and rural buildings, telecommunications, decoration and repairs profession distribution line, it is characterized in that its proportioning raw materials is: the major ingredient linear low density polyethylene is 100 weight fraction; Clorafin 6-8 weight part; Antimonous oxide 4.5-6 weight part; Antimony peroxide 1-2 weight part; Coupling agent 0.5-1.5 weight part; Decabromodiphenyl oxide 0.3-0.6 weight part; Light calcium carbonate 3.5-5 weight part, aluminium hydroxide 5-8 weight part.
2. the making method of fire retardant sleeve according to claim 1, it is characterized in that proportioning raw materials is: major ingredient linear low density polyethylene 100 weight parts are equipped with clorafin 6-8 weight part, antimonous oxide 4.5-6 weight part; Antimony peroxide 1-2 weight part, coupling agent 0.5-1.5 weight part, decabromodiphenyl oxide 0.3-0.6 weight part; Light calcium carbonate 3.5-5 weight part; Aluminium hydroxide 5-8 weight part, by compound-mediate-make and expect-plastify-extrude-coil the operation manufacturing, it is mediated temperature and is controlled at 90-110 ℃ with raw material, and plasticization temperature is controlled at 120-150 ℃.
CN93109001A 1993-07-21 1993-07-21 Linear low density polyethylene fire retardant sleeve and its method for mfg. Expired - Fee Related CN1043048C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN93109001A CN1043048C (en) 1993-07-21 1993-07-21 Linear low density polyethylene fire retardant sleeve and its method for mfg.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN93109001A CN1043048C (en) 1993-07-21 1993-07-21 Linear low density polyethylene fire retardant sleeve and its method for mfg.

Publications (2)

Publication Number Publication Date
CN1085920A CN1085920A (en) 1994-04-27
CN1043048C true CN1043048C (en) 1999-04-21

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CN93109001A Expired - Fee Related CN1043048C (en) 1993-07-21 1993-07-21 Linear low density polyethylene fire retardant sleeve and its method for mfg.

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104277311A (en) * 2013-07-04 2015-01-14 东港市远东节水灌溉设备有限公司 Agricultural thin-wall micro drip tube and making method thereof
CN104277310A (en) * 2013-07-04 2015-01-14 东港市远东节水灌溉设备有限公司 Flame-retardant linear low density polyethylene tube and its making method

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3943194A (en) * 1972-05-25 1976-03-09 Hoechst Aktiengesellschaft Flameproof moulding compositions based on polyolefins
CN86102719A (en) * 1985-03-20 1986-11-26 大日日本电缐株式会社 About flame-retardant resin composition

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3943194A (en) * 1972-05-25 1976-03-09 Hoechst Aktiengesellschaft Flameproof moulding compositions based on polyolefins
CN86102719A (en) * 1985-03-20 1986-11-26 大日日本电缐株式会社 About flame-retardant resin composition

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
《塑料助剂手册》 1986.3.1 吕世光,轻工业出版社 *

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