CN104292979A - Super-slip easily-flowing acrylic-resin printing ink - Google Patents
Super-slip easily-flowing acrylic-resin printing ink Download PDFInfo
- Publication number
- CN104292979A CN104292979A CN201410362531.5A CN201410362531A CN104292979A CN 104292979 A CN104292979 A CN 104292979A CN 201410362531 A CN201410362531 A CN 201410362531A CN 104292979 A CN104292979 A CN 104292979A
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- printing ink
- ink
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
Abstract
The invention relates to the field of printing ink, and concretely relates to super-slip easily-flowing acrylic-resin printing ink. The printing ink is prepared from the following raw materials in parts by weight: 5-8 parts of acetyl tributyl citrate, 3-4 parts of corn starch, 2-4 parts of 1,6-hexanediol, 1-3 parts of octyltrimethylammonium chloride, 28-32 parts of acrylic resin, 6-8 parts of talcum powder, 10-12 parts of an organic pigment, 12-15 parts of isopropanol, 20-25 parts of 1-methoxy-2-propyl acetate, and 2-4 parts of an auxiliary agent. The printing ink is low in content of toxic volatile organics and small in harm to environment and human body; corn starch processed by an isopropanol aqueous solution is well dispersed in resin and a solvent and helps to improve the printing adaptability, and by combining octyltrimethylammonium chloride, the auxiliary agent and the other raw materials for assisting printing ink to be dry and improve the printing quality, the prepared printing ink is low in surface tension, strong in adhesive force with a base material, good in levelling property, easy to transfer, clear and firm in printing traces, high in printing quality and efficient in printing.
Description
Technical field
The present invention relates to printing-ink field, be specifically related to the runny acrylic resin printing-ink of a kind of superslide.
Background technology
Printing-ink is a kind of common printed matter coloured material, and forming primarily of compositions such as pigment, low-melting ink vehicle, stopping composition, is the pulpous state adherent that a class is coloured, have certain degree of mobilization.Want to obtain gratifying printing effect, to the color of ink in actual use procedure, printing adaptability, rate of drying has certain requirement, also to possess water-fast according to environment for use simultaneously, fast light, acid and alkali-resistance, the features such as low toxic and environment-friendly, following printing-ink developing direction must be towards low toxicity, quick-drying, the future development of the naturally various and multifunction of color, but the inadequate environmental protection of existing ink ubiquity, viscosity controls uneven, not good and partial properties good ink such as to hold at high price at the shortcoming with base material sticking power, therefore, the composition and engineering of necessary improvement printing-ink, the transition of quickening industry, to reach the production model of high-efficiency environment friendly.
Summary of the invention
The object of the invention is to, provide a kind of superslide runny acrylic resin printing-ink, to achieve these goals, the technical solution used in the present invention is as follows:
The runny acrylic resin printing-ink of a kind of superslide, it is characterized in that, this ink is made up of the raw material of following weight part: tributyl acetylcitrate 5-8, W-Gum 3-4,1,6-hexylene glycol 2-4, octyltrimethylammonium chloride 1-3, acrylic resin 28-32, talcum powder 6-8, pigment dyestuff 10-12, Virahol 12-15,1-Methoxy-2-propyl acetate 20-25, auxiliary agent 2-4;
The raw material of following weight part is comprised: emulsifier op-10 2-4,2-pyridine carboxylic acid 0.1-0.2, naphthenic acid rare earth 1-2, dehydrated alcohol 10-15, graphene oxide 5-8 in described auxiliary agent, preparation method is: first add in dehydrated alcohol by 2-pyridine carboxylic acid, naphthenic acid rare earth, after dispersed with stirring 20-30min, add graphene oxide again, mixture ball milling 1-2h after stirring, add other remaining component subsequently, continue to stir 20-30min, to obtain final product.
The runny acrylic resin printing-ink of described a kind of superslide, its preparation method is as follows:
(1) first by W-Gum and 5 times in the deionized water of its weight part, furnishing pasty state, adds Virahol subsequently, and continue dispersed with stirring 40-50min, gained material is for subsequent use;
(2) acrylic resin, pigment dyestuff are mixed with 1-Methoxy-2-propyl acetate, after stirring, add octyltrimethylammonium chloride, continue dispersed with stirring 30-40min, finally add step (1) gained material and the mixing of other remaining component, after the rotating speed dispersed with stirring 50-60min of 1200-1500 rev/min, drop into ball-milling processing in ball mill, the particle diameter of gained slurry is made to be 5-20 μm, and adjusting viscosity as required, to obtain final product.
Ink advantage prepared by the present invention is: the principle that first have followed low toxic and environment-friendly in the preparation of raw material, toxic volatile organic content is low, little to the harm of environment and human body, W-Gum after isopropanol water solution process is energy good distribution in resin and solvent, improve the viscosity of ink, improve printing adaptability, again in conjunction with octyltrimethylammonium chloride, the energy such as auxiliary agent auxiliary inks is dry, improve the raw material of printing quality, ink surface tension prepared by the present invention is low, with the strong adhesion of base material, good leveling property, be easy to transfer, trace is smooth, clear, firmly, printing high-quality and high-efficiency.
Embodiment
Embodiment
Printing-ink prepared by the present embodiment is made up of the raw material of following weight part: tributyl acetylcitrate 6, W-Gum 3,1,6-hexylene glycol 4, octyltrimethylammonium chloride 1, acrylic resin 32, talcum powder 6, pigment dyestuff 12, Virahol 15,1-Methoxy-2-propyl acetate 25, auxiliary agent 2; Wherein auxiliary agent is made up of the raw material of following weight part: emulsifier op-10 4,2-pyridine carboxylic acid 0.1, naphthenic acid rare earth 2, dehydrated alcohol 15, graphene oxide 8, preparation method is: first add in dehydrated alcohol by 2-pyridine carboxylic acid, naphthenic acid rare earth, after dispersed with stirring 30min, add graphene oxide again, mixture ball milling 1h after stirring, add other remaining component subsequently, continue to stir 30min, to obtain final product.
The preparation method of this printing-ink is as follows:
(1) first by W-Gum and 5 times in the deionized water of its weight part, furnishing pasty state, adds Virahol subsequently, and continue dispersed with stirring 50min, gained material is for subsequent use;
(2) acrylic resin, pigment dyestuff are mixed with 1-Methoxy-2-propyl acetate, after stirring, add octyltrimethylammonium chloride, continue dispersed with stirring 40min, finally add step (1) gained material and the mixing of other remaining component, after the rotating speed dispersed with stirring 60min of 1500 revs/min, drop into ball-milling processing in ball mill, the particle diameter making gained slurry is 15 μm, to obtain final product.
The performance test results of ink of the present invention is:
| Test item | Detected result |
| Form and aspect | Consistent with standard colour card |
| Viscosity (coating No. 4 cups, s/25 DEG C) | 20 |
| Tinting strength (%) | 98.4 |
| First dryness (mm) | 12 |
| Gloss (60 DEG C, specular gloss instrument) | 70.2％ |
| Attachment fastness (%) | 97.6 |
| Acid and alkali-resistance, water tolerance | Well |
| Package stability (5 DEG C-30 DEG C) | Well |
Above-mentioned test is all followed relevant criterion and is carried out.
Claims (2)
1. the runny acrylic resin printing-ink of superslide, it is characterized in that, this printing-ink is made up of the raw material of following weight part: tributyl acetylcitrate 5-8, W-Gum 3-4,1,6-hexylene glycol 2-4, octyltrimethylammonium chloride 1-3, acrylic resin 28-32, talcum powder 6-8, pigment dyestuff 10-12, Virahol 12-15,1-Methoxy-2-propyl acetate 20-25, auxiliary agent 2-4;
Described auxiliary agent is made up of the raw material of following weight part: emulsifier op-10 2-4,2-pyridine carboxylic acid 0.1-0.2, naphthenic acid rare earth 1-2, dehydrated alcohol 10-15, graphene oxide 5-8, preparation method is: first add in dehydrated alcohol by 2-pyridine carboxylic acid, naphthenic acid rare earth, after dispersed with stirring 20-30min, add graphene oxide again, mixture ball milling 1-2h after stirring, add other remaining component subsequently, continue to stir 20-30min, to obtain final product.
2. the runny acrylic resin printing-ink of a kind of superslide as claimed in claim 1, its preparation method is as follows:
(1) first by W-Gum and 5 times in the deionized water of its weight part, furnishing pasty state, adds Virahol subsequently, and continue dispersed with stirring 40-50min, gained material is for subsequent use;
(2) acrylic resin, pigment dyestuff are mixed with 1-Methoxy-2-propyl acetate, after stirring, add octyltrimethylammonium chloride, continue dispersed with stirring 30-40min, finally add step (1) gained material and the mixing of other remaining component, after the rotating speed dispersed with stirring 50-60min of 1200-1500 rev/min, drop into ball-milling processing in ball mill, the particle diameter of gained slurry is made to be 5-20 μm, and adjusting viscosity as required, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410362531.5A CN104292979A (en) | 2014-07-28 | 2014-07-28 | Super-slip easily-flowing acrylic-resin printing ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410362531.5A CN104292979A (en) | 2014-07-28 | 2014-07-28 | Super-slip easily-flowing acrylic-resin printing ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104292979A true CN104292979A (en) | 2015-01-21 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410362531.5A Pending CN104292979A (en) | 2014-07-28 | 2014-07-28 | Super-slip easily-flowing acrylic-resin printing ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104292979A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105086618A (en) * | 2015-10-08 | 2015-11-25 | 苏州市永津彩印包装有限公司 | High-quality anti-setoff printing ink |
| CN107118615A (en) * | 2017-05-23 | 2017-09-01 | 广西真龙实业有限责任公司 | A kind of printing-ink containing porous-starch and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101426923A (en) * | 2006-02-10 | 2009-05-06 | 杜邦塔特和莱尔生物产品有限责任公司 | Biodegradable compositions comprising renewably-based, biodegradable 1,3-propanediol |
| US20120045510A1 (en) * | 2010-08-18 | 2012-02-23 | Joel Waldman | Tablet sleeve for improved performance |
| CN102711723A (en) * | 2009-12-11 | 2012-10-03 | 荷兰联合利华有限公司 | Multi-phase hair conditioner |
| CN102892823A (en) * | 2010-04-14 | 2013-01-23 | 路博润高级材料公司 | Thickened amino acid surfactant compositions and methods therefor |
| CN103113786A (en) * | 2013-03-07 | 2013-05-22 | 苏州牛剑新材料有限公司 | Graphene conductive ink and preparation method thereof |
-
2014
- 2014-07-28 CN CN201410362531.5A patent/CN104292979A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101426923A (en) * | 2006-02-10 | 2009-05-06 | 杜邦塔特和莱尔生物产品有限责任公司 | Biodegradable compositions comprising renewably-based, biodegradable 1,3-propanediol |
| CN102711723A (en) * | 2009-12-11 | 2012-10-03 | 荷兰联合利华有限公司 | Multi-phase hair conditioner |
| CN102892823A (en) * | 2010-04-14 | 2013-01-23 | 路博润高级材料公司 | Thickened amino acid surfactant compositions and methods therefor |
| US20120045510A1 (en) * | 2010-08-18 | 2012-02-23 | Joel Waldman | Tablet sleeve for improved performance |
| CN103113786A (en) * | 2013-03-07 | 2013-05-22 | 苏州牛剑新材料有限公司 | Graphene conductive ink and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105086618A (en) * | 2015-10-08 | 2015-11-25 | 苏州市永津彩印包装有限公司 | High-quality anti-setoff printing ink |
| CN107118615A (en) * | 2017-05-23 | 2017-09-01 | 广西真龙实业有限责任公司 | A kind of printing-ink containing porous-starch and preparation method thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20150121 |