CN104275188B - Visible light-responded photocatalyst CuTi2V4O15And preparation method thereof - Google Patents
Visible light-responded photocatalyst CuTi2V4O15And preparation method thereof Download PDFInfo
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- CN104275188B CN104275188B CN201410548140.2A CN201410548140A CN104275188B CN 104275188 B CN104275188 B CN 104275188B CN 201410548140 A CN201410548140 A CN 201410548140A CN 104275188 B CN104275188 B CN 104275188B
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Abstract
The invention discloses a kind of visible light-responded photocatalyst CuTi2V4O15And preparation method thereof.The chemical constitution formula of this photocatalyst is CuTi2V4O15.The preparation method that the invention also discloses above-mentioned material.The photocatalyst that the present invention obtains has spectral response range width, and light conversion efficiency is high and the advantage such as good stability has the effect decomposing harmful chemical, organic-biological matter and sterilization under visible light illumination；Additionally preparation method is simple, synthesis temperature is low, and cost is low, is suitable for commercial production and application.
Description
Technical field
The present invention relates to a kind of visible light-responded photocatalyst CuTi2V4O15And preparation method thereof, belong to inorganic field of photocatalytic material.
Background technology
Along with socioeconomic development, people increasingly pay close attention to for the energy and ecological environment, solve energy shortage and problem of environmental pollution be realize sustainable development, improve people's living standard and safeguard national security in the urgent need to.
From phase late 1970s, there has been proposed and utilize in photocatalyst decomposition water and the Organic substance such as pesticide in air and odorant, and scribble the application example such as self-cleaning of the surface of solids of photocatalyst.The principle of light-catalyzed reaction is that photocatalyst is absorbing after higher than the photon of its band-gap energy, generates hole and electronics, and these holes and electronics carry out oxidation reaction and reduction reaction respectively, reaches to decompose the purpose of harmful chemical, organic-biological matter and sterilization.Photocatalyst has many kinds, and wherein most representative is titanium dioxide (TiO2), utilize titanium dioxide that the Organic substances such as the pesticide in water and in air and odorant are decomposed, but the band gap of titanium dioxide is 3.2eV, under the ultraviolet irradiation shorter than 400nm, only just can show activity, can only at indoor or the local work having uviol lamp, being little to utilize visible ray, this greatly limits the use of titanium dioxide optical catalyst.
Considering photocatalyst practicality in decomposing harmful substances, it is indispensable for utilizing sunlight as light source.Irradiate the sunlight medium wavelength maximum intensity of visible ray near 500nm to earth's surface, the energy that wavelength is the visible region of 400nm ~ 750nm is about the 43% of sunlight gross energy, so for efficient utilization, the R and D of bismuth series photocatalyst have been achieved for a series of great achievement, bismuthous complex such as BiVO4、Bi2MoO6、Bi2Mo2O9、Bi2Mo3O12And Bi2WO4It is in the news and there is good absorption under visible light.A series of niobiums (tantalum) hydrochlorate photocatalyst is widely studied owing to having higher photocatalytic activity.Such as, niobate photocatalyst Pb3Nb4O13、BiNbO4And Bi2MNbO7(M=Al, Ga, In, Y, rare earth element and Fe) etc. and niobium potassium compound oxide photocatalyst such as KNbO3、KNb3O8、K4Nb6O17And K6Nb10.6O30Deng all having good photocatalysis performance, but its intrinsic photocatalytic effect is very weak or do not have activity in visible-range.
Although photocatalysis research has been carried out the several years, but at present report to have visible light-responded photocatalyst kind still very limited, still suffer from that light conversion efficiency is low, poor stability and the problem such as spectral response range is narrow, so it is very necessary for researching and developing the new visible light-responded high efficiency photocatalyst that has.We are to consisting of ZnTi2V4O15、MgTi2V4O15、CuTi2V4O15、NiTi2V4O15Compound carried out Photocatalytic Performance Study, found that CuTi2V4O15Band gap be 2.73eV, have excellence visible light-responded photocatalysis performance, the band gap width of other sample both is greater than 3.2eV, just can only can show activity under ultraviolet irradiation.
Summary of the invention
It is an object of the invention to provide and a kind of there is visible light-responded photocatalyst CuTi2V4O15And preparation method thereof.
The chemical constitution formula with visible light-responded photocatalyst that the present invention relates to is: CuTi2V4O15。
The preparation method of above-mentioned visible light-responded photocatalyst concretely comprises the following steps:
(1) by 99.9% analytically pure chemical raw material CuO, TiO2And V2O5Starting powder press CuTi2V4O15Composition weigh dispensing.
(2) raw material mixing step (1) prepared, puts in ball grinder, adds zirconia ball and distilled water, ball milling 8 hours, be mixed and finely ground, take out and dry, cross 200 mesh sieves.
(3) by the powder of step (2) mix homogeneously 750 ~ 800 DEG C of pre-burnings, and it is incubated 6 hours, naturally cools to room temperature, then pass through ball mill pulverizing and make average diameter of particles diminish, lower than 2 μm, namely obtain CuTi2V4O15Powder.
The spectral response range width of the photocatalyst that the present invention obtains, light conversion efficiency height and good stability, have the effect decomposing harmful chemical, organic-biological matter and sterilization under visible light illumination；Additionally preparation method is simple, synthesis temperature is low, and cost is low, is suitable for commercial production and application.
Detailed description of the invention
Present invention will be described in detail below:
1, in order to obtain the composite oxides used in the present invention, prepare powder first by solid-phase synthesis, namely various oxides or the carbonate as raw material is measured ratio according to target constitutional chemistry and mixes, then synthesize in air atmosphere at ambient pressure.
2 in order to effectively utilize light, and the size of the photocatalyst in the present invention is preferably in micron level, or even nanoparticle, and specific surface area is bigger.The oxide powder prepared with solid-phase synthesis, its particle is relatively big and surface area is less, but can be by ball mill and pulverize means and make particle diameter diminish.
3, the photocatalysis experiment of the present invention is using methyl orange as simulation organic pollution, and its concentration is 20mg/L；Photocatalyst CuTi2V4O15Addition be 1g/L；Light source uses the xenon lamp of 300W, and reactive tank uses the vessel that pyrex is made, and obtains the wavelength light more than 420nm by wave filter, then irradiates photocatalyst；Catalysis time is set as 60 minutes.
Embodiment 1:
(1) by 99.9% analytically pure chemical raw material CuO, TiO2And V2O5Starting powder press CuTi2V4O15Composition weigh dispensing.
(2) raw material mixing step (1) prepared, puts in ball grinder, adds zirconia ball and distilled water, ball milling 8 hours, be mixed and finely ground, take out and dry, cross 200 mesh sieves.
(3) by the powder of step (2) mix homogeneously 750 DEG C of pre-burnings, and it is incubated 6 hours, naturally cools to room temperature, then pass through ball mill pulverizing and make average diameter of particles diminish, lower than 2 μm, namely obtain CuTi2V4O15Powder.
Prepared photocatalyst, under the wavelength radiation of visible light more than 420nm, reaches 97.8% to methyl orange clearance in 60 minutes.
Embodiment 2:
(1) by 99.9% analytically pure chemical raw material CuO, TiO2And V2O5Starting powder press CuTi2V4O15Composition weigh dispensing.
(2) raw material mixing step (1) prepared, puts in ball grinder, adds zirconia ball and distilled water, ball milling 8 hours, be mixed and finely ground, take out and dry, cross 200 mesh sieves.
(3) by the powder of step (2) mix homogeneously 780 DEG C of pre-burnings, and it is incubated 6 hours, naturally cools to room temperature, then pass through ball mill pulverizing and make average diameter of particles diminish, lower than 2 μm, namely obtain CuTi2V4O15Powder.
Prepared photocatalyst, under the wavelength radiation of visible light more than 420nm, reaches 98.3% to methyl orange clearance in 60 minutes.
Embodiment 3:
(1) by 99.9% analytically pure chemical raw material CuO, TiO2And V2O5Starting powder press CuTi2V4O15Composition weigh dispensing.
(2) raw material mixing step (1) prepared, puts in ball grinder, adds zirconia ball and distilled water, ball milling 8 hours, be mixed and finely ground, take out and dry, cross 200 mesh sieves.
(3) by the powder of step (2) mix homogeneously 800 DEG C of pre-burnings, and it is incubated 6 hours, naturally cools to room temperature, then pass through ball mill pulverizing and make average diameter of particles diminish, lower than 2 μm, namely obtain CuTi2V4O15Powder.
Prepared photocatalyst, under the wavelength radiation of visible light more than 420nm, methyl orange clearance is reached 97.7% by 60min.
The present invention is never limited to above example.The bound of each temperature, interval value can realize the present invention, embodiment numerous to list herein.
The made photocatalyst powder of above inventive embodiments can be carried on multiple matrix surface.Matrix can be glass, pottery, activated carbon or quartz sand etc., and photocatalyst can be carried on matrix surface in the form of a film.
Claims (1)
1. photocatalyst one kind visible light-responded, it is characterised in that the chemical constitution formula of described photocatalyst is CuTi2V4O15；
The preparation method of described photocatalyst concretely comprises the following steps:
(1) by 99.9% analytically pure chemical raw material CuO, TiO2And V2O5Starting powder press CuTi2V4O15Composition weigh dispensing；
(2) raw material mixing step (1) prepared, puts in ball grinder, adds zirconia ball and distilled water, ball milling 8 hours, be mixed and finely ground, take out and dry, cross 200 mesh sieves；
(3) by the powder of step (2) mix homogeneously 750 ~ 800 DEG C of pre-burnings, and it is incubated 6 hours, naturally cools to room temperature, then pass through ball mill pulverizing and make average diameter of particles lower than 2 μm, namely obtain CuTi2V4O15Powder.
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| CN1329115C (en) * | 2005-04-28 | 2007-08-01 | 中国科学技术大学 | High activaty 24 photocatalyst Caln2O4 and its preparation process |
| CN1817453A (en) * | 2006-03-02 | 2006-08-16 | 上海交通大学 | Bismuthic acid barium-sodium catalyst with visible light respond and production thereof |
| CN100522350C (en) * | 2006-11-03 | 2009-08-05 | 中国科学院上海硅酸盐研究所 | Hydrothermal method for preparing superstructure visible light responsive Bi2WO6 photcatalyst |
| CN100551831C (en) * | 2008-04-11 | 2009-10-21 | 浙江大学 | Visible light-responded Bi 2WO 6The photocatalyst fused salt preparation method |
| CN101362084B (en) * | 2008-09-18 | 2010-10-13 | 武汉理工大学 | Visible-light response nano Bi3NbO7 photocatalyst preparation method and use thereof |
| CN101362083B (en) * | 2008-09-18 | 2010-06-30 | 武汉理工大学 | Visible-light response nano Bi3TaO7 photocatalyst preparation method and use thereof |
| CN101670285B (en) * | 2009-09-16 | 2012-07-04 | 桂林理工大学 | Visible light responding Bi-system composite oxide photocatalyst Bi2-xRxO3 and preparation method |
| CN101745378B (en) * | 2010-01-02 | 2013-07-24 | 桂林理工大学 | Visible-light response composite oxide photocatalyst Li9Ti5Nb5-xTaxO27 and preparation method thereof |
| CN101745379B (en) * | 2010-01-02 | 2012-07-04 | 桂林理工大学 | Visible-light response composite oxide photocatalyst Li7Ti5Nb3-xTaxO21 and preparation method thereof |
| CN101880159B (en) * | 2010-07-08 | 2012-12-26 | 桂林理工大学 | Group VB doping CaCu3Ti4O12 based pressure sensitive material and preparation method |
| CN103447035B (en) * | 2013-09-09 | 2016-01-13 | 桂林理工大学 | CuTi 2o 5as the application of visible light-responded photochemical catalyst |
| CN103706352B (en) * | 2013-11-17 | 2016-03-02 | 桂林理工大学 | Visible light-responded photochemical catalyst SrLa 10v 4o 26and preparation method thereof |
| CN104069850A (en) * | 2014-05-17 | 2014-10-01 | 桂林理工大学 | Photocatalyst LiTi2V3O12 in response to visible light and preparation method thereof |
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