CN104262823A - High-wear-resistance polyvinyl chloride foamed shoe sole material and manufacturing method thereof - Google Patents
High-wear-resistance polyvinyl chloride foamed shoe sole material and manufacturing method thereof Download PDFInfo
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- CN104262823A CN104262823A CN201410448774.0A CN201410448774A CN104262823A CN 104262823 A CN104262823 A CN 104262823A CN 201410448774 A CN201410448774 A CN 201410448774A CN 104262823 A CN104262823 A CN 104262823A
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- polyvinyl chloride
- sole
- shoe
- high abrasion
- chloride material
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- 239000000463 material Substances 0.000 title claims abstract description 40
- 239000004800 polyvinyl chloride Substances 0.000 title claims abstract description 40
- 229920000915 polyvinyl chloride Polymers 0.000 title claims abstract description 39
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 23
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 17
- 239000007822 coupling agent Substances 0.000 claims abstract description 14
- 239000000314 lubricant Substances 0.000 claims abstract description 3
- 238000005187 foaming Methods 0.000 claims description 32
- 239000006260 foam Substances 0.000 claims description 29
- 238000005299 abrasion Methods 0.000 claims description 28
- 238000001816 cooling Methods 0.000 claims description 16
- 238000010438 heat treatment Methods 0.000 claims description 16
- 238000007493 shaping process Methods 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 13
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- 238000007599 discharging Methods 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 8
- 238000009775 high-speed stirring Methods 0.000 claims description 8
- 238000004898 kneading Methods 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 229920003023 plastic Polymers 0.000 claims description 8
- 239000004033 plastic Substances 0.000 claims description 8
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 8
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000004902 Softening Agent Substances 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 claims description 2
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 claims description 2
- GWOWVOYJLHSRJJ-UHFFFAOYSA-L cadmium stearate Chemical compound [Cd+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O GWOWVOYJLHSRJJ-UHFFFAOYSA-L 0.000 claims description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical group [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 2
- 239000008116 calcium stearate Substances 0.000 claims description 2
- 235000013539 calcium stearate Nutrition 0.000 claims description 2
- UQLDLKMNUJERMK-UHFFFAOYSA-L di(octadecanoyloxy)lead Chemical compound [Pb+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O UQLDLKMNUJERMK-UHFFFAOYSA-L 0.000 claims description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 2
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 claims description 2
- UMKARVFXJJITLN-UHFFFAOYSA-N lead;phosphorous acid Chemical compound [Pb].OP(O)O UMKARVFXJJITLN-UHFFFAOYSA-N 0.000 claims description 2
- SJOCPYUKFOTDAN-ZSOIEALJSA-N methyl (4z)-4-hydroxyimino-6,6-dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophene-1-carboxylate Chemical group C1C(C)(C)C\C(=N\O)C=2C1=C(C(=O)OC)SC=2SC SJOCPYUKFOTDAN-ZSOIEALJSA-N 0.000 claims description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 claims description 2
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical compound CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 claims description 2
- AGGKEGLBGGJEBZ-UHFFFAOYSA-N tetramethylenedisulfotetramine Chemical compound C1N(S2(=O)=O)CN3S(=O)(=O)N1CN2C3 AGGKEGLBGGJEBZ-UHFFFAOYSA-N 0.000 claims description 2
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000004088 foaming agent Substances 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/102—Azo-compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/107—Nitroso compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
The invention provides a high-wear-resistance polyvinyl chloride foamed shoe sole material which is prepared from the following components in parts by weight: 50-60 parts of polyvinyl chloride, 5-10 parts of nano silicon carbide, 30-40 parts of plasticizer, 0.5-1 part of foaming agent, 0.1-0.5 part of coupling agent, 1-4 parts of ACR, 1.5-3 parts of stabilizer and 0.5-1 part of lubricant. The invention also provides a manufacturing method of the high-wear-resistance polyvinyl chloride foamed shoe sole material. The polyvinyl chloride foamed shoe sole material provided by the invention has favorable wear resistance.
Description
Technical field:
The present invention relates to a kind of material for sole of shoe, particularly relate to a kind of foam polyvinyl chloride material for sole of shoe and manufacture method thereof of high abrasion.
Background technology:
Foam polyvinyl chloride material for sole of shoe is matrix with polyvinyl chloride (PVC) RESINS, adds the auxiliary agents such as appropriate whipping agent, stablizer, and through mediating granulation, injection moulding obtains.More soft than common polyvinyl chloride material for sole of shoe, quality lightens, and elasticity is better, and various aspects of performance is close to urethane-PU material for sole of shoe, and cost is low a lot.But, while pliability raising, weight reduce, the wear resistance of foam polyvinyl chloride material for sole of shoe is also weakened much, shortens its work-ing life.
Summary of the invention:
The technical problem to be solved in the present invention is to provide a kind of foam polyvinyl chloride material for sole of shoe of high abrasion, has good wear resisting property.
For solving the problems of the technologies described above, technical scheme of the present invention is:
A foam polyvinyl chloride material for sole of shoe for high abrasion, its weight part consists of:
Preferably, softening agent of the present invention is at least one in n-butyl phthalate, dinoctyl phthalate, Phthalic acid, diallyl ester, diethyl phthalate.
Preferably, whipping agent of the present invention is Cellmic C 121, the sub-methyne tetramine of dinitroso or Diisopropyl azodicarboxylate.
Preferably, coupling agent of the present invention is titanate coupling agent.
Preferably, stablizer of the present invention is dibasic lead stearate, second base lead sulfate or dibasic lead phosphite.
Preferably, lubricant of the present invention is calcium stearate, lead stearate, barium stearate, Zinic stearas or cadmium stearate.
Another technical problem that the present invention will solve is to provide the manufacture method of the foam polyvinyl chloride material for sole of shoe of above-mentioned high abrasion.
For solving the problems of the technologies described above, technical scheme is:
A manufacture method for the foam polyvinyl chloride material for sole of shoe of high abrasion, comprises the following steps:
(1) nanometer silicon carbide is dissolved in the aqueous solution of coupling agent, high-speed stirring 5 minutes, is placed in baking oven and dries 3 hours at 130 DEG C, obtain modified Nano silicon carbide;
(2) the modified Nano silicon nitride that other components and step (1) obtain is added kneader heating to mediate, mediate discharging after 2.5 hours;
(3) the complete compound of kneading is added twin-roll plastic mixing mill to plasticate pulling-on piece, plasticating temperature is 110 DEG C, obtains sheet stock;
(4) sheet stock is sent into thermocompressor heating plasticizing, foaming, cooling and shaping after foaming, obtains blank after the demoulding;
(5) blank to be sent in drying room foamable 35 minutes, temperature is 130 DEG C, and after obtaining foaming sheet stock, a few days is placed in cooling;
(6) foaming sheet stock stamping-out step (5) obtained is shaping, obtains the foam polyvinyl chloride material for sole of shoe of high abrasion.
Therefore compared with prior art, the present invention has following beneficial effect:
Nanometer silicon carbide density is low, hardness is high, there is excellent thermodynamic stability, wear resisting property and chemical proofing, fill nanometer silicon carbide in polyvinyl-chloride foam material after, improve its ultimate compression strength, hardness and creep-resistant property, when rubbing with other materials, nanometer silicon carbide can play carrying effect, therefore improves the wear resisting property of this material for sole of shoe, affinity between nanometer silicon carbide and PVC base system is poor, interface bond strength is lower, therefore the present invention has carried out modification by coupling agent to nanometer silicon carbide, after process its dispersiveness in PVC base system be improved significantly, reunion smaller volume and being evenly distributed, its intrinsic wetting ability is also changed, significantly improve with the interface bond strength of polyvinyl chloride, in friction process, nanometer silicon carbide not easily comes off from resin, reduce the abrasive wear of material, thus reduce abrasion loss and the rubbing factor of whole material for sole of shoe, significantly improve its wear resisting property.
Embodiment:
Describe the present invention in detail below in conjunction with specific embodiment, be used for explaining the present invention in this illustrative examples of the present invention and explanation, but not as a limitation of the invention.
Embodiment 1
A foam polyvinyl chloride material for sole of shoe for high abrasion, its weight part consists of:
Its manufacture method comprises the following steps:
(1) nanometer silicon carbide is dissolved in the aqueous solution of coupling agent, high-speed stirring 5 minutes, is placed in baking oven and dries 3 hours at 130 DEG C, obtain modified Nano silicon carbide;
(2) the modified Nano silicon nitride that other components and step (1) obtain is added kneader heating to mediate, mediate discharging after 2.5 hours;
(3) the complete compound of kneading is added twin-roll plastic mixing mill to plasticate pulling-on piece, plasticating temperature is 110 DEG C, obtains sheet stock;
(4) sheet stock is sent into thermocompressor heating plasticizing, foaming, cooling and shaping after foaming, obtains blank after the demoulding;
(5) blank to be sent in drying room foamable 35 minutes, temperature is 130 DEG C, and after obtaining foaming sheet stock, a few days is placed in cooling;
(6) foaming sheet stock stamping-out step (5) obtained is shaping, obtains the foam polyvinyl chloride material for sole of shoe of high abrasion.
Embodiment 2
A foam polyvinyl chloride material for sole of shoe for high abrasion, its weight part consists of:
Its manufacture method comprises the following steps:
(1) nanometer silicon carbide is dissolved in the aqueous solution of coupling agent, high-speed stirring 5 minutes, is placed in baking oven and dries 3 hours at 130 DEG C, obtain modified Nano silicon carbide;
(2) the modified Nano silicon nitride that other components and step (1) obtain is added kneader heating to mediate, mediate discharging after 2.5 hours;
(3) the complete compound of kneading is added twin-roll plastic mixing mill to plasticate pulling-on piece, plasticating temperature is 110 DEG C, obtains sheet stock;
(4) sheet stock is sent into thermocompressor heating plasticizing, foaming, cooling and shaping after foaming, obtains blank after the demoulding;
(5) blank to be sent in drying room foamable 35 minutes, temperature is 130 DEG C, and after obtaining foaming sheet stock, a few days is placed in cooling;
(6) foaming sheet stock stamping-out step (5) obtained is shaping, obtains the foam polyvinyl chloride material for sole of shoe of high abrasion.
Embodiment 3
A foam polyvinyl chloride material for sole of shoe for high abrasion, its weight part consists of:
Its manufacture method comprises the following steps:
(1) nanometer silicon carbide is dissolved in the aqueous solution of coupling agent, high-speed stirring 5 minutes, is placed in baking oven and dries 3 hours at 130 DEG C, obtain modified Nano silicon carbide;
(2) the modified Nano silicon nitride that other components and step (1) obtain is added kneader heating to mediate, mediate discharging after 2.5 hours;
(3) the complete compound of kneading is added twin-roll plastic mixing mill to plasticate pulling-on piece, plasticating temperature is 110 DEG C, obtains sheet stock;
(4) sheet stock is sent into thermocompressor heating plasticizing, foaming, cooling and shaping after foaming, obtains blank after the demoulding;
(5) blank to be sent in drying room foamable 35 minutes, temperature is 130 DEG C, and after obtaining foaming sheet stock, a few days is placed in cooling;
(6) foaming sheet stock stamping-out step (5) obtained is shaping, obtains the foam polyvinyl chloride material for sole of shoe of high abrasion.
Embodiment 4
A foam polyvinyl chloride material for sole of shoe for high abrasion, its weight part consists of:
Its manufacture method comprises the following steps:
(1) nanometer silicon carbide is dissolved in the aqueous solution of coupling agent, high-speed stirring 5 minutes, is placed in baking oven and dries 3 hours at 130 DEG C, obtain modified Nano silicon carbide;
(2) the modified Nano silicon nitride that other components and step (1) obtain is added kneader heating to mediate, mediate discharging after 2.5 hours;
(3) the complete compound of kneading is added twin-roll plastic mixing mill to plasticate pulling-on piece, plasticating temperature is 110 DEG C, obtains sheet stock;
(4) sheet stock is sent into thermocompressor heating plasticizing, foaming, cooling and shaping after foaming, obtains blank after the demoulding;
(5) blank to be sent in drying room foamable 35 minutes, temperature is 130 DEG C, and after obtaining foaming sheet stock, a few days is placed in cooling;
(6) foaming sheet stock stamping-out step (5) obtained is shaping, obtains the foam polyvinyl chloride material for sole of shoe of high abrasion.
Embodiment 5
A foam polyvinyl chloride material for sole of shoe for high abrasion, its weight part consists of:
Its manufacture method comprises the following steps:
(1) nanometer silicon carbide is dissolved in the aqueous solution of coupling agent, high-speed stirring 5 minutes, is placed in baking oven and dries 3 hours at 130 DEG C, obtain modified Nano silicon carbide;
(2) the modified Nano silicon nitride that other components and step (1) obtain is added kneader heating to mediate, mediate discharging after 2.5 hours;
(3) the complete compound of kneading is added twin-roll plastic mixing mill to plasticate pulling-on piece, plasticating temperature is 110 DEG C, obtains sheet stock;
(4) sheet stock is sent into thermocompressor heating plasticizing, foaming, cooling and shaping after foaming, obtains blank after the demoulding;
(5) blank to be sent in drying room foamable 35 minutes, temperature is 130 DEG C, and after obtaining foaming sheet stock, a few days is placed in cooling;
(6) foaming sheet stock stamping-out step (5) obtained is shaping, obtains the foam polyvinyl chloride material for sole of shoe of high abrasion.
Embodiment 6
A foam polyvinyl chloride material for sole of shoe for high abrasion, its weight part consists of:
Its manufacture method comprises the following steps:
(1) nanometer silicon carbide is dissolved in the aqueous solution of coupling agent, high-speed stirring 5 minutes, is placed in baking oven and dries 3 hours at 130 DEG C, obtain modified Nano silicon carbide;
(2) the modified Nano silicon nitride that other components and step (1) obtain is added kneader heating to mediate, mediate discharging after 2.5 hours;
(3) the complete compound of kneading is added twin-roll plastic mixing mill to plasticate pulling-on piece, plasticating temperature is 110 DEG C, obtains sheet stock;
(4) sheet stock is sent into thermocompressor heating plasticizing, foaming, cooling and shaping after foaming, obtains blank after the demoulding;
(5) blank to be sent in drying room foamable 35 minutes, temperature is 130 DEG C, and after obtaining foaming sheet stock, a few days is placed in cooling;
(6) foaming sheet stock stamping-out step (5) obtained is shaping, obtains the foam polyvinyl chloride material for sole of shoe of high abrasion.
Above-described embodiment is illustrative principle of the present invention and effect thereof only, but not for limiting the present invention.Any person skilled in the art scholar all without prejudice under spirit of the present invention and category, can modify above-described embodiment or changes.Therefore, such as have in art usually know the knowledgeable do not depart from complete under disclosed spirit and technological thought all equivalence modify or change, must be contained by claim of the present invention.
Claims (7)
1. a foam polyvinyl chloride material for sole of shoe for high abrasion, is characterized in that: its weight part consists of:
2. the foam polyvinyl chloride material for sole of shoe of a kind of high abrasion according to claim 1, is characterized in that: described softening agent is at least one in n-butyl phthalate, dinoctyl phthalate, Phthalic acid, diallyl ester, diethyl phthalate.
3. the foam polyvinyl chloride material for sole of shoe of a kind of high abrasion according to claim 1, is characterized in that: described whipping agent is Cellmic C 121, the sub-methyne tetramine of dinitroso or Diisopropyl azodicarboxylate.
4. the foam polyvinyl chloride material for sole of shoe of a kind of high abrasion according to claim 1, is characterized in that: described coupling agent is titanate coupling agent.
5. the foam polyvinyl chloride material for sole of shoe of a kind of high abrasion according to claim 1, is characterized in that: described stablizer is dibasic lead stearate, second base lead sulfate or dibasic lead phosphite.
6. the foam polyvinyl chloride material for sole of shoe of a kind of high abrasion according to claim 1, is characterized in that: described lubricant is calcium stearate, lead stearate, barium stearate, Zinic stearas or cadmium stearate.
7. the manufacture method of the foam polyvinyl chloride material for sole of shoe of a kind of high abrasion according to claim 1 ~ 6 any one, is characterized in that: comprise the following steps:
(1) nanometer silicon carbide is dissolved in the aqueous solution of coupling agent, high-speed stirring 5 minutes, is placed in baking oven and dries 3 hours at 130 DEG C, obtain modified Nano silicon carbide;
(2) the modified Nano silicon nitride that other components and step (1) obtain is added kneader heating to mediate, mediate discharging after 2.5 hours;
(3) the complete compound of kneading is added twin-roll plastic mixing mill to plasticate pulling-on piece, plasticating temperature is 110 DEG C, obtains sheet stock;
(4) sheet stock is sent into thermocompressor heating plasticizing, foaming, cooling and shaping after foaming, obtains blank after the demoulding;
(5) blank to be sent in drying room foamable 35 minutes, temperature is 130 DEG C, and after obtaining foaming sheet stock, a few days is placed in cooling;
(6) foaming sheet stock stamping-out step (5) obtained is shaping, obtains the foam polyvinyl chloride material for sole of shoe of high abrasion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410448774.0A CN104262823B (en) | 2014-09-04 | The foam polyvinyl chloride material for sole of shoe of a kind of high abrasion and manufacture method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410448774.0A CN104262823B (en) | 2014-09-04 | The foam polyvinyl chloride material for sole of shoe of a kind of high abrasion and manufacture method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
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| CN112029210A (en) * | 2020-09-10 | 2020-12-04 | 张海强 | Wear-resistant foamed sole material and preparation method thereof |
| CN113527750A (en) * | 2020-04-20 | 2021-10-22 | 林祖实 | Modified polyvinyl chloride resin paste mixture directional foaming sole and preparation method thereof |
| CN115104807A (en) * | 2022-07-04 | 2022-09-27 | 界首市玉丰塑业有限公司 | Anti-skid easy-to-dry slipper |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106048592A (en) * | 2016-06-27 | 2016-10-26 | 滁州帝邦科技有限公司 | Method of producing corrosion-resistant water-cooling tank |
| CN107200958A (en) * | 2017-06-13 | 2017-09-26 | 合肥远科服装设计有限公司 | A kind of high performance plastic sole and preparation method thereof |
| CN107254121A (en) * | 2017-07-28 | 2017-10-17 | 合肥布竹梦依服装贸易有限公司 | A kind of high performance plastic sole and preparation method thereof |
| CN113527750A (en) * | 2020-04-20 | 2021-10-22 | 林祖实 | Modified polyvinyl chloride resin paste mixture directional foaming sole and preparation method thereof |
| CN112029210A (en) * | 2020-09-10 | 2020-12-04 | 张海强 | Wear-resistant foamed sole material and preparation method thereof |
| CN115104807A (en) * | 2022-07-04 | 2022-09-27 | 界首市玉丰塑业有限公司 | Anti-skid easy-to-dry slipper |
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