CN104260479A - Polymer alloy waterproof coiled material and production method thereof - Google Patents
Polymer alloy waterproof coiled material and production method thereof Download PDFInfo
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- CN104260479A CN104260479A CN201410428720.8A CN201410428720A CN104260479A CN 104260479 A CN104260479 A CN 104260479A CN 201410428720 A CN201410428720 A CN 201410428720A CN 104260479 A CN104260479 A CN 104260479A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/085—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyolefins
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- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/082—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising vinyl resins; comprising acrylic resins
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- B32B15/00—Layered products comprising a layer of metal
- B32B15/18—Layered products comprising a layer of metal comprising iron or steel
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/15—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J109/00—Adhesives based on homopolymers or copolymers of conjugated diene hydrocarbons
- C09J109/06—Copolymers with styrene
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
- B32B37/1207—Heat-activated adhesive
- B32B2037/1215—Hot-melt adhesive
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/06—Coating on the layer surface on metal layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/20—Inorganic coating
- B32B2255/205—Metallic coating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/54—Yield strength; Tensile strength
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/558—Impact strength, toughness
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/752—Corrosion inhibitor
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Abstract
The invention relates to a polymer alloy waterproof coiled material and a production method thereof. The coiled material comprises an alloy plate layer and a polymer material layer, which are integrated together. Two side surfaces of the alloy plate layer are both painted by an anti-oxidant material. At least one side of the waterproof coiled material is provided with a waterproof anticorrosion self-adhesive rubber layer, whose external side is covered by a silicone oil membrane. The waterproof anticorrosion self-adhesive rubber is composed of the following components in percentage by weight: 20 to 45% of thermoplastic butadiene styrene rubber, 10 to 35% of aromatic hydrocarbon oil, 3 to 25% of thermoplastic solid acrylic resin, 3 to 5% of antirust antiseptic, and 8 to 19% of talcum powder. The coiled material has the advantages of good waterproofness, good corrosion resistance, UV resistance, low temperature resistance, aging resistance, puncture resistance, and quickness for construction, is a novel waterproof material that can be perfectly bound and integrated with buildings, is suitable for various construction projects such as subways, tunnels, bridges, roads, underground projects, roofs, and the like, and is especially suitable for waterproof projects on the surface layer of plant roots.
Description
Technical field
The present invention relates to a kind of waterproof roll, particularly a kind of a kind of high polymer alloy waterproof roll being applied to construction field.
Background technology
At present, face channeling water seepage and the large technical barrier of settlement influence two in the waterproof construction of building field, how to have challenging task for structural concrete provides effective waterproofing protection to be one.Pre-laid method is adopted to construct in prior art, cast directly over by liquid concrete on waterproof roll, after concrete setting, xoncrete structure and waterproof roll are bonded to and are integrated, effectively can prevent moisture from infiltrating the gap of waterproof roll and xoncrete structure, improve waterproof system reliability.Alloy plate layer and macromolecular material composite of water-proof coiled material are current developing direction, but it still exists many deficiencies, as:
1, in manufacturing process, the bonding of polymer material layer and alloy plate layer is difficult, bonds insecure, easily has gap, cause coiled material integral waterproofing impaired performance;
2. most in the waterproof roll overlay at present is modified pitch class adhesive, the peel strength that not only bonds is lower, pitch itself is a kind of hot-fluid cold-short material, therefore high temperature resistant the and poor performance at low temperatures of modified pitch class adhesive, and this makes troubles for summer and construction in winter;
3. alloy plate layer lacks effective anti-oxidant treatment, causes the easy oxidized corrosion of sheet material to cause drainage, cannot carry out resource circulation utilization, cause coiled material whole service life short, and cannot reclaim, and forms solid waste rubbish, waste resource, contaminated environment;
4. the surface of coiled material is without aluminum coated steel, sticky pin, and workman cannot in coiled material surface assembling reinforcement; Also without special protection layer, as because of working-day claims, under the effect of ultraviolet and wind and rain, lose bonding effect and cause product rejection.
To sum up, be badly in need of at present a kind of constructability, high and low temperature resistance is good, bonding peel strength is high, corrosion-resistant ageing-resistant, long service life can be recycled and the high polymer alloy waterproof roll of environmental protection.
Summary of the invention
The object of the invention is to provide a kind of high polymer alloy waterproof roll and production method thereof, to solve in prior art most in waterproof roll be modified pitch class adhesive, lower, the high temperature resistant and poor performance at low temperatures of adhesion strength, to summer and construction in winter bringing the problem of difficulty; Also solve existing high polymer alloy waterproof roll alloy plate layer and macromolecule layer directly bonds, without effective anti-oxidant treatment, cause the easy oxidized corrosion of sheet material to cause drainage, cannot carry out resource circulation utilization, cause that coiled material whole service life is short, problem to environment; Also solve simultaneously existing coiled material surface without polymer material layer and alloy plate layer in aluminum coated steel and manufacturing process bonding difficulty, bond problem that is insecure, that easily have gap, cause coiled material integral waterproofing impaired performance.
For solving above technical problem, the present invention takes following technical scheme;
A kind of high polymer alloy waterproof roll, comprises polymer material layer and the alloy plate layer of compound, it is characterized in that: the coating on both sides of described alloy plate layer has oxidation-resistant material layer; The outside of described polymer material layer and/or alloy plate layer is laid with the water-tight corrosion-proof self-adhesive bed of material, and the outside of the described water-tight corrosion-proof self-adhesive bed of material is provided with silicon oil membrane;
In the described water-tight corrosion-proof self-adhesive bed of material component of water-tight corrosion-proof self-adhesion sizing material and percentage by weight as follows,
Thermoplastic styrene butadiene rubber 20 ~ 45%;
Aromatic naphtha 10 ~ 35%;
Solid thermoplastics acrylic resin 3 ~ 25%;
Resistance rust anticorrisive agent 3 ~ 5%;
Talcum powder 8 ~ 19%.
As the preferred technical solution of the present invention, described alloy plate layer is the layers of foil of copper alloy, ferroalloy, ashbury metal, metal, aluminium alloy or terne metal.
As present invention further optimization technical scheme, described polymer material layer is HDPE macromolecular sheet material, EVA macromolecular sheet material, PVC macromolecular sheet material or APAO macromolecular sheet material.
As present invention further optimization technical scheme, described oxidation-resistant material layer (2) is the material layer of the copper antioxidant corresponding with alloy plate layer (3) material, iron antioxidant, tin antioxidant, plumbous antioxidant, aluminum antioxidant agent or slicker solder antioxidant.
As present invention further optimization technical scheme, the described water-tight corrosion-proof self-adhesive bed of material by percentage by weight be 28% thermoplastic styrene butadiene rubber, 34% aromatic naphtha, 19% solid thermoplastics acrylic resin, 4% resistance become rusty anticorrisive agent and 15% talcum powder form.
Described thermoplastic styrene butadiene rubber is SBS188 butadiene-styrene rubber; Arene content >=86% in described aromatic naphtha; Described solid thermoplastics acrylic resin is BR series acrylic resin; Described resistance rust anticorrisive agent is MS-105 resistance rust anticorrisive agent.
Preferred, one deck protective cloth is also laid respectively in the both sides of high polymer alloy waterproof roll.
Preferred, described protective cloth is non-woven fabrics, chemical fabric, glass-fiber-fabric or woven cloth.
The present invention also establishes the production method relating to a kind of above-mentioned a kind of high polymer alloy waterproof roll, macromolecular material requires to distribute through material dispenser in proportion, enter again three rollers prolong pressure device carry out prolonging pressure and with alloy plate layer compound, then coating system gluing is entered through traction, enter cooling flattening system subsequently, enter deviation-rectifying system, diced system again, finally carry out rolling, packaging, concrete steps are as follows:
Step one, each composition of water-tight corrosion-proof self-adhesion sizing material is weighed by proportioning after put into hot melt case and carry out melten gel;
Step 2, the plastics of polymer material layer, rubber and additive will be formed load the mixed material being uniformly mixed in blender and forming macromolecular material;
Step 3, preheating extrusion equipment, be extremely front heated to 140 ~ 190 degree by extrusion equipment by rear;
Step 4, with charging equipment, the mixed material of the macromolecular material in blender is squeezed into extrusion equipment, extrude from extrusion equipment after material dispenser and form thin layer macromolecular material;
Step 5, thin layer macromolecular material caused first of roll unit roll and second roll between carry out prolonging pressure, form macromolecular sheet material;
Step 6, alloy plate layer coating on both sides oxidation-resistant material layer formed alloy plate layer;
The alloy plate layer that step 7, macromolecular sheet material step 5 obtained and step 6 obtain carries out compound and prolongs pressure between second rolls and the 3rd rolls, and forms composite sheet;
Step 8, by composite sheet traction to application system coating water-tight corrosion-proof self-adhesion sizing material, during this period, application system must connect hot melt case, treats that hot melt adhesive temperature rises to 160 DEG C, the water-tight corrosion-proof self-adhesion sizing material after fusing is squeezed into application system and carries out coating and become the water-tight corrosion-proof self-adhesive bed of material;
Step 9, deposited silicon oil membrane: silicon oil membrane is applied on the surface of the composite sheet after step 8 process;
Step 10, enter cooling flattening system, deviation-rectifying system by hauling machine, finally cut to cutting equipment, the shaping laggard row finished product packing of rolling.
As the optional technical scheme of the present invention, described step 3 or four extrusion equipment be Single screw extrusion equipment or twin-screw extrusion equipment.In described step 8, being that one side is deposited or two-sided during the coating water-tight corrosion-proof self-adhesive bed of material applies.
Compared with prior art, technical advantage of the present invention is:
1. alloy plate layer material prolongs pressure compound with rubber and plastic macromolecular sheet material through hot melt after anti-oxidant treatment, efficiently solves the difficult problem that metal can not bond with polymer base material, makes the character of its simultaneously described macromolecule coiled material and alloy rolled material.Be that raw material adds adjuvant film forming with polymer rubber, imbed underground not perishable, can the life-span same with building when making flush type waterproof material; Macromolecule layer has its tension intensity good high, good percentage elongation, and high and low temperature resistance is good, bonding peel strength is high, the puncture of resistance to water, corrosion resistance, lower temperature resistance and uvioresistant, good, the more resistance to root system of ageing-resistant performance; Alloy plate layer has the puncture well stoping root system, and has good tension intensity;
2. alloy plate layer is with alloy plate layer material for base material, and in addition antioxidant process, in case the oxide etch of alloy plate layer, can protect alloy better, effectively extends the service life of waterproof roll;
3. the water-tight corrosion-proof self-adhesive bed of material replaces traditional modified pitch class adhesive, the water-tight corrosion-proof self-adhesive bed of material comprises thermoplastic elastomer, aromatic naphtha, solid thermoplastics acrylic resin, the water-tight corrosion-proof self-adhesion sizing material thermoplastic elastomer of resistance rust anticorrisive agent and talc agent synthesis, there is the double grading of rubber and plastics, in it, polystyrene segment is as hard segment, form physics cross-linked structure, impart the mechanical property that waterproof roll is good, there is high resilience, high-elongation, hot strength can reach 20 ~ 35MPa, than generally all high by the elastomeric hot strength that chemical action is crosslinked, aromatic naphtha is high temperature resistant and low temperature, not volatile, significantly can improve the processing characteristics of rubber, makes its ageing-resistant, acid and alkali-resistance, and resistance rust antiseptic property is superior, can adapt to winter or hot weather construction, adhesive property is strong, applied widely, can bond on multiple base material, as cement, metal-impregnated wood etc., also can on the basal plane of humidity paving construction, the time, longer bond effect was better,
4. the arranged outside silicon oil membrane of waterproof roll is in case bond between material, for coiled material provides protection, and convenient construction simultaneously.
5. need not construct by naked light, safety and environmental protection.
To sum up, high polymer alloy waterproof roll of the present invention has good waterproof effect and good anti-root system of plant penetrates function, can with building generation self-adhesive, form the waterproof material of tight one, be applicable to the subway of all kinds of architectural engineering, tunnel, Qiao Lu, underground or roofing, be specially adapted to the waterproof construction of anti-root system of plant surface layer.
Accompanying drawing explanation
Fig. 1 is the structural representation of the high polymer alloy waterproof roll of the embodiment 1 that the present invention relates to;
Fig. 2 is the structural representation of the high polymer alloy waterproof roll of the embodiment 2 that the present invention relates to;
Fig. 3 is the structural representation of the high polymer alloy waterproof roll of the embodiment 3 that the present invention relates to;
Fig. 4 is the structural representation of the high polymer alloy waterproof roll of the embodiment 4 that the present invention relates to;
Fig. 5 is the structural representation of the high polymer alloy waterproof roll of the embodiment 5 that the present invention designs;
Fig. 6 is the pipeline organization schematic diagram of the making high polymer alloy waterproof roll that the present invention relates to.
Reference numeral: 1-polymer material layer, 2-oxidation-resistant material layer, 3-alloy plate layer, the 4-water-tight corrosion-proof self-adhesive bed of material, 5-silicon oil membrane, 6-protective cloth, 7-blender, 8-charging equipment, 9-extrusion equipment, 10-roll unit, 11-hot melt case, 12-cool flattening equipment, 13-correcting device, 14-cutting equipment, 15-winding device, 16-packaging facilities.
Detailed description of the invention
If Fig. 1 to Fig. 5 is five embodiments, the high polymer alloy waterproof roll structure of embodiment 1 is as shown in Figure 1 silicon oil membrane 5, the water-tight corrosion-proof self-adhesive bed of material 4, polymer material layer 1, oxidation-resistant material layer 2, alloy plate layer 3 and oxidation-resistant material layer 2 from top to bottom; The structure of the high polymer alloy waterproof roll of embodiment 2 is as shown in Figure 2 polymer material layer 1, oxidation-resistant material layer 2, alloy plate layer 3, oxidation-resistant material layer 2, the water-tight corrosion-proof self-adhesive bed of material 4 and silicon oil membrane 5 from top to bottom; The structure of the high polymer alloy waterproof roll of embodiment 3 is as shown in Figure 3 silicon oil membrane 5, the water-tight corrosion-proof self-adhesive bed of material 4, polymer material layer 1, oxidation-resistant material layer 2, alloy plate layer 3 and oxidation-resistant material layer 2 from top to bottom; The structure of the high polymer alloy waterproof roll of embodiment 4 is as shown in Figure 4 protective cloth 6, polymer material layer 1, oxidation-resistant material layer 2, alloy plate layer 3 and oxidation-resistant material layer 2 from top to bottom; The structure of the high polymer alloy waterproof roll of embodiment 5 is as shown in Figure 5 polymer material layer 1, oxidation-resistant material layer 2, alloy plate layer 3 and oxidation-resistant material layer 2 from top to bottom.Below in conjunction with five embodiments, the present invention is further explained.
A kind of high polymer alloy waterproof roll, comprises polymer material layer 1 and the alloy plate layer 3 of compound, it is characterized in that: described alloy plate layer 3 comprises middle alloy plate layer 31 and is coated in the oxidation-resistant material layer 32 of alloy plate layer both sides; The outside of described polymer material layer 1 and/or alloy plate layer 3 is laid with the water-tight corrosion-proof self-adhesive bed of material 4, and the outside of the described water-tight corrosion-proof self-adhesive bed of material 4 is provided with silicon oil membrane 5; Described alloy plate layer 31 can be the layers of foil of copper alloy, ferroalloy, ashbury metal, metal, aluminium alloy or terne metal.Described polymer material layer 1 can be HDPE macromolecular sheet material, EVA macromolecular sheet material, PVC macromolecular sheet material or APAO macromolecular sheet material.Described oxidation-resistant material layer 2 is the material layer of the copper antioxidant corresponding with alloy plate layer 3 material, iron antioxidant, tin antioxidant, plumbous antioxidant, aluminum antioxidant agent or slicker solder antioxidant.
As Fig. 1 to Fig. 3, waterproof roll at least side is laid with the water-tight corrosion-proof self-adhesive bed of material 4, and the outside of the water-tight corrosion-proof self-adhesive bed of material 4 is provided with silicon oil membrane 5.Wherein, Fig. 1 is the structural representation only arranging the water-tight corrosion-proof self-adhesive bed of material 4 in side of the embodiment 1 that the present invention relates to, Fig. 2 is the embodiment 2 that the present invention relates to arranges the water-tight corrosion-proof self-adhesive bed of material 4 structural representation at opposite side, and Fig. 3 is the structural representation that the both sides of embodiment 3 coiled material that the present invention relates to all arrange the water-tight corrosion-proof self-adhesive bed of material 4.As shown in Figure 4, one deck protective cloth 6 can also respectively be laid in the both sides of waterproof roll of the present invention, and protective cloth 6 can be non-woven fabrics, chemical fabric, glass-fiber-fabric or woven cloth.As shown in Figure 5, the upper and lower surface of described alloy plate layer 3 is laid with the structural representation of one deck oxidation-resistant material 2.
The component of the water-tight corrosion-proof self-adhesion sizing material of the described water-tight corrosion-proof self-adhesive bed of material 4 and the thermoplastic styrene butadiene rubber of percentage by weight 20 ~ 45%, 10 ~ 35% aromatic naphtha, the solid thermoplastics acrylic resin of 3 ~ 25%, the resistance rust anticorrisive agent of 3 ~ 5% and 8 ~ 19% talcum powder, wherein, preferred percentage be 28% thermoplastic styrene butadiene rubber, 34% aromatic naphtha, 19% solid thermoplastics acrylic resin, 4% resistance rust anticorrisive agent and 15% talcum powder composition.Described thermoplastic styrene butadiene rubber is SBS188 butadiene-styrene rubber; Arene content >=86% in described aromatic naphtha; Described solid thermoplastics acrylic resin is BR series acrylic resin; Described resistance rust anticorrisive agent is MS-105 resistance rust anticorrisive agent.
The invention still further relates to the production method of above-mentioned high polymer alloy waterproof roll, as shown in Figure 6, its production line is: blender, and------------coating device--applies film device--and stores material equipment-cooling flattening equipment-correcting device-cutting equipment-winding device-packaging facilities coating device roll unit extrusion equipment charging equipment to apply film device; Concrete making step is as follows:
Step one, each composition of water-tight corrosion-proof self-adhesion sizing material is weighed by proportioning after put into hot melt case 11 and carry out melten gel;
Step 2, the plastics of polymer material layer 1, rubber and additive will be formed load the mixed material being uniformly mixed in blender 7 and forming macromolecular material;
Step 3, preheating extrusion equipment 9, be extremely front heated to 140 ~ 190 degree by extrusion equipment by rear;
Step 4, with charging equipment 8, the mixed material of the macromolecular material in blender 7 is squeezed into extrusion equipment 9, extrude from extrusion equipment after material dispenser and form thin layer macromolecular material;
Step 5, thin layer macromolecular material caused first of roll unit 10 roll and second roll between carry out prolonging pressure, form macromolecular sheet material;
Step 6, form alloy plate layer 3 in the coating on both sides of alloy plate layer 31 at oxidation-resistant material layer 32;
The alloy plate layer 3 that step 7, macromolecular sheet material step 5 obtained and step 6 obtain carries out compound and prolongs pressure between second rolls and the 3rd rolls, and forms composite sheet;
Step 8, by composite sheet traction to application system coating water-tight corrosion-proof self-adhesion sizing material, carry out deposited film (silicone oil paper/film) at rubber surface.The coating rubber membrane of another side is carried out at deposited film cooling rear haulage to second application system, then draw to application system coating self-adhering rubber film, rubber hot melt case should be connected at application system, treat that the temperature to 160 of hot melt rubber is spent, self-adhering rubber after fusing is squeezed into application system carry out coating and become rubber pattern, after coating self-adhering rubber membrane process completes, carry out deposited film (silicone oil paper/film) at rubber surface;
Step 9, deposited silicon oil membrane: silicon oil membrane is applied on the surface of the composite sheet after step 8 process;
Step 10, enter cooling flattening system 12, deviation-rectifying system 13 by hauling machine, finally cut to cutting equipment 14, the shaping laggard row finished product packing of rolling.
Claims (10)
1. a high polymer alloy waterproof roll, comprises polymer material layer (1) and the alloy plate layer (3) of compound, it is characterized in that: the coating on both sides of described alloy plate layer (3) has oxidation-resistant material layer (2); The outside of described polymer material layer (1) and/or alloy plate layer (3) is laid with the water-tight corrosion-proof self-adhesive bed of material (4), and the outside of the described water-tight corrosion-proof self-adhesive bed of material (4) is provided with silicon oil membrane (5);
Component and the percentage by weight of the middle water-tight corrosion-proof self-adhesion sizing material of the described water-tight corrosion-proof self-adhesive bed of material (4) are as follows,
Thermoplastic styrene butadiene rubber 20 ~ 45%;
Aromatic naphtha 10 ~ 35%;
Solid thermoplastics acrylic resin 3 ~ 25%;
Resistance rust anticorrisive agent 3 ~ 5%;
Talcum powder 8 ~ 19%.
2. a kind of high polymer alloy waterproof roll according to claim 1, is characterized in that: described alloy plate layer (3) is copper alloy layers of foil, ferroalloy layers of foil, ashbury metal layers of foil, metal layers of foil, aluminum alloy foil layers or terne metal layers of foil.
3. a kind of high polymer alloy waterproof roll according to claim 1, is characterized in that: described polymer material layer (1) is HDPE macromolecular sheet material, EVA macromolecular sheet material, PVC macromolecular sheet material or APAO macromolecular sheet material.
4. a kind of high polymer alloy waterproof roll according to claim 1, is characterized in that: described oxidation-resistant material layer (2) is the material layer of the copper antioxidant corresponding with alloy plate layer (3) material, iron antioxidant, tin antioxidant, plumbous antioxidant, aluminum antioxidant agent or slicker solder antioxidant.
5. a kind of high polymer alloy waterproof roll according to claim 1, is characterized in that: the described water-tight corrosion-proof self-adhesive bed of material (4) by percentage by weight be 28% thermoplastic styrene butadiene rubber, 34% aromatic naphtha, 19% solid thermoplastics acrylic resin, 4% resistance become rusty anticorrisive agent and 15% talcum powder form.
6. a kind of high polymer alloy waterproof roll according to claim 1, is characterized in that: the both sides of high polymer alloy waterproof roll also lay one deck protective cloth (6) respectively.
7. a kind of high polymer alloy waterproof roll according to claim 6, is characterized in that: described protective cloth (6) is non-woven fabrics, chemical fabric, glass-fiber-fabric or woven cloth.
8. be applied to a production method for a kind of high polymer alloy waterproof roll described in claim 1 ~ 7 any one, it is characterized in that, concrete making step is as follows:
Step one, each composition of water-tight corrosion-proof self-adhesion sizing material is weighed by proportioning after put into hot melt case (11) and carry out melten gel;
Step 2, load forming the plastics of polymer material layer (1), rubber and additive the mixed material being uniformly mixed in blender (7) and forming macromolecular material;
Step 3, preheating extrusion equipment (9), be extremely front heated to 140 ~ 190 degree by extrusion equipment by rear;
Step 4, with charging equipment (8), the mixed material of the macromolecular material in blender (7) is squeezed into extrusion equipment (9), extrude from extrusion equipment after material dispenser and form thin layer macromolecular material;
Step 5, thin layer macromolecular material caused first of roll unit (10) roll and second roll between carry out prolonging pressure, form macromolecular sheet material;
Step 6, alloy plate layer coating on both sides oxidation-resistant material layer (2) formed alloy plate layer (3);
The alloy plate layer (3) that step 7, macromolecular sheet material step 5 obtained and step 6 obtain carries out compound and prolongs pressure between second rolls and the 3rd rolls, and forms composite sheet;
Step 8, by composite sheet traction to application system coating water-tight corrosion-proof self-adhesion sizing material, during this period, application system must connect hot melt case (11), treat that hot melt adhesive temperature rises to 160 DEG C, the water-tight corrosion-proof self-adhesion sizing material after fusing is squeezed into application system and carries out coating and become the water-tight corrosion-proof self-adhesive bed of material (4);
Step 9, deposited silicon oil membrane: silicon oil membrane is applied on the surface of the composite sheet after step 8 process;
Step 10, enter cooling flattening system (12), deviation-rectifying system (13) by hauling machine, finally cut to cutting equipment (14), the shaping laggard row finished product packing of rolling.
9. the production method of a kind of high polymer alloy waterproof roll according to claim 8, is characterized in that: described step 3 or four extrusion equipment (9) be Single screw extrusion equipment or twin-screw extrusion equipment.
10. the production method of a kind of high polymer alloy waterproof roll according to claim 8, is characterized in that: being that one side is deposited or two-sided when applying the water-tight corrosion-proof self-adhesive bed of material in described step 8 applies.
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| CN110028690A (en) * | 2019-05-22 | 2019-07-19 | 潍坊仁鼎防水材料有限公司 | Metal uvioresistant root resistance polymer membranes and its production equipment and technique |
| CN110029782A (en) * | 2019-05-18 | 2019-07-19 | 潍坊仁鼎防水材料有限公司 | Root-resistance waterproof coiled material and its single machine Preparation equipment |
| CN112455025A (en) * | 2020-11-02 | 2021-03-09 | 左麦斯建筑科技(南京)有限公司 | Processing technology and production system of multifunctional polymer coiled material metal composite plate |
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