CN104213465B - Refreshing UV paper gloss oil of release effect, superslide and preparation method thereof is had after a kind of UV ultraviolet light polymerization - Google Patents
Refreshing UV paper gloss oil of release effect, superslide and preparation method thereof is had after a kind of UV ultraviolet light polymerization Download PDFInfo
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- CN104213465B CN104213465B CN201410371587.7A CN201410371587A CN104213465B CN 104213465 B CN104213465 B CN 104213465B CN 201410371587 A CN201410371587 A CN 201410371587A CN 104213465 B CN104213465 B CN 104213465B
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- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 238000003756 stirring Methods 0.000 claims abstract description 44
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 39
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 39
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 28
- 239000004593 Epoxy Substances 0.000 claims abstract description 19
- 239000000178 monomer Substances 0.000 claims abstract description 19
- 238000002156 mixing Methods 0.000 claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 239000003921 oil Substances 0.000 claims description 59
- 239000000203 mixture Substances 0.000 claims description 16
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 14
- -1 1, 6 hexanediyl esters Chemical class 0.000 claims description 11
- 239000013530 defoamer Substances 0.000 claims description 9
- 230000000977 initiatory effect Effects 0.000 claims description 8
- 229920002545 silicone oil Polymers 0.000 claims description 8
- 150000003512 tertiary amines Chemical class 0.000 claims description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical group C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 7
- 239000012965 benzophenone Substances 0.000 claims description 7
- 229940106691 bisphenol a Drugs 0.000 claims description 7
- 229920002635 polyurethane Polymers 0.000 claims description 7
- 239000004814 polyurethane Substances 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 239000010703 silicon Substances 0.000 claims description 7
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 claims description 6
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 claims description 6
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 claims description 2
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 claims description 2
- 235000011157 hong shi Nutrition 0.000 claims description 2
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 claims description 2
- 239000000853 adhesive Substances 0.000 abstract description 6
- 230000001070 adhesive effect Effects 0.000 abstract description 6
- 230000008901 benefit Effects 0.000 abstract description 4
- LJRSZGKUUZPHEB-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical class C=CC(=O)OC(C)COC(C)COC(C)COC(=O)C=C LJRSZGKUUZPHEB-UHFFFAOYSA-N 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical class C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- MDDUHVRJJAFRAU-YZNNVMRBSA-N tert-butyl-[(1r,3s,5z)-3-[tert-butyl(dimethyl)silyl]oxy-5-(2-diphenylphosphorylethylidene)-4-methylidenecyclohexyl]oxy-dimethylsilane Chemical compound C1[C@@H](O[Si](C)(C)C(C)(C)C)C[C@H](O[Si](C)(C)C(C)(C)C)C(=C)\C1=C/CP(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 MDDUHVRJJAFRAU-YZNNVMRBSA-N 0.000 description 4
- 239000002390 adhesive tape Substances 0.000 description 3
- JMWGZSWSTCGVLX-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;2-methylprop-2-enoic acid Chemical class CC(=C)C(O)=O.CC(=C)C(O)=O.CC(=C)C(O)=O.CCC(CO)(CO)CO JMWGZSWSTCGVLX-UHFFFAOYSA-N 0.000 description 2
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 2
- 238000001723 curing Methods 0.000 description 2
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- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
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- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical class OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000000852 hydrogen donor Substances 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Paper (AREA)
- Adhesive Tapes (AREA)
Abstract
The present invention relates to gloss oil technical field, having refreshing UV paper gloss oil of release effect, superslide and preparation method thereof after particularly relating to a kind of UV ultraviolet light polymerization, the UV paper gloss oil of the present invention is made up of feel well stripping auxiliary agent, the auxiliary agent of 14 parts of the epoxy acrylic resin of 15 30 parts, the modified acrylic resin of 25 40 parts, the acrylic monomer of 40 50 parts, the light trigger of 10 15 parts, the superslide of 26 parts；The preparation method of the present invention is: a, by refreshing to acrylic monomer, delustering agent, superslide peel off auxiliary agent and auxiliary agent add agitated kettle is carried out pre-dispersed, mixing and stirring；B, again toward agitated kettle adds epoxy acrylic resin, modified acrylic resin, acrylic monomer, light trigger, mixing and stirring, prepare oil plant；C, oil plant is filtered successively.The UV paper gloss oil of the present invention have good superslide may just as well, the advantage such as glossiness height, good, the high-wearing feature of adhesive force.
Description
Technical field
The present invention relates to gloss oil technical field, after particularly relating to a kind of UV ultraviolet light polymerization, have refreshing UV paper gloss oil of release effect, superslide and preparation method thereof.
Background technology
Release paper, also known as release paper, separate paper, is that one both can prevent pressure sensitive adhesive adhesion, can protect again the most contaminated separate paper of pressure sensitive adhesive, be widely used in the fields such as electronic product, automobile foam, packaging industry, advertisement, printing.Having a lot of release paper in the market, its manufacture method majority is all by the release emulsion of coated heat curing type on paper product or to prepare from dry mould release, and rate of drying is slow, has a strong impact on production efficiency.Although it addition, the most also occur in that some with the addition of the UV paper gloss oil of the auxiliary agent that can improve slipping, but this analog assistant reduces capillary poor performance, smooth degree is low, does not has peeling effect, is attached to film coated surface with adhesive tape, does not has release effect when pulling at.Therefore, problems described above is urgently to be resolved hurrily.
Summary of the invention
Present invention aims to the deficiencies in the prior art, and have refreshing UV paper gloss oil of release effect, superslide and preparation method thereof after providing a kind of UV ultraviolet light polymerization, this UV paper light oil surface tension is low, surface superslide refreshing, release excellent.
The present invention is achieved through the following technical solutions.
Having the UV paper gloss oil that release effect, superslide are refreshing after a kind of UV ultraviolet light polymerization, it is made up of the component of following weight portion:
Epoxy acrylic resin
15-30 part
Modified acrylic resin
25-40 part
Acrylic monomer
40-50 part
Light trigger
10-15 part
Superslide is refreshing peels off auxiliary agent
2-6 part
Auxiliary agent
1-4 part.
Preferably, having the UV paper gloss oil that release effect, superslide are refreshing after a kind of UV ultraviolet light polymerization, it is made up of the component of following weight portion:
Epoxy acrylic resin
20-25 part
Modified acrylic resin
30-35 part
Acrylic monomer
42-48 part
Light trigger
12-14 part
Superslide is refreshing peels off auxiliary agent
3-5 part
Auxiliary agent
2-3 part.
Being more highly preferred to, have the UV paper gloss oil that release effect, superslide are refreshing after a kind of UV ultraviolet light polymerization, it is made up of the component of following weight portion:
Epoxy acrylic resin
22 parts
Modified acrylic resin
32 parts
Acrylic monomer
45 parts
Light trigger
13 parts
Superslide is refreshing peels off auxiliary agent
4 parts
Auxiliary agent
2.5 part.
Wherein, described superslide is felt well and peeled off auxiliary agent is that silicone oil and antiseized slip aid mix the mixture of composition in the ratio of 1-2:3-5, antiseized slip aid be the model of Di Gao company be the antiseized slip aid of TEGO Rad 2700.The chemical composition of the antiseized slip aid of TEGO Rad 2700 is response type silicone acrylates, it has extraordinary slipping, tissue adhesion/peeling effect and good deaeration, the refreshing auxiliary agent of peeling off of superslide is made can strongly to reduce UV light oil surface tension, surface superslide is made to feel well, with on the glutinous film after hardening of adhesive tape, can remove easily, make the UV gloss oil prepared have good release effect.
Wherein, epoxy acrylic resin is the bisphenol-A epoxy acrylic resin that model is OG4705K3 of Dongguan Hongshi Function Materials Co., Ltd., it, as main body film forming matter, substantially increases wearability and the glossiness of the film body that the refreshing UV paper gloss oil of superslide is formed after ultraviolet light polymerization；Acrylic resin modified for modified polyurethane acrylic resin, it, as film forming matter, substantially increases adhesive force and the pliability of the film body that the refreshing UV paper gloss oil of superslide is formed after ultraviolet light polymerization.
Wherein, described acrylic monomer is 1, any one in 6 hexanediyl esters, tripropylene glycol diacrylate, trimethylolpropane trimethacrylate, or be 1, any two kinds in 6 hexanediyl esters, tripropylene glycol diacrylate, trimethylolpropane trimethacrylate are mixed the mixture formed in the ratio of 1-3:2-4, or be that 1,6 hexanediyl esters, tripropylene glycol diacrylate, trimethylolpropane trimethacrylate three are in the mixture of the ratio mixing composition of 3-5:2-4:1-3.Acrylic monomer scalable system viscosity, improves laser curing velocity.
Wherein, described light trigger is benzophenone, 2-hydroxy-2-methyl-1-phenylacetone, 1-hydroxy cyclohexyl phenylketone or 2, any one or a few mixture with tertiary amine aided initiating in 4,6-trimethylbenzoy-dipheny phosphine oxides.Light trigger can absorb the ultraviolet of high voltage mercury lamp radiation and forms free radical or cation, cause acrylic monomer and acrylic resin that polymerization and cross-linking reaction occur, the high molecular polymer of tridimensional network it is solidify to form in the shortest time, this polymer and the organic matting agent polymer inside gloss oil become to be coated with membranaceous, are attached to paper surface, the refreshing UV paper gloss oil of this superslide be coated on paper have the most impermeable, glossiness is high, richness is good, and adhesive force is fine, practical.
Benzophenone belongs to hydrogen-capture-type light initiator, after hydrogen-capture-type light initiator molecule absorption luminous energy, alter between exciting and being and jump to excited triplet state, with the tertiary amine aided initiating generation bimolecular effect as hydrogen donor, produce living radical through electron transfer, and then cause oligomer or reactive diluent cross-linked polymeric.The tertiary amine aided initiating compatibility is good, and activity is high, and xanthochromia is low, and abnormal smells from the patient is low, and zest is little, and efficiency is high, and will not migrate.
Wherein, described auxiliary agent is levelling agent and defoamer, and defoamer is Bi Ke company or the organic silicon defoamer of Di Gao company, and levelling agent is the organosilicon levelling agent of Di Gao company.
Having the preparation method of the refreshing UV paper gloss oil of release effect, superslide after above-mentioned UV ultraviolet light polymerization, it includes following preparation process:
A, acrylic monomer is divided into two parts, a part of acrylic monomer, delustering agent are added by weight agitated kettle is carried out pre-dispersed, mixing and stirring；
B, it is further continued in agitated kettle adding epoxy acrylic resin, modified acrylic resin, another part acrylic monomer, light trigger and auxiliary agent by weight, mixing and stirring, prepares oil plant；
C, the oil plant filter bag of 320 mesh is filtered, after i.e. preparing UV ultraviolet light polymerization, have the UV paper gloss oil that release effect, superslide are refreshing.
Wherein, in step a, the rotating speed of stirring is 700-900r/min, and the time of stirring is 25-35min；In step b, the rotating speed of stirring is 900-1100r/min, and the time of stirring is 80-100min.
nullRelease effect is had after the invention have the benefit that the UV ultraviolet light polymerization of the present invention、The UV paper gloss oil that superslide is felt well is a kind of roller coat printing UV oil polish，Mainly by absorbing ultraviolet light generation polymerization crosslinking reaction formation high molecular polymer，And the superslide that can participate in UV cross-linking reaction is refreshing peels off auxiliary agent by adding，This superslide is felt well and is peeled off the mixture that auxiliary agent is silicone oil and the antiseized slip aid that model is TEGO Rad 2700 of the Di Gao company that can participate in UV cross-linking reaction，The reduction UV light oil surface tension that energy is strong，Surface superslide is made to feel well，With on the glutinous film after hardening of adhesive tape，Can remove easily，The UV gloss oil prepared is made to have good release effect，And arrange in pairs or groups by adding the refreshing auxiliary agent of peeling off of distinctive modified urethane acrylate and superslide，Further up to good release effect and higher adhesive force，There is good superslide may just as well、Glossiness is high、Richness is good、Explosion-proof is good、Adhesive force is good、The advantages such as high-wearing feature；Further, since use the speed of printer coating UV paper gloss oil soon, therefore the UV paper gloss oil of the present invention replaces the release emulsion of the heat cure used on the market, can increase substantially production efficiency, use manpower and material resources sparingly, also save production cost simultaneously.
The preparation method of the present invention is simple, and production efficiency is high, is suitable to large-scale production.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment
1
。
Having the preparation method of the refreshing UV paper gloss oil of release effect, superslide after the UV ultraviolet light polymerization of the present embodiment, it includes following preparation process:
A, by 30 part 1,6 hexanediyl esters, 2 parts of silicone oil, 4 parts of antiseized slip aid of TEGO Rad 2700 add and carry out pre-dispersed in agitated kettles, and mixing and stirring, the rotating speed of stirring is 700r/min, and the time of stirring is 35min；
B, be further continued in agitated kettle add 15 parts of bisphenol-A epoxy acrylic resins, 25 parts of modified polyurethane acrylic resins, 20 parts of tripropylene glycol diacrylates, 3 parts of benzophenone, 4 parts of tertiary amine aided initiatings, 4 parts of 2-hydroxy-2-methyl-1-phenylacetones, 4 parts of 1-hydroxy cyclohexyl phenylketones, 2 parts of organosilicon levelling agents, 2 parts of organic silicon defoamers, mixing and stirring, the rotating speed of stirring is 1100r/min, the time of stirring is 80min, prepares oil plant；
C, the oil plant filter bag of 320 mesh is filtered, after i.e. preparing UV ultraviolet light polymerization, have the UV paper gloss oil that release effect, superslide are refreshing.
Embodiment
2
。
Having the preparation method of the refreshing UV paper gloss oil of release effect, superslide after the UV ultraviolet light polymerization of the present embodiment, it includes following preparation process:
A, by 16 part 1,6 hexanediyl esters, 2 parts of silicone oil, 3 parts of antiseized slip aid of TEGO Rad 2700 add and carry out pre-dispersed in agitated kettles, and mixing and stirring, the rotating speed of stirring is 750r/min, and the time of stirring is 32min；
B, be further continued in agitated kettle adding 20 parts of bisphenol-A epoxy acrylic resins, 30 parts of modified polyurethane acrylic resins, 32 parts of tripropylene glycol diacrylates, 2 parts of benzophenone, 5 parts of tertiary amine aided initiatings, 3 parts of 2-hydroxy-2-methyl-1-phenylacetones, 4 part 2; 4; 6-trimethylbenzoy-dipheny phosphine oxide, 1 part of organosilicon levelling agent, 2 parts of organic silicon defoamers; mixing and stirring; the rotating speed of stirring is 1050r/min; the time of stirring is 85min, prepares oil plant；
C, the oil plant filter bag of 320 mesh is filtered, after i.e. preparing UV ultraviolet light polymerization, have the UV paper gloss oil that release effect, superslide are refreshing.
Embodiment
3
。
Having the preparation method of the refreshing UV paper gloss oil of release effect, superslide after the UV ultraviolet light polymerization of the present embodiment, it includes following preparation process:
A, by 18 part 1,6 hexanediyl esters, 1 part of silicone oil, 3 parts of antiseized slip aid of TEGO Rad 2700 add and carry out pre-dispersed in agitated kettles, and mixing and stirring, the rotating speed of stirring is 800r/min, and the time of stirring is 30min；
B, be further continued in agitated kettle adding 22 parts of bisphenol-A epoxy acrylic resins, 32 parts of modified polyurethane acrylic resins, 27 parts of tripropylene glycol diacrylates, 3 parts of benzophenone, 3 parts of tertiary amine aided initiatings, 3 parts of 1-hydroxy cyclohexyl phenylketones, 4 part 2; 4; 6-trimethylbenzoy-dipheny phosphine oxide, 1.5 parts of organosilicon levelling agents, 1 part of organic silicon defoamer; mixing and stirring; the rotating speed of stirring is 1000r/min; the time of stirring is 90min, prepares oil plant；
C, the oil plant filter bag of 320 mesh is filtered, after i.e. preparing UV ultraviolet light polymerization, have the UV paper gloss oil that release effect, superslide are refreshing.
Embodiment
4
。
Having the preparation method of the refreshing UV paper gloss oil of release effect, superslide after the UV ultraviolet light polymerization of the present embodiment, it includes following preparation process:
A, by 21 part 1,6 hexanediyl esters, 14 parts of tripropylene glycol diacrylates, 0.5 part of silicone oil, 2.5 parts of TEGO Rad 2700 antiseized slip aid addition agitated kettles are carried out pre-dispersed, mixing and stirring, the rotating speed of stirring is 850r/min, and the time of stirring is 28min；
B, be further continued in agitated kettle adding 25 parts of bisphenol-A epoxy acrylic resins, 35 parts of modified polyurethane acrylic resins, 7 parts of trimethylolpropane trimethacrylates, 2 parts of benzophenone, 3 parts of 2-hydroxy-2-methyl-1-phenylacetones, 2 parts of 1-hydroxy cyclohexyl phenylketones, 5 part 2; 4; 6-trimethylbenzoy-dipheny phosphine oxide, 1 part of organosilicon levelling agent, 1 part of organic silicon defoamer; mixing and stirring; the rotating speed of stirring is 950r/min; the time of stirring is 95min, prepares oil plant；
C, the oil plant filter bag of 320 mesh is filtered, after i.e. preparing UV ultraviolet light polymerization, have the UV paper gloss oil that release effect, superslide are refreshing.
Embodiment
5
。
Having the preparation method of the refreshing UV paper gloss oil of release effect, superslide after the UV ultraviolet light polymerization of the present embodiment, it includes following preparation process:
A, by 20 part 1,6 hexanediyl esters, 10 parts of trimethylolpropane trimethacrylates, 0.5 part of silicone oil, 1.5 parts of TEGO Rad 2700 antiseized slip aid addition agitated kettles are carried out pre-dispersed, mixing and stirring, the rotating speed of stirring is 900r/min, and the time of stirring is 25min；
B, be further continued in agitated kettle adding 30 parts of bisphenol-A epoxy acrylic resins, 40 parts of modified polyurethane acrylic resins, 10 parts of tripropylene glycol diacrylates, 2 part 2; 4; 6-trimethylbenzoy-dipheny phosphine oxide, 3 parts of tertiary amine aided initiatings, 2 parts of 2-hydroxy-2-methyl-1-phenylacetones, 3 parts of 1-hydroxy cyclohexyl phenylketones, 0.5 part of organosilicon levelling agent, 0.5 part of organic silicon defoamer; mixing and stirring; the rotating speed of stirring is 900r/min; the time of stirring is 100min, prepares oil plant；
C, the oil plant filter bag of 320 mesh is filtered, after i.e. preparing UV ultraviolet light polymerization, have the UV paper gloss oil that release effect, superslide are refreshing.
The performance detection data having the refreshing UV paper gloss oil of release effect, superslide after the UV ultraviolet light polymerization that embodiments of the invention 1 ~ embodiment 5 prepares is shown in Table 1.
Table 1
。
As can be seen from Table 1, having the UV paper gloss oil that release effect, superslide are refreshing, the advantages such as its wearability is good, adhesive force good, glossiness is high, curing rate is fast after the UV ultraviolet light polymerization that embodiments of the invention 1 ~ embodiment 5 prepares, product quality is good, serviceability is good, and marketing degree is high.
Finally should be noted that; above example is only in order to illustrate technical scheme; rather than limiting the scope of the invention; although having made to explain to the present invention with reference to preferred embodiment; it will be understood by those within the art that; technical scheme can be modified or equivalent, without deviating from the spirit and scope of technical solution of the present invention.
Claims (9)
1. after a UV ultraviolet light polymerization, there is the UV paper gloss oil that release effect, superslide are refreshing, it is characterised in that: it is made up of the component of following weight portion:
Epoxy acrylic resin
15-30 part
Modified acrylic resin
25-40 part
Acrylic monomer
40-50 part
Light trigger
10-15 part
Superslide is refreshing peels off auxiliary agent
2-6 part
Auxiliary agent
1-4 part；
Wherein, described superslide is felt well and peeled off auxiliary agent is that silicone oil and antiseized slip aid mix the mixture of composition in the ratio of 1-2:3-5, antiseized slip aid be the model of Di Gao company be the antiseized slip aid of TEGO Rad 2700；
Described modified acrylic resin is modified polyurethane acrylic resin.
The UV paper gloss oil that release effect, superslide are refreshing is had after a kind of UV ultraviolet light polymerization the most according to claim 1, it is characterised in that: it is made up of the component of following weight portion:
Epoxy acrylic resin
20-25 part
Modified acrylic resin
30-35 part
Acrylic monomer
42-48 part
Light trigger
12-14 part
Superslide is refreshing peels off auxiliary agent
3-5 part
Auxiliary agent
2-3 part.
The UV paper gloss oil that release effect, superslide are refreshing is had after a kind of UV ultraviolet light polymerization the most according to claim 1, it is characterised in that: it is made up of the component of following weight portion:
Epoxy acrylic resin
22 parts
Modified acrylic resin
32 parts
Acrylic monomer
45 parts
Light trigger
13 parts
Superslide is refreshing peels off auxiliary agent
4 parts
Auxiliary agent
2.5 part.
The UV paper gloss oil that release effect, superslide are refreshing is had after a kind of UV ultraviolet light polymerization the most according to claim 1, it is characterised in that: epoxy acrylic resin is the bisphenol-A epoxy acrylic resin that model is OG4705K3 of Dongguan Hongshi Function Materials Co., Ltd..
Release effect is had after a kind of UV ultraviolet light polymerization the most according to claim 1, the UV paper gloss oil that superslide is refreshing, it is characterized in that: described acrylic monomer is 1, 6 hexanediyl esters, tripropylene glycol diacrylate, any one in trimethylolpropane trimethacrylate, or be 1, 6 hexanediyl esters, tripropylene glycol diacrylate, any two kinds in trimethylolpropane trimethacrylate are mixed the mixture formed in the ratio of 1-3:2-4, or be 1, 6 hexanediyl esters, tripropylene glycol diacrylate, trimethylolpropane trimethacrylate three mixes the mixture of composition in the ratio of 3-5:2-4:1-3.
The UV paper gloss oil that release effect, superslide are refreshing is had after a kind of UV ultraviolet light polymerization the most according to claim 1; it is characterized in that: described light trigger is benzophenone, 2-hydroxy-2-methyl-1-phenylacetone, 1-hydroxy cyclohexyl phenylketone or 2; any one or a few mixture with tertiary amine aided initiating in 4,6-trimethylbenzoy-dipheny phosphine oxides.
The UV paper gloss oil that release effect, superslide are refreshing is had after a kind of UV ultraviolet light polymerization the most according to claim 1, it is characterized in that: described auxiliary agent is levelling agent and defoamer, defoamer is Bi Ke company or the organic silicon defoamer of Di Gao company, and levelling agent is the organosilicon levelling agent of Di Gao company.
8. after a kind of UV ultraviolet light polymerization described in claim 1-7 any one, there is the preparation method of the refreshing UV paper gloss oil of release effect, superslide, it is characterised in that: it includes following preparation process:
A, acrylic monomer is divided into two parts, by refreshing to a part of acrylic monomer, superslide peel off auxiliary agent, auxiliary agent add by weight agitated kettle is carried out pre-dispersed, mixing and stirring；
B, it is further continued in agitated kettle adding epoxy acrylic resin, modified acrylic resin, another part acrylic monomer and light trigger by weight, mixing and stirring, prepares oil plant；
C, oil plant filter bag is filtered, after i.e. preparing UV ultraviolet light polymerization, have the UV paper gloss oil that release effect, superslide are refreshing.
The preparation method of the refreshing UV paper gloss oil of release effect, superslide is had after a kind of UV ultraviolet light polymerization the most according to claim 8, it is characterised in that: in step a, the rotating speed of stirring is 700-900r/min, and the time of stirring is 25-35min；In step b, the rotating speed of stirring is 900-1100r/min, and the time of stirring is 80-100min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410371587.7A CN104213465B (en) | 2014-07-31 | 2014-07-31 | Refreshing UV paper gloss oil of release effect, superslide and preparation method thereof is had after a kind of UV ultraviolet light polymerization |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410371587.7A CN104213465B (en) | 2014-07-31 | 2014-07-31 | Refreshing UV paper gloss oil of release effect, superslide and preparation method thereof is had after a kind of UV ultraviolet light polymerization |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104213465A CN104213465A (en) | 2014-12-17 |
| CN104213465B true CN104213465B (en) | 2016-09-14 |
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| CN104877568A (en) * | 2015-05-15 | 2015-09-02 | 成都纳硕科技有限公司 | Ultraviolet curable high-strippability anti-adhesive agent used in electronic field |
| CN105131779B (en) * | 2015-09-14 | 2018-06-29 | 上海应用技术学院 | A kind of ultraviolet curing organic silicon mould release and preparation method thereof |
| CN110305510A (en) * | 2019-06-13 | 2019-10-08 | 广州骏捷环保科技有限公司 | A kind of method for stamping of UV gloss oil and its 3D imprinting apparatus |
| CN110330868B (en) * | 2019-07-11 | 2021-03-16 | 中体彩印务技术有限公司 | UV (ultraviolet) insulating oil suitable for printing instant lottery and preparation method thereof |
| CN110525075A (en) * | 2019-09-20 | 2019-12-03 | 湖北中烟工业有限责任公司 | A kind of process of cigarette 3D raster print product |
| CN110757973A (en) * | 2019-11-11 | 2020-02-07 | 保定永丽印务有限公司 | Kraft paper suitable for low-temperature printing and black card flat screen printing process |
| CN112552758A (en) * | 2020-12-11 | 2021-03-26 | 广东昊辉新材料有限公司 | UV-cured high-surface-tension gloss oil, and preparation method and application thereof |
| CN115139674B (en) * | 2021-11-17 | 2024-02-23 | 山东泰宝防伪制品有限公司 | Raised substitution process |
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| CN103013295A (en) * | 2012-12-05 | 2013-04-03 | 北京化工大学常州先进材料研究院 | UV (ultraviolet) paper varnish and preparation method thereof |
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| US9765199B2 (en) * | 2012-10-31 | 2017-09-19 | Topasol, LLC | Non-yellowing easy-to-clean antimicrobial plastic |
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| CN101575827A (en) * | 2009-03-30 | 2009-11-11 | 上海东升新材料有限公司 | Aqueous calendering oil for glazing of calendaring technology of paper printing products |
| CN102492358A (en) * | 2011-11-14 | 2012-06-13 | 厦门市豪尔新材料有限公司 | Thermo-setting transfer mould release agent and method for preparing and using same |
| CN102964969A (en) * | 2012-11-14 | 2013-03-13 | 京东方科技集团股份有限公司 | Ultraviolet curing light oil and preparation method and curing method thereof as well as touch screen |
| CN103013295A (en) * | 2012-12-05 | 2013-04-03 | 北京化工大学常州先进材料研究院 | UV (ultraviolet) paper varnish and preparation method thereof |
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