CN104209074B - A kind of medium strengthening reaction method and facilities and equipments thereof - Google Patents
A kind of medium strengthening reaction method and facilities and equipments thereof Download PDFInfo
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- CN104209074B CN104209074B CN201410447665.7A CN201410447665A CN104209074B CN 104209074 B CN104209074 B CN 104209074B CN 201410447665 A CN201410447665 A CN 201410447665A CN 104209074 B CN104209074 B CN 104209074B
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- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
The present invention relates to method and the facilities and equipments thereof of a kind of medium strengthening reaction, equipment comprises hydraulic pump, microvesicle generators, gas supply device, air pocket generator.Air pocket generator is located on the first transfer pipeline, the downside of microvesicle generators is communicated with circuit lines by the second transfer pipeline, the right side of the raw device of microvesicle is communicated with gas supply device by supply air line, and the upside of the raw device of microvesicle is communicated with air pocket generator by the 3rd transfer pipeline.The method of medium strengthening reaction have safe and reliable, implement easily, advantage that effect is controlled, in fact arrange structure of having got everything ready simple, be widely used, the feature of precise control.
Description
Technical field
The present invention relates to a kind of medium strengthening reaction method and facilities and equipments thereof, especially relate to a kind of hole principle weight feed nanoscale microvesicle that utilizes and make medium that method and the facilities and equipments thereof of strengthening reaction occur.
Background technology
In liquid stream when certain point pressure lower than liquid at temperature air separation pressure time, the gas be dissolved in liquid can separate generation bubble, there is cavitation, when pressure reduce further and saturated vapor pressure lower than liquid time, liquid can form a large amount of vapor bubbles by rapid vaporization, make cavitation more violent, thus make liquid stream be discrete state.
Cavitation makes liquid produce the higher-order of oscillation under kinetic energy effect, longitudinally positive and negative nip is produced at the wave of oscillation, and generate a large amount of microvesicle, the negative pressuren zone growth that countless tiny bubbles is formed in wave of oscillation longitudinal propagation, and at zone of positive pressure rapid closing, thus be compressed under alternately positive and negative pressure action and expand.Microvesicle occurs mutually to clash into, rub with liquid motion, can form powerful shock wave, release huge energy when microvesicle sharply bursts, and the temporary impact wave pressure of generation can up to tens MPas to MPa up to a hundred.Known detection is learnt: cavitation can make the temperature in gas-phase reaction district reach more than 5000K, and the effective temperature in liquid phase reactor district reaches more than 2000K, and with the microjet of strong shock wave and more than 100m/s.
Cavitation can produce the series of effects such as mechanical effect, fuel factor, chemical effect, biological effect.Mechanical effect is mainly manifested in the increase at heterogeneous reaction interface; Chemical effect is mainly manifested in the HTHP produced in microvesicle sharply explosion process can make that macromolecule decomposes, chemical bond rupture produce free radical etc.; Fuel factor is mainly hydrothermal exchange, high pyrohydrolysis reaction etc.
Current each technical field all have utilize cavitation to produce mechanical effect, fuel factor, chemical effect, biological effect technology example, utilize the technology of mechanical effect mainly to comprise absorption, crystallization, electrochemistry, heterogeneous phase chemical reaction, filtration and ultrasonic cleaning etc.; The process of chemical effect is utilized to mainly include the degraded of machine thing, polymer chemistry reaction, scale removal and radical reaction.
The free radical that cavitation produces is the basic reason causing and strengthen medium reaction, and the quantity of free radical affects the intensity of cavitation and the key factor of medium strengthening reaction effect.The technology that each effect utilizing it to produce according to cavitation theory in prior art realizes controlled medium strengthening reaction also needs to promote, and has the free radical technology also imperfection that object control cavitation produces.Therefore, quantitatively provide the controlled microvesicle of size and and then control utilize cavitation to produce free radical quantity for medium strengthening react tool be of great significance.
Summary of the invention
The object of this invention is to provide method and the facilities and equipments thereof of a kind of medium strengthening reaction, the method for medium strengthening reaction have safe and reliable, implement easily, advantage that effect is controlled, in fact arrange structure of having got everything ready simple, be widely used, the feature of precise control.
For solving the mechanical effect utilizing cavitation to produce in prior art, fuel factor, chemical effect, biological effect, the technical problem that its controllability is poor and control accuracy is not enough, the facilities and equipments of the invention process medium strengthening reaction comprise hydraulic pump, microvesicle generators, gas supply device, air pocket generator, the left side of hydraulic pump is communicated with feeding pipe, the upside of hydraulic pump is communicated with the left end of the first transfer pipeline, the downside of hydraulic pump is communicated with the left end of circuit lines, with discharging pipeline connection while that the right-hand member of the first transfer pipeline being communicated with the right-hand member of circuit lines also, feeding pipe is provided with bi-directional path valve F
1, the first transfer pipeline is provided with bi-directional path valve F
2with bi-directional path valve F
3, circuit lines is provided with bi-directional path valve F
4with bi-directional path valve F
5, discharging pipeline is provided with bi-directional path valve F
6,
Air pocket generator is located at bi-directional path valve F
2with bi-directional path valve F
3between the first transfer pipeline on and be communicated with the first transfer pipeline of both sides respectively; The downside of microvesicle generators is communicated with circuit lines by the second transfer pipeline, and the second transfer pipeline is located at bi-directional path valve F with the position that is communicated with of circuit lines
4with bi-directional path valve F
5between, the right side of microvesicle generators is communicated with gas supply device by supply air line, and the upside of microvesicle generators is communicated with air pocket generator by the 3rd transfer pipeline; The two ends of the 4th transfer pipeline are communicated with circuit lines with the first transfer pipeline respectively, and the 4th transfer pipeline is located at bi-directional path valve F with the position that is communicated with of the first transfer pipeline
2and between air pocket generator, the 4th transfer pipeline is located at bi-directional path valve F with the position that is communicated with of circuit lines
4with bi-directional path valve F
5between.
Preferably, described bi-directional path valve F
1and the feeding pipe between hydraulic pump is provided with oxygen dissolved sampling instrument DO
1with oxidation-reduction potential sampling instrument R
1; The first transfer pipeline between the connection position of the 4th transfer pipeline and the first transfer pipeline and air pocket generator is provided with flowmeter L successively
1, pressure-measuring device V
1, pH value measuring instrument pH
1, temperature measuring set T
1; Air pocket generator and bi-directional path valve F
3between the first transfer pipeline on be provided with pressure-measuring device V successively
2, oxidation-reduction potential sampling instrument R
2, pH value measuring instrument pH
2, temperature measuring set T
2; Bi-directional path reset valve F
0be communicated with the first transfer pipeline with air pocket generator respectively by bypass conduit, the position that bypass conduit is communicated with the first transfer pipeline is located at air pocket generator and pressure-measuring device V
2between; Second transfer pipeline is provided with bi-directional path valve F
7with pressure-measuring device V
3; Supply air line is provided with flowmeter L
2; 3rd transfer pipeline is provided with bi-directional path valve F
8; 4th transfer pipeline is provided with bi-directional path valve F
9with flowmeter L
3; Bi-directional path valve F
6the discharging pipeline on right side is provided with flowmeter L
4with oxygen dissolved sampling instrument DO
2.
Preferably, facilities and equipments also comprise control system, described control system is provided with programmable logic controller (PLC) PLC, and control system is for carrying out data sampling, control realize management automatically to the bi-directional path valve on feeding pipe, the first transfer pipeline, circuit lines, discharging pipeline, the second transfer pipeline, supply air line, the 3rd transfer pipeline, the 4th transfer pipeline, oxygen dissolved sampling instrument, oxidation-reduction potential sampling instrument, flowmeter, pressure-measuring device, pH value measuring instrument, temperature measuring set.
Alternatively, described microvesicle generators comprises housing and is arranged at least one group of microvesicle generators assembly in housing cavity, housing left side wall is provided with inlet and air inlet, and housing right side wall is provided with discharging opening, is provided with ring washer between adjacent microvesicle generators assembly; Microvesicle generators assembly is combined by left cover, right cover and the palette be arranged between left cover and right cover and forms, left cover, right cover and palette are discoid, the equal diameters of left cover and right cover and be greater than the diameter of palette, the center of left cover and right cover is equipped with through hole, and housing is provided with for adjusting the coaxial device in relative rotation of left cover and right cover;
The right flank edge of left cover is provided with the first protruding lug edge to the right, protruding and equal with palette radius short cylindrical is provided with to the right in the middle part of the right flank of left cover, gap is provided with between the circumferential wall of short cylindrical and the madial wall on the first lug edge, the right side of short cylindrical is provided with central recess, circular groove and semi-circular recesses, central recess arranges one and is arranged on short cylindrical right flank medium position, circular groove is arranged on the outer circumferential of central recess, semi-circular recesses is arranged on the edge of short cylindrical, the edge of central recess is provided with an equally distributed n semi-circular groove, n >=3, circular groove multiple that number is n is set and each limit along the m centered by central recess positive n limit shape is with one heart uniformly distributed, m >=1, semi-circular recesses the quantity sum that number equals the circular groove that Xing Ge limit, outermost positive n limit distributes is set, minimum range between each semi-circular recesses and adjacent circular groove is all equal, adjacent central recess, circular groove, semi-circular recesses minimum range each other is all less than the radius of circular groove, preferably, 8 >=n >=5,6 >=m >=3.The left surface edge of right cover is provided with protruding and with the first lug in left cover along the second symmetrical lug edge left, palette is fixedly connected with by joint pin with right cover, be provided with gap between the right flank of palette and the left surface of right cover, between the circumferential wall of palette and the madial wall on the second lug edge, be provided with gap; The left side of palette is provided with the groove structure identical with the right side of short cylindrical; The first lug in left cover is fitted along with the second lug in right cover along sealing, and the right side of short cylindrical and the left side of palette seal fits.
Alternatively, described air pocket generator comprises shell and is arranged at the medium strengthening reaction chamber in shell, medium strengthening reaction chamber comprises the thick chamber of the equal opening in two ends, contraction chamber and thin chamber, by contraction chamber transition between thick chamber and thin chamber, the left end in thick chamber enters accent with the medium be arranged on shell and is communicated with, right-hand member and the medium in thin chamber go out accent and are communicated with, and it is open to the right horn-like that medium goes out accent; Shell also offers the microvesicle transfer passage be communicated with thin chamber left end.
Preferably, the diameter in described thick chamber is D1, and the diameter in thin chamber is D2, and the length of contraction chamber adds that the length in thin chamber is L, 0.01≤(D1-D2)/L≤0.1; The angle of the section edges line of contraction chamber and the section edges line in thin chamber is α, 35 °≤α≤75 °; The angle that medium goes out the section edges line of accent and the cross-sectional right side limit in thin chamber is β, 45 °≤β≤85 °; Further preferably, 0.015≤(D
1-D
2)/L≤0.03; 45 °≤α≤65 °; 55 °≤β≤75 °.
Adopt the facilities and equipments of the method for a kind of medium strengthening of the present invention reaction, control system is by opening bi-directional path valve F
1, bi-directional path valve F
2, bi-directional path valve F
3, bi-directional path valve F
6, bi-directional path valve F
7, bi-directional path valve F
8, bi-directional path valve F
9, and close bi-directional path valve F
4with bi-directional path valve F
5, make medium by bi-directional path valve F
1enter hydraulic pump, according to the different requirements of medium strengthening reaction object, hydraulic pump flows to air pocket generator medium by the first transfer pipeline with certain pressure, simultaneously by the 4th transfer pipeline, circuit lines, second transfer pipeline flows to microvesicle generators, gas supply device carries specific gas by supply air line to microvesicle generators as required, physical-chemical reaction is there is in medium and specific gas in gas microvesicle generators, make in medium containing highly concentrated nano level microvesicle, the medium mixture containing highly concentrated nano level microvesicle obtained after reaction flows to air pocket generator by the 3rd transfer pipeline, and occur to strengthen according to hole principle with the medium carried by the first transfer pipeline in air pocket generator and react.
Run in whole process at equipment, by control system, data sampling, monitoring, control carry out management are automatically carried out to the bi-directional path valve on feeding pipe, the first transfer pipeline, circuit lines, discharging pipeline, the second transfer pipeline, supply air line, the 3rd transfer pipeline, the 4th transfer pipeline, oxygen dissolved sampling instrument, oxidation-reduction potential sampling instrument, flowmeter, pressure-measuring device, pH value measuring instrument, temperature measuring set.When the product that control system monitoring obtains obtaining after medium strengthening reaction is up to standard or meet the requirements, just allow it by bi-directional path valve F
6export; When control system monitor the product that obtains after medium strengthening reaction do not reach manufacture object or undesirable time, just by closing bi-directional path valve F
6, and open bi-directional path valve F simultaneously
4with bi-directional path valve F
5, make nonconforming medium strengthen reacted product and be back to hydraulic pump by circuit lines and microvesicle generators reacts again.
A kind of medium strengthening reaction method, comprises the steps:
Quantization liquid is passed in equipment of the present invention through hydraulic pump, oxygen dissolved DO
1for 6.12mg/L, oxidation-reduction potential R
1for 255.6mv; Water temperature T
1it is 17.0 DEG C; PH
1value is 6.8-7.0; It is 1.0Mpa that hydraulic pump provides equipment to supply pressure to equipment, the inlet-pressure V of air pocket generator
1for 0.45Mpa; Flowmeter L
1for 80 liters per minute, flowmeter L
3for 20 liters per minute, flowmeter L
2for 0.15-0.5 liter per minute, the inlet-pressure V of microvesicle generators
3for 0.5-0.6Mpa, the outlet pressure V of air pocket generator
2for 0.02Mpa; Oxidation-reduction potential R
2for 282.5-382.5mv; Water temperature T
1for 72.0-77.0 DEG C, water temperature difference T
2-T
1=55 DEG C, pH
1value is 2.0-5.8, after equipment normal operation, from bi-directional path valve F
5go out sampling, collect the product obtained containing nanometer microvesicle, containing the density of 12-14 hundred million microvesicles in every milliliter of product, content is 0.092-0.628ppm;
Wherein, described quantization liquid is suspension, comprises quantum carbon element liquid and solvent, and the concentration of described quantum carbon element liquid is 0.1%-0.45%, and the addition of quantum carbon element liquid is the 1%-3% of solvent volume, containing quantum carbon element in described quantum carbon element liquid.
Medium strengthening reaction method of the present invention, wherein said quantum carbon element comprises the carbon particle that particle diameter is 0.6-100nm, described carbon particle is single carbon and/or Graphene particle, have on the top layer of described carbon particle containing carbon, hydrogen, oxygen, nitrogen compound, describedly comprise condensed-nuclei aromatics, the compound containing carbon oxygen singly-bound, the compound containing C=O bond, compound containing C-H bond containing carbon, hydrogen, oxygen, nitrogen compound.
Medium strengthening reaction method of the present invention, wherein said quantum carbon element is made up of the carbon particle of following mass percent: the carbon particle 10% ~ 50% of carbon particle 50% ~ 95%, 0.9 < particle diameter < 50.0nm of 0.6≤particle diameter≤0.9nm, the carbon particle 0% ~ 20% of 50≤particle diameter≤100nm; Described containing carbon, hydrogen, oxygen, nitrogen compound be condensed-nuclei aromatics, the compound containing carbon oxygen singly-bound, the compound containing C=O bond, compound containing C-H bond the mixture of one or more, wherein each element ratio is: C45% ~ 55%, H0.2% ~ 2.0%, N0.1% ~ 0.3%, O45% ~ 65%; Described quantum carbon element liquid is the aqueous solution containing quantum carbon element, and concentration is 0.1%-0.45%, and the ORP of described quantum carbon element liquid is 280mv-380mv, conductivityσ is 1-5ms/cm, electromotive force is 280mv ~ 380mv, pH value is 1.5-3.2;
Described nanometer microvesicle is the mixture of one or more in air, oxygen, hydrogen, nitrogen, argon gas, helium, neon, Krypton, methane, ethane, propane, coal gas, natural gas, carbon monoxide, carbon dioxide, nitrous oxide, fluoride gas;
Described solvent is the mixture of one or more of oil, water, low-carbon alcohols, and described oil is petrochemical industry oil product, light oil or heavy oil, and described water is running water or seawater, and the carbon number of described low-carbon alcohols is 1-8, and the purity of described low-carbon alcohols is more than 90%.
Medium strengthening reaction method of the present invention, wherein, described solvent is made up of the raw material of following percentage by volume: oil: 30%-80%, water: 10%-60%, quantum carbon element liquid: the 1%-3% of solvent; Low-carbon alcohols 5%-60%.
Medium strengthening reaction method of the present invention, wherein, the degree feature of the liquid medium strengthening process of air pocket generator, obey Weber number theorem, the computing formula of Weber number is:
W＝ρυ
2Ι/σ
Wherein: ρ is medium fluid density;
υ is dielectric attribute flow velocity;
Ι is characteristic length;
σ is the surface tension coefficient of fluid;
Weber number represents the ratio of inertia force and surface tension effect, and ρ medium fluid density is 650 ~ 2000kg/m
3, Ι characteristic length is the surface tension coefficient of 10mm ~ 1000mm, σ fluid be 0.001N/m ~ 0.090N/m, υ be dielectric attribute flow velocity is 2.7x10
-5m
3/ s ~ 2.7x10
-1m
3/ s, media fluid viscosity is 10000mPas ~ 15000mPas under normal temperature 20 DEG C and normal pressure, gas viscosity 100 μ Pas ~ 120 μ Pas, and medium steam pressure 0.15kPa ~ 101.33kPa, the Weber number of described product is 5 ~ 300.
Medium strengthening reaction method of the present invention, wherein, ρ medium fluid density is 700 ~ 1600kg/m
3; Ι characteristic length is 50mm ~ 300mm; The surface tension coefficient of σ fluid is 0.010N/m ~ 0.078N/m; υ is dielectric attribute flow velocity is 1.4x10
-4m
3/ s ~ 2.7x10
-2m
3/ s, media fluid viscosity is 11000mPas under normal temperature 20 DEG C and normal pressure, gas viscosity 110 μ Pas.
Below in conjunction with detailed description of the invention shown in accompanying drawing, a kind of high heating value novel gas of the present invention and preparation method thereof and equipment are described in further detail:
Accompanying drawing explanation
Fig. 1 is the general assembly structural representation of the equipment of the invention process medium strengthening reaction;
Fig. 2 is the structural representation of microvesicle generators in the equipment of the invention process medium strengthening reaction;
Fig. 3 is the left cover structural representation of the first embodiment of microvesicle generators assembly in the equipment of the invention process medium strengthening reaction;
Fig. 4 is the A-A schematic cross-section of Fig. 3;
Fig. 5 is the palette structural representation of the first embodiment of microvesicle generators assembly in the equipment of the invention process medium strengthening reaction;
Fig. 6 is the B-B schematic cross-section of Fig. 5;
Fig. 7 is the right cover structural representation of the first embodiment of microvesicle generators assembly in the equipment of the invention process medium strengthening reaction;
Fig. 8 is the B-B schematic cross-section of Fig. 7;
Fig. 9 is the structural representation when palette of the first embodiment of microvesicle generators assembly and right cover combine in the equipment of the invention process medium strengthening reaction;
Figure 10 is the B-B schematic cross-section of Fig. 9;
Structural representation when Figure 11 is the left cover of the first embodiment of microvesicle generators assembly in the equipment of the invention process medium strengthening reaction, palette, right cover combination;
Figure 12 is when to be that in the equipment of the invention process medium strengthening reaction, the left cover of the first embodiment of microvesicle generators assembly is relative with palette rotate 30 degree, the groove perspective view on left cover and palette;
Figure 13 is the left cover structural representation of microvesicle generators assembly the second embodiment in the equipment of the invention process medium strengthening reaction;
Figure 14 is the A-A schematic cross-section of Figure 13;
Figure 15 is the palette structural representation of microvesicle generators assembly the second embodiment in the equipment of the invention process medium strengthening reaction;
Figure 16 is the B-B schematic cross-section of Figure 15;
Figure 17 is the right cover structural representation of microvesicle generators assembly the second embodiment in the equipment of the invention process medium strengthening reaction;
Figure 18 is the B-B schematic cross-section of Figure 17;
Figure 19 is the structural representation when palette of microvesicle generators assembly the second embodiment and right cover combine in the equipment of the invention process medium strengthening reaction;
Figure 20 is the B-B schematic cross-section of Figure 19;
Structural representation when Figure 21 is the left cover of microvesicle generators assembly the second embodiment in the equipment of the invention process medium strengthening reaction, palette, right cover combination;
Figure 22 is when to be that in the equipment of the invention process medium strengthening reaction, the left cover of microvesicle generators assembly the second embodiment is relative with palette rotate 25 degree, the groove perspective view on left cover and palette;
Figure 23 is the left cover structural representation of the third embodiment of microvesicle generators assembly in the equipment of the invention process medium strengthening reaction;
Figure 24 is the A-A schematic cross-section of Figure 23;
Figure 25 is the palette structural representation of the third embodiment of microvesicle generators assembly in the equipment of the invention process medium strengthening reaction;
Figure 26 is the B-B schematic cross-section of Figure 25;
Figure 27 is the right cover structural representation of the third embodiment of microvesicle generators assembly in the equipment of the invention process medium strengthening reaction;
Figure 28 is the B-B schematic cross-section of Figure 27;
Figure 29 is the structural representation when palette of the third embodiment of microvesicle generators assembly and right cover combine in the equipment of the invention process medium strengthening reaction;
Figure 30 is the B-B schematic cross-section of Figure 29;
Structural representation when Figure 31 is the left cover of the third embodiment of microvesicle generators assembly in the equipment of the invention process medium strengthening reaction, palette, right cover combination;
Figure 32 is when to be that in the equipment of the invention process medium strengthening reaction, the left cover of the third embodiment of microvesicle generators assembly is relative with palette rotate 20 degree, the groove perspective view on left cover and palette;
Figure 33 is the left cover structural representation of microvesicle generators assembly the 4th kind of embodiment in the equipment of the invention process medium strengthening reaction;
Figure 34 is the A-A schematic cross-section of Figure 33;
Figure 35 is the palette structural representation of microvesicle generators assembly the 4th kind of embodiment in the equipment of the invention process medium strengthening reaction;
Figure 36 is the B-B schematic cross-section of Figure 35;
Figure 37 is the right cover structural representation of microvesicle generators assembly the 4th kind of embodiment in the equipment of the invention process medium strengthening reaction;
Figure 38 is the B-B schematic cross-section of Figure 37;
Figure 39 is the structural representation when palette of microvesicle generators assembly the 4th kind of embodiment and right cover combine in the equipment of the invention process medium strengthening reaction;
Figure 40 is the B-B schematic cross-section of Figure 39;
Structural representation when Figure 41 is the left cover of microvesicle generators assembly the 4th kind of embodiment in the equipment of the invention process medium strengthening reaction, palette, right cover combination;
Figure 42 is when to be that in the equipment of the invention process medium strengthening reaction, the left cover of microvesicle generators assembly the 4th kind of embodiment is relative with palette rotate 20 degree, the groove perspective view on left cover and palette;
The bubble size that in the equipment that Figure 43 is the invention process medium strengthening reaction, microvesicle generators produces and frequency schematic diagram;
Electric charge on the microbubble surface that in the facilities and equipments that Figure 44 is the invention process medium strengthening reaction, microvesicle generators produces and electromagnetism field domain schematic diagram;
Figure 45 is the structural representation of air pocket generator in the facilities and equipments of a kind of medium strengthening of the present invention reaction method;
Figure 46 is the anodic oxidation synthetic reaction process of electrochemical anodic oxidation device;
Figure 47 is one and adopts U.S. Buddhist nun high-tensile strength AVATAR360ESPFT-IR to carry out infrared spectrum (IR) analysis result to quantum carbon element liquid;
Figure 48 carries out infrared spectrum (IR) analysis result for another Zhang Caiyong U.S. Buddhist nun high-tensile strength AVATAR360ESPFT-IR to quantum carbon particle;
Figure 49 carries out transmission electron microscope (TEM) analysis result for adopting NEC company JEM-2010 high-resolution universal type transmission electron microscope;
Figure 50 carries out transmission electron microscope (TEM) analysis result for another company of Zhang Caiyong NEC JEM-2010 high-resolution universal type transmission electron microscope;
Figure 51-Figure 57 adopts the AFM of U.S. Wei Yike (Veeco) precision instrument Co., Ltd to carry out AFM analysis result to quantum carbon element of the present invention;
Figure 58 is the result adopting internal standard method for gas chromatography to detect embodiments of the invention 2 sample;
Figure 59 is mellitic acid international standard infrared absorption spectra;
Figure 60 is the infrared absorption spectrum analysis result of embodiments of the invention 3 sample;
The XRD standard card figure of Figure 61 graphitic carbon (carbongraphite), card number is 75-1621;
Figure 62 is the result figure adopting the AutomatedD/MaxB type diffractometer of Rigaku Rigaku company to detect the solid matter in quantum carbon element liquid;
Figure 63 is quantum carbon particle x-ray photoelectron power spectrum (XPS) analysis chart;
Figure 64 carries out narrow analysis of spectrum (electron spectroscopy analysis) figure to the C1s in quantum carbon particle;
Figure 65 carries out narrow analysis of spectrum (electron spectroscopy analysis) figure to the O1s in quantum carbon particle.
English in accompanying drawing contrasts as follows with Chinese:
DigitalInstrumentsNanoScope nanoscale digital display
Scansize scan size scope 1.000um
Scanrate scan frequency 1.969Hz
Numberofsamples sample size 256ml
ImageData view data gets maximum point
Datascale ratio data yardstick 2.000nm
Viewangle visual angle
Lightangle light angle
X0.200um/divX axle 0.200 micron/scale
Z2.000nm/divZ axle 2.000 nanometers/scale
0deg0 degree
SectionAnalysis cross-section analysis
Spectrum spectrum
Surfacedistance fore-and-aft distance
Horizdistance (L) horizontal direction distance
Vertdistance vertical direction
Angledeg differences in angle
SpectralperiodDC spectrum cycle direct current
Spectralfreq0Hz spectral frequency 0Hz
SpectralRMSamp0nm spectrum RMS amplifier 0 nanometer
%Transmittance transmissivity %
Wavenumbers (cm-1) cycle cm-1
BENZENEHEXACARBOXYLICACID mellitic acid
RelativeAbundance relative abundance
Time (min) time (second)
M/z mass-to-charge ratio
The 2-thetascale2 θ angle of diffraction
Intensity intensity
BindingEnergy (eV) electron binding energy (electron volts)
The photoelectronic measured intensity of C/S
Detailed description of the invention
A kind of medium strengthening of the present invention reaction method, have safe and reliable, implement easily, advantage that effect is controlled, its facilities and equipments structure is simple, be widely used, precise control.
As shown in Figure 1, it is the general assembly structural representation of the facilities and equipments of a kind of medium strengthening of the present invention reaction method, comprise hydraulic pump 1, microvesicle generators 2, gas supply device 3, air pocket generator 4, the left side of hydraulic pump 1 is communicated with feeding pipe 5, the upside of hydraulic pump 1 is communicated with the left end of the first transfer pipeline 6, the downside of hydraulic pump 1 is communicated with the left end of circuit lines 7, and the first transfer pipeline 6 right-hand member is communicated with circuit lines 7 right-hand member and is communicated with discharging pipeline 8 simultaneously; Feeding pipe 5 is provided with bi-directional path valve F
1, the first transfer pipeline 6 is provided with bi-directional path valve F
2with bi-directional path valve F
3, circuit lines 7 is provided with bi-directional path valve F
4with bi-directional path valve F
5, discharging pipeline 8 is provided with bi-directional path valve F
6.
Air pocket generator 4 is located at bi-directional path valve F
2with bi-directional path valve F
3between the first transfer pipeline 6 on and be communicated with the first transfer pipeline 6 of both sides respectively; The downside of microvesicle generators 2 is communicated with circuit lines 7 by the second transfer pipeline 9, and the second transfer pipeline 9 is located at bi-directional path valve F with the position that is communicated with of circuit lines 7
4with bi-directional path valve F
5between, the right side of microvesicle generators 2 is communicated with gas supply device 3 by supply air line 10, and the upside of microvesicle generators 2 is communicated with air pocket generator 4 by the 3rd transfer pipeline 11; The two ends of the 4th transfer pipeline 12 are communicated with circuit lines 7 with the first transfer pipeline 6 respectively, and the 4th transfer pipeline 12 is located at bi-directional path valve F with the position that is communicated with of the first transfer pipeline 6
2and between air pocket generator 4, the 4th transfer pipeline 12 is located at bi-directional path valve F with the position that is communicated with of circuit lines 7
4with bi-directional path valve F
5between.
It should be noted that, for sampling to the medium in each pipeline, the flow of measuring media, hydraulic pressure, pH value and temperature, can at bi-directional path valve F
1and the feeding pipe 5 between hydraulic pump 1 is arranged oxygen dissolved sampling instrument DO
1with oxidation-reduction potential sampling instrument R
1; The first transfer pipeline 6 between the connection position and air pocket generator 4 of the 4th transfer pipeline 12 and the first transfer pipeline 6 sets gradually flowmeter L
1, pressure-measuring device V
1, pH value measuring instrument pH
1, temperature measuring set T
1; At air pocket generator 4 and bi-directional path valve F
3between the first transfer pipeline 6 on set gradually pressure-measuring device V
2, oxidation-reduction potential sampling instrument R
2, pH value measuring instrument pH
2, temperature measuring set T
2; Bi-directional path reset valve F
0be communicated with the first transfer pipeline 6 with air pocket generator 4 respectively by bypass conduit, the position that bypass conduit is communicated with the first transfer pipeline 6 is located at air pocket generator 4 and pressure-measuring device V
2between, bi-directional path valve F
0for finely tuning the running status of air pocket generator 4; Second transfer pipeline 9 arranges bi-directional path valve F
7with pressure-measuring device V
3; Supply air line 10 arranges flowmeter L
2; 3rd transfer pipeline 11 arranges bi-directional path valve F
8; 4th transfer pipeline 12 arranges bi-directional path valve F
9with flowmeter L
3; At bi-directional path valve F
6the discharging pipeline 8 on right side arranges flowmeter L
4with oxygen dissolved sampling instrument DO
2.
Further, for realizing real-time monitoring, improve automatic management degree, also can set up control system (not shown), programmable logic controller (PLC) PLC is set in the controls, control system is used for feeding pipe 5, first transfer pipeline 6, circuit lines 7, discharging pipeline 8, second transfer pipeline 9, supply air line 10, 3rd transfer pipeline 11, bi-directional path valve on 4th transfer pipeline 12, oxygen dissolved sampling instrument, oxidation-reduction potential sampling instrument, , flowmeter, pressure-measuring device, pH value measuring instrument, temperature measuring set carries out data sampling, monitoring, control to realize automatic management.
As shown in Figure 2, microvesicle generators 2 comprises housing and is arranged at five groups of microvesicle generators assemblies in housing cavity, and it should be noted that, the group number of microvesicle generators does not limit five groups, as long as arrange more than one group can implement the object of the invention.Housing left side wall arranges inlet 201 and air inlet 202, housing right side wall arranges discharging opening 203, and ring washer 204 is set between adjacent microvesicle generators assembly, relatively fixing to make between microvesicle generators assembly; Microvesicle generators assembly is combined by left cover 21, right cover 22 and the palette 23 be arranged between left cover 21 and right cover 22 and forms, left cover 21, right cover 22 and palette 23 are all set to discoid, the diameter of left cover 21 and right cover 22 arranges equal and is greater than the diameter of palette 23, left cover 21 is equipped with through hole with the center of right cover 22, and housing is provided with for adjusting left cover 21 and the coaxial device (not shown) in relative rotation of right cover 22.
It should be noted that, microvesicle generators assembly can have different structural designs, as long as make left cover 21 become symmetric design with the groove on palette 23, makes each groove on both be interconnected when both confronting coaxial turn an angle.
As shown in Figures 3 to 12, it is the first embodiment of microvesicle generators assembly, in the right flank edge of left cover 21, the first protruding lug is set along 2101 to the right, protruding to the right and equal with palette 23 radius short cylindrical 2102 is set in the middle part of the right flank of left cover 21, makes to leave gap between the circumferential wall of short cylindrical 2102 and the first lug madial wall along 2101, a central recess 2103 is set in the right side of short cylindrical 2102, 12 circular grooves 2104 and 12 semi-circular recesses 2105, central recess 2103 is arranged on the right flank medium position of short cylindrical 2102, the edge of central recess 2103 is provided with equally distributed six semi-circular groove, circular groove 2104 is arranged on the outer circumferential of central recess 2103 and is uniformly distributed along the positive six each limits connected, semi-circular recesses 2105 is arranged on the edge of short cylindrical 2102 and makes the minimum range between each semi-circular recesses 2105 and adjacent circular groove 2104 all equal, and make adjacent central recess 2103, circular groove 2104, semi-circular recesses 2105 minimum range each other is all less than the radius of circular groove 2104.
Arrange protruding and with the first lug in left cover 21 along the second lug of 2101 symmetries along 2201 left in the left surface edge of right cover 22, palette 23 is fixedly connected with by joint pin 24 with right cover 22, make to leave gap between the left surface of the right flank of palette 23 and right cover 22, between the circumferential wall of palette 23 and the second lug madial wall along 2201, leave gap.In the left side of palette 23, the groove structure identical with the right side of short cylindrical 2102 is set.When left cover 21, palette 23 and right cover 22 are assembled into microvesicle generators assembly, the first lug in left cover 21 will realize sealing along 2201 with the second lug in right cover 22 along 2101 and fit, and the right side of short cylindrical 2102 also will realize sealing with the left side of palette 12 fits.
As shown in Figure 13 to Figure 22, for the second embodiment of microvesicle generators assembly, its structure and the first embodiment unlike, set up 18 circular grooves 2104, and on the orthohexagonal each limit allowing the circular groove 2104 set up be evenly distributed on outside original circular groove 2104; Semi-circular recesses 2105 is increased to 18 simultaneously, the minimum range between each semi-circular recesses 2105 and adjacent circular groove 2104 to be made equally all equal, and make adjacent central recess 2103, circular groove 2104, semi-circular recesses 2105 minimum range each other all be less than the radius of circular groove 2104.The second embodiment makes microvesicle generators assembly contain the structure of double circular groove 2104.By increasing circular groove 2104 and semi-circular recesses 2105 quantity, microvesicle generators can be made to comprise more microvesicle generation cavity, make gas-liquid mixture carry out physical-chemical reaction more thoroughly in microvesicle generators, making control more accurate.It should be noted that, microvesicle generators component design can be become comprise the structure of numerous heavy circular groove 2104 in theory, based on application target and manufacturing cost, can selective gist according to actual needs.
As shown in Figure 23 to Figure 32, for the third embodiment of microvesicle generators assembly, its structure and the second embodiment unlike, at the right flank of short cylindrical 2102 by arranging a central recess 2103, 25 circular grooves 2104 and 15 semi-circular recesses 2105, equally distributed five semi-circular groove are set at the edge of central recess 2103, circular groove 2104 is made to be evenly distributed on each limit of two concentric regular pentagons, the minimum range between each semi-circular recesses 2105 and adjacent circular groove 2104 will be made equally all equal, and make adjacent central recess 2103, circular groove 2104, semi-circular recesses 2105 minimum range each other is all less than the radius of circular groove 2104.
As Figure 33 to Figure 42 is depicted as the 4th kind of embodiment of microvesicle generators assembly, its structure and the second and the third embodiment unlike, at the right flank of short cylindrical 2102 by arranging a central recess 2103, 35 circular grooves 2104 and 21 semi-circular recesses 2105, equally distributed seven semi-circular groove are set at the edge of central recess 2103, circular groove 2104 is made to be evenly distributed on two concentric just heptagonal each limits, the minimum range between each semi-circular recesses 2105 and adjacent circular groove 2104 will be made equally all equal, and make adjacent central recess 2103, circular groove 2104, semi-circular recesses 2105 minimum range each other is all less than the radius of circular groove 2104.
It should be noted that, the structure of microvesicle generators assembly is not limited to the above embodiment enumerated, can at the edge of central recess by arranging an equally distributed n semi-circular groove, circular groove multiple that number is n is set and each limit along the m centered by central recess positive n limit shape is with one heart uniformly distributed, and semi-circular recesses arranged the quantity sum that number equals the circular groove that Xing Ge limit, outermost positive n limit distributes, make the minimum range between each semi-circular recesses and adjacent circular groove all equal simultaneously, make adjacent central recess, circular groove, semi-circular recesses minimum range each other is all less than the radius of circular groove.Make n >=3 in theory, the structural design of m >=1 all can realize the object of the invention, considers factors such as using needs and design and manufacture cost, 8 >=n >=5, the most suitable during 6 >=m >=2, and effect preferably controls.
When each groove in left cover 21 and palette 23 is in symmetric position, each groove fit on left cover 21 and palette 23 forms multiple closed microvesicle generation cavity, through hole in the middle part of left cover 21 and the through hole in the middle part of right cover 22 are closed because of microvesicle generation cavity and are not communicated with, when left cover 21 is relative with right cover 22 rotate to an angle time, because palette 23 is fixedly connected with right cover 22, each groove of short cylindrical 2102 right flank in left cover 21 and the respective slot of palette 23 left surface should stagger mutually, because the distance between each groove is less than the radius of circular groove 2104, and circular groove 2104 is equally distributed by orthohexagonal each limit, therefore each microvesicle generation cavity should be interconnected, and by right cover 22 and between left cover 21 and palette 23 because leaving the passage that gap is formed, make to form effective path between the through hole in the middle part of the through hole in the middle part of left cover 21 and right cover 22.Liquid medium and gas medium enter microvesicle generators assembly by the through hole in the middle of left cover 21, after gas-liquid mixture microvesicle is nascent, carry out in microvesicle generation cavity under different parameters state growing, expand, compress, degeneration, through too much organizing microvesicle generators assembly, conquassation stretching resilience regeneration occurs repeatedly, making the size of microvesicle often regenerate once then fission is numerous small size microvesicle.
It should be noted that, by adjustment left cover 21 and the relative angle of palette 23 coaxial rotating, air demand number, the technical parameter such as the flow of medium, hydraulic pressure, temperature and kinematic viscosity, effectively can control size and the density of microvesicle.Under usual use feelings, medium pressure liquid scope is 0.01Mpa ~ 100Mpa, preferred 0.02Mpa ~ 10Mpa; Liquid medium flow rate scope is 0.01 liter/min ~ 100 liters/min, preferably 0.1 liter/min ~ 30 liters/min; Liquid medium kinematic viscosity range: 0.20mm2/s ~ 180.00mm2/s, preferred 0.50mm2/s ~ 180.00mm2/s; Gas medium kinematic viscosity range is 1.00mm2/s ~ 110.00mm2/s, preferred 1.20mm2/s ~ 30.00mm2/s.Microvesicle generators of the present invention output can contain the medium mixture of the highly concentrated nano level microvesicle of below 25nm level in batches.As shown in figure 43, be the size of nanoscale microvesicle and the frequency figure of concentration, bubble size frequency when about 100nm is maximum, is about every milliliter of concentration containing 1,200,000,000 microvesicles.As shown in figure 44, in microvesicle generative process, when bubble size reaches below nanoscale, because the various factors such as ionization, ionic adsorption, ionic compartmentation, CONTACT WITH FRICTION influence each other, microbubble surface can gather a large amount of negative electrical charge.Because charged particle can attract the ion of the oppositely charged disperseed, the ion nearer apart from microbubble surface will be restrain strongly, and the ion far away apart from microbubble surface then can form a loose electron cloud.The symmetrical ionosphere of electric double layer will be formed according to capacitance principle, thus around each microvesicle, form spherical super electric field, and the ion of oppositely charged in medium solution can be attracted to move together.Microvesicle carries electric field energy in media as well can forming energy air pocket, makes more multi-energy participate in medium strengthening reaction.
Air pocket generator 4 comprises shell and is arranged at the medium strengthening reaction chamber in shell, medium strengthening reaction chamber comprises the thick chamber 41 of the equal opening in two ends, contraction chamber 42 and thin chamber 43, by contraction chamber 42 transition between thick chamber 41 and thin chamber 43, the left end in thick chamber 41 enters accent with the medium be arranged on shell and is communicated with, right-hand member and the medium in thin chamber 43 go out accent 44 and are communicated with, and it is horn-like for what open to the right that medium goes out accent 44; Shell also offers the microvesicle transfer passage be communicated with thin chamber 43 left end.
If the diameter in thick chamber 41 is D
1, the diameter in thin chamber 43 is D
2, the length of contraction chamber 42 adds that the length in thin chamber 43 is L, makes 0.01≤(D
1-D
2)/L≤0.1; If the angle of the section edges line in the section edges line of contraction chamber 42 and thin chamber 43 is α, make 35 °≤α≤75 °; If the angle that medium goes out the section edges line of accent 44 and the cross-sectional right side limit in thin chamber 43 is β, make 45 °≤β≤85 °.As further preferred embodiment, 0.015≤(D
1-D
2)/L≤0.03; 45 °≤α≤65 °; 55 °≤β≤75 °.
The process that reaction occurs to strengthen medium in air pocket generator 4 is as follows, and medium is transported to air pocket generator 4 with certain pressure intensity by hydraulic pump, flows through thick chamber 41, contraction chamber 42 and thin chamber 43 successively, goes out accent 44 export after strengthening reaction from medium.Medium flows to the process of contraction chamber 42 from thick chamber 41, and strengthen because cavity shrinks velocity of medium, now pressure medium main manifestations is dynamic pressure.At left end place, thin chamber 43 owing to having passed into the dielectric mixture containing highly concentrated nano level microvesicle, the earth pressure release in medium, thus produce negative pressuren zone, be equivalent to cavity and reduce further, velocity of medium is accelerated further, and sucks a large amount of nanoscale microvesicle; After medium flows through negative pressuren zone, pressure recovers, and flow rate of liquid declines, and medium dynamic pressure is transformed to static pressure; Go out accent 44 place at medium, become suddenly large owing to going out accent, medium is after sufficient microvesicle dissolved under pressure, in addition liquid becomes hypersaturated state, can produce a large amount of high-speed jets, fault offset, detection shows, this stage medium temperature can reach 40 DEG C ~ 250 DEG C.It should be noted that, different with application target according to preparation, can to the conveying pressure of hydraulic pump, rate-of flow and temperature, and carry the flow of microvesicle and pressure to adjust.
The present invention study fully water character and and the interactional basis of nanometer microvesicle on, propose to prepare method and the weight feed air pocket of nanometer microvesicle, reach the strengthening effect in abundanter radical pair hole, thus reach the object of the efficient green energy.
The fundamental property of water is: the ionic product (25 DEG C) of molten point 0 DEG C, boiling point 100 DEG C, critical-temperature 373.99 DEG C, maximal density temperature 3.98 DEG C, surface tension 72.75gyn/cm, impedance 2.5 × 107 Ω cm, O-H spacing 0.09572nm, H-O-H angle 104.52 °, hydrolytic dissociation H+, OH-is { H+}*{OH-}=1.27 × 10
-14.The present invention finds, if change H-O-H angle, so the character of water and the fused property of water and other materials all will change.As everyone knows, a lot of method is had now to change the character of water and to be applied.Such as the method for brine electrolysis and use magnetite makes H+, OH-ionization have an impact, and attempts to make water clusters become less, makes water obtain special character and is applied.Also often having hydrocarbon fuel can improve efficiency of combustion by magnetic field recently, to reduce report etc. the example of cost a lot, but, be not the too small effect not reaching anticipation of active force be exactly that high cost is difficult to carry out application.
Present invention utilizes hydrone quantization and control preparation method, focus on the indices and character that change water comprehensively, between hydrone, between H-O-H, between O-H, give multiband sympathetic resonance field and the super electric field of nanoscale microvesicle, make the original character of water that following change occur: the surface tension of water can drop to from 72.75gyn/cm and trends towards minimum numerical value; The angle 104.52 ° of H-O-H becomes 145-160 ° (reckoning); Impedance tends to 0 from 2.5 × 107 Ω cm; Become less than-20 DEG C etc. character from 0 DEG C at molten o'clock to change.If become 145-160 ° from the angle 104.52 ° of the H-O-H of hydrone, so hexagonal 20 set dignity of water isolate a hydrogen ion all respectively, like this, the physical of water has an impact as pressure, thermal and magnetic field etc., can prepare high concentration quantization water body simultaneously.
The present invention prepares high concentration quantization water body, and described quantization water body refers in pure nonionic water, running water and substance dissolves water, applies the liquid water of the quantum carbon element composition of specified quantitative.And have employed the method that special construction and physical method prepare nano gas microvesicle to implement, the character of described nano gas can be air, the paraffin gas such as the elementary gas such as oxygen, hydrogen, nitrogen, argon, helium, neon, krypton, methane, ethane, propane, oxidation of coal gas, the fluoride gas etc. such as the petrochemical industry such as coal gas, natural gas gas, carbon monoxide, carbon dioxide, nitrous oxide, comprise the mist of above-mentioned gas.Utilize the modification of water fluid and the preparation of nanometer microvesicle to provide, and with the coordinating of air pocket generation mechanism, produce a series of cavitation effect such as high fuel factor, chemical effect, photoelectricity of HTHP, free radical, shock wave and high-speed jet etc.
Embodiment 1
Quantization liquid is passed in equipment of the present invention through hydraulic pump 1, oxygen dissolved DO
1for 6.12mg/L, oxidation-reduction potential R
1for 255.6mv; Water temperature T
1it is 17.0 DEG C; PH
1value is 6.8-7.0; It is 1.0Mpa that hydraulic pump 1 provides equipment to supply pressure to equipment, the inlet-pressure V of air pocket generator 4
1for 0.45Mpa; Flowmeter L
1for 80 liters per minute, flowmeter L
3for 20 liters per minute, flowmeter L
2for 0.15-0.5 liter per minute, the inlet-pressure V of microvesicle generators 2
3for 0.5-0.6Mpa, the outlet pressure V of air pocket generator 4
2for 0.02Mpa; Oxidation-reduction potential R
2for 282.5-382.5mv; Water temperature T
1for 72.0-77.0 DEG C, water temperature difference T
2-T
1=55 DEG C, pH
1value is 2.0-5.8, after equipment normal operation, from bi-directional path valve F
5go out sampling, collect the product obtained containing nanometer microvesicle, containing the density of 12-14 hundred million microvesicles in every milliliter of product, content is 0.092-0.628ppm;
Wherein, quantization liquid is suspension, comprises quantum carbon element liquid and solvent, and the concentration of quantum carbon element liquid is 0.1%-0.45%, and the addition of quantum carbon element liquid is the 1%-3% of solvent, and quantum carbon element liquid comprises quantum carbon element.
Quantum carbon element, comprise the carbon particle that particle diameter is 0.6-100nm, carbon particle is single carbon and/or Graphene particle, have on the top layer of carbon particle containing carbon, hydrogen, oxygen, nitrogen compound, comprise condensed-nuclei aromatics, the compound containing carbon oxygen singly-bound, the compound containing C=O bond, compound containing C-H bond containing carbon, hydrogen, oxygen, nitrogen compound.
Preferably, quantum carbon element is made up of the carbon particle of following mass percent: the carbon particle 10% ~ 50% of carbon particle 50% ~ 95%, 0.9 < particle diameter < 50.0nm of 0.6≤particle diameter≤0.9nm, the carbon particle 0% ~ 20% of 50≤particle diameter≤100nm; Containing carbon, hydrogen, oxygen, nitrogen compound be condensed-nuclei aromatics, the compound containing carbon oxygen singly-bound, the compound containing C=O bond, compound containing C-H bond the mixture of one or more, wherein each element ratio is: C45% ~ 55%, H0.2% ~ 2.0%, N0.1% ~ 0.3%, O45% ~ 65%.
Results of elemental analyses adopts U.S. EAI company CE-440 type quick elemental analyser to obtain, analysis precision: 0.15%, accuracy of analysis: 0.15%, and proportionate relationship can be found out, the number of quantum carbon particle oxy radical is on the whole very high.
It is further preferred that the carbon content0.433 in the present invention in condensed-nuclei aromatics structure, structural formula following (being not limited to following structural formula):
Preferably, the carbon structural formula content0.335 in carbon oxygen single key structure following (being not limited to following structural formula):
Preferably, the carbon structural formula content0.232 in C=O bond structure is as follows, (being not limited to following structural formula):
Each element ratio in quantum carbon element is: when C50.19%, H0.42%, N0.22%, O49.17%.Carbon in quantum carbon element is condensed-nuclei aromatics structural carbon, and mass percent is 43.3%, and the carbon mass percent in carbon oxygen single key structure is 33.5%, and the carbon mass percent in C=O bond structure is 23.2%.Oxygen element mass percent in carbon oxygen single key structure is 54.3%, and the oxygen element mass percent in C=O bond structure is 45.7%.The characteristic index of quantum carbon element liquid is: ORP is 360mv, conductivityσ is 2.0ms/cm, pH value is 2.2, concentration is 0.40%.
Quantum carbon element liquid, wherein quantum carbon element liquid is the aqueous solution containing quantum carbon element, and the ORP of quantum carbon element liquid is 280mv-380mv, conductivityσ is 1-5ms/cm, electromotive force is 280mv ~ 380mv, pH value is 1.5-3.2, concentration is 0.1%-0.45%.
Pure surfaces of carbon particles should be alkaline, because its microporous surface is made up of huge aromatic condensed ring structure, this is lewis base, in water, easily absorb hydrogen ion and make surrounding liquid be alkalescence, acidity just occurs after surface bond oxygen offsets lewis base property to a certain extent, pH value is exactly the mark of carbon nano-particles content of surface oxygen, and the height of pH value depends primarily on the number of carbon nano-particles Surface oxygen-containing groups.
In the present invention:
Figure 46 is the anodic oxidation synthetic reaction process of electrochemical anodic oxidation device, therefrom can find out that liquid water has a large amount of O under the effect of nanometer microvesicle
2oxygen atom group and H
+, OH
-the group products such as ion, graphitic carbon, in electrochemical anodic oxidation process, produces carbon-carbon bond and breaks to form a large amount of carbon and hang key, be atom in liquid state and ionic group in conjunction with time, define the chemical modification figure of each group in carbene surface illustrated in figure.
Figure 47 is one and adopts U.S. Buddhist nun high-tensile strength AVATAR360ESPFT-IR instrument quantum carbon element liquid to carry out infrared spectrum (IR) analysis result, find that the spectrogram of infrared spectrum and pure water is basically identical, this shows in the water slurry of carbon nanometer in addition to water not containing other solvents;
Figure 48 carries out infrared spectrum (IR) analysis result for another Zhang Caiyong U.S. Buddhist nun high-tensile strength AVATAR360ESPFT-IR to quantum carbon particle, finds that the peak at 3434cm-1 place should be the hydroxyl-OH absworption peak in adsorbed water; The characteristic absorption peak of the C=O base of absworption peak on surface carboxyl groups at 1701cm-1 place; 1449cm-1 and 861cm-1 is the absorption region of carbon-carbon double bond C=C; 1232cm-1 place is-OHRockingbending deformation vibration absworption peak in surface carboxyl groups;
Figure 49 carries out transmission electron microscope (TEM) analysis result for adopting NEC company JEM-2010 high-resolution universal type transmission electron microscope, therefrom can find out the nanoparticle morphology 300,000 times (40nm scale) under different amplification, 500,000 times (20nm scale), 800,000 times (10nm scale).
Figure 50 carries out transmission electron microscope (TEM) analysis result for another company of Zhang Caiyong NEC JEM-2010 high-resolution universal type transmission electron microscope, and graphenic surface (two dimension) lines (atom gap) when therefrom can find out multiplication factor 1,000,000 times (5nm scale) is high-visible.
Figure 51-Figure 57 adopts the AFM of U.S. Wei Yike (Veeco) precision instrument Co., Ltd to carry out AFM analysis result to quantum carbon element of the present invention, from measurement data, the particle diameter of known quantum carbon element is 0.6 ~ 0.9nm, quantization carbon particle has good dispersiveness, and the result of its particle diameter AFM is substantially consistent with the result of TEM;
Figure 58 is the result adopting internal standard method for gas chromatography to detect embodiments of the invention 2 sample, gas-chromatography and mass spectrographic common combination analysis, the composition that chromatogram detects only has one (chromatogram only has a peak), contrast two kinds of detection things and occur that the time at peak is known, the main component of sample is the same, again according to mass spectral analysis, known main component is normal octane C8H18;
Figure 59 is the international standard infrared absorption spectra of mellitic acid;
Figure 60 is the infrared absorption spectrum analysis result of embodiments of the invention 3 sample, and the constituent structure contrasting known sample with the international standard absorption spectra of mellitic acid is mellitic acid material.
The XRD standard card figure of Figure 61 graphitic carbon (carbongraphite), card number is 75-1621.
Figure 62 is the result figure adopting the AutomatedD/MaxB type diffractometer of Rigaku Rigaku company to detect the solid matter in quantum carbon element liquid, X-ray diffraction analysis (XRD) can be found out in analyzing, and XRD standard card learns that the material in quantum carbon element liquid is graphite.
Figure 63 is quantum carbon particle x-ray photoelectron power spectrum (XPS) analysis chart, can find out in Japan's vacuum (ULVAC-pHI) companies scan imaging, x-ray photoelectron power spectrum (pHIQuantera) result that the analysis for surface carbon oxygen relative amount adopts atomic sensitivity factor method to measure, the mass percent of the carbon and oxygen that can be regarded as out quantum carbon particle surface is 59.8% and 40.2%;
Figure 64 carries out narrow analysis of spectrum (electron spectroscopy analysis) figure to the C1s in quantum carbon particle; Therefrom can find out, carbon mainly exists with condensed-nuclei aromatics structural carbon (code name 1), mass percent is 43.3%, carbon mass percent in carbon oxygen single key structure (code name 2) is 33.5%, and the carbon mass percent in C=O bond structure (code name 3) is 23.2%.
Figure 65 carries out narrow analysis of spectrum (electron spectroscopy analysis) figure to the O1s in quantum carbon particle; In all oxygen elements in quantum carbon element, the oxygen element mass percent in carbon oxygen single key structure (code name 1) is 54.3%, and the oxygen element mass percent in C=O bond structure (code name 2) is 45.7%.
Nanometer microvesicle is the mixture of one or more in air, oxygen, hydrogen, nitrogen, argon gas, helium, neon, Krypton, methane, ethane, propane, coal gas, natural gas, carbon monoxide, carbon dioxide, nitrous oxide, fluoride gas.Quantization liquid also comprises additive, and additive is the mixture of one or more in aphthenic acids, metallic salt, and the addition of additive is the 0.1%-1% of quantization liquid quality.
The degree feature of the liquid medium strengthening process of air pocket generator, obey Weber number theorem, the computing formula of Weber number is:
W＝ρυ
2Ι/σ
Wherein: ρ is medium fluid density;
υ is dielectric attribute flow velocity;
Ι is characteristic length;
σ is the surface tension coefficient of fluid;
Weber number represents the ratio of inertia force and surface tension effect, and ρ medium fluid density is 650 ~ 2000kg/m
3, Ι characteristic length is the surface tension coefficient of 10mm ~ 1000mm, σ fluid be 0.001N/m ~ 0.090N/m, υ be dielectric attribute flow velocity is 2.7x10
-5m
3/ s ~ 2.7x10
-1m
3/ s, media fluid viscosity is 10000mPas ~ 15000mPas under normal temperature 20 DEG C and normal pressure, gas viscosity 100 μ Pas ~ 120 μ Pas, and medium steam pressure 0.15kPa ~ 101.33kPa, the Weber number of product is 5 ~ 300.
Preferably, ρ medium fluid density is 700 ~ 1600kg/m
3; Ι characteristic length is 50mm ~ 300mm; The surface tension coefficient of σ fluid is 0.010N/m ~ 0.078N/m; υ is dielectric attribute flow velocity is 1.4x10
-4m
3/ s ~ 2.7x10
-2m
3/ s, media fluid viscosity is 11000mPas under normal temperature 20 DEG C and normal pressure, gas viscosity 110 μ Pas.
Embodiment 2
Liquid upgrading example when liquid medium is pure water
The deionized water (being equivalent to redistilled water) that pH value is 6.5 ~ 7.2, resistance value is 120M Ω, enters present system through hydraulic pump 1.Oxygen dissolved (inolabOxiLevel2 dissolved oxygen meter, German WTW company) DO
1for 6.12mg/L; Oxidation-reduction potential (IIANNA211 acidity tester, Italian Kim Yong-jin) R
1for 255.6mv; Water temperature T
1it is 17.0 DEG C; PH1 value is 6.8; It is 1.0Mpa that hydraulic pump 1 provides system to supply pressure to system; The inlet-pressure V of air pocket generator 4
1for 0.45Mpa (bi-directional path valve F
0the optimum state reset valve of air pocket generator 4); Flowmeter (LRT-1, Shanghai He Ji instrument and meter for automation company) L
1for 80 liters per minute; Flowmeter L
3for 20 liters per minute; The medium of gas supply device 3 is air, flowmeter L
2for 0.15 liter per minute; Microvesicle generators assembly 2 is single group; The inlet-pressure V of microvesicle generators assembly 2
3for 0.5Mpa.After apparatus of the present invention normal operation, from bi-directional path valve F
5go out sampling, with laser diffraction granularity analyzer (LS-13-320, Beckman Coulter Inc. of the U.S.) mensuration detection is carried out to the size of the bubble contained in water obtain, in liquid, bubble size frequency when about 100nm is maximum, and every milliliter about containing the density of 1,200,000,000 microvesicles.The size of nanoscale microvesicle and the frequency figure of concentration as shown in figure 42.As above the process microbubble diameter sampled calculates according to 100nm, volume=(π/6) (100 × 10 of microvesicle
-9) 3=5.23 × 10
-22m3=5.23 × 10
-16cm3; So volume=1.2 × 109 × 5.23 × 10 of 1,200,000,000 microvesicles
-16=6.28 × 10
- 7cm3.Result represents that microvesicle content is in a liquid below ppm, but enormous amount and because of every microvesicle all carries electric field energy can forming energy air pocket in media as well, more multi-energy can be made to participate in medium strengthening reaction.The electric charge electromagnetism field domain schematic diagram of microvesicle on it as shown in figure 43.The present invention as air pocket generator 4 for from pure water be rich in microvesicle liquid and carry out liquid strengthening upgrading reaction treatment.After the reaction of air pocket generator semi-finals upgrading, the character of the liquid of the present embodiment is changed.The outlet pressure V of air pocket generator 4
2for 0.02Mpa; Oxidation-reduction potential R
2for 382.5mv; Water temperature T
1be 72.0 DEG C of (water temperature difference T
2-T
1=55 DEG C); PH
1value is 2.2; Moltenly in liquid deposit about 1,200,000,000 microvesicles, content 0.628ppm.。The liquid of this character can be widely used in thermal source provides system, water treatment, cleaning and solid and liquid to carry out Ultrafine and homogenising, improves the quality of fluid etc. field.
Embodiment 3
Heavy-oxygen-enriched water style
The deionized water (being equivalent to redistilled water) that pH value is 6.5 ~ 7.2, resistance value is 120M Ω, enters present system through hydraulic pump 1.Oxygen dissolved DO
1for 6.12mg/L; Oxidation-reduction potential R
1for 255.6mv; Water temperature T
1it is 17.0 DEG C; PH
1value is 6.8; It is 1.0Mpa that hydraulic pump 1 provides system to supply pressure to system; The inlet-pressure V of air pocket generator 4
1for 0.45Mpa (bi-directional path valve F
0the optimum state reset valve of air pocket generator 4); Flowmeter L
1for 80 liters per minute; Flowmeter L
3for 20 liters per minute; The medium of gas supply device 3 is oxygen O2, flowmeter L
2for 0.20 liter per minute; Microvesicle generators assembly 2 is eight groups; The inlet-pressure V of microvesicle generators assembly 2
3for 0.6Mpa.After apparatus of the present invention normal operation, from bi-directional path valve F
5go out sampling, carry out mensuration detection with laser diffraction granularity analyzer to the size of the oxygen bubble contained in water and obtain, in liquid, bubble size frequency when about 50nm is maximum, and every milliliter about containing the density of 1,400,000,000 microvesicles.The present invention as air pocket generator 4 for from pure water be rich in bubbles of oxygen liquid and carry out liquid strengthening upgrading reaction treatment.The outlet pressure V of air pocket generator 4
2for 0.02Mpa; Oxidation-reduction potential R
2for 380.5mv; Water temperature T
1be 77.0 DEG C of (water temperature difference T
2-T
1=60 DEG C); PH
1value is 2.0; Moltenly in liquid deposit about 1,400,000,000 microvesicles, content 0.092ppm.。The liquid of this character can be widely used in thermal source provides system, high heavy-oxygen-enriched water, water treatment, cleaning and solid and liquid to carry out Ultrafine and homogenising, improves the quality of fluid etc. field.
Embodiment 4
Fresh-keeping water liquid example
Running water (comprising seawater), enters present system through hydraulic pump 1.Oxygen dissolved DO
1for 6.12mg/L; Oxidation-reduction potential R
1for 255.6mv; Water temperature T
1it is 17.0 DEG C; PH
1value is 7.0; It is 1.0Mpa that hydraulic pump 1 provides system to supply pressure to system; The inlet-pressure V of air pocket generator 4
1for 0.45Mpa (bi-directional path valve F
0the optimum state reset valve of air pocket generator 4); Flowmeter L
1for 80 liters per minute; Flowmeter L
3for 20 liters per minute; The medium of gas supply device 3 is nitrogen N 2, flowmeter L
2for 0.5 liter per minute; Microvesicle generators assembly 2 is five groups; The inlet-pressure V of microvesicle generators assembly 2
3for 0.5Mpa.After apparatus of the present invention normal operation, from bi-directional path valve F
5go out sampling, carry out mensuration detection with laser diffraction granularity analyzer to the size of the bubble contained in water and obtain, in liquid, bubble size frequency when about 80nm is maximum, and every milliliter about containing the density of 1,300,000,000 microvesicles.The present invention as air pocket generator 4 for from pure water be rich in nitrogen microvesicle liquid and carry out liquid strengthening upgrading reaction treatment.The outlet pressure V of air pocket generator 4
2for 0.02Mpa; Oxidation-reduction potential R2 is 282.5mv; Water temperature T
1be 75.0 DEG C of (water temperature difference T
2-T
1=58 DEG C); PH
1value is 5.8; Moltenly in liquid deposit about 1,300,000,000 microvesicles, content 0.350ppm.。The liquid of this character can be widely used in the fresh-keeping and food preserving of animals and plants etc. field.
Can to the gas of liquid and liquid, liquid and oxygen, hydrogen, nitrogen etc. by apparatus of the present invention; And the upgrading of the liquid fluid such as oil, fats, pure water, running water, seawater be object, the solid that also can carry out seaweeds etc. and liquid carries out Ultrafine and homogenising, improve the quality of fluid, can be used by wide spectrum industrially.
Embodiment 5
Biodiesel is a kind of higher fatty acids low-carbon alkyl fat, with various grease for raw material, is prepared into liquid fuel with low-carbon alcohols through esterification or transesterification process, and being the petrochemical industry oil substitute of high-quality, is typical green energy resource.Glyceride stock comprises the vegetable oil materials such as castor-oil plant, palm, soybean, cream paulownia, rubber, cotton, rape oil, peanut, Chinese tallow tree, and the water plant such as Wild oil plant and engineering microalgae and microbial grease, animal fat, discarded food and drink oil, vegetable oil processing fent etc., preparation method of the present invention and equipment carry out ester exchange process, make and can replace the reproducibility biodiesel fuel of petrifaction diesel and obtain special effect.Concrete example is as shown in table 1:
The each fuel parameter of table 1.
Embodiment 6
China's coal-burned industrial boiler about has 600,000, year consumes about about 800,000,000 tons, raw coal, also have a large amount of civil coal boiler, efficiency low SI, the problem such as pollutant emission is serious, automatization level is low, become the most serious coal-smoke pollution source, the whole nation and haze source, various places.Great national policy and the social concern of necessary solution are arrived." 12 " planning outline clearly proposes, within the period of planning, close down and rectify and improve coal-burning boiler, going back blue sky and the people.The invention provides Zero-discharge energy-saving type and heat heat supply method.For heating, the present invention heats heat supply and coal-burning boiler and oil burning boiler, and to carry out example comparative result as shown in table 2:
Table 2. the present invention heats heat supply and compares with coal-burning boiler and oil burning boiler
Embodiment 7
The present invention is to the clean method for preparing of the profit homogeneous micro emulsion dispersion mixing that grease adds water.Be applicable to petroleum fuel comprising light oil, mink cell focus, impure waste oil and waste oil, vegetable oil, to improving earth environment, more effectively utilizing limited petroleum resources to have great importance.Mix water in oil, add a certain amount of additive by apparatus of the present invention and modification is carried out to water, and the W/O microemulsion dosage unthickened fuel that oil has intermiscibility and formed.The component of W/O microemulsion dosage unthickened fuel is: oil product (petrochemical industry oil product, light oil, heavy oil etc.) 30%-80%; Water H
2o (not having particular/special requirement to water, can be running water, seawater etc.) 10%-60%; The 1%-3% of quantum carbon element liquid solvent; Low-carbon alcohols (C
nh
2n+1oH; 1≤n≤8; Purity more than 90%) 5%-60%.
Preparation method 1: existing by input 0.2 kilogram of quantum carbon element liquid and 20 kilograms of methyl alcohol CH in 20 kg of water
4o mixes, and mixed liquor prepares 30 minutes in apparatus of the present invention.The pH value of mixing material carries out adjusting to pH with micro-quantum carbon element liquid
5namely scope completes carries out upgrading to water.In mixing material, add 60 kilograms of oil products again prepare in apparatus of the present invention and within 30 minutes, namely obtain 100.2 kilograms of (loss is ignored) clean oil products.
Preparation method 2: existing by input 0.3 kilogram of quantum carbon element liquid and 15 kg ethanol C in 25 kg of water
2h
6o mixes, and mixed liquor prepares 30 minutes in apparatus of the present invention.The pH value of mixing material carries out adjusting to pH with micro-quantum carbon element liquid
5namely scope completes carries out upgrading to water.In mixing material, add 60 kilograms of oil products again prepare in apparatus of the present invention and within 30 minutes, namely obtain 100.3 kilograms of (loss is ignored) clean oil products.
Preparation method 3: existing by input 0.5 kilogram of quantum carbon element liquid and 10 kilograms of octanol C in 30 kg of water
8h
18o mixes, and mixed liquor prepares 30 minutes in apparatus of the present invention.The pH value of mixing material carries out adjusting to pH with micro-quantum carbon element liquid
5namely scope completes carries out upgrading to water.In mixing material, add 60 kilograms of oil products again prepare in apparatus of the present invention and within 30 minutes, namely obtain 100.5 kilograms of (loss is ignored) clean oil products.
Preparation method 4: existing by input 0.1 kilogram of quantum carbon element liquid and 60 kilograms of methyl alcohol CH in 10 kg of water
4o mixes, and mixed liquor prepares 30 minutes in apparatus of the present invention.The pH value of mixing material carries out adjusting to pH with micro-quantum carbon element liquid
5namely scope completes carries out upgrading to water.In mixing material, add 30 kilograms of oil products again prepare in apparatus of the present invention and within 30 minutes, namely obtain 100.1 kilograms of (loss is ignored) clean oil products.
Through method and apparatus of the present invention, the cleansing oil prepared, its outward appearance is transparent bright, and long-term storage is unchanged.Its every physical index meets the national standard of each oil product completely.
Burn results citing (preparation method 1):
C# heavy oil (S:0.8%) thousand. watt/hour be 8156; Air ratio is 1.16
Cleansing oil (S:0.8%) kilocalorie/hour be 8980; Air ratio is 1.16
Boiler model 1H1SCM080 type evaporation capacity 5t/h
Wirking pressure 12kg/cm2 Fuel Consumption 396l/h
| Project | OIL％ | Viscosity (mm 2/s) | H 2O％ | Additive % |
| Heavy oil fuel oil | 100 | 28.06 | 0 | 0 |
| Liquefaction of the present invention | 70 | 24.32 | 30 | 1.2 |
Under the condition that air ratio is identical, energy-saving and emission-reduction and efficiency all improve more than 30%, can think this be quantum carbon element and special processing method of the present invention increase the combustion-supporting effect of great amount of hydroxy group.
The invention is not restricted to citing scope, have more wide spectrum purposes.Heat heating system, artificial hot-spring (micromolecular water and the effect of nanometer microvesicle), chemical synthesis, scale removal rust and antiscale rust, cleaning, fluid food (comprising dairy products etc.) as all and make ripe sterilization etc. industry specialty, all belong to the scope that the present invention relates to.
Above embodiment is only be described the preferred embodiment of the present invention; not scope of the present invention is limited; under not departing from the present invention and designing the prerequisite of spirit; the various distortion that those of ordinary skill in the art make technical scheme of the present invention and improvement, all should fall in protection domain that claims of the present invention determines.
Claims (14)
1. implement an equipment for medium strengthening reaction, comprise hydraulic pump (1), microvesicle generators (2), gas supply device (3), air pocket generator (4), it is characterized in that:
The left side of described hydraulic pump (1) is communicated with feeding pipe (5), the upside of hydraulic pump (1) is communicated with the left end of the first transfer pipeline (6), the downside of hydraulic pump (1) is communicated with the left end of circuit lines (7), and the first transfer pipeline (6) right-hand member is communicated with circuit lines (7) right-hand member and is communicated with discharging pipeline (8) simultaneously;
Feeding pipe (5) is provided with bi-directional path valve F
1, the first transfer pipeline (6) is provided with bi-directional path valve F
2with bi-directional path valve F
3, circuit lines (7) is provided with bi-directional path valve F
4with bi-directional path valve F
5, discharging pipeline (8) is provided with bi-directional path valve F
6;
Air pocket generator (4) is located at bi-directional path valve F
2with bi-directional path valve F
3between the first transfer pipeline (6) upper and be communicated with first transfer pipeline (6) of both sides respectively; The downside of microvesicle generators (2) is communicated with circuit lines (7) by the second transfer pipeline (9), and the second transfer pipeline (9) is located at bi-directional path valve F with the position that is communicated with of circuit lines (7)
4with bi-directional path valve F
5between, the right side of microvesicle generators (2) is communicated with gas supply device (3) by supply air line (10), and the upside of microvesicle generators (2) is communicated with air pocket generator (4) by the 3rd transfer pipeline (11); The two ends of the 4th transfer pipeline (12) are communicated with circuit lines (7) with the first transfer pipeline (6) respectively, and the 4th transfer pipeline (12) is located at bi-directional path valve F with the position that is communicated with of the first transfer pipeline (6)
2and between air pocket generator (4), the 4th transfer pipeline (12) is located at bi-directional path valve F with the position that is communicated with of circuit lines (7)
4with bi-directional path valve F
5between.
2., according to the equipment of enforcement medium strengthening reaction according to claim 1, it is characterized in that:
Bi-directional path valve F
1and the feeding pipe (5) between hydraulic pump (1) is provided with oxygen dissolved sampling instrument DO
1with oxidation-reduction potential sampling instrument R
1;
The first transfer pipeline (6) between the connection position of the 4th transfer pipeline (12) and the first transfer pipeline (6) and air pocket generator (4) is provided with flowmeter L successively
1, pressure-measuring device V
1, pH value measuring instrument pH
1, temperature measuring set T
1;
Air pocket generator (4) and bi-directional path valve F
3between the first transfer pipeline (6) on be provided with pressure-measuring device V successively
2, oxidation-reduction potential sampling instrument R
2, pH value measuring instrument pH
2, temperature measuring set T
2;
Bi-directional path reset valve F
0be communicated with the first transfer pipeline (6) with air pocket generator (4) respectively by bypass conduit, the position that bypass conduit is communicated with the first transfer pipeline (6) is located at air pocket generator (4) and pressure-measuring device V
2between;
Second transfer pipeline (9) is provided with bi-directional path valve F
7with pressure-measuring device V
3; Supply air line (10) is provided with flowmeter L
2; 3rd transfer pipeline (11) is provided with bi-directional path valve F
8; 4th transfer pipeline (12) is provided with bi-directional path valve F
9with flowmeter L
3; Bi-directional path valve F
6the discharging pipeline (8) on right side is provided with flowmeter L
4with oxygen dissolved sampling instrument DO
2.
3. according to the equipment of enforcement medium strengthening reaction according to claim 2, it is characterized in that: also comprise control system, described control system is provided with programmable logic controller (PLC) PLC, control system is used for feeding pipe (5), first transfer pipeline (6), circuit lines (7), discharging pipeline (8), second transfer pipeline (9), supply air line (10), 3rd transfer pipeline (11), bi-directional path valve on 4th transfer pipeline (12), oxygen dissolved sampling instrument, oxidation-reduction potential sampling instrument, flowmeter, pressure-measuring device, pH value measuring instrument, temperature measuring set carries out data sampling, monitoring, control.
4. according to the equipment of enforcement medium strengthening reaction according to claim 3, it is characterized in that: described microvesicle generators (2) comprises housing and is arranged at least one group of microvesicle generators assembly in housing cavity, housing left side wall is provided with inlet (201) and air inlet (202), housing right side wall is provided with discharging opening (203), is provided with ring washer (204) between adjacent microvesicle generators assembly;
Microvesicle generators assembly is combined by left cover (21), right cover (22) and the palette (23) be arranged between left cover (21) and right cover (22) and forms, left cover (21), right cover (22) and palette (23) are discoid, the equal diameters of left cover (21) and right cover (22) and be greater than the diameter of palette (23), left cover (21) is equipped with through hole with the center of right cover (22), and housing is provided with for adjusting left cover (21) and the coaxial device in relative rotation of right cover (22);
The right flank edge of left cover (21) is provided with the first protruding lug to the right along (2101), protruding and equal with palette (23) radius short cylindrical (2102) is provided with to the right in the middle part of the right flank of left cover (21), gap is provided with between the madial wall of the circumferential wall of short cylindrical (2102) and the first lug edge (2101), the right side of short cylindrical (2102) is provided with central recess (2103), circular groove (2104) and semi-circular recesses (2105), central recess (2103) arranges one and is arranged on the right flank medium position of short cylindrical (2102), circular groove (2104) is arranged on the outer circumferential of central recess (2103), semi-circular recesses (2105) is arranged on the edge of short cylindrical (2102), the edge of central recess (2103) is provided with an equally distributed n semi-circular groove, n >=3, circular groove (2104) multiple that number is n is set and each limit along the m centered by central recess (2103) positive n limit shape is with one heart uniformly distributed, m >=1, semi-circular recesses (2105) the quantity sum that number equals the circular groove (2104) that Xing Ge limit, outermost positive n limit distributes is set, minimum range between each semi-circular recesses (2105) and adjacent circular groove (2104) is all equal, adjacent central recess (2103), circular groove (2104), semi-circular recesses (2105) minimum range each other is all less than the radius of circular groove (2104),
The left surface edge of right cover (22) is provided with protruding and with the first lug in left cover (21) along (2101) symmetrical second lug along (2201) left, palette (23) is fixedly connected with by joint pin (24) with right cover (22), be provided with gap between the right flank of palette (23) and the left surface of right cover (22), between the madial wall of the circumferential wall of palette (23) and the second lug edge (2201), be provided with gap;
The left side of palette (33) is provided with the groove structure identical with the right side of short cylindrical (2102); The first lug in left cover (21) seals along the second lug on (2101) and right cover (22) along (2201) and fits, and the right side of short cylindrical (2102) and the left side of palette (23) seal fits.
5., according to the equipment of enforcement medium strengthening reaction according to claim 4, it is characterized in that: 8 >=n >=5,6 >=m >=3.
6. according to the equipment of the enforcement medium strengthening reaction described in any one of claim 1-5, it is characterized in that: described air pocket generator (4) comprises shell and is arranged at the medium strengthening reaction chamber in shell, medium strengthening reaction chamber comprises the thick chamber (41) of the equal opening in two ends, contraction chamber (42) and thin chamber (43), by contraction chamber (42) transition between thick chamber (41) and thin chamber (43), the left end in thick chamber (41) enters accent with the medium be arranged on shell and is communicated with, right-hand member and the medium in thin chamber (43) go out accent (44) and are communicated with, it is horn-like for what open to the right that medium goes out accent (44), shell also offers the microvesicle transfer passage be communicated with thin chamber (43) left end.
7., according to the equipment of enforcement medium strengthening reaction according to claim 6, it is characterized in that: the diameter of described thick chamber (41) is D
1, the diameter of thin chamber (43) is D
2, the length of contraction chamber (42) adds that the length in thin chamber (43) is L, 0.01≤(D
1-D
2)/L≤0.1; The angle of the section edges line of contraction chamber (42) and the section edges line of thin chamber (43) is α, 35 °≤α≤75 °; The angle that medium goes out the section edges line of accent (44) and the cross-sectional right side limit of thin chamber (43) is β, 45 °≤β≤85 °.
8., according to the equipment of enforcement medium strengthening reaction according to claim 7, it is characterized in that: 0.015≤(D
1-D
2)/L≤0.03; 45 °≤α≤65 °; 55 °≤β≤75 °.
9. a medium strengthening reaction method, is characterized in that, comprise the steps:
In the equipment that quantization liquid is passed in claim 1-7 described in any claim through hydraulic pump (1), oxygen dissolved DO
1for 6.12mg/L, oxidation-reduction potential R
1for 255.6mv; Water temperature T
1it is 17.0 DEG C; PH
1value is 6.8-7.0; It is 1.0Mpa that hydraulic pump (1) provides equipment to supply pressure to equipment, the inlet-pressure V of air pocket generator (4)
1for 0.45Mpa; Flowmeter L
1for 80 liters per minute, flowmeter L
3for 20 liters per minute, flowmeter L
2for 0.15-0.5 liter per minute, the inlet-pressure V of microvesicle generators (2)
3for 0.5-0.6Mpa, the outlet pressure V of air pocket generator (4)
2for 0.02Mpa; Oxidation-reduction potential R
2for 282.5-382.5mv; Water temperature T
1for 72.0-77.0 DEG C, water temperature difference T
2-T
1=55 DEG C, pH
1value is 2.0-5.8, after equipment normal operation, from bi-directional path valve F
5go out sampling, collect the product obtained containing nanometer microvesicle, containing the density of 12-14 hundred million microvesicles in every milliliter of product, content is 0.092-0.628ppm;
Wherein, described quantization liquid is suspension, comprises quantum carbon element liquid and solvent, and the concentration of described quantum carbon element liquid is 0.1%-0.45%, and the addition of quantum carbon element liquid is the 1%-3% of solvent volume, containing quantum carbon element in described quantum carbon element liquid.
10. medium strengthening reaction method according to claim 9, it is characterized in that, described quantum carbon element comprises the carbon particle that particle diameter is 0.6-100nm, described carbon particle is single carbon and/or Graphene particle, have on the top layer of described carbon particle containing carbon, hydrogen, oxygen, nitrogen compound, describedly comprise condensed-nuclei aromatics, the compound containing carbon oxygen singly-bound, the compound containing C=O bond, compound containing C-H bond containing carbon, hydrogen, oxygen, nitrogen compound.
11. medium strengthening reaction methods according to claim 10, it is characterized in that, described quantum carbon element is made up of the carbon particle of following mass percent: the carbon particle 10% ~ 50% of carbon particle 50% ~ 95%, 0.9 < particle diameter < 50.0nm of 0.6≤particle diameter≤0.9nm, the carbon particle 0% ~ 20% of 50≤particle diameter≤100nm; Described containing carbon, hydrogen, oxygen, nitrogen compound be condensed-nuclei aromatics, the compound containing carbon oxygen singly-bound, the compound containing C=O bond, compound containing C-H bond the mixture of one or more, wherein each element ratio is: C45% ~ 55%, H0.2% ~ 2.0%, N0.1% ~ 0.3%, O45% ~ 65%; Described quantum carbon element liquid is the aqueous solution containing quantum carbon element, and concentration is 0.1%-0.45%, and the ORP of described quantum carbon element liquid is 280mv-380mv, conductivityσ is 1-5ms/cm, electromotive force is 280mv ~ 380mv, pH value is 1.5-3.2;
Described nanometer microvesicle is the mixture of one or more in air, oxygen, hydrogen, nitrogen, argon gas, helium, neon, Krypton, methane, ethane, propane, coal gas, natural gas, carbon monoxide, carbon dioxide, nitrous oxide, fluoride gas;
Described solvent is the mixture of one or more of oil, water, low-carbon alcohols, and described oil is petrochemical industry oil product, and described water is running water or seawater, and the carbon number of described low-carbon alcohols is 1-8, and the purity of described low-carbon alcohols is more than 90%.
12. medium strengthening reaction methods according to claim 11, is characterized in that: described solvent is made up of the raw material of following percentage by volume: oil: 30%-80%, water: 10%-60%, quantum carbon element liquid: the 1%-3% of solvent; Low-carbon alcohols 5%-60%.
13. medium strengthening reaction methods according to claim 9, it is characterized in that, the degree feature of the liquid medium strengthening process of air pocket generator, obey Weber number theorem, the computing formula of Weber number is:
W＝ρυ
2Ι/σ
Wherein: ρ is medium fluid density;
υ is dielectric attribute flow velocity;
Ι is characteristic length;
σ is the surface tension coefficient of fluid;
Weber number represents the ratio of inertia force and surface tension effect, and ρ medium fluid density is 650 ~ 2000kg/m
3, Ι characteristic length is the surface tension coefficient of 10mm ~ 1000mm, σ fluid be 0.001N/m ~ 0.090N/m, υ be dielectric attribute flow velocity is 2.7x10
-5m
3/ s ~ 2.7x10
-1m
3/ s, media fluid viscosity is 10000mPas ~ 15000mPas under normal temperature 20 DEG C and normal pressure, gas viscosity 100 μ Pas ~ 120 μ Pas, and medium steam pressure 0.15kPa ~ 101.33kPa, the Weber number of described product is 5 ~ 300.
14. medium strengthening reaction methods according to claim 9, it is characterized in that, ρ medium fluid density is 700 ~ 1600kg/m
3; Ι characteristic length is 50mm ~ 300mm; The surface tension coefficient of σ fluid is 0.010N/m ~ 0.078N/m; υ is dielectric attribute flow velocity is 1.4x10
-4m
3/ s ~ 2.7x10
-2m
3/ s, media fluid viscosity is 11000mPas under normal temperature 20 DEG C and normal pressure, gas viscosity 110 μ Pas.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| EP3498670A4 (en) * | 2016-08-10 | 2020-07-22 | Yulinghua Technology Co. Ltd | Quantum carbon and method and device for producing same |
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| CN1186179A (en) * | 1997-12-01 | 1998-07-01 | 李廷浩 | Air-cave generating pump |
| JP2010155212A (en) * | 2008-12-26 | 2010-07-15 | Daikin Ind Ltd | Minute bubble generation apparatus |
| CN103170263A (en) * | 2013-03-19 | 2013-06-26 | 联邦奈泡科技股份有限公司 | Nano-bubble generating device |
| CN204107491U (en) * | 2014-09-04 | 2015-01-21 | 朱光华 | A kind of equipment implementing medium strengthening reaction |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20140016433A1 (en) * | 2009-04-23 | 2014-01-16 | Peter Douglas Jack | Method and apparatus for generating micro bubbles in a fluid flow |
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|---|---|---|---|---|
| CN1186179A (en) * | 1997-12-01 | 1998-07-01 | 李廷浩 | Air-cave generating pump |
| JP2010155212A (en) * | 2008-12-26 | 2010-07-15 | Daikin Ind Ltd | Minute bubble generation apparatus |
| CN103170263A (en) * | 2013-03-19 | 2013-06-26 | 联邦奈泡科技股份有限公司 | Nano-bubble generating device |
| CN204107491U (en) * | 2014-09-04 | 2015-01-21 | 朱光华 | A kind of equipment implementing medium strengthening reaction |
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| EP3498670A4 (en) * | 2016-08-10 | 2020-07-22 | Yulinghua Technology Co. Ltd | Quantum carbon and method and device for producing same |
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