CN104193655A - Binary fluorine-containing sulfimide and preparation method of alkali metal salt of binary fluorine-containing sulfimide - Google Patents
Binary fluorine-containing sulfimide and preparation method of alkali metal salt of binary fluorine-containing sulfimide Download PDFInfo
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Abstract
The invention discloses a method for preparing binary or ternary fluorine-containing sulfimide, a method for preparing an ionic liquid from an alkali metal salt of the binary or ternary fluorine-containing sulfimide, and an application of the alkali metal salt and the ionic liquid as electrolyte in a carbon-based super capacitor, a secondary lithium (ion) battery, and the like. The method for preparing the alkali metal salt of the binary or ternary fluorine-containing sulfimide is simple and short in operation step, a product is easy to separate and purify, and the yield and the purity of the product are both high; the binary or ternary fluorine-containing sulfimide lithium disclosed by the invention is good in thermal stability and hydrolysis resistance, a non-water electrolysis liquid of the binary or ternary fluorine-containing sulfimide lithium is relatively high in conductivity and lithium ion transference number, relatively good in oxidation resistance and good in compatibility with electrode materials which are used widely; and meanwhile the ionic liquid containing binary or ternary fluorine-containing sulfimide anions is low in viscosity, high in conductivity and wide in electrochemical window.
Description
Dividing an application of the 201110131558.x patent application that the application is, the application number of former patent application is 201110131558.x; The title of former patent application is " an alkali metal salt of binary or the fluorine-containing sulfimide of ternary and ionic liquid and application thereof "; The applying date of former patent application is on May 20th, 2011.
Technical field
The invention belongs to organic fluorine chemistry, novel material and advanced power technique fields, be specifically related to a kind of binary or an alkali metal salt of the fluorine-containing sulfimide of ternary and the preparation method of ionic liquid, and an alkali metal salt and ionic liquid application in lithium (ion) battery and carbon back ultracapacitor as electrolyte.
Background technology
Fluorine-containing sulfimide and an alkali metal salt thereof and ionic liquid, particularly lithium salts are important fluorine-containing organic ionic compounds.They, all have important commercial application and are worth with fields such as high-performance nonaqueous electrolyte material and efficient catalysts at clean energy devices such as secondary lithium (ion) battery, ultracapacitor and aluminium electrolutic capacitors.Therefore, people are always in the synthetic and applied research of being devoted to carry out novel fluorine sulfimide and derivative thereof.
At present, about the research of fluorine-containing sulfimide, mainly concentrating on the fluorine-containing sulfimide of monobasic (is in molecule, only to contain a sulphonyl imido group-SO
2-N-SO
2-) (Coord.Chem.Rev., 1997,158,413), as perfluoroalkyl sulfimide (H[(R
fsO
2)
2n], R
f=C
mf
2m+1, m=1-8) and an alkali metal salt (M[(R
fsO
2)
2n], M=Li, Na, K, Rb, Cs), that representative is two (trimethyl fluoride sulfonyl) imine lithium (Li[(CF
3sO
2)
2n], be called for short LiTFSI) and two (fluorine sulphonyl) imine lithium (Li[(FSO
2)
2n], be called for short LiFSI) etc.Applicant, recently in preparation and the Application Areas thereof of fluorine-containing sulfimide and an alkali metal salt thereof, has also developed some new methods and technology (CN101654229, CN101747242, CN101747242, Chem.Lett., 2010,39,472).
Research report about polynary sulfimide and metal-salt thereof is less.Argropoulos etc. adopt two (chlorine sulphonyl) imines (H[(ClSO
2)
2n]) obtain the ternary sulfimide of corresponding arylamine with arylamine condensation, and its structure has been carried out characterizing (J.Appli.Poly.Sci., 1981,26,3073).Nie Jin etc. utilize two (chlorine sulphonyl) imines (H[(ClSO
2)
2n]) and perfluoroalkyl sulphonamide (R
fsO
2nH
2) reaction; the ternary sulfimide and an alkali metal salt and the transition metal salt that contain two (perfluoroalkyl group sulfonyl) have been made; and their application (CN1450052 aspect ionogen and catalyzer have been reported; CN1450053, J.Fluorine Chem., 2004; 125; 27), but its work only limits to the ternary sulfonyl imide compounds that contains perfluoroalkyl, does not comprise that substituted radical is preparation method and the application of ternary sulfimide, an alkali metal salt and other derivative of fluorine atom.DesMarteau etc. have reported a kind of binary sulfimide lithium salts and perfluoroalkyl sulfimide lithium salts polymkeric substance connecting with the fluorine-containing long-chain of aliphatics, and studied conductivity (the Solid State Ionics of the polymer solid electrolyte that these lithium salts and polyethers (PEO) blend form, 2002,148,173).But this class binary of DesMarteau etc. report and the synthesis step of the fluorine-containing sulfimide lithium salts of polymkeric substance are loaded down with trivial details, and on molecular structure owing to being failed to form conjugation delocalization system by fluoroalkyl interval between sulfimide group.In addition, Zhang etc. utilizes urea and sulfuryl chloride (SO
2cl
2) or two (chlorine sulphonyl) imines (H[(ClSO
2)
2n]) reaction, or utilize thionamic acid (NH
2sO
3h) with phosphorus pentachloride (PCl
5) react, made respectively oligomer and the polymkeric substance of phosphinylidyne sulfimide and sulfimide.The oligomer of gained phosphinylidyne sulfimide or sulfimide and polymkeric substance further react with lithium hydride; make corresponding lithium salts oligomer and polymkeric substance, and measured chemical property (Electrochim.Acta, 2000 of these lithium salts as polymer dielectric; 45,1229).
The report of the fluorine-containing sulfimide of relevant binary is few.Roesky etc. utilize (Cl
3p=N)
2sO
2with fluosulfonic acid (FSO
3h) reaction, has prepared two (fluorine sulphonyl) sulphonyl diimine (H
2[(FSO
2n)
2sO
2]) (Chem.Ber., 1968,101,162.).But this synthetic route is not only attended by two fluorine sulfimide (HN (SO
2f)
2) by product generation, cause product separation purification difficult, and Fluoride for Raw Material sulfonic acid (FSO
3h) toxicity is larger, is not easy to operation.Jan etc. have reported and have utilized trimethyl fluoride sulfonyl trichlorine phosphonitrile (CF
3sO
2n=PCl
3) and fluosulfonic acid (FSO
3h) two (trimethyl fluoride sulfonyl) sulphonyl diimine (H of reaction preparation
2[(CF
3sO
2n)
2sO
2]), and characterized the crystalline structure (Acta Crystallographica, Section C:Crystal Structure Communs., 2004, C60, O79.) of this compound.The method is equally owing to using the fluosulfonic acid acid (FSO that toxicity is larger
3h) be reaction raw materials, be unfavorable for experimental implementation and scale operation.
On the other hand, nonaqueous electrolytic solution is one of critical material of the energy storage devices such as high specific energy (secondary) lithium ion battery, its over-all properties, and as chemistry and electrochemical stability, security etc., directly affect the use of secondary lithium (ion) battery.At present, business-like (secondary) lithium-ion battery electrolytes mainly by organic carbonate as methylcarbonate, diethyl carbonate, vinyl carbonate etc., and ionogen conducting salt (is mainly LiPF
6) form.In this system, the inflammable and easy volatile of organic carbonate is main potential safety hazard (as burning, blast, leaks etc.) (J.Electrochem.Soc., 2001,148,1100 of current lithium ion battery; Chem.Rev., 2004,104,4303).Meanwhile, traditional ionogen conducting salt LiPF
6due to its chemical instability (comprising thermally labile and easily hydrolysis), make to use LiPF
6(secondary) lithium ion battery when the lower work of high temperature (>55 ℃), greatly reduce (Electrochem.Communs, 2005,7,669) in cycle performance and work-ing life.And in other common lithium salts, as lithium perchlorate (LiClO
4), LiBF4 (LiBF
4), trifluoromethyl sulfonic acid lithium (Li[CF
3sO
3]), two (trimethyl fluoride sulfonyl) imine lithium (LiTFSI), di-oxalate lithium borate (LiBOB) etc., owing to there being respectively the performance deficiency of different aspect, as LiClO
4there is potential explosivity, LiBF
4specific conductivity is too low, Li[SO
3cF
3] and LiTFSI anodal current collector material aluminium foil is corrosive, LiBOB solubleness in carbonic ether is low, makes these lithium salts fail to obtain and be widely used in lithium ion battery.Therefore, research and development chemical stability (as thermostability, water stability, etc.) height, the excellent novel conductive lithium salts electrolyte of chemical property (as high conductivity, wide electrochemical window, does not have corrodibility etc. to aluminium foil) replaces traditional lithium salts LiPF
6it is the important research direction of exploitation large-sized power battery and large-scale energy storage electron device.
Up to the present, about an alkali metal salt (particularly lithium salts) of the fluorine-containing sulfimide of binary and the preparation of ionic liquid, and the research that they are applied in lithium ion battery as electrolyte there is not yet report.
Summary of the invention
Task of the present invention is to provide an alkali metal salt of a kind of binary or the fluorine-containing sulfimide of ternary and such binary or the fluorine-containing sulfimide of ternary and preparation method thereof.
Another task of the present invention be to provide a kind of containing above-mentioned binary or the fluorine-containing sulfimide anion ion liquid of ternary and preparation method thereof with its in lithium cell, lithium ion battery and carbon back ultracapacitor as electrolytical application.
Another task of the present invention is to provide binary or the ternary purposes containing fluorine-based sulfimide lithium, in lithium cell, lithium ion battery and carbon back ultracapacitor as electrolytical application.
Realizing technical scheme of the present invention is:
The fluorine-containing sulfimide of binary provided by the invention has structure shown in following formula I,
In formula I:
R
f 1c
mf
2m+1, wherein m=0-8, (CF
3)
2cHO,, CF
3cH
2o, HCF
2cH
2o or H (CF
2cF
2o)
ncF
2cF
2, n=1-6 wherein;
R
f 2c
mf
2m+1, wherein m=0-8, (CF
3)
2cHO,, CF
3cH
2o, HCF
2cH
2o or H (CF
2cF
2o)
ncF
2cF
2, n=1-6 wherein;
R
f 1and R
f 2can be identical or different.
Binary fluorine-containing sulfimide alkali metal salt provided by the invention has structure shown in formula II,
In formula II:
M=Li, Na, K, Rb or Cs;
R
f 1c
mf
2m+1, wherein m=0-8, (CF
3)
2cHO,, CF
3cH
2o, HCF
2cH
2o or H (CF
2cF
2o)
ncF
2cF
2, n=1-6 wherein;
R
f 2c
mf
2m+1, wherein m=0-8, (CF
3)
2cHO,, CF
3cH
2o, HCF
2cH
2o or H (CF
2cF
2o)
ncF
2cF
2, n=1-6 wherein;
R
f 1and R
f 2can be identical or different.
Ternary fluorine sulfimide provided by the invention has structure shown in formula III,
Ternary fluorine sulfimide alkali metal salt provided by the invention has structure shown in formula IV,
In formula IV:
M=Li, Na, K, Rb or Cs;
The preparation method of the fluorine-containing sulfimide of binary provided by the invention and an alkali metal salt thereof and the fluorine-containing sulfimide of ternary and an alkali metal salt thereof, comprises the following steps:
Step 1: by sulphamide (NH
2sO
2nH
2) or two (amido sulphonyl) imines (NH
2sO
2nHSO
2nH
2), thionyl chloride is 1:1～1:5 by stoichiometry mol ratio, preferably 1:1～1:3 mixing is placed in reaction flask, add and sulphamide (or two (amido sulphonyl) imines) stoichiometry mol ratio is 1:1～1:3, preferably chlorsulfonic acid (the ClSO of 1:1～1:2
3h) or perfluoro alkyl sulfonic acid (R
fsO
3h), at 60～150 ℃, preferably stir at 100～120 ℃, the reaction times is 4～24 hours, and preferably 8～12 hours, after completion of the reaction, underpressure distillation obtained two (chlorine sulphonyl) sulphonyl diimine (H accordingly
2[(ClSO
2n)
2sO
2]) or two (perfluoroalkyl sulphonyl) sulphonyl diimine (H
2[(R
fsO
2n)
2sO
2]) or two (chlorine sulphonyl)-bis-(sulphonyl) three imines (H
3{ (ClSO
2n)
2[(SO
2)
2n] });
Step 2: two (chlorine sulphonyl) sulphonyl diimine (H that obtain to above-mentioned step 1
2[(ClSO
2n)
2sO
2]), or two (chlorine sulphonyl)-bis-(sulphonyl) three imines (H
3{ (ClSO
2n)
2[(SO
2)
2n] }) in, by stoichiometry, adding mol ratio is 1:1～1:3, preferably antimony trifluoride (the SbF of 1:1～1:2
3), at 0～60 ℃, preferably to stir at 20～40 ℃, the reaction times is 4～24 hours, preferably 8～12 hours, after completion of the reaction, underpressure distillation obtained respectively two (fluorine sulphonyl) sulphonyl diimine (H
2[(FSO
2n)
2sO
2]) or two (fluorine sulphonyl)-bis-(sulphonyl) three imines (H
3{ (FSO
2n)
2[(SO
2)
2n] });
Step 3: to prepared two (perfluoroalkyl sulphonyl) sulphonyl diimine (H of step 1
2[(R
fsO
2n)
2sO
2]) or prepared two (fluorine sulphonyl) sulphonyl diimine (H of step 2
2[(FSO
2n)
2sO
2]) or two (fluorine sulphonyl)-bis-(sulphonyl) three imines (H
3{ (FSO
2n)
2[(SO
2)
2n] }) compound adds polar aprotic solvent, gradation is by 1.2～5 times of stoichiometry mol ratios, preferably 1.5～3 times of Anhydrous potassium carbonates to group with imine moiety mole number or Carbon Dioxide caesium or Carbon Dioxide rubidium solid, join in above-mentioned organic solution, continue reaction 5～20 hours, preferably 10～12 hours, filtration under diminished pressure, elimination insolubles obtains an alkali metal salt ([(R of the fluorine-containing sulfimide of binary
fsO
2n)
2sO
2] M, M=K, Rb or Cs) or an alkali metal salt ([(FSO of the fluorine-containing sulfimide of ternary
2n)
2sO
2] M, M=K, Rb or Cs).
Step 4: the fluorine-containing sulfimide potassium of binary prepared by step 3 or ternary is dissolved in polar aprotic solvent, with the MClO of the mole numbers such as stoichiometry
4or MBF
4, M=Li, or Na, carry out metathesis exchange reaction, obtains lithium salts or the sodium salt ([(R of the colourless fluorine-containing sulfimide of binary
fsO
2n)
2sO
2] M, M=Li or Na) or lithium salts or the sodium salt ([(FSO of the fluorine-containing sulfimide of ternary
2n)
2sO
2] M, M=Li or Na), described polar aprotic solvent can be methylcarbonate, diethyl carbonate, acetonitrile, acetone or Nitromethane 99Min..
The method of preparation provided by the invention (fluorine sulphonyl) (perfluoroalkyl sulphonyl) sulphonyl diimine and its an alkali metal salt, comprises the following steps:
Step (1) under agitation, by (perfluoroalkyl sulphonyl) (aminosulfonyl) imines (R
fsO
2nHSO
2nH
2) and thionyl chloride (SOCl
2), chlorsulfonic acid (ClSO
3h), after mixing by mole ratio 1:1.2:1, at 80～150 ℃, preferably back flow reaction 8～40 hours at 110～130 ℃, preferably 12～24 hours, after underpressure distillation, obtains (chlorine sulphonyl) (perfluoroalkyl sulphonyl) sulphonyl diimine (H
2[(ClSO
2n) (R
fsO
2n) SO
2]);
(chlorine sulphonyl) (perfluoroalkyl sulphonyl) sulphonyl diimine (H that step (2) obtains to above-mentioned steps (1)
2[(ClSO
2n) (R
fsO
2n) SO
2]) in, add 1～4 times of stoichiometry mol ratio, preferably antimony trifluoride (the SbF of 1.5～2 times of amounts
3), after room temperature reaction 10-20 hour, underpressure distillation can obtain (fluorine sulphonyl) (perfluoroalkyl sulphonyl) sulphonyl diimine (H
2[(FSO
2n) (R
fsO
2n) SO
2]), add the polar aprotic solvent of 4～10 times of diimine volumes to be prepared into imide liquor; The preferred acetonitrile of aprotic, polar, Nitromethane 99Min., tetrahydrofuran (THF), methylcarbonate, Methyl ethyl carbonate, diethyl carbonate, Nitromethane 99Min., tetrahydrofuran (THF);
Step (3) is to prepared (fluorine sulphonyl) (perfluoroalkyl sulphonyl) sulphonyl diimine (H of step (2)
2[(FSO
2n) (R
fsO
2n) SO
2]) solution in add 1～5 times of stoichiometry mol ratio, preferably the alkaline carbonate of 1.5～2 times of amounts reacts, after completion of the reaction, suction filtration, revolve to steam and remove an alkali metal salt that obtains (fluorine sulphonyl) (perfluoroalkyl sulphonyl) sulphonyl diimine after solvent.
Ionic liquid provided by the invention represents with following general formula (V),
C
+A
－ (Ⅴ)
In formula (V): C
+the positively charged ion being selected from following formula (a) to (j):
With the substituent R in above formula (a) to (j)
1-R
4identical or not identical, and respectively, separately or jointly there is following implication:
-C
mh
2m+1, m=1-12 wherein;
-(CH
2)
ny, n=1-8 wherein, Y=CN;
-CO
2r, wherein R=C
1-C
4alkyl;
-(CH
2cH
2o)
x(CH
2)
ycH
3, x=1-12 wherein; Y=0-4;
-CH
2o (CH
2)
zcH
3, z=0-4 wherein;
-(CH
2cH
2o)
xr
f, x=1-12 wherein, R
f=C
mf
2m+1, m=1-8;
-(CH
2cH
2s)
xr
f, x=1-12 wherein, R
f=C
mf
2m+1, m=1-8);
And
A
-the negatively charged ion that is selected from following formula VI or formula (VII):
In formula VI:
R
f 1c
mf
2m+1, wherein m=0-8, (CF
3)
2cHO, CF
3cH
2o, HCF
2cH
2o or H (CF
2cF
2o)
ncF
2cF
2, n=1-6 wherein;
R
f 2c
mf
2m+1, wherein m=0-8, (CF
3)
2cHO, CF
3cH
2o, HCF
2cH
2o or H (CF
2cF
2o)
ncF
2cF
2, n=1-6 wherein;
R
f 1and R
f 2can be identical or different.
The preparation method of above-mentioned ionic liquid provided by the invention, comprise the following steps: by an alkali metal salt of the fluorine-containing sulfimide of binary of structure shown in the following formula II of having of stoichiometry equimolar amount or have structure shown in following formula IV the fluorine-containing sulfimide of ternary an alkali metal salt with following formula (a) sulfonium salt to (j) representative, the halogenide of ammonium salt microcosmic salt or guanidinesalt is dissolved in respectively in deionized water, be generally 20mmol salt and be dissolved in 10mL deionized water, then at room temperature mix, after stir about 0.5 hour, stratification, with separating funnel, separate lower floor's liquid, be dissolved in methylene dichloride, use again deionized water wash 3～5 times, decompression is removed after dichloromethane solvent, 90 ℃ of vacuum decompressions are dried 12 hours, obtain colourless or light yellow ionic liquid.
In formula II:
M=Li, Na, K, Rb or Cs;
R
f 1c
mf
2m+1, wherein m=0-8, (CF
3)
2cHO,, CF
3cH
2o, HCF
2cH
2o or H (CF
2cF
2o)
ncF
2cF
2, n=1-6 wherein;
R
f 2c
mf
2m+1, wherein m=0-8, (CF
3)
2cHO,, CF
3cH
2o, HCF
2cH
2o or H (CF
2cF
2o)
ncF
2cF
2, n=1-6 wherein;
R
f 1and R
f 2can be identical or different;
In formula IV:
M=Li, Na, K, Rb or Cs;
One or two or more kinds mixed system and lithium salts in the invention described above ionic liquid can form il electrolyte.
One or two or more kinds in the invention described above ionic liquid and the mixed system of other ionic liquids and lithium salts also can form il electrolyte, and other described ionic liquids are by negatively charged ion TFSI
-, FSI
-, PF
6 -, BF
4 -in any one with following formula (a) sulfonium salt to (j) representative, ammonium salt, any one composition in the positively charged ion of microcosmic salt, guanidinesalt.
One or two or more kinds in the invention described above ionic liquid and the mixture of organic solvent and lithium salts also can form il electrolyte, described organic solvent can be cyclic carbonate, chain linear carbonate or carboxylicesters, and described cyclic carbonate can be NSC 11801 (EC) or propylene carbonate (PC); Described chain linear carbonate can be one or two or more kinds the mixture in methylcarbonate (DMC), Methyl ethyl carbonate (EMC), diethyl carbonate (DEC), dipropyl carbonate (DPC); Described carboxylicesters can be CH
3cO
2cH
3(MA), CF
3cO
2cF
3(MA-f), CH
3cO
2cH
2cH
3(EA), CF
3cO
2cF
2cF
3(EA-f), CH
3cO
2cH
2cF
3(TFEA), CF
3cO
2cH
2cH
3(ETFA), CH
3cH
2cO
2cH
3(MP), CF
3cF
2cO
2cF
3(MP-f) mixture of one or two or more kinds in.
Nonaqueous electrolytic solution provided by the invention is comprised of electric conducting lithium salt and organic solvent, the content of electric conducting lithium salt in organic solvent is 0.1-3 mol/L, described electric conducting lithium salt is the fluorine-containing sulfimide lithium of binary or ternary, described organic solvent is one or two or more kinds the mixed solvent in cyclic carbonate, chain linear carbonate, carboxylicesters, annular lactone, and the described cyclic carbonate as organic solvent is NSC 11801 (EC) or propylene carbonate (PC); The described chain linear carbonate as organic solvent is one or two or more kinds the mixture in methylcarbonate (DMC), Methyl ethyl carbonate (EMC), diethyl carbonate (DEC), dipropyl carbonate (DPC); The described carboxylicesters as organic solvent is CH
3cO
2cH
3(MA), CF
3cO
2cF
3(MA-f), CH
3cO
2cH
2cH
3(EA), CF
3cO
2cF
2cF
3(EA-f), CH
3cO
2cH
2cF
3(TFEA), CF
3cO
2cH
2cH
3(ETFA), CH
3cH
2cO
2cH
3(MP), CF
3cF
2cO
2cF
3(MP-f) mixture of one or two or more kinds in; The described annular lactone as organic solvent is the mixture of one or two or more kinds in beta-propiolactone (BPL), beta-butyrolactone (BBL), gamma-butyrolactone (GBL), Alpha-Methyl-gamma-butyrolactone (AMGBL), γ-valerolactone (GVL), δ-valerolactone (DVL), γ-hexalactone (GCL), 6-caprolactone (ECL) specifically.
Above-mentioned nonaqueous electrolytic solution provided by the invention, can also contain functional additive, described functional additive is solid electrolyte interface (the Solid electrolyte interface of carbon back negative material, SEI) film forming accelerating, anti-overshoot additive, fire retardant is or/and stablizer, wherein said SEI membrane-forming agent can be one or two or more kinds the mixture in following SEI membrane-forming agent: vinylene carbonate (VC), fluorinated ethylene ester (FEC), chloroethylenes ester (ClEC), propyl sulfonic acid lactone (PS), butyl sulfonic acid lactone, tetraalkyl-dialkylene siloxanes, (to vinyl benzene sulphonyl) (perfluoroalkyl sulphonyl) inferior amine salt.
Nonaqueous electrolytic solution provided by the invention can be used for the preparation of lithium ion battery and lithium cell and carbon back ultracapacitor.
Employing contains in above-mentioned binary or lithium (ion) battery of the fluorine-containing sulfimide lithium of ternary as conducting salt, comprise can reversible doff lithium positive electrode active materials, can be, but not limited to is the oxidate for lithium of single transition metal oxidate for lithium or multiple hybrid transition metal.Described single transition metal oxidate for lithium is cobalt acid lithium (LiCoO
2), lithium nickelate (LiNiO
2) or the LiMn of spinel type
2o
4; The oxidate for lithium of described multiple hybrid transition metal is ternary material LiNi
xa
yb
(1-x-y)o
2, A wherein, B is Co, Al, a kind of in Mn, and A, not identical with B, 0<x<1,0<y<1, or the LiMPO of olivine-type
4, wherein M is Co, Ni, Fe, the mixture of one or more in Mn, or Li
1-x(A
yb
zc
1-y-z) O
2, 0≤x<1 wherein, 0≤y<1,0≤z<1, A, B, C is Co, Ni, Fe, the mixture of one or more in Mn.
Employing contains in above-mentioned binary or lithium (ion) battery of the fluorine-containing sulfimide lithium of ternary as conducting salt, comprise can reversible doff lithium negative active core-shell material to can be, but not limited to be metallic lithium, or under be listed in <2V versus Li/Li
+below can embed one or more the mixture in the material of metallic lithium: natural graphite, synthetic graphite, the mutually micro-carbon ball in centre (MCMB), hard carbon, soft carbon, Li-Sn alloy, Li-Sn-O alloy, Sn, SnO, SnO
2, spinel structure lithiumation TiO
2-Li
4ti
5o
12, Li-Al alloy.
The method operation steps of preparing binary or ternary fluorine-containing sulfimide alkali metal salt provided by the invention is brief, the easily separated purification of product, the productive rate of its product and purity are all very high, can as in ionogen, (comprise liquid state, gel, solid-state) the preparation of lithium salts conducting salt, catalyzer and high-performance ionic liquid synthetic etc.
Innovative point of the present invention is in prepared binary or the fluorine-containing sulfimide negatively charged ion of ternary, due to its SO
2-N-SO
2the conjugated structure of group, makes this anionoid have negative charge and disperses, and structural flexibility is good, and two ends-SO
2-group also can effectively shield the negative charge on N atom.So this class imines negatively charged ion presents the performance of weak coordination, thereby specific conductivity, dissociation constant and the cationic transport number thereof of the fluorine-containing sulfimide lithium of the binary of effectively raising or ternary electrolytic solution, shown good oxidation resistance, thermostability and hydrolytic resistance simultaneously.Make can show low viscosity containing binary or the fluorine-containing sulfimide anion ion liquid of ternary, the character of high conductivity, and there is wide electrochemical window, while being applied to field of electronic devices, can effectively improve the high rate performance of lithium ion battery etc.
Accompanying drawing explanation
Fig. 1: the lithium ion battery of making by embodiment 29 (lithium salts adopts two (fluorine sulphonyl) sulphonyl diimine lithiums and lithium hexafluoro phosphate to compare), at 25 ℃ of circulation times, the graph of a relation of specific discharge capacity and cycle index; Filled symbols represents specific discharge capacity, and open symbols represents coulombic efficiency.
Fig. 2: press the lithium ion battery (lithium salts adopts two (fluorine sulphonyl) sulphonyl diimine lithiums) that embodiment 29 makes, at 25 ℃ of circulation times, respectively at the 1st week, the 3rd week, the 30th week and the charging and discharging specific storage of the 100th week and the curve of current potential.
Fig. 3: two (fluorine sulphonyl) sulfimide lithiums (LiFSDI)
19f NMR spectrum.
Fig. 4: aluminium foil (working electrode) is at two (fluorine sulphonyl) the sulphonyl diimine lithium (H of 1M
2[(FSO
2n)
2sO
2]), the cyclic voltammetry curve of LiFSDI)-EC/EMC (3:7, v/v) electrolytic solution.
Two (fluorine sulphonyl) the sulphonyl diimine lithium (H of Figure 51 M
2[(FSO
2n)
2sO
2]), the specific conductivity of the corresponding electrolytic solution of LiFSDI)-EC/EMC (3:7, v/v) electrolytic solution and several frequently seen lithium salts varies with temperature curve comparison figure.
Embodiment
Enumerate part of compounds preparation involved in the present invention below, so that the present invention is further detailed explanation, but the preparation method of embodiment is not restricted to the preparation of cited compound.
Embodiment 1-10 relates to the preparation of binary fluorine-containing sulfimide alkali metal salt and ternary fluorine-containing sulfimide alkali metal salt.
Embodiment 1: two (chlorine sulphonyl) sulphonyl diimine (H
2[(ClSO
2n)
2sO
2]) preparation
Building-up reactions route is as follows:
NH
2SO
2NH
2+SOCl
2+ClSO
3H→H
2[(ClSO
2N)
2SO
2]+SO
2+HCl
In 500mL there-necked flask, add sulphamide (NH
2sO
2nH
2) (48g, 0.5mol), SOCl
2(167g, 1.4mol), ClSO
3h (116g, 1mol).Magnetic agitation, was heated to 120 ℃ of backflows after 24 hours, underpressure distillation, the cut of 112-114 ℃/1-2mm of collection Hg.Obtain 135g colourless liquid, yield 92%.
Embodiment 2:(chlorine sulphonyl) (perfluoro butyl sulphonyl) sulphonyl diimine (H
2[(ClSO
2n) (C
4f
9sO
2n) SO
2]) preparation
In 250mL flask, add prepared C
4f
9sO
2nHSO
2nH
2(37.8g, 0.1mol), SOCl
2(16.7g, 0.14mol), ClSO
3h (11.6g, 0.1mol).Under stirring, be heated to 120 ℃, the underpressure distillation after 24 hours that refluxes, the cut of 141-143 ℃/1-2mm of collection Hg.Obtain 40g product, yield 84%.
Embodiment 3: the preparation of the fluorine-containing sulfimide of binary and the fluorine-containing sulfimide of ternary
Preparation condition, the experimental result of the fluorine-containing sulfimide of part binary and the fluorine-containing sulfimide of ternary are listed in table 1.
The experimental result of table 1 preparation binary and the fluorine-containing sulfimide of ternary
Embodiment 4: two (fluorine sulphonyl) sulphonyl diimine (H
2[(FSO
2n)
2sO
2]) preparation
Building-up reactions route is as follows:
3H
2[(ClSO
2N)
2SO
2]+2SbF
3→3H
2[(FSO
2N)
2SO
2]+2SbCl
3
Under stirring and nitrogen protection, by the H of 117g (0.4mol)
2[(ClSO
2n)
2sO
2], and the anhydrous antimony trifluoride of 48g (0.27mol) is placed in the there-necked flask of 250mL, stirs lower reaction after 12 hours under room temperature, carries out underpressure distillation, collects the cut of 102-104 ℃/1-2mmHg, obtains H
2[(FSO
2n)
2sO
2] colourless liquid 92g, yield 88%.
Embodiment 5: the fluoridizing of the chloride sulfimide of binary and the chloride sulfimide of ternary
Fluorination conditions, the experimental result of the chloride sulfimide of part binary and the chloride sulfimide of ternary are listed in table 2.
Table 2 binary and the chloride sulfimide of ternary fluoridize result
Embodiment 6: two (fluorine sulphonyl) sulphonyl diimine potassium (K
2[(FSO
2n)
2sO
2]) preparation
Building-up reactions route is as follows:
H
2[(FSO
2N)
2SO
2]+K
2CO
3→K
2[(FSO
2N)
2SO
2]+CO
2+H
2O
In 250mL flask, add the H of 65g (0.25mol)
2[(FSO
2n)
2sO
2], 100mL anhydrous acetonitrile slowly adds the potash solid of 34.5g (0.25mol) in batches under stirring, continue stirring reaction after 2 hours, then add a small amount of salt of wormwood regulation system to be pH6～7.Standing filtration, obtains white solid after filtrate is spin-dried for, and recrystallization in acetone/methylene dichloride, obtains 78g white crystal, yield 93%.
Embodiment 7: the preparation of binary fluorine-containing sulfimide alkali metal salt and ternary fluorine-containing sulfimide alkali metal salt
Preparation condition, the experimental result of part binary fluorine-containing sulfimide alkali metal salt and ternary fluorine-containing sulfimide alkali metal salt are listed in table 3.
The experimental result of table 3 binary and ternary fluorine-containing sulfimide alkali metal salt
Embodiment 8: two (fluorine sulphonyl) sulphonyl diimine lithium (Li
2[(FSO
2n)
2sO
2]) preparation
Building-up reactions route is as follows:
K
2[(FSO
2N)
2SO
2]+2LiBF
4→Li
2[(FSO
2N)
2SO
2]+2KBF
4
In vacuum glove box, by 84.1g (0.25mol) K
2[(FSO
2n)
2sO
2], the methylcarbonate of 200mL joins in the there-necked flask of 500mL successively, after stirring and dissolving, slowly splashes into the LiBF4 (LiBF that is dissolved with 46.8g (0.50mol)
4) methylcarbonate solution, under room temperature, stirring reaction is 12 hours, filtration under diminished pressure is removed undissolved potassium tetrafluoroborate.Filtrate is concentrated into 50mL continuation pressurization and pumps solvent, add methylene dichloride recrystallization, obtain the Li of 66.6g
2[(FSO
2n)
2sO
2] (LiFSDI) white solid, yield 98%.Its
19f NMR spectrum as shown in Figure 3.
Embodiment 9: two (fluorine sulphonyl) sulphonyl diimine sodium (Na
2[(FSO
2n)
2sO
2]) preparation
Building-up reactions route is as follows:
K
2[(FSO
2N)
2SO
2]+2NaBF
4→Na
2[(FSO
2N)
2SO
2]+2KBF
4
In vacuum glove box, by 84.1g (0.25mol) K
2[(FSO
2n)
2sO
2], the methylcarbonate of 200mL joins in the there-necked flask of 500mL successively, after stirring and dissolving, slowly splashes into the sodium tetrafluoroborate (NaBF that is dissolved with 54.9g (0.50mol)
4) methylcarbonate solution, under room temperature, stirring reaction is 12 hours, filtration under diminished pressure is removed undissolved potassium tetrafluoroborate.Filtrate is concentrated into 50mL continuation pressurization and pumps solvent, add methylene dichloride recrystallization, obtain the Na of 73.8g
2[(FSO
2n)
2sO
2] white solid, yield 97%.
Embodiment 10: the preparation of binary sulfimide lithium and sodium salt, ternary sulfimide lithium and sodium salt
Preparation condition, the experimental result of part binary sulfimide lithium and sodium salt, ternary sulfimide lithium and sodium salt are listed in table 4.
The experimental result of table 4 preparation binary and ternary sulfimide lithium and sodium
Embodiment 11-26 relates to the preparation of the ionic liquid of binary or the fluorine-containing sulfimide of ternary
The general preparation method of the ionic liquid that following examples are cited is as follows: by equimolar an alkali metal salt, and the halogenide of sulfonium salt, ammonium salt, microcosmic salt or guanidinesalt is dissolved in respectively in appropriate amount of deionized water and (is generally 20mmol salt and is dissolved in 10mL deionized water), then mixed at room temperature, after stirring reaction 30 minutes, stratification.With separating funnel, separate lower floor's liquid, be dissolved in 20～30mL methylene dichloride, then use deionized water wash 3 times, each deionized water consumption is 5mL, and decompression is removed after dichloromethane solvent, and 90 ℃ of vacuum decompressions are dried 12 hours, obtain colourless or light yellow ionic liquid.
Referring to specific embodiment, the present invention is described, it will be appreciated by those skilled in the art that these examples are only for illustrating object of the present invention, the scope that it does not limit the present invention in any way.Take embodiment 13 as example, and other embodiment intermediate ion liquid are by similar approach preparation.
Embodiment 11: ionic liquid [(CH
3cH
2)
3s]
2[(FSO
2n)
2sO
2]
By [(CH
3cH
2)
3s] I and K
2[(FSO
2n)
2sO
2] reaction preparation.Concrete operations are as follows: by 7.5g (20mmol) [(CH
3cH
2)
3s] I and 3.4g (10mmol) K
2[(FSO
2n)
2sO
2], be dissolved in respectively in 10mL deionized water, after two solution mix, induction stirring reaction 30 minutes, stratification, lower floor is dissolved in 20mL methylene dichloride, deionized water wash 3 times (3 * 5mL), decompression is removed after dichloromethane solvent, and 90 ℃ of vacuum decompressions are dried 12 hours, obtain 9.5 grams of colorless oil, productive rate 92%.
Nuclear magnetic resonance data:
1h NMR (acetone-d
6, TMS, 400MHz): δ=1.55 (t, 3 * 3H), 3.55ppm (q, 3 * 2H);
19f NMR (acetone-d
6, CCl
3f, 376.5MHz): δ=51.5 (s, 2F).Ultimate analysis: theoretical value C
12h
30f
2n
2o
6s
5: C, 29.02; H, 6.09; N, 5.64; Experimental value C, 28.95; H, 6.05; N, 5.60.
Embodiment 12: ionic liquid [(CH
3)
2sCH
2cH
2oCH
3]
2[(FSO
2n)
2sO
2]
By [(CH
3)
2sCH
2cH
2oCH
3] I and K
2[(FSO
2n)
2sO
2] room temperature reaction preparation.
Colourless liquid, productive rate 85%.Nuclear magnetic resonance data:
1h NMR (acetone-d
6, TMS, 400MHz): δ=3.16 (s, 2 * 3H), 3.41 (s, 3H), 3.78 (m, 2H), 3.97ppm (m, 2H);
19f NMR (acetone-d
6, CCl
3f, 376.5MHz): δ=51.6 (s, 2F).Ultimate analysis: theoretical value C
10h
26f
2n
2o
8s
5: C, 23.99; H, 5.23; N, 5.60; Experimental value C, 23.95; H, 5.20; N, 5.55.
Embodiment 13: ionic liquid [(CH
3) (CH
3cH
2)
2nCH
2cH
2cH
3]
2[(FSO
2n)
2sO
2]
By [(CH
3) (CH
3cH
2)
2nCH
2cH
2cH
3] Br and K
2[(FSO
2n)
2sO
2] room temperature reaction preparation.
Colourless liquid, productive rate 95%.Nuclear magnetic resonance data:
1h NMR (acetone-d
6, TMS, 400MHz): δ=1.00 (t, 3H), 1.42 (t, 2 * 3H), 1.88 (m, 2H) .3.13 (s, 3H), 3.38 (m, 2H), 3.51ppm (q, 2 * 2H);
19f NMR (acetone-d
6, CCl
3f, 376.5MHz): δ=51.6 (s, 2F).Ultimate analysis: theoretical value C
16h
40f
2n
4o
6s
3: C, 37.05; H, 7.77; N, 10.80; Experimental value C, 37.00; H, 7.75; N, 10.75.
Embodiment 14: ionic liquid [(CH
3) (CH
3cH
2)
2nCH
2cH
2oCH
3]
2[(FSO
2n)
2sO
2]
By [(CH
3) (CH
3cH
2)
2nCH
2cH
2oCH
3] Br and K
2[(FSO
2n)
2sO
2] room temperature reaction preparation.
Colourless liquid, productive rate 87%.Nuclear magnetic resonance data:
1h NMR (acetone-d
6, TMS, 400MHz): δ=1.41 (t, 2 * 3H), 3.21 (s, 3H), 3.36 (s, 3H), 3.60 (q, 2 * 2H), 3.67 (t, 2H), 3.90ppm (s, 2H);
19f NMR (acetone-d
6, CCl
3f, 376.5MHz): δ=51.6 (s, 2F).Ultimate analysis: theoretical value C
16h
40f
2n
4o
8s
3: C, 34.90; H, 7.32; N, 10.17; Experimental value C, 34.88; H, 7.28; N, 10.15.
Embodiment 15: ionic liquid [(CH
3oCH
2cH
2)
4n]
2[(FSO
2n)
2sO
2]
By [(CH
3oCH
2cH
2)
4n] I and K
2[(FSO
2n)
2sO
2] room temperature reaction preparation.
Colourless liquid, 91%.Nuclear magnetic resonance data: (acetone-d
6, TMS, 400MHz): δ=3.34 (br s, 4 * 3H), 3.93-3.86 (m, 8 * 2H);
19f NMR (acetone-d
6, CCl
3f, 376.5MHz): δ=51.4 (s, 2F).Ultimate analysis: theoretical value C
24h
56f
2n
4o
14s
3: C, 37.98; H, 7.44; N, 7.38; Experimental value C, 37.95; H, 7.42; N, 7.36.
Embodiment 16: ionic liquid [(CH
3)
3nCH
2cH
2cN]
2[(FSO
2n)
2sO
2]
By [(CH
3)
3nCH
2cH
2cN] Br and K
2[(FSO
2n)
2sO
2] room temperature reaction preparation.
Colourless liquid, productive rate 64%.Nuclear magnetic resonance data:
1h NMR (acetone-d
6, TMS, 400MHz): δ=3.33 (t, 2H), 3.42 (s, 3 * 3H), 3.98ppm (t, 2H);
19f NMR (acetone-d
6, CCl
3f, 376.5MHz): δ=51.5 (s, 2F).Ultimate analysis: theoretical value C
12h
26f
2n
6o
6s
3: C, 29.74; H, 5.41; N, 17.34; Experimental value C, 29.70; H, 5.40; N, 17.28.
Embodiment 17: ionic liquid [Py (CH
3) (CH
2cH
2cH
3)]
2[(FSO
2n)
2sO
2]
By [Py (CH
3) (CH
2cH
2cH
3)] Br and K
2[(FSO
2n)
2sO
2] room temperature reaction preparation.
Colourless liquid, productive rate 91%.Nuclear magnetic resonance data:
1h NMR (acetone-d
6, TMS, 400MHz): δ=1.00 (t, 3H), 1.30 (t, 3 * 2H), 1.67-1.81 (m, 2H), 2.92 (s, 3H), 3.09-3.14 (m, 2H), 3.29ppm (q, 2 * 2H);
19f NMR (acetone-d
6, CCl
3f, 376.5MHz): δ=51.5 (s, 2F).Ultimate analysis: theoretical value C
16h
36f
2n
4o
6s
3: C, 37.34; H, 7.05; N, 10.89; Experimental value C, 37.30; H, 7.02N, 10.85.
Embodiment 18: ionic liquid [Py (CH
3) (CH
2cH
2cN)]
2[(FSO
2n)
2sO
2]
By [Py (CH
3) (CH
2cH
2cN)] Br and K
2[(FSO
2n)
2sO
2] room temperature reaction preparation.
Colourless liquid, productive rate 75%.Nuclear magnetic resonance data:
1h NMR (acetone-d
6, TMS, 400MHz): δ=2.39 (br, 2 * 2H), 3.37 (t, 2H), 3.39 (s, 3H), 3.84-3.90 (m, 2 * 2H), 4.03ppm (t, 2H);
19f NMR (acetone-d
6, CCl
3f, 376.5MHz): δ=51.6 (s, 2F).Ultimate analysis: theoretical value C
16h
30f
2n
6o
6s
3: C, 35.81; H, 5.63; N, 15.66; Experimental value C, 35.75; H, 5.60; N, 15.62.
Embodiment 19: ionic liquid [Py (CH
3) (CH
2cH
2oCH
3)]
2[(FSO
2n)
2sO
2]
By [Py (CH
3) (CH
2oCH
3)] Br and K
2[(FSO
2n)
2sO
2] room temperature reaction preparation.
Colourless liquid, productive rate 85%.Nuclear magnetic resonance data:
1h NMR (acetone-d
6, TMS, 400MHz): δ=2.28 (m, 2 * 2H), 3.24 (s, 3H), 3.62 (m, 2H), 3.70 (m, 5H), 4.78ppm (s, 2H).
19F NMR(acetone-d
6,CCl
3F，376.5MHz)：δ＝51.7(s,2F)。Ultimate analysis: theoretical value C
16h
36f
2n
4o
8s
3: C, 35.15; H, 6.64; N, 10.25; Experimental value C, 35.13; H, 6.60; N, 10.22.
Embodiment 20: ionic liquid [Pi (CH
3) (CH
2cH
2cH
2cH
3)]
2[(FSO
2n)
2sO
2]
By [Pi (CH
3) (CH
2cH
2cH
2cH
3)] Br and K
2[(FSO
2n)
2sO
2] room temperature reaction preparation.
Colourless liquid, productive rate 85%.Nuclear magnetic resonance data:
1h NMR (acetone-d
6, TMS, 400MHz): δ=0.98 (t, 3H), 1.45 (m, 2H), 1.74 (m, 2H), 1.87 (br s, 2H), 1.97 (br s, 2 * 2H), 3.23 (s, 3H), 3.52ppm (m, 3 * 2H);
19f NMR (acetone-d
6, CCl
3f, 376.5MHz): δ=51.5 (s, 2F).Ultimate analysis: theoretical value C
20h
44f
2n
4o
6s
3: C, 42.09; H, 7.77; N, 9.82; Experimental value C, 42.04; H, 7.75; N, 9.85.
Embodiment 21: ionic liquid [Im (CH
3) (CH
2cH
3)]
2[(FSO
2n)
2sO
2]
By [Im (CH
3) (CH
2cH
3)] Br and K
2[(FSO
2n)
2sO
2] room temperature reaction preparation.
Colourless liquid, productive rate 95%.Nuclear magnetic resonance data:
1h NMR (acetone-d
6, TMS, 400MHz): δ=1.55 (t, 3H), 4.03 (s, 3H), 4.36 (q, 2H), 7.67 (s, 1H), 7.74 (s, 1H), 8.94ppm (s, 1H);
19f NMR (acetone-d
6, CCl
3f, 376.5MHz): δ=51.5 (s, 2F).Ultimate analysis: theoretical value C
12h
22f
2n
4o
6s
3: C, 31.85; H, 4.90; N, 12.38; Experimental value C, 31.82; H, 4.88; N, 10.35.
Embodiment 22: ionic liquid [G (CH
3)
4(CH
3) (CH
2cH
2oCH
3)]
2[(FSO
2n)
2sO
2]
By [G (CH
3)
4(CH
3) (CH
2cH
2oCH
3)] Br and K
2[(FSO
2n)
2sO
2] room temperature reaction preparation.
Colourless liquid, productive rate 84%.Nuclear magnetic resonance data:
1h NMR (acetone-d
6, TMS, 400MHz): δ=3.13-3.55 (m, 7H), 2.85-2.88 (t, 15H);
19f NMR (acetone-d
6, CCl
3f, 376.5MHz): δ=51.5 (s, 2F).Ultimate analysis: theoretical value C
18h
44f
2n
8o
8s
3: C, 34.06; H, 6.99; N, 17.65; Experimental value C, 34.02; H, 6.95; N, 17.62.
Embodiment 23: ionic liquid [CG (CH
2cH
2) (CH
3)
2(CH
2cH
3) (CH
2cH
2oCH
3)]
2[(FSO
2n)
2sO
2]
By [CG (CH
2cH
2) (CH
3)
2(CH
2cH
3) (CH
2cH
2oCH
3)] Br and K
2[(FSO
2n)
2sO
2] room temperature reaction preparation.
Colourless liquid, productive rate 86%.Nuclear magnetic resonance data:
1h NMR (acetone-d
6, TMS, 400MHz): δ=1.14 (t, 3H), 2.91 (s, 6H), 2.26-3.31 (m, 5H), 3.35 (t, 2H), 3.42 (t, 2H), 3.70 (s, 4H);
19f NMR (acetone-d
6, CCl
3f, 376.5MHz): δ=51.6 (s, 2F).Ultimate analysis: theoretical value C
20h
44f
2n
8o
8s
3: C, 36.46; H, 6.73; N, 17.01; Experimental value C, 36.41; H, 6.70; N, 16.95.
Embodiment 24: ionic liquid [(CH
3cH
2)
3s]
3[(FSO
2n)
2(SO
2)
2n]
By [(CH
3cH
2)
3s] I and K
3[(FSO
2n)
2(SO
2)
2n] room temperature reaction preparation.
Colourless liquid, productive rate 90%.Nuclear magnetic resonance data:
1h NMR (acetone-d
6, TMS, 400MHz): δ=1.56 (t, 3 * 3H), 3.54ppm (q, 3 * 2H);
19f NMR (acetone-d
6, CCl
3f, 376.5MHz): δ=51.3 (s, 2F).Ultimate analysis: theoretical value C
18h
45f
2n
3o
8s
7: C, 31.15; H, 6.54; N, 6.05; Experimental value C, 31.12; H, 6.52; N, 6.00.
Embodiment 25: ionic liquid [(CH
3)
2sCH
2cH
2oCH
3]
3[(FSO
2n)
2(SO
2)
2n]
By [(CH
3)
2sCH
2cH
2oCH
3] I and K
3[(FSO
2n)
2(SO
2)
2n] room temperature reaction preparation.
Colourless liquid, productive rate 84%.Nuclear magnetic resonance data:
1h NMR (acetone-d
6, TMS, 400MHz): δ=3.15 (s, 2 * 3H), 3.42 (s, 3H), 3.78 (m, 2H), 3.97ppm (m, 2H);
19f NMR (acetone-d
6, CCl
3f, 376.5MHz): δ=51.4 (s, F).Ultimate analysis: theoretical value C
15h
39f
2n
3o
11s
7: C, 25.74; H, 5.62; N, 6.00; Experimental value C, 25.72; H, 5.58; N, 5.96.
Embodiment 26: the ionic liquid of the ionic liquid of the fluorine-containing sulfimide of binary and the fluorine-containing sulfimide of ternary, referred to as: the ionic liquid of binary or the fluorine-containing sulfimide of ternary.
The experimental result of prepared part binary and ternary sulfimide ionic liquid is listed in table 5.
The experimental result of table 5 preparation binary and the fluorine-containing sulfimide ionic liquid of ternary
Embodiment 27-30 is the application example of low viscosity ionic liquid in ultracapacitor and serondary lithium battery
The application of embodiment 27 in ultracapacitor
Adopt 2032 (diameter 2.0cm, height 0.32cm) button electric capacity, activated carbon is positive and negative electrode material (diameter 1.0cm, thickness 0.6mm), polypropylene diaphragm, and the ionic liquid in table 5 and common organic electrolyte are assembled electrical condenser in vacuum glove box.Ultracapacitor impulse electricity test condition is: voltage V=0 to 2.8V, electric current 5mA.At 25 ℃, the electrical capacity of mensuration is as shown in table 6.
Table 6 ionic liquid and the electrolytical carbon back ultracapacitor of common organic electrolyte electrical capacity (25 ℃)
The application of embodiment 28 ionic liquid electrolytes in serondary lithium battery
(1) anodal making
With LiCoO
2positive electrode material is example: by anodal LiCoO
2powder, carbon black (granularity is 1000nm), poly(vinylidene fluoride) (PVDF) and N, N-dimethyl pyrrolidone (NMP) is mixed and made into the slurry of homogeneous, and slurry is evenly coated on aluminium foil (15 μ m) collector, is then dried, rolling, obtains LiCoO
2positive electrode material.At 120 ℃, dry 12 hours, in dried pole piece, LiCoO
2account for 94% of total painting application, binding agent accounts for 4%, and carbon black accounts for 2%.Then gained pole piece being cut into diameter is that 8mm disk is as positive pole.Other positive electrode material LiMn
2o
4, LiFePO
4, Li (CoNiMn)
1/3o
2preparation in the same way.
(2) making of negative pole
Take artificial plumbago negative pole material as example: by synthetic graphite, poly(vinylidene fluoride) (PVDF) and N, N-dimethyl pyrrolidone (NMP) is mixed and made into the slurry of homogeneous, slurry is evenly coated on Copper Foil (15 μ m) collector, then be dried, rolling, obtains carbon negative pole material.At 120 ℃, dry 12 hours, in dried pole piece, graphite accounts for 96.4% of total painting application, and binding agent accounts for 3.6%, and then gained pole piece being cut into diameter is that 9mm disk is as positive pole.Other negative material Li
4ti
5o
12preparation in the same way.
(3) preparation of electrolytic solution
To after conducting salt binary fluorine sulfimide lithium and the vacuum-drying of ternary fluorine sulfimide lithium, proceed to glove box, weigh a certain amount of lithium salts, organic solvent EC/EMC (the 3:7 that slowly adds ionic liquid or prepare in advance, v/v), be mixed with the electrolytic solution that concentration is respectively 0.7M and 1M, seal stand-by.
(4) composition of CR2032 fastening lithium ionic cell and performance evaluation
Polyethylene porous membrane is placed between above-mentioned steps (1) and (2) prepared positive/negative plate, drips the electrolytic solution that above-mentioned steps (3) prepares, pole piece is flooded, be assembled into the button cell of CR2032.Upper at micro-processor controlled auto charge and discharge instrument (Land, CT2001A), carry out cycle performance of battery test.Test condition: rate of charge is 0.5C, discharge-rate is 0.2C, graphite/LiCoO
2electrode system: 3.0～4.2V; Metallic lithium/LiCoO
2electrode system: 3.0～4.2V; Graphite/LiFePO
4electrode system: 2.75～3.9V; Metallic lithium/LiFePO
4electrode system: 2.75～3.9V; Li
4ti
5o
12/ LiCoO
2electrode system: 1.0～2.6V; Li
4ti
5o
12/ LiFePO
4electrode system: 1.0～2.6V, probe temperature: 25 ℃.The test data of the present embodiment is referring to table 7.As shown in Figure 1, charging and discharging curve as shown in Figure 2 for the recycle ratio capacity of battery and coulombic efficiency.
The performance of the serondary lithium battery of table 7 based on lithium salts/ionic liquid electrolyte
Embodiment 29 binary and the fluorine-containing sulfimide lithium of ternary carbonate solvent are combined into the application of electrolytic solution in serondary lithium battery
Change the ion liquid solvent in embodiment 28 into carbonic ether, other implementation conditions are consistent with embodiment 28 with evaluation method.The test data of the present embodiment is in Table 8.
The performance of table 8 based on the electrolytical secondary lithium of lithium salts/carbonic ether (ion) battery
The fluorine-containing sulfimide lithium of embodiment 30 binary and ternary and ionic liquid or carbonate solvent are combined into the mensuration of electrolytic solution electrochemical properties
(1) corrosion measurement of aluminium foil in electrolytic solution: on Autolab electrochemical workstation, adopt 3 electrode systems, aluminium foil (S=0.30cm
2) be working electrode, metallic lithium is to electrode and reference electrode, at open circuit voltage (OCV), measures the vs.Li to 5.0V
+between/Li, measure volt-ampere curve, sweep velocity is 0.1mV s
-1.It is example that difluoro sulphonyl diimine lithium-EC/EMC (3:7, v/v) electrolytic solution is take in the present invention, and the volt-ampere curve of front 5 circulations as shown in Figure 4.
(2) mensuration of specific conductivity: use the platinum black conductance electrode of DJS-10, Julabo type temperature controller, Autolab electrochemical workstation is measured electrolytic solution prepared by embodiment 28 steps (3) specific conductivity between-20 to 60 ℃, and result is as shown in Figure 5.
Claims (4)
1. a preparation method for the fluorine-containing sulfimide of binary and an alkali metal salt thereof, comprises the following steps:
Step 1: by sulphamide (NH
2sO
2nH
2), thionyl chloride is that 1:1～1:5 mixes and is placed in reaction flask by stoichiometry mol ratio, the chlorsulfonic acid (ClSO that to add with sulphamide stoichiometry mol ratio be 1:1～1:3
3h) or perfluoro alkyl sulfonic acid (R
fsO
3h), at 60～150 ℃, stir, the reaction times is 4～24 hours, and after completion of the reaction, underpressure distillation obtains two (chlorine sulphonyl) sulphonyl diimine (H accordingly
2[(ClSO
2n)
2sO
2]) or two (perfluoroalkyl sulphonyl) sulphonyl diimine (H
2[(R
fsO
2n)
2sO
2]);
Step 2: two (chlorine sulphonyl) sulphonyl diimine (H that obtain to above-mentioned step 1
2[(ClSO
2n)
2sO
2]) in, by stoichiometry, adding mol ratio is the antimony trifluoride (SbF of 1:1～1:3
3), at 0～60 ℃, to stir, the reaction times is 4～24 hours, after completion of the reaction, underpressure distillation obtains two (fluorine sulphonyl) sulphonyl diimine (H
2[(FSO
2n)
2sO
2]);
Step 3: to prepared two (perfluoroalkyl sulphonyl) sulphonyl diimine (H of step 1
2[(R
fsO
2n)
2sO
2]) or prepared two (fluorine sulphonyl) sulphonyl diimine (H of step 2
2[(FSO
2n)
2sO
2]) compound adds polar aprotic solvent, gradation is by 1.2～5 times of Anhydrous potassium carbonates to group with imine moiety mole number of stoichiometry mol ratio or Carbon Dioxide caesium or Carbon Dioxide rubidium solid, join in above-mentioned organic solution, continue reaction 5～20 hours, filtration under diminished pressure, elimination insolubles obtains an alkali metal salt [(R of the fluorine-containing sulfimide of binary
fsO
2n)
2sO
2] M, M=K, Rb or Cs.
2. a preparation method for the fluorine-containing sulfimide lithium salts of binary or sodium salt, comprises the following steps:
The fluorine-containing sulfimide potassium of binary is dissolved in polar aprotic solvent, with the MClO of the mole numbers such as stoichiometry
4or MBF
4, M=Li or Na, carry out metathesis exchange reaction, obtains lithium salts or the sodium salt [(R of the colourless fluorine-containing sulfimide of binary
fsO
2n)
2sO
2] M, M=Li or Na.
3. preparation method according to claim 2, is characterized in that, described polar aprotic solvent is methylcarbonate, diethyl carbonate, acetonitrile, acetone or Nitromethane 99Min..
4. preparation method according to claim 2, is characterized in that, the fluorine-containing sulfimide potassium of described binary is to make according to method described in claim 1.
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| CN110563614A (en) * | 2019-09-10 | 2019-12-13 | 河北工业大学 | Guanidine salt ionic liquid and preparation method and application thereof |
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