CN104151975B - A kind of aqueous reflective insulation stone-like coating and preparation method thereof - Google Patents
A kind of aqueous reflective insulation stone-like coating and preparation method thereof Download PDFInfo
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- CN104151975B CN104151975B CN201410390537.3A CN201410390537A CN104151975B CN 104151975 B CN104151975 B CN 104151975B CN 201410390537 A CN201410390537 A CN 201410390537A CN 104151975 B CN104151975 B CN 104151975B
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Abstract
The invention discloses a kind of aqueous reflective insulation stone-like coating and preparation method thereof, it includes each component of following percentage by weight: paint 30%～50% based on component A, B component is protecting colloid solution 12%～25%, component C is varnish 30%～60%, use above component and ratio thereof, then reflective insulation technology is applied to wherein in base paint, the coating of a kind of aqueous stone can be prepared, have reflective insulation function concurrently, there is stone though the present invention solves current aqueous colorful paint but not there is the defect of heat preservation energy-saving effect, decorative effect of the present invention is strong, environmental protection and energy saving simultaneously, easy construction, easily operation, there is broader practice prospect.
Description
Technical field
The present invention relates to building coating field, particularly to a kind of aqueous reflective insulation stone-like coating and preparation method thereof.
Background technology
Water-in-water multicolor coating is in recent years the most popular in building coating industry new product type, and product is with physical chemistry
Colloid technology and process for treating surface be theoretical basis；The multiple gluey hydrate colour granule that will vary in size, vary in color,
In the continuous phase aqueous emulsion paint that even stable suspension dispersion is, through a construction molding, and the artificial granite of finished product
The effect of decorative patterns of stone material can reach the degree mixed the spurious with the genuine.
As disclosed in China Patent Publication No. CN103849280A, " a kind of overstable high durable water-in-water type artificial granite is many
The preparation method of color coating material "；Disclosed " a kind of environment-friendlywater-in-water water-in-water colorful coating of China Patent Publication No. CN103319969A
And preparation method thereof ".
The technical research of water-water multi-color is day by day ripe with in application, but at energy-conservation aspect or such as common latex
Equally, there is no reflective insulation function, still could not meet the requirement of national energy-saving environmental protection.
Also it is related to the research of reflective heat-insulation paint both at home and abroad, utilizes the reflective insulation principle of hollow glass micropearl to building
Thing carries out heat preservation energy-saving.As disclosed in Chinese patent notification number CN102311690B, " a kind of aqueous external elasticity reflective insulation is coated with
Material and production method thereof ", but its color is single, mostly based on light color or white, it is impossible to meet client's External Wall ornamental
Requirement.
Summary of the invention
An object of the present invention is just to provide a kind of aqueous reflective insulation stone-like coating, and this aqueous reflective insulation is imitated stone and is coated with
Material is mainly applied to building wall, is the coating of a aesthetic effect i.e. with high imitative degree granite stone, basis simultaneously
Paint gives the effect with the external light and heat of reflection, so that the color particle of paint reaches reflective insulation function, meets country
Environment-friendly insulating power conservation requirement, accords with the demands of the market.
The two of the object of the invention are just to provide the preparation method of above-mentioned aqueous reflective insulation stone-like coating.The purpose of the present invention
It is achieved in that
A kind of aqueous reflective insulation stone-like coating, is prepared from the following ingredients in percentage by and is prepared from:
Based on paint component A: 30%～50%；
B component as protecting colloid solution: 12%～25%；
Component C as varnish: 30%～60%；
Based on wherein said, the component A of paint is prepared from by the raw material of following mass percent:
Described protecting colloid solution is prepared from by the raw material of following mass percent:
Water 85～94%；
Protecting colloid 6～15%；
The B component of described protecting colloid solution is prepared from by the raw material of following mass percent:
Water 85～94%；
Protecting colloid 6～15%；
The described component C as varnish is prepared from by the raw material of following mass percent:
The cellulose ether of described component A is methyl cellulose ether, cellulose ether, hydroxymethyl cellulose ether, ethoxy
Cellulose ether, hydroxypropylcelluloether ether, TYLOSE 30000 or methylhydroxypropylcellulose ether.
The dispersant of described component A is polyacrylic acid dipersant.
The infrared reflecting paint of described component A is the ALTIRIS 550 or ALTIRIS 800 that Hensel steps, and they are to have
The titanium white of the highest properties of infrared reflection, it is possible to need to recall shades of colour according to stone is durable in use.
The thermal insulating filling of described component A is the hollow glass micro-ball of particle diameter 20-100 micron, due to its glass material, has relatively
Good infrared barrier effect, glass also has stronger reflection for sunlight, and its hollow-core construction is used in coating and has in addition
Preferably reduce the effect of heat conductivity.
The film forming matter of described component A is in pure acrylic latex, Styrene And Chloroalkyl Acrylates copolymer emulsion and silicone acrylic emulsion
Kind, there is certain flexibility.
The anion wetting agent of described component A is HG-6 or the Shanghai grid trade Co., Ltd of Shanghai Hao Guan trading company
399。
The defoamer of described component A and component C is the compounding of siloxane-based defoamer or siloxane-based defoamer.
The thickening agent of described component A and component C is polyurethane-type thickening agent or alkali swollen thickener.
The pH adjusting agent of described component A is any one in 2-amino-2 methyl isophthalic acid propanol, sodium hydrate aqueous solution, ammonia
Kind.
The protecting colloid of described component A and B component is zeopan.
The coalescents of described component C be 2,2,4-trimethyl-1.3 pentanediol mono isobutyrates, dipropylene glycol methyl ether, two
Propandiol butyl ether or propylene glycol.
The film forming matter of described component C is in pure acrylic latex, Styrene And Chloroalkyl Acrylates copolymer emulsion and silicone acrylic emulsion
Kind, resistance to water to be got well.
The antibacterial of described component C is selected from isothiazoline alcohol/ketone mixtures or imdazole derivatives.
The preparation method of a kind of aqueous reflective insulation stone-like coating, comprises the steps:
(1) prepare the protecting colloid solution in component A and the B component as protecting colloid solution: by protecting colloid by than
Example is added to the water, uniform with dispersion machine low rate mixing, and stirring 30min becomes clear gum liquid to make the protecting colloid in component A
Solution and the B component as protecting colloid solution；
(2) preparing component A: be proportionally added in water by cellulose ether, with dispersion machine moderate-speed mixer until dissolving, then adding
Entering dispersant, pH value regulator, defoamer, stirring, until mix homogeneously, adds infrared reflecting paint, thermal insulating filling the most according to this
High speed dispersion, until being uniformly dispersed, then it is molten to add the protecting colloid in the component A of film forming matter, anion wetting agent, step (1)
Liquid, thickening agent, and be uniformly mixed；
(3) component C is prepared: by film forming matter, coalescents, defoamer, thickening agent, antibacterial are proportionally added into water successively
In, moderate-speed mixer, mix homogeneously；
(4) pelletize: component A aqueous color paste toning step (2) prepared, according to stone furnishing multiple color
Colored paint, adds the B component as protecting colloid solution prepared by step (1) using described colored paint, forms AB mixture；And by cutting
Cutting speed degree and time control color tablets size, and shear rate is 100～1000r/min, and shear time is adjusted between 1～20min
Whole；
(5) aqueous reflective insulation stone-like coating is prepared: AB colour particles mixture step (4) prepared adds step
(3), in the component C prepared, stir, both a kind of aqueous reflective insulation stone-like coating.
The present invention compared with prior art has the advantage that
Colorful dispersion used by the present invention has decorative surface, improves the defect that conventional latex paint color is dull, shape
Become marmorean decorative effect, have very strong ornamental.The colour particles of the present invention has reflective insulation function, plays body of wall
Fine effect of heat insulation, belongs to green energy conservation product.The present invention have good environmental-protecting performance, good storage stability and
Wall protection function, decoration functions, construction is simple.
Detailed description of the invention:
Embodiment 1:
A kind of aqueous reflective insulation stone-like coating, containing the component of following weight percents: based on the component A of paint
32%, as the B component 16% of protecting colloid solution, as the component C 52% of varnish.
Based on paint component A be prepared from by the raw material of following mass percent:
Protecting colloid solution is prepared from by the raw material of following mass percent:
Water 93%；
Zeopan 7%.
B component as protecting colloid solution is prepared from by the raw material of following mass percent:
Water 93%；
Zeopan 7%.
Component C varnish includes, by mass percentage:
The preparation method of embodiment 1, comprises the steps:
(1) prepare the protecting colloid solution in component A and the B component as protecting colloid solution: by protecting colloid by than
Example is added to the water, uniform with dispersion machine low rate mixing, and stirring 30min becomes clear gum liquid to make the protecting colloid in component A
Solution and the B component as protecting colloid solution；
(2) preparing component A: be added to the water by cellulose ether, with dispersion machine moderate-speed mixer until dissolving, being subsequently adding dispersion
Agent, pH value regulator, defoamer, stirring, until mix homogeneously, adds infrared reflecting paint ALTIRIS 550, sky the most according to this
Heart glass microsphere, high speed dispersion, until being uniformly dispersed, then it is molten to add styrene-acrylic emulsion, anion wetting agent HG-6, protecting colloid
Liquid, thickening agent, and be uniformly mixed；
(3) preparing component C: by silicone acrylic emulsion, coalescents, defoamer, thickening agent, antibacterial are sequentially added in water, in
Speed stirring, mix homogeneously；
(4) pelletize: component A aqueous color paste toning step (2) prepared, according to stone furnishing multiple color
Colored paint, adds B component prepared by step (1) by colored paint, forms AB mixture according to component ratio；And by shear rate and time
Between control color tablets size, shear rate is 200r/min, and shear time is 3min.
(5) aqueous reflective insulation stone-like coating is prepared: AB colour particles mixture step (4) prepared adds according to ratio
Enter in component C prepared by step (3), stir, both a kind of aqueous reflective insulation stone-like coating.
Embodiment 2:
A kind of aqueous reflective insulation stone-like coating, containing the component of following weight percents: based on the component A of paint
38%, as the B component 20% of protecting colloid solution, as the component C 42% of varnish.
Based on paint component A be prepared from by the raw material of following mass percent:
Protecting colloid solution is prepared from by the raw material of following mass percent:
Water 92%；
Zeopan 8%.
B component as protecting colloid solution is prepared from by the raw material of following mass percent:
Water 92%；
Zeopan 8%.
Component C as varnish is prepared from by the raw material of following mass percent:
The preparation method of embodiment 2, comprises the steps:
(1) prepare the protecting colloid solution in component A and the B component as protecting colloid solution: by protecting colloid by than
Example is added to the water, uniform with dispersion machine low rate mixing, and stirring 30min becomes clear gum liquid to make the protecting colloid in component A
Solution and the B component as protecting colloid solution；
(2) preparing component A: be added to the water by cellulose ether, with dispersion machine moderate-speed mixer until dissolving, being subsequently adding dispersion
Agent, pH value regulator, defoamer, stirring, until mix homogeneously, adds infrared reflecting paint ALTIRIS 550, sky the most according to this
Heart glass microsphere, high speed dispersion, until being uniformly dispersed, then it is molten to add styrene-acrylic emulsion, anion wetting agent HG-6, protecting colloid
Liquid, thickening agent, and be uniformly mixed；
(3) preparing component C: by silicone acrylic emulsion, coalescents, defoamer, thickening agent, antibacterial are sequentially added in water, in
Speed stirring, mix homogeneously；
(4) pelletize: component A aqueous color paste toning step (2) prepared, according to stone furnishing multiple color
Colored paint, adds B component prepared by step (1) by colored paint, forms AB mixture according to component ratio；And by shear rate and time
Between control color tablets size, shear rate is 200r/min, and shear time is 3min.
(5) aqueous reflective insulation stone-like coating is prepared: AB colour particles mixture step (4) prepared adds according to ratio
Enter in component C prepared by step (3), stir, both a kind of aqueous reflective insulation stone-like coating.
Above-described embodiment 1 and embodiment 2 are by " HGT 4343-2012 aqueous colorful building coating " and " JG/T235-2008
Architectural reflective heat-insulation paint " standard carry out the detection of various index, partial results is as shown in the table:
The ultimate principle of the present invention, principal character and advantages of the present invention have more than been shown and described.The technology of the industry
Personnel, it should be appreciated that the present invention is not restricted to the described embodiments, simply illustrating this described in above-described embodiment and description
The principle of invention, the present invention also has various changes and modifications without departing from the spirit and scope of the present invention, and these become
Change and improvement both falls within scope of the claimed invention.Claimed scope by appending claims and
Equivalent defines.
Claims (8)
1. an aqueous reflective insulation stone-like coating, is prepared from the following ingredients in percentage by and is prepared from:
Based on paint component A: 30%～50%；
B component as protecting colloid solution: 12%～25%；
Component C as varnish: 30%～60%；
Above component A, B component, component C sum are 100%；
Based on wherein said, the component A of paint is prepared from by the raw material of following mass percent:
Described protecting colloid solution is prepared from by the raw material of following mass percent:
Water 85～94%；
Protecting colloid 6～15%；
The B component of described protecting colloid solution is prepared from by the raw material of following mass percent:
Water 85～94%；
Protecting colloid 6～15%；
The described component C as varnish is prepared from by the raw material of following mass percent:
The dispersant of described component A is polyacrylic acid dipersant；
The infrared reflecting paint of described component A is the ALTIRIS 550 or ALTIRIS 800 that Hensel steps；
The thermal insulating filling of described component A is the hollow glass micro-ball of particle diameter 20-100 micron；
The protecting colloid of described component A and B component is zeopan；
The preparation method of described aqueous reflective insulation stone-like coating, it is characterised in that comprise the steps:
(1) the protecting colloid solution in component A and the B component as protecting colloid solution are prepared: added in proportion by protecting colloid
Entering in water, uniform with dispersion machine low rate mixing, stirring 30min becomes clear gum liquid to make the protecting colloid solution in component A
With the B component as protecting colloid solution；
(2) preparing component A: be proportionally added in water by cellulose ether, with dispersion machine moderate-speed mixer until dissolving, being subsequently adding point
Powder, pH value regulator, defoamer, stirring, until mix homogeneously, adds infrared reflecting paint, thermal insulating filling at a high speed the most according to this
Dispersion, until being uniformly dispersed, then adds the protecting colloid solution in the component A of film forming matter, anion wetting agent, step (1), increasing
Thick dose, and be uniformly mixed；
(3) preparing component C: by film forming matter, coalescents, defoamer, thickening agent, antibacterial are proportionally added in water successively, in
Speed stirring, mix homogeneously；
(4) pelletize: component A aqueous color paste toning step (2) prepared, according to the color of stone furnishing multiple color
Paint, adds the B component as protecting colloid solution prepared by step (1) using described colored paint, forms AB mixture；And by shearing
Speed and time control color tablets size, and shear rate is 100～1000r/min, and shear time adjusts between 1～20min；
(5) aqueous reflective insulation stone-like coating is prepared: AB colour particles mixture step (4) prepared adds step (3) system
In standby component C, stir, obtain a kind of aqueous reflective insulation stone-like coating.
Aqueous reflective insulation stone-like coating the most according to claim 1, it is characterised in that the cellulose ether of described component A
It is methyl cellulose ether, cellulose ether, hydroxymethyl cellulose ether, hydroxyethyl ether cellulose, hydroxypropylcelluloether ether, carboxylic first
Base cellulose ether or methylhydroxypropylcellulose ether.
Aqueous reflective insulation stone-like coating the most according to claim 1, it is characterised in that described component A and the one-tenth of component C
Film thing is the one in pure acrylic latex, Styrene And Chloroalkyl Acrylates copolymer emulsion and silicone acrylic emulsion.
Aqueous reflective insulation stone-like coating the most according to claim 1, it is characterised in that disappearing of described component A and component C
Infusion is the compounding of siloxane-based defoamer or siloxane-based defoamer.
Aqueous reflective insulation stone-like coating the most according to claim 1, it is characterised in that described component A and the increasing of component C
Thick dose is polyurethane-type thickening agent or alkali swollen thickener.
Aqueous reflective insulation stone-like coating the most according to claim 1, it is characterised in that the pH adjusting agent of described component A
It is any one in 2-amino-2 methyl isophthalic acid propanol, sodium hydrate aqueous solution, ammonia.
Aqueous reflective insulation stone-like coating the most according to claim 1, it is characterised in that the coalescents of described component C
It is 2,2,4-trimethyl-1,3 pentanediol mono isobutyrates, dipropylene glycol methyl ether, dipropylene or propylene glycol.
Aqueous reflective insulation stone-like coating the most according to claim 1, it is characterised in that the antibacterial of described component C is
Selected from isothiazoline alcohol/ketone mixtures or imdazole derivatives.
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Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0625318B2 (en) * | 1988-05-17 | 1994-04-06 | 大日本塗料株式会社 | Multicolor pattern forming paint and multicolor pattern forming method |
| CN101845260B (en) * | 2010-03-10 | 2012-09-05 | 杭州德尔福涂料有限公司 | Full-aqueous multicolour paint and preparation method thereof |
| CN102643587A (en) * | 2012-03-21 | 2012-08-22 | 深圳市嘉达节能环保科技有限公司 | Water-in water type colorful thermal insulation coating and preparation method thereof |
| CN103319969A (en) * | 2013-06-20 | 2013-09-25 | 江门市华石涂料有限公司 | Environment-friendly water-in-water colorful coating and preparation method thereof |
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Effective date of registration: 20220107 Address after: 201799 6th floor, building 1, 1318 Xiangda East Road, Qingpu District, Shanghai Patentee after: Crocodile Nica (Shanghai) new materials Co.,Ltd. Address before: Floor 17, No. 468, Changshou Road, Putuo District, Shanghai 200060 Patentee before: ALLIGATOR COATINGS (SHANGHAI) CO.,LTD. Patentee before: Shanghai Shen Zhen Enterprise Development Co., Ltd. |