CN104140761A - Sprayed rapid hardening rubber asphalt water-proof material used in severe cold areas - Google Patents
Sprayed rapid hardening rubber asphalt water-proof material used in severe cold areas Download PDFInfo
- Publication number
- CN104140761A CN104140761A CN201410382425.3A CN201410382425A CN104140761A CN 104140761 A CN104140761 A CN 104140761A CN 201410382425 A CN201410382425 A CN 201410382425A CN 104140761 A CN104140761 A CN 104140761A
- Authority
- CN
- China
- Prior art keywords
- rubber
- asphalt
- rapid hardening
- rubber asphalt
- severe cold
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a sprayed rapid hardening rubber asphalt water-proof material used in severe cold areas. The sprayed rapid hardening rubber asphalt water-proof material is prepared by modified montmorillonite-rubber asphalt suspension and a coagulating agent through the following formula, wherein the modified montmorillonite-rubber asphalt suspension comprises by mass, 55-67 parts of modified montmorillonite-rubber asphalt emulsified particles, 0.1-1.3 parts of stabilizing agent, 0-2.2 parts of pH modifier, 0.1-1.3 parts of interface modifier, 1.0-3.8 parts of first emulgator and 30-40 parts of water, the coagulating agent comprises, by mass, 10-20 parts of calcium chloride, 0.05-0.4 part of sodium chloride, 0.05-0.5 part of compounded ferro-aluminium polymer and 80-90 parts of water. The modified montmorillonite-rubber asphalt suspension and the coagulating agent are sprayed to the surface of a building according to the ratio of 3.5/1-15/1, and then a layer of antifreezing agent is sprayed on the surface of the sprayed object. The sprayed rapid hardening rubber asphalt water-proof material is used on the surface layers of buildings in severe cold areas.
Description
Technical field
The present invention relates to a kind of water-proof material, particularly a kind of spraying rapid hardening water-proof material.
Background technology
Spraying rapid hardening rubber-asphalt waterproof material main component is comprised of two or more high-performance modified emulsified rubber asphalts and the short solidifying catalyzer of chemistry, has the two-component system of rapid initial set consolidation behavior.It is the cold mechanical high pressure painting job execution technology of a kind of employing, can make nano components in material and small molecule micelle rapidly with concrete cement basic unit formation sucker effect, stop up basal plane pore firm film forming, there is the glued membrane system product of excellent waterproof, anticorrosion, barrier propterty.
Spraying rapid hardening rubber-asphalt waterproof material is except having the advantage of conventional waterproof coating, also there is following characteristic: 1) spraying rapid hardening rubber asphalt product is the domestic water-proof material that adopts cold-working industry spraying application novel process, construct simple, quick and easy, the duration is short, effect improves, and unit rush-harvesting and rush-planting (3 people's group) 8h continuous spray (thickness 2mm) area is at 1000m
2; 2) this product is composited by ipn technology and nanotechnology and asphalt modification by multiple compounded rubber, utilizes short solidifying Catalysis Principles to make the rapid initial set of product, and film forming speed is fast, and initial set set time is only 3～5s; 3) can accomplish one-pass film-forming in coating film thickness 1～4mm, save time, laborsaving, efficient, and keep the homogeneity that glued membrane is good; 4) this product is to on-the-spot strong adaptability, and basic level requirement is wide in range, and execution conditions are not harsh, is applicable to various special-shaped basal planes, only need substrate surface clean, without open fire; Construction Qian Jinxudui basic unit carries out simple smooth processing, does not generally need another screed-coat; 5) after formed product, there is higher elasticity and puncture resistance, tension set 1200%～1800%, and there is excellent self-healing function; 6) have good heat-resistant stability and cold resistance, applied environment temperature is-35～80 ℃; 7) between glued membrane and multiple basic unit (except resene, nickeliferous, containing chronium metal, containing lipid) and water-proof material, there is good cohesiveness, anti-aging and erosion resistance is strong; 8) this product fire protection flame retarding, from fire, from putting out, combustionproperty meets safe construction requirement; 9) product is water base, and VOC content is low, nontoxic, tasteless, non-stimulated, production, construction process Non-carbonized, the flames of anger, pollution-free, environmental protection, convenient transportation; 10) material cost performance is high, compare with same kind of products at abroad, and performance index basically identical (indivedual indexs are slightly low), but price is only 1/2～1/3 of same kind of products at abroad.Due to above-mentioned plurality of advantages, spraying rapid hardening rubber asphalt series waterproof materials is widely used, and can be used for that building and underground project waterproof, Industrial buildings and hardware are antiseptic and rustproof, concrete and brick structures protects, percolating water improvement and reparation, large pool, gas tank, disposal site, sewage work's waterproof protective etc.
However, the application of spraying rapid hardening rubber asphalt series waterproof materials still will be subject to the restriction of its working conditions: 1) spraying rapid hardening rubber asphalt product is bicomponent system, need to adopt custom-designed spraying transmit machine device operating system construction, dry under field conditions (factors) after film forming rapidly; 2) the standard consumption of this product is: when waterproof coating thickness is 1mm, material usage is 1.5～2.0kg/m
2; 3) product initial set film forming in 5s after spraying, seasoning molding time can be affected by the conditions such as envrionment temperature and humidity.During standard thickness 1mm, 23 ℃, relative humidity 50% time, glued membrane is complete drying moulding in 24h; 4) material is at the moulding initial stage, and due to the effect of 2 kinds of components, it is normal phenomenon that certain moisture can be separated out in glued membrane surface; In drying and moulding process, glued membrane will fade to black (drying regime) from brown (dampness); 5) this product can not be when lower than 5 ℃ spraying operation, before there is no moulding, can not endure cold, can not have the basal plane construction of frost (dewfall), the in the situation that of can not be rainy in rainy day or 6 h, use; 6) substrate surface that should guarantee to construct is clean, without open fire, dust, grease or other loosening thing and pollutent (as benzene class) etc.; 7) engineering water-proof material intensity being had higher requirements or the keypoint part of waterproof should be established enhancement Layer.
In above-mentioned condition, especially, during for spraying rapid hardening rubber-asphalt waterproof material spraying, envrionment temperature is not less than the requirement of 5 ℃, and for the longer area of northern China severe cold time remaining, this requirement is by the application of restriction spraying rapid hardening rubber-asphalt waterproof material.
Based on the above, a kind of exploitation of the spraying rapid hardening rubber-asphalt waterproof material for severe cold area design is by necessary property.
Summary of the invention
The object of the present invention is to provide spraying rapid hardening rubber-asphalt waterproof material for a kind of severe cold area, described spraying rapid hardening rubber-asphalt waterproof material makes by following formula, in mass fraction: modified montmorillonoid-rubber asphalt suspension, comprise, modified montmorillonoid-rubber asphalt emulsified particle, 55-67 part; Stablizer, 0.1-1.3 part; PH adjusting agent, 0-2.2 part; Interface modifier, 0.1-1.3 part; The first emulsifying agent, 1.0-3.8 part, water 30-40 part; Peptizer, comprises, calcium chloride, 10-20 part; Sodium-chlor, 0.05-0.4 part; Compound ferro-aluminum polymkeric substance, 0.05-0.5 part; Water, 80-90 part.Wherein, described modified montmorillonoid-rubber asphalt suspension and described peptizer are sprayed into building surface with 3.5/1-15/1 proportioning, spray one deck frostproofer thereafter on spray surface again.
Preferably, spraying rapid hardening rubber-asphalt waterproof material for described a kind of severe cold area, wherein, described modified montmorillonoid-rubber asphalt emulsified particle makes by reversed emulsion polymerization, described modified montmorillonoid-rubber asphalt emulsified particle makes by following formula, according to the mass fraction, modified montmorillonoid 10-30 part; Rubber asphalt, is SBS modifying asphalt and/or styrene butadiene rubber modified asphalt, 65-85 part; The second emulsifying agent, 1.0-4.0 part; Pigment, 1.0-10 part.Wherein rubber asphalt is external phase, it is the theme composition in structure, modified montmorillonoid is by two-layer Si-O tetrahedron and the octahedra layered silicate crystal forming of one deck Al-O, by letex polymerization, the micro-reticulated structure of rubber asphalt is present between described modified montmorillonoid lamella, this compact layer structure is made to emulsion, the polynite of breakdown of emulsion post-modification and building surface adhesivity.Described modified montmorillonoid is to make its inner hydrophilic base become the consistency of hydrophobic group improvement and described rubber modified asphalt by modification, and the severe cold area climatope condition of the selection of bituminous material of the present invention and use adapts.
Preferably, spraying rapid hardening rubber-asphalt waterproof material for described a kind of severe cold area, wherein, described the first emulsifying agent is nonionic emulsifier, described nonionic emulsifier is selected from one or more in polyoxyethylene-type, polyvalent alcohol type and polyether-type; Described the second emulsifying agent is anionic emulsifier, and described anionic emulsifier is one or more in metal carboxylate, sulfuric ester salt, Sulfonates or phosphates surfactant material.When described water-proof material is sprayed into building surface, described modified montmorillonoid-rubber asphalt emulsified particle breakdown of emulsion, described rubber asphalt forms netted at building surface breakdown of emulsion, and described modified montmorillonoid is arranged in reticulated structure, contact with described building surface, form certain adhesive power.
Preferably, spraying rapid hardening rubber-asphalt waterproof material for described a kind of severe cold area, wherein, described stablizer is preferably inorganic salts, as one or more in soluble chloride salt, vitriol, nitrate, phosphoric acid salt and silicate.Described stablizer can, by adjusting ion-conductance potential difference, increase the repulsive force between particle, the stability of enhancing modified polynite-rubber asphalt emulsified particle.
Preferably, spraying rapid hardening rubber-asphalt waterproof material for described a kind of severe cold area, wherein, described pH value conditioning agent can be acid or alkali.Wherein, acid can be mineral acid and/or organic acid, for example one or more in hydrochloric acid, sulfuric acid, Glacial acetic acid, citric acid, lipid acid and Whitfield's ointment.Alkali can be strong alkaline substance and/or weakly alkaline material, for example one or more in sodium hydroxide, potassium hydroxide, sodium carbonate and sodium bicarbonate.It can, by regulating the potential of hydrogen of modified montmorillonoid-rubber asphalt emulsified particle solution to improve emulsifying effectiveness and ionic strength, improve stability.
Preferably, spraying rapid hardening rubber-asphalt waterproof material for described a kind of severe cold area, wherein, described interface modifier can be the mixture of Soxylat A 25-7, alkylamine and polyocarboxy acid type polymeric surface active agent.Wherein, according to the difference of working conditions, in mass fraction, in interface modifier, the ratio of three kinds of components is, Soxylat A 25-7 accounts for 0-1 part, and alkylamine accounts for 0-0.5 part, and polyocarboxy acid type polymeric surface active agent accounts for 1.0-2.5 part.Its role is to improve the interface bonding state of organic constituent and inorganic component, reduce the temperature sensitivity of rubber asphalt, improve the consistency between rubber asphalt and modified montmorillonoid, thereby improve the frost resistance that makes modified montmorillonoid-rubber asphalt emulsified particle.
Preferably, spraying rapid hardening rubber-asphalt waterproof material for described a kind of severe cold area, wherein, described pigment is that red iron oxide, light chrome yellow, cobalt blue, the cobalt titanium on market, bought are one of green, red iron oxide wherein takes on a red color Powdered; Light chrome yellow is the Powdered of yellow, and its main component is the lead chrome pigment of lead chromate and lead sulfate Solid solution, and wherein lead chromate is about 65%-71%, and lead sulfate is about 23%-30%; Cobalt blue is the nontoxic mineral dye of a kind of blue high-performance environment-friendly, is blue powder shape, and main component is Leyden blue; The nontoxic mineral dye of the green a kind of environmental protection of cobalt titanium, is green flour powder.
The present invention also provides a kind of severe cold area preparation method with spraying rapid hardening rubber-asphalt waterproof material, makes as follows 1) prepare modified montmorillonoid-rubber asphalt emulsion; 2) the first emulsifying agent, stablizer and interface modifier are added to the water stirring and dissolving, the temperature of water is 40 ℃-70 ℃, by pH adjusting agent, regulates the pH value of dissolving gained emulsion to 2-12; 3) by step 1) modified montmorillonoid-rubber asphalt emulsion and the step 2 that obtain) solution mixing and emulsifying, make required water-proof material, described water-proof material is cooled to temperature and uses after 35 ℃.
Preferably, the preparation method of spraying rapid hardening rubber-asphalt waterproof material for described described a kind of severe cold area, wherein, the preparation method of described modified montmorillonoid-rubber asphalt emulsion, by reversed emulsion polymerization, make, comprise the following steps: 1) rubber asphalt heating melting maintenance are stirred; 2) modified montmorillonoid and the second emulsifying agent are added successively, make described modified montmorillonoid-rubber asphalt emulsion.
The beneficial effect of spraying rapid hardening rubber-asphalt waterproof material for a kind of severe cold area provided by the invention: 1) introduce modified montmorillonoid, described modified montmorillonoid is lamella inorganic materials, described laminated structure has certain storage capacity, so adding of modified montmorillonoid will increase the water leakage of material, simultaneously, the inorganic materials adhesive power of modified montmorillonoid and building surface is also better, contributes to formation and the maintenance of this water-proof material; 2) rubber asphalt is SBS modifying asphalt and/or styrene butadiene rubber modified asphalt, and choosing of described rubber asphalt is applicable to cold district, is conducive to the maintenance of described water-proof material; 3) after spraying application, spray again the shallow freezing that one deck frostproofer causes due to water suction when guaranteeing that described water-proof material is sprayed into building surface moulding.
Embodiment
Below the present invention is described in further detail, to make those skilled in the art can implement according to this with reference to specification sheets word.
The invention provides spraying rapid hardening rubber-asphalt waterproof material for a kind of severe cold area, described spraying rapid hardening rubber-asphalt waterproof material makes by following formula, in mass fraction: modified montmorillonoid-rubber asphalt suspension, comprises, modified montmorillonoid-rubber asphalt emulsified particle, 55-67 part; Stablizer, 0.1-1.3 part; PH adjusting agent, 0-2.2 part; Interface modifier, 0.1-1.3 part; The first emulsifying agent, 1.0-3.8 part, water 30-40 part; Peptizer, comprises, calcium chloride, 10-20 part; Sodium-chlor, 0.05-0.4 part; Compound ferro-aluminum polymkeric substance, 0.05-0.5 part; Water, 80-90 part.Wherein, described modified montmorillonoid-rubber asphalt suspension and described peptizer are sprayed into building surface with 3.5/1-15/1 proportioning, spray one deck frostproofer thereafter on spray surface again.Wherein, described modified montmorillonoid-rubber asphalt emulsified particle makes by reversed emulsion polymerization, and described modified montmorillonoid-rubber asphalt emulsified particle makes by following formula, according to the mass fraction, and modified montmorillonoid 10-30 part; Rubber asphalt, is SBS modifying asphalt and/or styrene butadiene rubber modified asphalt, 65-85 part; The second emulsifying agent, 1.0-4.0 part; Pigment, 1.0-10 part.Wherein rubber asphalt is external phase, it is the theme composition in structure, modified montmorillonoid is by two-layer Si mono-0 tetrahedrons and the octahedra layered silicate crystal forming of one deck Al-0, by letex polymerization, the micro-reticulated structure of rubber asphalt is present between described modified montmorillonoid lamella, this compact layer structure is made to emulsion, the polynite of breakdown of emulsion post-modification and building surface adhesivity.Described modified montmorillonoid is to make its inner hydrophilic base become the consistency of hydrophobic group improvement and described rubber modified asphalt by modification, and the severe cold area climatope condition of the selection of bituminous material of the present invention and use adapts.Described the first emulsifying agent is nonionic emulsifier, and described nonionic emulsifier is selected from one or more in polyoxyethylene-type, polyvalent alcohol type and polyether-type; Described the second emulsifying agent is anionic emulsifier, and described anionic emulsifier is one or more in metal carboxylate, sulfuric ester salt, Sulfonates or phosphates surfactant material.When described water-proof material is sprayed into building surface, described modified montmorillonoid-rubber asphalt emulsified particle breakdown of emulsion, described rubber asphalt forms netted at building surface breakdown of emulsion, and described modified montmorillonoid is arranged in reticulated structure, contact with described building surface, form certain adhesive power.Described stablizer is preferably inorganic salts, as one or more in soluble chloride salt, vitriol, nitrate, phosphoric acid salt and silicate.Described stablizer can, by adjusting ion-conductance potential difference, increase the repulsive force between particle, the stability of enhancing modified polynite-rubber asphalt emulsified particle.Described pH value conditioning agent can be acid or alkali.Acid can be mineral acid and/or organic acid, for example one or more in hydrochloric acid, sulfuric acid, Glacial acetic acid, citric acid, lipid acid and Whitfield's ointment.Alkali can be strong alkaline substance and/or weakly alkaline material, for example one or more in sodium hydroxide, potassium hydroxide, sodium carbonate and sodium bicarbonate.It can, by regulating the potential of hydrogen of modified montmorillonoid-rubber asphalt emulsified particle solution to improve emulsifying effectiveness and ionic strength, improve stability.Described interface modifier can be the mixture of Soxylat A 25-7, alkylamine and polyocarboxy acid type polymeric surface active agent.Wherein, according to the difference of working conditions, in mass fraction, in interface modifier, the ratio of three kinds of components is, Soxylat A 25-7 accounts for 0-1 part, and alkylamine accounts for 0-0.5 part, and polyocarboxy acid type polymeric surface active agent accounts for 1.0-2.5 part.Its role is to improve the interface bonding state of organic constituent and inorganic component, reduce the temperature sensitivity of rubber asphalt, improve the consistency between rubber asphalt and modified montmorillonoid, thereby improve the frost resistance that makes modified montmorillonoid-rubber asphalt emulsified particle.Described pigment is that red iron oxide, light chrome yellow, cobalt blue, the cobalt titanium on market, bought are one of green, and red iron oxide wherein takes on a red color Powdered; Light chrome yellow is the Powdered of yellow, and its main component is the lead chrome pigment of lead chromate and lead sulfate Solid solution, and wherein lead chromate is about 65%-71%, and lead sulfate is about 23%-30%; Cobalt blue is the nontoxic mineral dye of a kind of blue high-performance environment-friendly, is blue powder shape, and main component is Leyden blue; The nontoxic mineral dye of the green a kind of environmental protection of cobalt titanium, is green flour powder.
The present invention also provides a kind of severe cold area preparation method with spraying rapid hardening rubber-asphalt waterproof material, makes as follows 1) prepare modified montmorillonoid-rubber asphalt emulsion; 2) the first emulsifying agent, stablizer and interface modifier are added to the water stirring and dissolving, the temperature of water is 40 ℃-70 ℃, by pH adjusting agent, regulates the pH value of dissolving gained emulsion to 2-12; 3) by step 1) modified montmorillonoid-rubber asphalt emulsion and the step 2 that obtain) solution mixing and emulsifying, make required water-proof material, described water-proof material is cooled to temperature and uses after 35 ℃.The preparation method of described modified montmorillonoid-rubber asphalt emulsion, makes by reversed emulsion polymerization, comprises the following steps: 1) rubber asphalt heating melting maintenance are stirred; 2) modified montmorillonoid and the second emulsifying agent are added successively, make described modified montmorillonoid-rubber asphalt emulsion.
A kind of severe cold area provided by the invention sprays the shallow freezing that one deck frostproofer causes due to water suction when guaranteeing that described water-proof material is sprayed into building surface moulding after by spraying application again with spraying rapid hardening rubber-asphalt waterproof material.
Although embodiment of the present invention are open as above, but it is not restricted to listed utilization in specification sheets and embodiment, it can be applied to various applicable the field of the invention completely, for those skilled in the art, can easily realize other modification, therefore do not deviating under the universal that claim and equivalency range limit, the present invention is not limited to specific details.
Claims (10)
1. a spraying rapid hardening rubber-asphalt waterproof material for severe cold area, is characterized in that, described spraying rapid hardening rubber-asphalt waterproof material makes by following formula, in mass fraction:
Modified montmorillonoid-rubber asphalt suspension, comprises, modified montmorillonoid-rubber asphalt emulsified particle, 55-67 part; Stablizer, 0.1-1.3 part; PH adjusting agent, 0-2.2 part; Interface modifier, 0.1-1.3 part; The first emulsifying agent, 1.0-3.8 part, water 30-40 part;
Peptizer, comprises, calcium chloride, 10-20 part; Sodium-chlor, 0.05-0.4 part; Compound ferro-aluminum polymkeric substance, 0.05-0.5 part; Water, 80-90 part.
Wherein, described modified montmorillonoid-rubber asphalt suspension and described peptizer are sprayed into building surface with 3.5/1-15/1 proportioning, spray one deck frostproofer thereafter on spray surface again.
2. a kind of severe cold area as claimed in claim 1 is with spraying rapid hardening rubber-asphalt waterproof material, it is characterized in that, described modified montmorillonoid-rubber asphalt emulsified particle makes by reversed emulsion polymerization, described modified montmorillonoid-rubber asphalt emulsified particle makes by following formula, according to the mass fraction
Modified montmorillonoid 10-30 part
Rubber asphalt, is SBS modifying asphalt and/or styrene butadiene rubber modified asphalt, 65-85 part;
The second emulsifying agent, 1.0-4.0 part;
Pigment, 1.0-10 part.
3. a kind of severe cold area as claimed in claim 1 or 2 is with spraying rapid hardening rubber-asphalt waterproof material, it is characterized in that, described the first emulsifying agent is nonionic emulsifier, and described nonionic emulsifier is selected from one or more in polyoxyethylene-type, polyvalent alcohol type and polyether-type; Described the second emulsifying agent is anionic emulsifier, and described anionic emulsifier is one or more in metal carboxylate, sulfuric ester salt, Sulfonates or phosphates surfactant material.
4. spraying rapid hardening rubber-asphalt waterproof material for a kind of severe cold area as claimed in claim 1, is characterized in that, described stablizer is preferably inorganic salts, as one or more in soluble chloride salt, vitriol, nitrate, phosphoric acid salt and silicate.Described stablizer can, by adjusting ion-conductance potential difference, increase the repulsive force between particle, the stability of enhancing modified polynite-rubber asphalt.
5. spraying rapid hardening rubber-asphalt waterproof material for a kind of severe cold area as claimed in claim 1, is characterized in that, described thermo-stabilizer material therefor is selected from 2,2,4-trimethylammonium-1,2-dihyaroquinoline polymkeric substance, N-(1,3-dimethylbutyl)-4-aminodiphenylamine, N, N-two (1,4-dimethyl amyl group)-Ursol D or 2,2,4-trimethylammonium-1, in 2-dihyaroquinoline one or more.
6. a kind of severe cold area as claimed in claim 1 is with spraying rapid hardening rubber-asphalt waterproof material, it is characterized in that, described pH value conditioning agent can be acid or alkali, and described acid is selected from one or more in hydrochloric acid, sulfuric acid, Glacial acetic acid, citric acid, lipid acid and Whitfield's ointment; Described alkali is selected from one or more in sodium hydroxide, potassium hydroxide, sodium carbonate and sodium bicarbonate.
7. spraying rapid hardening rubber-asphalt waterproof material for a kind of severe cold area as claimed in claim 1, is characterized in that, described pigment is that red iron oxide, light chrome yellow, cobalt blue, the cobalt titanium on market, bought are one of green.
8. spraying rapid hardening rubber-asphalt waterproof material for a kind of severe cold area as claimed in claim 1, is characterized in that, described interface modifier is the mixture of Soxylat A 25-7, alkylamine and polyocarboxy acid type polymeric surface active agent.Wherein, according to the difference of working conditions, in mass fraction, in interface modifier, the ratio of three kinds of components is, Soxylat A 25-7 accounts for 0-1 part, and alkylamine accounts for 0-0.5 part, and polyocarboxy acid type polymeric surface active agent accounts for 1.0-2.5 part.
9. a preparation method for spraying rapid hardening rubber-asphalt waterproof material for severe cold area, is characterized in that, makes as follows 1) prepare modified montmorillonoid-rubber asphalt emulsion; 2) the first emulsifying agent, stablizer and interface modifier are added to the water stirring and dissolving, the temperature of water is 40 ℃-70 ℃, by pH adjusting agent, regulates the pH value of dissolving gained emulsion to 2-12; 3) by step 1) modified montmorillonoid-rubber asphalt emulsion and the step 2 that obtain) solution mixing and emulsifying, make required water-proof material, described water-proof material is cooled to temperature and uses after 35 ℃.
10. a kind of severe cold area as claimed in claim 9 use sprays the preparation method of rapid hardening rubber-asphalt waterproof material, it is characterized in that, the preparation method of described modified montmorillonoid-rubber asphalt emulsion, by reversed emulsion polymerization, make, comprise the following steps: 1) rubber asphalt heating melting maintenance are stirred; 2) modified montmorillonoid and the second emulsifying agent are added successively, make described modified montmorillonoid-rubber asphalt emulsion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410382425.3A CN104140761A (en) | 2014-08-06 | 2014-08-06 | Sprayed rapid hardening rubber asphalt water-proof material used in severe cold areas |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410382425.3A CN104140761A (en) | 2014-08-06 | 2014-08-06 | Sprayed rapid hardening rubber asphalt water-proof material used in severe cold areas |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104140761A true CN104140761A (en) | 2014-11-12 |
Family
ID=51850105
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410382425.3A Pending CN104140761A (en) | 2014-08-06 | 2014-08-06 | Sprayed rapid hardening rubber asphalt water-proof material used in severe cold areas |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104140761A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104726024A (en) * | 2015-03-12 | 2015-06-24 | 北京金盾建材有限公司 | Spray quick-setting modified asphalt waterproof paint and preparation method thereof |
| CN105949480A (en) * | 2016-05-23 | 2016-09-21 | 中海沥青股份有限公司 | Emulsified asphalt special for spraying rubber asphalt paint and preparation method of emulsified asphalt |
| CN115746708A (en) * | 2022-12-10 | 2023-03-07 | 河北泽润工程橡塑有限公司 | Bio-based low-temperature-resistant spraying quick-setting rubber asphalt waterproof material and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5716070A (en) * | 1980-07-04 | 1982-01-27 | Nippon Oil & Fats Co Ltd | Composition for water-proofing coat |
| CN101235252A (en) * | 2008-01-15 | 2008-08-06 | 大连美宸特环保节能产品有限公司 | Multifunctional liquid rubber spray-coating material, preparation method, using method and special-purpose device |
| CN102964929A (en) * | 2012-11-30 | 2013-03-13 | 山东北方创信防水技术有限公司 | Spraying rapid-hardening rubber asphalt water proofing material for drinking water pond |
| CN103788662A (en) * | 2012-10-29 | 2014-05-14 | 中国石油化工股份有限公司 | Emulsified asphalt, a preparation method thereof, applications thereof, a water-proof coating material and a water-proof coating |
| CN103897595A (en) * | 2014-04-09 | 2014-07-02 | 苏州中材非金属矿工业设计研究院有限公司 | Spraying quickly-hardening rubber asphalt waterproof paint |
-
2014
- 2014-08-06 CN CN201410382425.3A patent/CN104140761A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5716070A (en) * | 1980-07-04 | 1982-01-27 | Nippon Oil & Fats Co Ltd | Composition for water-proofing coat |
| CN101235252A (en) * | 2008-01-15 | 2008-08-06 | 大连美宸特环保节能产品有限公司 | Multifunctional liquid rubber spray-coating material, preparation method, using method and special-purpose device |
| CN103788662A (en) * | 2012-10-29 | 2014-05-14 | 中国石油化工股份有限公司 | Emulsified asphalt, a preparation method thereof, applications thereof, a water-proof coating material and a water-proof coating |
| CN102964929A (en) * | 2012-11-30 | 2013-03-13 | 山东北方创信防水技术有限公司 | Spraying rapid-hardening rubber asphalt water proofing material for drinking water pond |
| CN103897595A (en) * | 2014-04-09 | 2014-07-02 | 苏州中材非金属矿工业设计研究院有限公司 | Spraying quickly-hardening rubber asphalt waterproof paint |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104726024A (en) * | 2015-03-12 | 2015-06-24 | 北京金盾建材有限公司 | Spray quick-setting modified asphalt waterproof paint and preparation method thereof |
| CN105949480A (en) * | 2016-05-23 | 2016-09-21 | 中海沥青股份有限公司 | Emulsified asphalt special for spraying rubber asphalt paint and preparation method of emulsified asphalt |
| CN105949480B (en) * | 2016-05-23 | 2018-04-03 | 中海沥青股份有限公司 | One kind spraying rubber-asphalt coating special-purpose emulsifying pitch and preparation method thereof |
| CN115746708A (en) * | 2022-12-10 | 2023-03-07 | 河北泽润工程橡塑有限公司 | Bio-based low-temperature-resistant spraying quick-setting rubber asphalt waterproof material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102031002B (en) | Non-cured asphalt mastic | |
| CN103627258A (en) | Spraying quick-setting rubber asphalt waterproof coating material | |
| CN103897595A (en) | Spraying quickly-hardening rubber asphalt waterproof paint | |
| CN106398536A (en) | Anionic water-based non-curing rubber asphalt waterproof coating and preparation method thereof | |
| CN107010890B (en) | Environment-friendly polymer cement wall waterproof slurry and preparation method thereof | |
| CN101397433B (en) | Composite water-soluble multicolor paint | |
| CN102965016A (en) | High-temperature resistant spray fast-setting rubber asphalt waterproof coating | |
| CN102329566A (en) | High-permeability liquid rubber spray coating | |
| CN102838939B (en) | Modified water-base nano binder | |
| CN105542494A (en) | Colored emulsified asphalt | |
| CN101328389A (en) | Nanometer grade environment-friendly type color aqueous waterproof coating material | |
| CN102086349A (en) | Non-curing waterproof glue with double character | |
| CN104140761A (en) | Sprayed rapid hardening rubber asphalt water-proof material used in severe cold areas | |
| CN102965014A (en) | Spraying rapid-hardening rubber asphalt water-proofing material for pitched roof | |
| CN107502190A (en) | A kind of hydrophobic type Emulsificated asphalt water-proof painting material and preparation method thereof | |
| CN102965018A (en) | Nano spraying quick-setting rubber asphalt waterproof coating for metro tunnels | |
| CN108329891A (en) | A kind of waterproof roll adhesive and preparation method thereof | |
| CN111809407A (en) | Novel modified asphalt waterproof coiled material and preparation method thereof | |
| CN104478342A (en) | Wet base surface treating agent | |
| CN108165109A (en) | A kind of environmental protection wall surface strengthening agent and preparation method thereof | |
| CN101701138B (en) | Cohesive glue for flexible decorative tile and manufacturing method thereof | |
| CN102965017B (en) | Salt tolerant alkaline spraying rapid hardening rubber-asphalt waterproof material | |
| CN112794937B (en) | High-molecular polymer emulsion and preparation method thereof, functional coating, film layer and waterproof roll | |
| CN108359285B (en) | High-performance green waterproof adhesive cement and preparation method thereof | |
| CN106189862B (en) | A kind of polymer modified asphalt waterproof composite material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20141112 |