CN104109333A - Fluoride whisker ABS (acrylonitrile-butadiene-styrene) plastic material - Google Patents
Fluoride whisker ABS (acrylonitrile-butadiene-styrene) plastic material Download PDFInfo
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- CN104109333A CN104109333A CN201410344234.8A CN201410344234A CN104109333A CN 104109333 A CN104109333 A CN 104109333A CN 201410344234 A CN201410344234 A CN 201410344234A CN 104109333 A CN104109333 A CN 104109333A
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Abstract
The invention discloses a fluoride whisker ABS (acrylonitrile-butadiene-styrene) plastic material which is prepared from the following raw materials in parts by weight: 92-100 parts of ABS resin, 2-3 parts of citronellol, 1-2 parts of potassium fluoaluminate, 1-2 parts of potassium hexatitanate whisker, 1-2 parts of fluoridized graphite, 1-2 parts of casein, 0.1-0.2 part of butylated hydroxyanisole, 1-2 parts of 2-bromo-4-methylphenol, 0.2-0.4 part of butyl tin mercaptide, 2-3 parts of dimethyl succinate, 5-7 parts of dicapryl phthalate, 0.2-0.3 part of benzyltriethylammonium chloride, 1-2 parts of N-hydroxymethyl acrylamide, 10-14 parts of meerschaum powder and 2-4 parts of modifying assistant. The plastic material has the advantages of favorable compatibility among the raw materials, favorable binding effect, high flame retardancy, high stretching resistance, high bending resistance, high abrasion resistance, favorable surface strength, no peculiar smell, favorable environment friendliness, high antimicrobial and anticorrosive properties, wide application range, excellent comprehensive properties and long service life.
Description
Technical field
The present invention relates generally to Material Field, relates in particular to a kind of whisker ABS plastic material of fluoridizing.
Background technology
The micro-Huang of ABS resin outward appearance is opaque, relative density 1.04.It has good dimensional stability, outstanding shock-resistance, fluoridizes whisker ABS plastic material, dielectricity, wear resistance, and surface luster property is good, easily application and the advantage such as painted.Vinyl cyanide makes ABS have good chemical stability and surface hardness, and divinyl makes ABS have the toughness of rubber bodies and fluoridize whisker ABS plastic material performance, and vinylbenzene makes ABS have good processing fluidity, tint permanence and electrodepositable; BS is one of current most widely used engineering plastics, because it has, stronger fluoridize that whisker ABS plastic material intensity, proportion are low, good stability of the dimension, acid-proof alkaline are strong, the easy advantage such as processing, extensive in sector applications such as machinery, household electrical appliance, daily apparatus, especially in televisor, refrigerator, washing machine shell field, obtained development fast.
Summary of the invention
The object of the invention is just to provide a kind of whisker ABS plastic material of fluoridizing.
The present invention is achieved by the following technical solutions:
Fluoridize a whisker ABS plastic material, it is characterized in that what it was comprised of the raw material of following weight parts:
ABS resin 92-100, geraniol 2-3, potassium fluoroaluminate 1-2, crystal whisker of hexa potassium titanate 1-2, fluorographite 1-2, casein food grade 1-2, butylated hydroxy anisole 0.1-0.2,2-bromo-4-methylphenol 1-2, butanethiol tin 0.2-0.4, Succinic acid dimethylester 2-3, di-sec-octyl phthalate 5-7, benzyltriethylammoinium chloride 0.2-0.3, N hydroxymethyl acrylamide 1-2, sepiolite powder 10-14, modified additive 2-4;
Described modified additive is comprised of the raw material of following weight parts:
Rosin 10-20, atlapulgite 20-30, bromohexadecane yl pyridines 1-2, ammonium meta-vanadate 1-2, pyrrolidone hydroxy acid sodium 1-2, Succinic acid dimethylester 2-3, SODIUM PHOSPHATE, MONOBASIC 1-2, potassium zirconium carbonate 0.2-0.4, antioxidant 1010 0.1-0.2, deionized water 6-10;
By rosin heating fusing, add Succinic acid dimethylester, be uniformly mixed, obtain gel;
Bromohexadecane yl pyridines, pyrrolidone hydroxy acid sodium are mixed to join in deionized water, stir, obtain dispersion liquid;
Atlapulgite is mixed with above-mentioned gel, add potassium zirconium carbonate, at 75-80 ℃, be uniformly mixed 3-5 minute, reduction temperature is 40-50 ℃, add ammonium meta-vanadate, be stirred to normal temperature, add above-mentioned dispersion liquid, 200-300 rev/min is stirred 10-20 minute, dry abrasive dust, mix with each raw material of residue, stir, obtain described modified additive.
A preparation method who fluoridizes whisker ABS plastic material, comprises the following steps:
Above-mentioned each raw material is mixed, sends into and in super mixer, be dry mixed 3-5 minute, then be placed in twin screw extruder through melt extruding, cooling, pelletizing, packing, described in obtaining, fluoridize whisker ABS plastic material.
Advantage of the present invention is:
The consistency of each stock yard of plastic material of the present invention is good, and bond effect is good, and flame retardant resistance is strong, stretch-proof, counter-bending, and resistance to abrasion is high, and surface strength is good, and without undesired off taste, the feature of environmental protection is good, and antibacterial preservative property are strong, and use range is wide, and over-all properties is superior, long service life.
Embodiment
Embodiment 1
Fluoridize a whisker ABS plastic material, it by following weight parts (kilogram) raw material form:
ABS resin 100, geraniol 3, potassium fluoroaluminate 1, crystal whisker of hexa potassium titanate 1, fluorographite 2, casein food grade 1, butylated hydroxy anisole 0.2,2-bromo-4-methylphenol 1, butanethiol tin 0.4, Succinic acid dimethylester 3, di-sec-octyl phthalate 5, benzyltriethylammoinium chloride 0.3, N hydroxymethyl acrylamide 1, sepiolite powder 14, modified additive 2;
Described modified additive is comprised of the raw material of following weight parts:
Rosin 20, atlapulgite 30, bromohexadecane yl pyridines 2, ammonium meta-vanadate 1, pyrrolidone hydroxy acid sodium 1, Succinic acid dimethylester 3, SODIUM PHOSPHATE, MONOBASIC 1, potassium zirconium carbonate 0.4, antioxidant 1010 0.2, deionized water 10;
By rosin heating fusing, add Succinic acid dimethylester, be uniformly mixed, obtain gel;
Bromohexadecane yl pyridines, pyrrolidone hydroxy acid sodium are mixed to join in deionized water, stir, obtain dispersion liquid;
Atlapulgite is mixed with above-mentioned gel, add potassium zirconium carbonate, be uniformly mixed 5 minutes at 80 ℃, reducing temperature is 50 ℃, add ammonium meta-vanadate, be stirred to normal temperature, add above-mentioned dispersion liquid, 300 revs/min are stirred 20 minutes, dry abrasive dust, mix with each raw material of residue, stir, obtain described modified additive.
A preparation method who fluoridizes whisker ABS plastic material, comprises the following steps:
Above-mentioned each raw material is mixed, sends in super mixer and be dry mixed 3 minutes, then be placed in twin screw extruder through melt extruding, cooling, pelletizing, packing, described in obtaining, fluoridize whisker ABS plastic material.
Performance test:
Tensile strength MPa:48;
Flame retardant rating: V0;
Flexural strength MPa:51.
Claims (2)
1. fluoridize a whisker ABS plastic material, it is characterized in that what it was comprised of the raw material of following weight parts:
ABS resin 92-100, fluorographite 1-2, geraniol 2-3, potassium fluoroaluminate 1-2, crystal whisker of hexa potassium titanate 1-2, casein food grade 1-2, butylated hydroxy anisole 0.1-0.2,2-bromo-4-methylphenol 1-2, butanethiol tin 0.2-0.4, Succinic acid dimethylester 2-3, di-sec-octyl phthalate 5-7, benzyltriethylammoinium chloride 0.2-0.3, N hydroxymethyl acrylamide 1-2, sepiolite powder 10-14, modified additive 2-4;
Described modified additive is comprised of the raw material of following weight parts:
Rosin 10-20, atlapulgite 20-30, bromohexadecane yl pyridines 1-2, ammonium meta-vanadate 1-2, pyrrolidone hydroxy acid sodium 1-2, Succinic acid dimethylester 2-3, SODIUM PHOSPHATE, MONOBASIC 1-2, potassium zirconium carbonate 0.2-0.4, antioxidant 1010 0.1-0.2, deionized water 6-10;
By rosin heating fusing, add Succinic acid dimethylester, be uniformly mixed, obtain gel;
Bromohexadecane yl pyridines, pyrrolidone hydroxy acid sodium are mixed to join in deionized water, stir, obtain dispersion liquid;
Atlapulgite is mixed with above-mentioned gel, add potassium zirconium carbonate, at 75-80 ℃, be uniformly mixed 3-5 minute, reduction temperature is 40-50 ℃, add ammonium meta-vanadate, be stirred to normal temperature, add above-mentioned dispersion liquid, 200-300 rev/min is stirred 10-20 minute, dry abrasive dust, mix with each raw material of residue, stir, obtain described modified additive.
2. a preparation method who fluoridizes whisker ABS plastic material as claimed in claim 1, is characterized in that comprising the following steps:
Above-mentioned each raw material is mixed, sends into and in super mixer, be dry mixed 3-5 minute, then be placed in twin screw extruder through melt extruding, cooling, pelletizing, packing, described in obtaining, fluoridize whisker ABS plastic material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410344234.8A CN104109333A (en) | 2014-07-18 | 2014-07-18 | Fluoride whisker ABS (acrylonitrile-butadiene-styrene) plastic material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410344234.8A CN104109333A (en) | 2014-07-18 | 2014-07-18 | Fluoride whisker ABS (acrylonitrile-butadiene-styrene) plastic material |
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| Publication Number | Publication Date |
|---|---|
| CN104109333A true CN104109333A (en) | 2014-10-22 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410344234.8A Pending CN104109333A (en) | 2014-07-18 | 2014-07-18 | Fluoride whisker ABS (acrylonitrile-butadiene-styrene) plastic material |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104845020A (en) * | 2015-04-27 | 2015-08-19 | 安徽海纳川塑业科技有限公司 | ABS/shell powder composite material and preparation method thereof |
| CN104845018A (en) * | 2015-04-27 | 2015-08-19 | 安徽海纳川塑业科技有限公司 | High-strength wear-resistant ABS composite material and preparation method thereof |
| CN105401144A (en) * | 2015-11-04 | 2016-03-16 | 合肥海源机械有限公司 | Composite acidized aluminum alloy cured film forming solution and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102702666A (en) * | 2012-05-15 | 2012-10-03 | 昆山天卓贸易有限公司 | Potassium titanate whisker and acrylonitrile butadiene styrene (ABS) modified high-impact composite material and preparation method thereof |
| CN103201397A (en) * | 2010-11-08 | 2013-07-10 | 大冶美有限公司 | Cu-based oil-containing sintered bearing |
-
2014
- 2014-07-18 CN CN201410344234.8A patent/CN104109333A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103201397A (en) * | 2010-11-08 | 2013-07-10 | 大冶美有限公司 | Cu-based oil-containing sintered bearing |
| CN102702666A (en) * | 2012-05-15 | 2012-10-03 | 昆山天卓贸易有限公司 | Potassium titanate whisker and acrylonitrile butadiene styrene (ABS) modified high-impact composite material and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104845020A (en) * | 2015-04-27 | 2015-08-19 | 安徽海纳川塑业科技有限公司 | ABS/shell powder composite material and preparation method thereof |
| CN104845018A (en) * | 2015-04-27 | 2015-08-19 | 安徽海纳川塑业科技有限公司 | High-strength wear-resistant ABS composite material and preparation method thereof |
| CN105401144A (en) * | 2015-11-04 | 2016-03-16 | 合肥海源机械有限公司 | Composite acidized aluminum alloy cured film forming solution and preparation method thereof |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20141022 |
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| RJ01 | Rejection of invention patent application after publication |