CN104109274A - Manufacturing technology of HDPE skeleton material for skeleton-type ribbon optical cable - Google Patents

Manufacturing technology of HDPE skeleton material for skeleton-type ribbon optical cable Download PDF

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Publication number
CN104109274A
CN104109274A CN201310135571.1A CN201310135571A CN104109274A CN 104109274 A CN104109274 A CN 104109274A CN 201310135571 A CN201310135571 A CN 201310135571A CN 104109274 A CN104109274 A CN 104109274A
Authority
CN
China
Prior art keywords
hdpe
skeleton
manufacturing technology
weight
white oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310135571.1A
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Chinese (zh)
Inventor
李兆顺
王君
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yangzhou Jinsen Optoelectronics Co Ltd
Original Assignee
Yangzhou Jinsen Optoelectronics Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yangzhou Jinsen Optoelectronics Co Ltd filed Critical Yangzhou Jinsen Optoelectronics Co Ltd
Priority to CN201310135571.1A priority Critical patent/CN104109274A/en
Publication of CN104109274A publication Critical patent/CN104109274A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00Making granules
    • B29B9/02Making granules by dividing preformed material
    • B29B9/06Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/92Measuring, controlling or regulating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/9258Velocity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/92704Temperature
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/24Crystallisation aids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/062HDPE

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

A manufacturing technology of an HDPE skeleton material for a skeleton-type ribbon optical cable. The invention provides the manufacturing technology of the HDPE skeleton material for the skeleton-type ribbon optical cable, wherein the manufacturing technology is suitable for a requirement of rotating extrusion of an extrusion die head and includes following steps: 1) adding 0.3%-0.5% by weight of 4# white oil to 90-94% by weight of HDPE and 4-8% by weight of EVA performing a stirring process for 6-10 min; 2) adding 0.1%-0.5% by weight of a polypropylene nucleating agent NA-21 after the stirring operation in the step 1) is finished, performing a stirring process in a mixing machine for 8-12 min; and 3) feeding the material mixed in the step 2) into a 1:25 co-directional exhaust-type double-screw extruder and carrying out a mixing process with temperature in each zone being 190-200 DEG C and a rotational speed being controlled within 45-60 r/min and performing an extruding granulation process. According to the invention, white oil is added to HDPE (high-density polyethylene) and EVA (ethylene-vinyl acetate copolymer). The white oil can enhance flexibility and smoothness of a surface of a loose tube is enhanced, thereby being beneficial to cabling. The polypropylene nucleating agent can increase the speed of a crystallization process. The requirement of rotating extrusion of the extrusion die head can be satisfied.

Description

A kind of production technique of skeleton optical fiber ribbon cable HDPE frame material
Technical field
The present invention relates to technical field of polymer materials, relate in particular to the production technique of the skeleton optical fiber ribbon cable material of a kind of HDPE.
Background technology
Along with the high speed development of opticfiber communication cause, the sharp increase of the quantity of information requirement, the optical cable that core number is large in the urgent need to a kind of external diameter is little.Slotted core fiber ribbon cable receives publicity due to plurality of advantages such as its density of optic fibre are high, construction install convenience.Slotted core cable overlays the fibre ribbon having made in spiral skeleton grooves and makes cable core, and with the wrapped skeleton of waterstop, skeleton adopts high-density polyethylene material (HDPE), then makes skeleton optical fiber ribbon cable at the additional protective material of cable core (PE material).Skeleton grooves becomes screw type rotary along optical cable, to guarantee to be positioned over optical fiber in groove with enough remaining length, has guaranteed tension, bending and the temperature profile of optical cable.Owing to adopting extrusion die rotation, make the seemingly fried dough twist of shape outside skeleton, processing is inconvenient, not easy-formation.
Summary of the invention
The present invention is directed to above problem, provide a kind of easy to process, the production technique of the skeleton optical fiber ribbon cable HDPE frame material that applicable extrusion die rotary extrusion requires.
Technical scheme of the present invention is: comprise the following steps:
1), in the HDPE of 90 ~ 94% weight ratios and the EVA of 4 ~ 8% weight ratios, add the 4# white oil of 3 ‰~5 ‰ weight ratios, stir 6 ~ 10 minutes;
2), 1) after step stirs and to finish, add the polypropylene nucleater NA-21 of 1 ‰~1.5 ‰ weight ratios, in mixer, stir 8 ~ 12 minutes;
3), by 2) material that mixes in step puts into 1:25 and carries out in vented twin-screw extruder in the same way mixingly, each district's temperature is 190~200 ℃, rotating speed is controlled at 45~60r/min, extruding pelletization.
The flow rate of described HDPE is less than 2g/10min.
The present invention is at HDPE(high density polyethylene(HDPE)) and EVA(ethylene-vinyl acetate copolymer) in increase white oil, white oil can increase flexibility, has improved its surperficial slickness, is beneficial to stranding; Polypropylene nucleater can accelerate crystallization, adapts to the needs of extrusion die rotary extrusion.
Embodiment
Embodiment mono-: comprise the following steps:
1), in 94% weight ratio flow rate, be less than the 4# white oil that adds 3 ‰ weight ratios in the HDPE of 2g/10min and the EVA of 4% weight ratio, stir 10 minutes;
2), 1) after step stirs and to finish, add the polypropylene nucleater NA-21 of 1 ‰ weight ratios, in mixer, stir 8 minutes;
3), by 2) material that mixes in step puts into 1:25 and carries out in vented twin-screw extruder in the same way mixingly, each district's temperature is 190 ℃, rotating speed is controlled at 60r/min, extruding pelletization, pelletizing particle size 2.1 ㎜ * 2.6 ㎜, long 2.8 ㎜; Vibratory screening apparatus screening, oven dry, check, packing.
Embodiment bis-: comprise the following steps:
1), in 92% weight ratio flow rate, be less than the 4# white oil that adds 4 ‰ weight ratios in the HDPE of 2g/10min and the EVA of 6% weight ratio, stir 8 minutes;
2), 1) after step stirs and to finish, add the polypropylene nucleater NA-21 of 1.25 ‰ weight ratios, in mixer, stir 10 minutes;
3), by 2) material that mixes in step puts into 1:25 and carries out in vented twin-screw extruder in the same way mixingly, each district's temperature is 195 ℃, rotating speed is controlled at 50r/min, extruding pelletization, pelletizing particle size 2.1 ㎜ * 2.6 ㎜, long 2.8 ㎜; Vibratory screening apparatus screening, oven dry, check, packing.
Embodiment tri-: comprise the following steps:
1), in 90% weight ratio flow rate, be less than the 4# white oil that adds 5 ‰ weight ratios in the HDPE of 2g/10min and the EVA of 8% weight ratio, stir 6 minutes;
2), 1) after step stirs and to finish, add the polypropylene nucleater NA-21 of 1.5 ‰ weight ratios, in mixer, stir 12 minutes;
3), by 2) material that mixes in step puts into 1:25 and carries out in vented twin-screw extruder in the same way mixingly, each district's temperature is 200 ℃, rotating speed is controlled at 45r/min, extruding pelletization, pelletizing particle size 2.1 ㎜ * 2.6 ㎜, long 2.8 ㎜; Vibratory screening apparatus screening, oven dry, check, packing.

Claims (2)

1. a production technique for skeleton optical fiber ribbon cable HDPE frame material, is characterized in that, comprises the following steps:
1), in the HDPE of 90 ~ 94% weight ratios and the EVA of 4 ~ 8% weight ratios, add the 4# white oil of 3 ‰~5 ‰ weight ratios, stir 6 ~ 10 minutes;
2), 1) after step stirs and to finish, add the polypropylene nucleater NA-21 of 1 ‰~1.5 ‰ weight ratios, in mixer, stir 8 ~ 12 minutes;
3), by 2) material that mixes in step puts into 1:25 and carries out in vented twin-screw extruder in the same way mixingly, each district's temperature is 190~200 ℃, rotating speed is controlled at 45~60r/min, extruding pelletization.
2. the production technique of a kind of skeleton optical fiber ribbon cable HDPE frame material according to claim 1, is characterized in that, the flow rate of described HDPE is less than 2g/10min.
CN201310135571.1A 2013-04-18 2013-04-18 Manufacturing technology of HDPE skeleton material for skeleton-type ribbon optical cable Pending CN104109274A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310135571.1A CN104109274A (en) 2013-04-18 2013-04-18 Manufacturing technology of HDPE skeleton material for skeleton-type ribbon optical cable

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310135571.1A CN104109274A (en) 2013-04-18 2013-04-18 Manufacturing technology of HDPE skeleton material for skeleton-type ribbon optical cable

Publications (1)

Publication Number Publication Date
CN104109274A true CN104109274A (en) 2014-10-22

Family

ID=51706270

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310135571.1A Pending CN104109274A (en) 2013-04-18 2013-04-18 Manufacturing technology of HDPE skeleton material for skeleton-type ribbon optical cable

Country Status (1)

Country Link
CN (1) CN104109274A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017215179A1 (en) * 2016-06-16 2017-12-21 扬州金森光电材料有限公司 Method for modifying optical cable framework material hdpe

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017215179A1 (en) * 2016-06-16 2017-12-21 扬州金森光电材料有限公司 Method for modifying optical cable framework material hdpe

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C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20141022