CN104109274A - Manufacturing technology of HDPE skeleton material for skeleton-type ribbon optical cable - Google Patents
Manufacturing technology of HDPE skeleton material for skeleton-type ribbon optical cable Download PDFInfo
- Publication number
- CN104109274A CN104109274A CN201310135571.1A CN201310135571A CN104109274A CN 104109274 A CN104109274 A CN 104109274A CN 201310135571 A CN201310135571 A CN 201310135571A CN 104109274 A CN104109274 A CN 104109274A
- Authority
- CN
- China
- Prior art keywords
- hdpe
- skeleton
- manufacturing technology
- weight
- white oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/24—Crystallisation aids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
A manufacturing technology of an HDPE skeleton material for a skeleton-type ribbon optical cable. The invention provides the manufacturing technology of the HDPE skeleton material for the skeleton-type ribbon optical cable, wherein the manufacturing technology is suitable for a requirement of rotating extrusion of an extrusion die head and includes following steps: 1) adding 0.3%-0.5% by weight of 4# white oil to 90-94% by weight of HDPE and 4-8% by weight of EVA performing a stirring process for 6-10 min; 2) adding 0.1%-0.5% by weight of a polypropylene nucleating agent NA-21 after the stirring operation in the step 1) is finished, performing a stirring process in a mixing machine for 8-12 min; and 3) feeding the material mixed in the step 2) into a 1:25 co-directional exhaust-type double-screw extruder and carrying out a mixing process with temperature in each zone being 190-200 DEG C and a rotational speed being controlled within 45-60 r/min and performing an extruding granulation process. According to the invention, white oil is added to HDPE (high-density polyethylene) and EVA (ethylene-vinyl acetate copolymer). The white oil can enhance flexibility and smoothness of a surface of a loose tube is enhanced, thereby being beneficial to cabling. The polypropylene nucleating agent can increase the speed of a crystallization process. The requirement of rotating extrusion of the extrusion die head can be satisfied.
Description
Technical field
The present invention relates to technical field of polymer materials, relate in particular to the production technique of the skeleton optical fiber ribbon cable material of a kind of HDPE.
Background technology
Along with the high speed development of opticfiber communication cause, the sharp increase of the quantity of information requirement, the optical cable that core number is large in the urgent need to a kind of external diameter is little.Slotted core fiber ribbon cable receives publicity due to plurality of advantages such as its density of optic fibre are high, construction install convenience.Slotted core cable overlays the fibre ribbon having made in spiral skeleton grooves and makes cable core, and with the wrapped skeleton of waterstop, skeleton adopts high-density polyethylene material (HDPE), then makes skeleton optical fiber ribbon cable at the additional protective material of cable core (PE material).Skeleton grooves becomes screw type rotary along optical cable, to guarantee to be positioned over optical fiber in groove with enough remaining length, has guaranteed tension, bending and the temperature profile of optical cable.Owing to adopting extrusion die rotation, make the seemingly fried dough twist of shape outside skeleton, processing is inconvenient, not easy-formation.
Summary of the invention
The present invention is directed to above problem, provide a kind of easy to process, the production technique of the skeleton optical fiber ribbon cable HDPE frame material that applicable extrusion die rotary extrusion requires.
Technical scheme of the present invention is: comprise the following steps:
1), in the HDPE of 90 ~ 94% weight ratios and the EVA of 4 ~ 8% weight ratios, add the 4# white oil of 3 ‰~5 ‰ weight ratios, stir 6 ~ 10 minutes;
2), 1) after step stirs and to finish, add the polypropylene nucleater NA-21 of 1 ‰~1.5 ‰ weight ratios, in mixer, stir 8 ~ 12 minutes;
3), by 2) material that mixes in step puts into 1:25 and carries out in vented twin-screw extruder in the same way mixingly, each district's temperature is 190~200 ℃, rotating speed is controlled at 45~60r/min, extruding pelletization.
The flow rate of described HDPE is less than 2g/10min.
The present invention is at HDPE(high density polyethylene(HDPE)) and EVA(ethylene-vinyl acetate copolymer) in increase white oil, white oil can increase flexibility, has improved its surperficial slickness, is beneficial to stranding; Polypropylene nucleater can accelerate crystallization, adapts to the needs of extrusion die rotary extrusion.
Embodiment
Embodiment mono-: comprise the following steps:
1), in 94% weight ratio flow rate, be less than the 4# white oil that adds 3 ‰ weight ratios in the HDPE of 2g/10min and the EVA of 4% weight ratio, stir 10 minutes;
2), 1) after step stirs and to finish, add the polypropylene nucleater NA-21 of 1 ‰ weight ratios, in mixer, stir 8 minutes;
3), by 2) material that mixes in step puts into 1:25 and carries out in vented twin-screw extruder in the same way mixingly, each district's temperature is 190 ℃, rotating speed is controlled at 60r/min, extruding pelletization, pelletizing particle size 2.1 ㎜ * 2.6 ㎜, long 2.8 ㎜; Vibratory screening apparatus screening, oven dry, check, packing.
Embodiment bis-: comprise the following steps:
1), in 92% weight ratio flow rate, be less than the 4# white oil that adds 4 ‰ weight ratios in the HDPE of 2g/10min and the EVA of 6% weight ratio, stir 8 minutes;
2), 1) after step stirs and to finish, add the polypropylene nucleater NA-21 of 1.25 ‰ weight ratios, in mixer, stir 10 minutes;
3), by 2) material that mixes in step puts into 1:25 and carries out in vented twin-screw extruder in the same way mixingly, each district's temperature is 195 ℃, rotating speed is controlled at 50r/min, extruding pelletization, pelletizing particle size 2.1 ㎜ * 2.6 ㎜, long 2.8 ㎜; Vibratory screening apparatus screening, oven dry, check, packing.
Embodiment tri-: comprise the following steps:
1), in 90% weight ratio flow rate, be less than the 4# white oil that adds 5 ‰ weight ratios in the HDPE of 2g/10min and the EVA of 8% weight ratio, stir 6 minutes;
2), 1) after step stirs and to finish, add the polypropylene nucleater NA-21 of 1.5 ‰ weight ratios, in mixer, stir 12 minutes;
3), by 2) material that mixes in step puts into 1:25 and carries out in vented twin-screw extruder in the same way mixingly, each district's temperature is 200 ℃, rotating speed is controlled at 45r/min, extruding pelletization, pelletizing particle size 2.1 ㎜ * 2.6 ㎜, long 2.8 ㎜; Vibratory screening apparatus screening, oven dry, check, packing.
Claims (2)
1. a production technique for skeleton optical fiber ribbon cable HDPE frame material, is characterized in that, comprises the following steps:
1), in the HDPE of 90 ~ 94% weight ratios and the EVA of 4 ~ 8% weight ratios, add the 4# white oil of 3 ‰~5 ‰ weight ratios, stir 6 ~ 10 minutes;
2), 1) after step stirs and to finish, add the polypropylene nucleater NA-21 of 1 ‰~1.5 ‰ weight ratios, in mixer, stir 8 ~ 12 minutes;
3), by 2) material that mixes in step puts into 1:25 and carries out in vented twin-screw extruder in the same way mixingly, each district's temperature is 190~200 ℃, rotating speed is controlled at 45~60r/min, extruding pelletization.
2. the production technique of a kind of skeleton optical fiber ribbon cable HDPE frame material according to claim 1, is characterized in that, the flow rate of described HDPE is less than 2g/10min.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310135571.1A CN104109274A (en) | 2013-04-18 | 2013-04-18 | Manufacturing technology of HDPE skeleton material for skeleton-type ribbon optical cable |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310135571.1A CN104109274A (en) | 2013-04-18 | 2013-04-18 | Manufacturing technology of HDPE skeleton material for skeleton-type ribbon optical cable |
Publications (1)
Publication Number | Publication Date |
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CN104109274A true CN104109274A (en) | 2014-10-22 |
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Family Applications (1)
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CN201310135571.1A Pending CN104109274A (en) | 2013-04-18 | 2013-04-18 | Manufacturing technology of HDPE skeleton material for skeleton-type ribbon optical cable |
Country Status (1)
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CN (1) | CN104109274A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017215179A1 (en) * | 2016-06-16 | 2017-12-21 | 扬州金森光电材料有限公司 | Method for modifying optical cable framework material hdpe |
-
2013
- 2013-04-18 CN CN201310135571.1A patent/CN104109274A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017215179A1 (en) * | 2016-06-16 | 2017-12-21 | 扬州金森光电材料有限公司 | Method for modifying optical cable framework material hdpe |
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Legal Events
Date | Code | Title | Description |
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C06 | Publication | ||
PB01 | Publication | ||
C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20141022 |