CN104106593A - Insecticide acaricidal composition containing xiaochongthion and etoxazole - Google Patents
Insecticide acaricidal composition containing xiaochongthion and etoxazole Download PDFInfo
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- CN104106593A CN104106593A CN201410261465.2A CN201410261465A CN104106593A CN 104106593 A CN104106593 A CN 104106593A CN 201410261465 A CN201410261465 A CN 201410261465A CN 104106593 A CN104106593 A CN 104106593A
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Abstract
The invention discloses an insecticide acaricidal composition containing xiaochongthion and etoxazole. Effective components of the insecticide acaricidal composition are the xiaochongthion and the etoxazole. The weight ratio of the xiaochongthion to the etoxazole is 30:1-1:30. Many indoor and outdoor experiments show that the composition has an obvious synergistic interaction effect and can be used for control of a plurality of pests in agriculture, such as red spider, white fly and scale insect. In addition, because the pesticide using amount is reduced, the residue amount on crops of pesticides is reduced, pollution to the environment is reduced and generation of pest drug resistance is delayed.
Description
Technical field
The present invention relates to agriculture chemical compounding technical field, specifically taking sulfur-phosphor and second mite azoles as the composite binary complex of active ingredient.
Background technology
Sulfur-phosphor belongs to organophosphorus insecticides, the inhibitor that the mechanism of action is acetylcholinesterase.The insects such as citrus red mite, arrowhead scales, cotton cotton bollworm, vegetables oriental tobacco budworm, diamond-back moth and rice fulgorid are had to good control efficiency.
Second mite azoles belongs to diphenyl oxazoline derivative, and the mechanism of action is to suppress embryo's formation of mite ovum and the process of casting off a skin from young mite to one-tenth mite, effective to ovum and young mite, to becoming mite invalid.Be mainly used in preventing and treating the two spotted spider mite on apple, oranges and tangerines.
The pesticide resistance problem of pest is a global problem, is the emphasis problem that agricultural science and technology worker pays close attention to always.Along with the increase of the continuity year in year out on Chemical Control of Harmful Insects, agricultural chemicals usage amount and non-science are used the impact of the factors such as agricultural chemicals, cause pest resistance day by day serious, the pest species that produces resistance is on the increase.Meanwhile, due to high-intensity use agricultural chemicals, cause that Practice for Pesticide Residue in Agricultural Products exceeds standard, the series of problems such as contaminated environment and the increase of peasant's drug cost, be unfavorable for agriculture sustainable development.
Therefore, development is efficient, low toxicity, low-residual, the different mechanism of action, has again the complex preparation of synergistic function simultaneously, not only contribute to delay the generation of pest resistance to insecticide, but also can extend the service life of pesticide species, reduce using dosage, cost-saving, reduce the pollution to environment.
The inventor conducts in-depth research the compounded formula screening of sulfur-phosphor and second mite azoles, find that sulfur-phosphor and second mite azoles carry out composite, within the scope of certain compound proportion, there is obvious synergistic function, in actual use simultaneously, to the insect in agricultural, as two spotted spider mite, aleyrodid, scale insect etc. have outstanding control efficiency, after further study, complete the present invention.
Summary of the invention
The object of the present invention is to provide a kind of insecticide acaricide composition that contains sulfur-phosphor and second mite azoles, this compound insecticidal miticide composition has obvious synergistic function, can be used for preventing and treating the insects such as two spotted spider mite in agricultural, aleyrodid, scale insect.
Another object of the present invention is to the insecticide acaricide composition that contains sulfur-phosphor and second mite azoles, in use can reduce dosage, reduced the residual quantity of agricultural chemicals on crops, delay the generation of pest resistance to insecticide, can also make it use and compare obvious raising separately than single dose the control efficiency of various insects, expand insecticidal spectrum, laborsaving, economical, reduce farmer's burdens.
Technical scheme of the present invention: a kind of insecticide acaricide composition that contains sulfur-phosphor and second mite azoles, active ingredient is sulfur-phosphor and second mite azoles, wherein the weight ratio of sulfur-phosphor and second mite azoles is 30:1～1:30, sulfur-phosphor and the gross weight percentage composition of second mite azoles in composition be 1～85% all the other use and acceptable auxiliary element for allowing in agricultural chemicals.
Described auxiliary element is one or more the combination in solvent, emulsifier, wetting agent, dispersant, stabilizing agent, antifreezing agent, thickener, disintegrant, binding agent, defoamer, bleeding agent, synergist, fire retardant, density adjuster and filler, above material is known substance conventional in pesticidal preparations, change to some extent according to being prepared into the different formulations of pesticide, but be not particularly limited.
Insecticide acaricide composition of the present invention can be prepared into any one formulation using in applicable agricultural production by known method, reasonable formulation has suspending agent, aqueous emulsion, microemulsion, water dispersible granules, wetting powder, ultra low volume liquids, microcapsule suspending agent and thermal fog.
The frequency of administration of insecticide acaricide composition of the present invention and amount of application have small variations with crops, insect, weather condition variation, can be by using suitable dosage to reach the object of effective control.
Compared with prior art, the invention has the advantages that:
1, sulfur-phosphor and second mite azoles are composite has a synergistic function, has obviously improved the control efficiency to insect than the independent use of single dose, has expanded insecticidal spectrum simultaneously, has solved the defect to some insect weak effect when single dose is used separately.
2, sulfur-phosphor and two kinds of active ingredients of second mite azoles are composite, have reduced agricultural chemicals usage amount, reduced use cost, alleviated pollution to environment, delayed pest resistance to insecticide generation, increased service life of agricultural chemicals.
Embodiment
In order to understand better essence of the present invention, below in conjunction with embodiment, content of the present invention is described further, but can not be considered as limitation of the present invention.
(1) formulation embodiment.
In following each embodiment, active ingredient adopts the former medicine of 90% sulfur-phosphor and the former medicine of 93% second mite azoles, and each component percentage composition is weight percentage.
Embodiment 1:25% sulfur-phosphor second mite azole suspending agent.
Sulfur-phosphor 24%, second mite azoles 1%, alkyl phenol formaldehyde resin polyoxyethylene ether 15%, alkylnaphthalene sulfonate 10%, aluminium-magnesium silicate 3%, glycerine 2%, silicone oil 0.1%, deionized water supplies 100%.Above-mentioned active ingredient, dispersant, wetting agent, thickener, antifreezing agent, defoamer and deionized water are mixed, sand milling in high speed shear dispersion, sand mill, the high dispersive forming in water-medium, stable suspension system, can make 25% sulfur-phosphor second mite azole suspending agent.
Embodiment 2:35% sulfur-phosphor second mite azoles aqueous emulsion.
Sulfur-phosphor 20%, second mite azoles 15%, solvent naphtha 30%, polyoxyethylene nonylphenol ether phosphate 10%, polycarboxylate 5%, triphenyl phosphite 1%, glycerine 1%, deionized water supplies 100%.Above-mentioned active ingredient, solvent, emulsifier, dispersant and stabilizing agent are mixed to form to oil phase, antifreezing agent dissolves and forms water in water, under clipper effect, slowly oil phase is added in water, and continue to shear approximately 30 minutes, can make 35% sulfur-phosphor second mite azoles aqueous emulsion.
Embodiment 3:40% sulfur-phosphor second mite azoles microemulsion.
Sulfur-phosphor 30%, second mite azoles 10%, solvent naphtha 30%, calcium dodecyl benzene sulfonate 15%, sodium citrate 2%, organosilicon 1%, thiophene ketone 2%, deionized water supplies 100%.Active ingredient is dissolved completely with solvent, and then add emulsifier, stabilizing agent, bleeding agent, synergist to mix, finally add deionized water, after fully stirring, can make 40% sulfur-phosphor second mite azoles microemulsion.
Embodiment 4:70% sulfur-phosphor second mite azoles wetting powder.
Sulfur-phosphor 65%, second mite azoles 5%, polycarboxylate 10%, calcium dodecyl benzene sulfonate 10%, kaolin supplies 100%.By above-mentioned, active ingredient, dispersant, wetting agent and filler are mixed, after mechanical crushing, again through air-flow crushing, mix, can make 70% sulfur-phosphor second mite azoles wetting powder.
Embodiment 5:60% sulfur-phosphor second mite azoles water dispersible granules.
Sulfur-phosphor 58%, second mite azoles 2%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 15%, neopelex 10%, urea 2%, polyvinyl alcohol 2%, kaolin supplies 100%.Above-mentioned active ingredient, dispersant, wetting agent, disintegrant, binding agent and filler are mixed, pulverize with micro jet, through mediating, then add in fluidized bed prilling dryer and carry out granulation, dry, screening, can make 60% sulfur-phosphor second mite azoles water dispersible granules.
Embodiment 6:20% sulfur-phosphor second mite azoles ultra low volume liquids.
Sulfur-phosphor 19%, second mite azoles 1%, 1-METHYLPYRROLIDONE 20%, calcium dodecyl benzene sulfonate 5%, polyoxyethylene nonylphenol ether 3%, azone 2.5%, vegetable oil complements to 100%.After above-mentioned active ingredient is dissolved by stirring solvent, then add other auxiliary agent, be fully uniformly mixed, can make 20% sulfur-phosphor second mite azoles ultra low volume liquids.
The agent of embodiment 7:15% sulfur-phosphor second mite azole microcapsule suspension.
Sulfur-phosphor 10%, second mite azoles 5%, the urea resin prepolymer aqueous solution 30%, cyclohexanone 15%, castor oil polyoxyethylene ether 5%, sodium lignin sulfonate 3%, sodium hydroxide 2%, deionized water complements to 100%.By above-mentioned active ingredient, macromolecule cyst material, solvent, make to be dissolved into even oil phase, under shearing condition, oil phase is joined in the aqueous phase solution that contains emulsifier, pH adjusting agent, dispersant, surplus is supplied by deionized water, bi-material reacts at oil-water interfaces, forms macromolecule cyst wall, can make 15% sulfur-phosphor second mite azole microcapsule suspension agent.
Embodiment 8:10% sulfur-phosphor second mite azoles thermal fog.
Sulfur-phosphor 9.5%, second mite azoles 0.5%, 1-METHYLPYRROLIDONE 20%, polycarboxylate 8%, calcium dodecyl benzene sulfonate 8%, azone 2%, zinc chloride 8%, triphenyl phosphate 2%, soybean oil complements to 100%.Above-mentioned active ingredient and solvent are dropped in the reaction vessel of band stirring, after active ingredient is fully dissolved, then add other auxiliary agent, fully stir about 60 minutes, mixes it, can make 10% sulfur-phosphor second mite azoles thermal fog.
(2) the indoor biological activity determination of insecticide acaricide composition of the present invention and field efficacy checking.
1, sulfur-phosphor and the indoor joint toxicity measuring of second mite azoles to scale insect.
For examination worm: select to be collected in citrus orchard and the indoor scale insect nymph of raising breeding.
Reagent agent: the former medicine of 90% sulfur-phosphor and the former medicine of 93% second mite azoles.
Test method: adopt spray-on process to measure, concrete grammar is as follows.
Select scale insect nymph healthy, that the length of time is consistent in laboratory, put into the culture dish with Citrus leaf, every ware 40 cephalont, 4 repetitions are established in every processing, spray with potter spray tower under 50PSI pressure, a ware of each spray, every ware spraying liquid 1ml, takes out culture dish after sedimentation 1min, then the culture dish of processing is put into 25 DEG C, in the illumination box of 12H/12H, cultivate, establish the processing of the corresponding organic solvent that does not contain medicament in contrast.After processing, 72h investigation examination worm death condition, records total borer population and dead borer population.
Carry out statistical analysis with DPS statistical analysis software, calculate the LC of each medicament
50, and according to the co-toxicity coefficient (CTC value) of the abundant method calculating of Sun Yun mixture.
Actual measurement toxicity index (ATI)=(standard medicament LC
50/ reagent agent LC
50) × 100.
The percentage composition of B in percentage composition+B medicament toxicity index × mixture of A in theoretical toxicity index (TTI)=A medicament toxicity index × mixture.
Co-toxicity coefficient (CTC)=[the theoretical toxicity index of mixture actual measurement toxicity index (ATI)/mixture (TTI)] × 100.
According to the NY/T11547.7-2006 insecticide synergy criteria for classifying: co-toxicity coefficient (CTC) >=120 shows as synergistic effect; Co-toxicity coefficient (CTC)≤80 shows as antagonism; 80 < co-toxicity coefficient (CTC) < 120 show as summation action.
Table 1, sulfur-phosphor and the second mite azoles indoor joint toxicity measuring result to scale insect.
| Medicament title and proportioning (weight ratio) | LC 50(mg/L) | ATI | TTI | CTC |
| Sulfur-phosphor | 6.14 | 100.00 | - | - |
| Second mite azoles | 43.29 | 14.18 | - | - |
| Sulfur-phosphor: second mite azoles (30:1) | 5.06 | 121.34 | 97.23 | 124.80 |
| Sulfur-phosphor: second mite azoles (20:1) | 4.59 | 133.77 | 95.91 | 139.47 |
| Sulfur-phosphor: second mite azoles (10:1) | 4.22 | 145.50 | 92.20 | 157.81 |
| Sulfur-phosphor: second mite azoles (5:1) | 4.06 | 151.23 | 85.70 | 176.46 |
| Sulfur-phosphor: second mite azoles (1:1) | 5.89 | 104.24 | 57.09 | 182.59 |
| Sulfur-phosphor: second mite azoles (1:5) | 10.82 | 56.75 | 28.48 | 199.26 |
| Sulfur-phosphor: second mite azoles (1:10) | 16.38 | 37.48 | 21.98 | 170.52 |
| Sulfur-phosphor: second mite azoles (1:20) | 22.16 | 27.71 | 18.27 | 151.67 |
| Sulfur-phosphor: second mite azoles (1:30) | 29.23 | 21.01 | 16.95 | 123.95 |
As can be seen from Table 1, when sulfur-phosphor and second mite azoles are composite in 30:1～1:30 scope of (by weight), co-toxicity coefficient (CTC) is all greater than 120, and scale insect is shown to synergistic function, and visible sulfur-phosphor and second mite azoles be composite has reasonability and feasibility.
2, sulfur-phosphor and the indoor joint toxicity measuring of second mite azoles to citrus red mite.
For examination worm: be collected in citrus orchard and the indoor two spotted spider mite mite of raising breeding if select.
Reagent agent: the former medicine of 90% sulfur-phosphor and the former medicine of 93% second mite azoles.
Test method adopts leaf butterfly spray-on process, and concrete operation method is as follows:
Choose the Citrus leaf of healthy growth, make leaf butterfly with card punch, in culture dish, place a wet sponge piece, on it, put filter paper, foliation butterfly on filter paper, every ware is put 2 leaf butterflies, is inoculated on leaf butterfly if select citrus red mite mite healthy, that the length of time is consistent, 20 of every leaf butterfly inoculations, 4 repetitions are established in every processing.The culture dish that is connected to leaf butterfly is placed under potter spray tower, under 50PSI pressure, spray, spray amount is 1ml, after sedimentation 1min, take out culture dish, then the culture dish of processing is put into 25 DEG C, in 12H/12H illumination box, cultivate, establish the processing of the corresponding organic solvent that does not contain medicament in contrast.After processing, 48h investigation examination worm death condition, records total borer population and dead borer population.
Carry out statistical analysis with DPS statistical analysis software, calculate the LC of each medicament
50, and according to the co-toxicity coefficient (CTC value) of the abundant method calculating of Sun Yun mixture.
Actual measurement toxicity index (ATI)=(standard medicament LC
50/ reagent agent LC
50) × 100.
The percentage composition of B in percentage composition+B medicament toxicity index × mixture of A in theoretical toxicity index (TTI)=A medicament toxicity index × mixture.
Co-toxicity coefficient (CTC)=[the theoretical toxicity index of mixture actual measurement toxicity index (ATI)/mixture (TTI)] × 100.
According to the NY/T11547.7-2006 insecticide synergy criteria for classifying: co-toxicity coefficient (CTC) >=120 shows as synergistic effect; Co-toxicity coefficient (CTC)≤80 shows as antagonism; 80 < co-toxicity coefficient (CTC) < 120 show as summation action.
Table 2, sulfur-phosphor and the second mite azoles indoor joint toxicity measuring result to citrus red mite.
| Medicament title and proportioning (weight ratio) | LC 50(mg/L) | ATI | TTI | CTC |
| Sulfur-phosphor | 17.69 | 100.00 | - | - |
| Second mite azoles | 4.35 | 406.67 | - | - |
| Sulfur-phosphor: second mite azoles (30:1) | 12.32 | 143.59 | 109.89 | 130.67 |
| Sulfur-phosphor: second mite azoles (20:1) | 10.74 | 164.71 | 114.60 | 143.73 |
| Sulfur-phosphor: second mite azoles (10:1) | 8.79 | 201.25 | 127.88 | 157.37 |
| Sulfur-phosphor: second mite azoles (5:1) | 7.15 | 247.41 | 151.11 | 163.73 |
| Sulfur-phosphor: second mite azoles (1:1) | 4.07 | 434.64 | 253.34 | 171.56 |
| Sulfur-phosphor: second mite azoles (1:5) | 2.66 | 665.04 | 355.56 | 187.04 |
| Sulfur-phosphor: second mite azoles (1:10) | 2.34 | 755.98 | 378.79 | 199.58 |
| Sulfur-phosphor: second mite azoles (1:20) | 2.71 | 652.77 | 392.07 | 166.49 |
| Sulfur-phosphor: second mite azoles (1:30) | 3.29 | 537.69 | 396.78 | 135.51 |
As can be seen from Table 2, when sulfur-phosphor and second mite azoles are composite in 30:1～1:30 scope of (by weight), co-toxicity coefficient (CTC) is all greater than 120, citrus red mite is shown to synergistic function, and visible sulfur-phosphor and second mite azoles be composite has reasonability and feasibility.
3, the composite field control effectiveness test to scale insect of sulfur-phosphor and second mite azoles.
Adopt embodiment 1 (25% sulfur-phosphor second mite azole suspending agent) for preventing and treating oranges and tangerines scale insect, investigation insect population radix before dispenser, after medicine, 7d, 14d, 30d investigate respectively residual borer population alive, 2 strains are looked in investigation Shi Mei community, every strain is looked into respectively 5 blades by orientation, 4 of the four corners of the world, each community is looked into 40 blades altogether, records the borer population of living, and calculates control efficiency.Control efficiency computational methods are as follows:
Preventive effect (%)=(1-CK
1× Pt
1/ CK
2× Pt
2) × 100.
Wherein: CK
1represent the front insect population number of check plot medicine; Pt
1represent insect population number after treatment region medicine;
CK
2represent insect population number after the medicine of check plot; Pt
2represent the front insect population number for the treatment of region medicine;
Table 3, respectively process the result of the test of chemical control scale insect.
As can be seen from Table 3, when 25% sulfur-phosphor second mite azole suspending agent uses 325-400mg a.i./kg, after medicine, 7d, 14d, 30d are all better than each single dose to the preventive effect of scale insect and use separately, and after medicine, 30d preventive effect all still reaches more than 80% simultaneously, illustrates that this compound drug has good lasting effect.In pilot survey process, do not find that this compound drug produces poisoning to mandarin tree.
4, the composite field control effectiveness test to citrus red mite of sulfur-phosphor and second mite azoles.
Adopt embodiment (60% sulfur-phosphor second mite azoles water dispersible granules) for preventing and treating citrus red mite, investigation insect population radix before dispenser, after medicine, 7d, 14d, 30d investigate respectively residual mite number alive, 2 strains are looked in investigation Shi Mei community, every strain is looked into respectively 5 blades by orientation, 4 of the four corners of the world, each community is looked into 40 blades altogether, records the mite number of living, and calculates control efficiency.Control efficiency computational methods are as follows:
Control efficiency (%)=(1-CK
1× Pt
1/ CK
2× Pt
2) × 100.
Wherein: CK
1represent the front insect population number of check plot medicine; Pt
1represent insect population number after treatment region medicine;
CK
2represent insect population number after the medicine of check plot; Pt
2represent the front insect population number for the treatment of region medicine;
Table 4, respectively process the result of the test of chemical control citrus red mite.
As can be seen from Table 4, when 60% sulfur-phosphor second mite azoles water dispersible granules uses 325-400mg a.i./kg, after medicine, 7d, 14d, 30d are all better than each single dose to the preventive effect of citrus red mite and use separately, after medicine, 30d preventive effect all still reaches more than 80% simultaneously, illustrates that this compound drug has good lasting effect.In pilot survey process, do not find that this compound drug produces poisoning to mandarin tree.
In sum, it is the compound insecticidal miticide composition of sulfur-phosphor and second mite azoles that the present invention adopts two kinds of active components, has synergistic function, compared with existing unitary agent, insecticidal effect obviously improves, and the lasting period is long, to crop safety, be worth applying in agricultural production.
Claims (4)
1. an insecticide acaricide composition that contains sulfur-phosphor and second mite azoles, it is characterized in that: active ingredient is sulfur-phosphor and second mite azoles, wherein the weight ratio of sulfur-phosphor and second mite azoles is 30:1～1:30, and sulfur-phosphor and the gross weight percentage composition of second mite azoles in composition are 1～85%.
2. a kind of insecticide acaricide composition that contains sulfur-phosphor and second mite azoles according to claim 1, is characterized in that: described composition also contains insecticides adjuvant, to make the application forms that is applicable to agricultural use.
3. a kind of insecticide acaricide composition that contains sulfur-phosphor and second mite azoles according to claim 1, is applicable to prevent and treat the insect in agricultural.
4. a kind of insecticide acaricide composition that contains sulfur-phosphor and second mite azoles according to claim 3, is characterized in that: described insect is two spotted spider mite, aleyrodid, scale insect.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104904743A (en) * | 2014-03-11 | 2015-09-16 | 江苏龙灯化学有限公司 | Insect disinfestation composition |
| CN107736372A (en) * | 2017-11-25 | 2018-02-27 | 惠州市无龄康态健康科技有限公司 | A kind of composition pesticide containing sulfur-phosphor and fluazinam |
| CN107873726A (en) * | 2017-11-25 | 2018-04-06 | 惠州市无龄康态健康科技有限公司 | A kind of composition pesticide containing sulfur-phosphor and flufenzine |
| CN113925057A (en) * | 2021-09-24 | 2022-01-14 | 陕西上格之路生物科学有限公司 | Insecticide composition containing nitre sulfur and phosphorus |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1089612A (en) * | 1993-01-12 | 1994-07-20 | 四川省化学工业研究设计院 | O, O-dialkyl group-O-(2,4-two chloro-6-nitrophenyls) phosphorothioate compound and method for making and purposes |
| CN103271081A (en) * | 2013-04-10 | 2013-09-04 | 湖南农大海特农化有限公司 | Etoxazole-triazophos pesticide composition |
-
2014
- 2014-06-12 CN CN201410261465.2A patent/CN104106593B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1089612A (en) * | 1993-01-12 | 1994-07-20 | 四川省化学工业研究设计院 | O, O-dialkyl group-O-(2,4-two chloro-6-nitrophenyls) phosphorothioate compound and method for making and purposes |
| CN103271081A (en) * | 2013-04-10 | 2013-09-04 | 湖南农大海特农化有限公司 | Etoxazole-triazophos pesticide composition |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104904743A (en) * | 2014-03-11 | 2015-09-16 | 江苏龙灯化学有限公司 | Insect disinfestation composition |
| CN104904743B (en) * | 2014-03-11 | 2018-02-13 | 江苏龙灯化学有限公司 | Pesticidal combination |
| CN107736372A (en) * | 2017-11-25 | 2018-02-27 | 惠州市无龄康态健康科技有限公司 | A kind of composition pesticide containing sulfur-phosphor and fluazinam |
| CN107873726A (en) * | 2017-11-25 | 2018-04-06 | 惠州市无龄康态健康科技有限公司 | A kind of composition pesticide containing sulfur-phosphor and flufenzine |
| CN113925057A (en) * | 2021-09-24 | 2022-01-14 | 陕西上格之路生物科学有限公司 | Insecticide composition containing nitre sulfur and phosphorus |
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|---|---|
| CN104106593B (en) | 2016-05-18 |
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