CN104093526A - Brush threads, multi-brush threads and manufacturing method therefor - Google Patents

Brush threads, multi-brush threads and manufacturing method therefor Download PDF

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Publication number
CN104093526A
CN104093526A CN201380002010.2A CN201380002010A CN104093526A CN 104093526 A CN104093526 A CN 104093526A CN 201380002010 A CN201380002010 A CN 201380002010A CN 104093526 A CN104093526 A CN 104093526A
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CN
China
Prior art keywords
brush
precursor
brush silk
bonding agent
silk
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Granted
Application number
CN201380002010.2A
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Chinese (zh)
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CN104093526B (en
Inventor
金正守
金相佑
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MA SAN CO Ltd
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MA SAN CO Ltd
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Publication of CN104093526A publication Critical patent/CN104093526A/en
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Publication of CN104093526B publication Critical patent/CN104093526B/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D13/00Wheels having flexibly-acting working parts, e.g. buffing wheels; Mountings therefor
    • B24D13/02Wheels having flexibly-acting working parts, e.g. buffing wheels; Mountings therefor acting by their periphery
    • B24D13/10Wheels having flexibly-acting working parts, e.g. buffing wheels; Mountings therefor acting by their periphery comprising assemblies of brushes
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • A46D1/02Bristles details
    • A46D1/0261Roughness structure on the bristle surface
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • A46D1/04Preparing bristles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/02Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
    • B24D3/20Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially organic
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B2200/00Brushes characterized by their functions, uses or applications
    • A46B2200/30Brushes for cleaning or polishing
    • A46B2200/3093Brush with abrasive properties, e.g. wire bristles

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Brushes (AREA)
  • Polishing Bodies And Polishing Tools (AREA)

Abstract

The present invention relates to brush threads and a manufacturing method therefor. The brush threads can enable an abrasive (11 contained therein to exhibit continuous effects even if the brush threads (50) are worn or cut since a first thread (51) contains the abrasive (11), and maintain the same toughness and strength as those of conventional brush threads while exhibiting remarkable grinding force since a second abrasive (12) and a third abrasive (13) are additionally injected into the outer surface of the first thread (51). In addition, the weight percent and type of the second abrasive (12) fixed to the outer surface of the first thread (51) can be actively adjusted.

Description

Brush silk, many brush silks and manufacture method thereof
Technical field
The present invention relates to brush silk, be specially, contain the above grinding agent of 30 % by weight, thereby there is high stock removal, although and the content of grinding agent high, also there is excellent toughness and intensity.
Background technology
Brush roll is used for grinding technics or the surface clean technique of steel plate.This brush roll is grinding and during surface clean, due to the frictional heat of steel plate and brush, causes brush easily impaired and cannot reach grinding effect or cleaning performance, therefore needs often replacing.
Existing brush device, remove dirt (oil or the dust on iron oxide or the surface) quality on steel plate (comprising non-ferrous metal board (strip)) surface, become one of benchmark determining steel plate quality, and before nineteen ninety there is limitation in the main natural fiber (vegetable fibres, horse-hair (horse hair) etc.) using, chemical fibre (nylon, pp etc.) when removing the dirt of surface of steel plate.
Therefore, the various countries' steel mill being at war with in the international market (producing steel plate, non-ferrous metal), thereby in order to remove foreign matter completely, produce the product that presents the intrinsic gloss of steel plate, the brush (brush) that contains abrasive sand by use before and after nineteen ninety (polish-brush: (oil or the dust on iron oxide or surface) abrasive brush) takes out stains.
Wherein, the roller of being made by the brush silk of larger abrasive sand particle (#60-500), mainly to remove iron oxide etc., to take grinding surface of steel plate as main purpose, the roller (roll) of being made by the brush silk of abrasive sand particle less (more than #500), the concavo-convex bending that is mainly used in removing trickle oxide-film and adapts to surface of steel plate is to improve clean power.
In addition the roller that, contains larger abrasive sand particle and have a less brush silk all needs to have excellent grinding force and durability and careful clean power.
In order to improve this grinding force and durability and clean power, comprise our company various countries man of brush manufacturing factory by brush silk outside (external diameter) braiding (covering) filament further to strengthen the support force of brush silk, thereby improve durability and grinding force.
In addition, in order to bring into play excellent grinding force and durability and careful clean power simultaneously, described brush roll by steel plate (strip) surface, apply certain pressure (take brush roll and surface of steel plate contact starting point as benchmark time the general 2-5m/m of recommendation), but, from the brush roll (brush roll) of these brush devices, certainly lead to because the wearing and tearing of brush silk (brush bristle) or the silk that contains abrasive sand are polished brush silk and remove the foreign matter (iron oxide being eliminated or surperficial oil or dust) producing.
These foreign matters (oil or the dust on the iron oxide being eliminated or surface) are most of to be removed by nozzle, this nozzle contacts starting point gas jet to carry out cooling to brush towards brush and steel plate, now, this brush in brush roll, contact starting point with surface of steel plate be that the drafts of benchmark is about 5m/m(and recommends peak) pressurized state.
On the other hand, the mother metal of normally used brush silk be take nylon synthetic resin as main body, and uses at least one the grinding agent being mixed with in diamond dust, powder of stainless steel, titanium powder, carborundum (Silicon carbide) powder, aluminium powder to extrude.
Existing brush silk is manufactured by the mode of extruding at nylon mixed-abrasive, and due to the characteristic of nylon molecule, after extruding, need to stretch to stablize nylon molecular structure to the brush silk of extruding, could be as a brush use.
But, because existing brush silk needs stretched process after extruding, therefore add the abrasive levels in brush silk to be limited in 30 % by weight.
; while stretching under the state of the grinding agent more than containing 30 % by weight; content due to described grinding agent; in drawing process, cause the fracture of brush silk; if manufacture brush silk without drawing process under the state that contains grinding agents more than 30 % by weight, cause losing in use procedure (fractureing).
Therefore, although the content of grinding agent is higher, the grinding force of brush silk is also stronger, and prior art cannot improve the content of grinding agent.
Technical literature formerly
Patent documentation
Patent documentation 1: Japanese Laid-Open Patent Publication JP 2002-187073
Patent document 2: Korean granted patent 10-0435299
Patent document 3: Korean granted patent 10-0468478
Patent document 4: Korean granted patent 10-1017450
Patent document 5: Korean granted patent 10-0395482
Patent document 6: Korean granted patent 10-0395481
Summary of the invention
Technical problem
The object of the present invention is to provide a kind of brush silk, it contains the above grinding agent of 30 % by weight, thereby has high stock removal, although and the content of grinding agent high, there is excellent toughness and intensity.
The means of dealing with problems
The invention provides the manufacture method of brush silk, by extruding and manufacture after synthetic resin and grinding agent mixing, it is characterized in that, comprise: step (S10), the first precursor 51 that contains synthetic resin 14 and the first grinding agent 11 is extruded, wherein, with respect to the weight of described the first precursor 51 after extruding, described the first grinding agent 11 contains 1 % by weight to 30 % by weight; Step (S20), is coated with the first bonding agent 21 to manufacture the second precursor 52 at the outer surface of described the first precursor 51; Step (S30), fixes the second grinding agent 12 to manufacture the 3rd precursor 53 at the outer surface that is coated with the second precursor 52 of described the first bonding agent 21.
Can comprise: step (S40), the 3rd precursor 53 surface-coated the second bonding agents 22 in described S30 step are to manufacture the 4th precursor 54; Step (S50), before described the second bonding agent 22 solidifies, is wound around the outer surface of described the 4th precursor 54, so that described the 4th precursor 54 impregnated in described the second bonding agent 22 with fabric 41.
Described the first grinding agent 11 can comprise at least one in diamond dust, hydrocarbon powder, alumina powder, iron powder.
Described S10 step is also included in described S10 step and extrudes the rear step that the first precursor 51 is stretched of described the first precursor 51.
With respect to the weight of the brush silk 50 making by described S50 step, the gross weight % of described the first grinding agent 11 and described the second grinding agent 12 can be 20 % by weight to 90 % by weight.
In addition, at least one in described the first bonding agent 21 and described the second bonding agent 22 has the material identical with described synthetic resin 14.
Another aspect of the present invention provides the manufacture method of many brush silks, and it comprises the following steps: step (S60), a plurality of described brush silks 50 are arranged, to form first order brush silk 61; Step (S70), is coated with the 3rd bonding agent 23 to cover the mode of each brush silk 50 of described first order brush silk 61 completely, thereby forms second order brush silk 62; Step (S80), on the 3rd bonding agent 23 of coating on described second order brush silk 62, is coated with and adsorbs the 3rd grinding agent 13, thereby form the 3rd, arranges brush silk 63; Step (S90), has the described the 3rd of the 3rd grinding agent 13 to arrange on brush silk 63 in absorption and is coated with the 4th bonding agent 24 to form the 4th arrangement brush silk 64; Step (S100), weaves and is wound around the described the 4th with the second fabric 42 and arrange the outside of brush silk 64, thereby manufactures many brush silks 60.
Invention effect
The manufacture method of brush silk of the present invention and brush silk, owing to also containing the first grinding agent 11 in the first precursor 51 inside, therefore, even if 50 wearing and tearing of described brush silk or fracture are contained in inner grinding agent and continue performance effect.
In addition, brush yarn production method of the present invention and brush silk, the content of the grinding agent of the first precursor 51 is in 30 % by weight (critical value), and in the outside of described the first precursor 51, append the second grinding agent 12, the 3rd grinding agent 13 and it is integral, therefore, when keeping as existing toughness and intensity, there is excellent grinding force.
In addition, brush yarn production method of the present invention and brush silk, can independently adjust the % by weight and the kind that are fixed on the second outside grinding agent 12.
Accompanying drawing explanation
Fig. 1 means the procedure chart of manufacture method of the brush silk of the first embodiment of the present invention.
Fig. 2 is the cross-sectional view of the brush silk of Fig. 1.
Fig. 3 is the longitudinal section of Fig. 2.
Fig. 4 is the front view of the brush silk of Fig. 1.
Fig. 5 means the procedure charts of brushing the manufacture method of silk of the second embodiment of the present invention more.
Fig. 6 is the cross-sectional view of many brush silks of Fig. 5.
Fig. 7 is the longitudinal section of many brush silks of Fig. 5.
The specific embodiment
Referring to accompanying drawing, describe the present invention in detail.
But, in explanation of the present invention, when the known function to relevant or to the detailed description of structure unnecessarily fuzzy during main idea of the present invention, omit detailed description thereof.And, even if term is identical, if represented position is different, illustrate that Reference numeral is different.
In addition, term described later is according to role in the present invention and selected, these terms may be according to the users' such as experimenter or mensuration personnel intention or convention and different, and therefore, its definition should determine for basis according to the full text content of this description.
In this description, first, second term such as grade can be used for illustrating different inscapes, and still, described inscape is not defined in described term.Described term only be take and an inscape is different to another inscape is used as object.For example, within not departing from interest field of the present invention, the first inscape can be named by the second inscape, and similarly, the second inscape also can be named by the first inscape.And/or etc. term comprise the combination of project of a plurality of relevant records or the some projects in the project of a plurality of relevant records.
Term as used in this specification is only used for specific embodiment is described and uses, and non-limiting the present invention.Unless conclusivelyed show the different meanings in article, the record of odd number comprises majority.
Unless had different definition, comprised as used herein technical term and scientific term and conventionally understand equivalent in meaning the meaning and the those skilled in the art of interior all terms.Conventionally the meaning being had in correlation technique article as being interpreted as by the defined term of dictionary of using is consistent, unless the application defines clearly, can not exceedingly be understood as the pro forma meaning.
In addition, certain part " comprises " statement of a certain inscape, unless it has specific contrary record, is not the inscape of getting rid of other, and is interpreted as may further include other inscape.
Fig. 1 means the procedure chart of manufacture method of the brush silk of the first embodiment of the present invention, and Fig. 2 is the cross-sectional view of the brush silk of Fig. 1, and Fig. 3 is the longitudinal section of Fig. 2, Fig. 4 be Fig. 1 brush silk front view.
As shown in the figure, brush yarn production method of the present invention comprises: the step (S10) that the first precursor 51 that contains the first grinding agent 11 and synthetic resin 14 is extruded; Outer surface at described the first precursor 51 is coated with the first bonding agent 21 to manufacture the step (S20) of the second precursor 52; Make outer surface that the second grinding agent 12 is fixed on the second precursor 52 that is coated with described the first bonding agent 21 to manufacture the step (S30) of the 3rd precursor 53; The 3rd precursor 53 surface-coated the second bonding agents 22 in described S30 step are to manufacture the step (S40) of the 4th precursor 54; Before solidifying, described the second bonding agent 22 is wound around the step (S50) of the outer surface of described the 4th precursor 54 with fabric 41.
Described S10 step for by extrude contain the first grinding agent 11 synthetic resin 14 to manufacture the step of the first precursor 51, wherein, described grinding agent 11 can be used the powder of diamond dust, hydrocarbon powder, alumina powder, iron or non-ferrous metal, the first grinding agent 11 in described the first precursor 51 can be used 1 % by weight to 30 % by weight, and described synthetic resin 14 can be used 80 % by weight to 50 % by weight.
In the present embodiment, described synthetic resin 14 is used nylon, but with the present embodiment differently, also can use the synthetic resin of various materials.
In addition, the size of described the first grinding agent 11 can be the difference size between 60 order~2000 orders, and can, according to the diameter of extruding of described the first precursor 51, use different sizes.
In the present embodiment, after described the first precursor 51 is extruded with the diameter of 4mm, stretched process, forms the diameter of 1.2mm, and in described drawing process nylon molecule with arranged in a straight line.
The size of described the first grinding agent 11 is relevant with the diameter of described the first precursor 51, when the diameter of described precursor 51 is large, can use large diameter grinding agent, when the diameter hour of described precursor 51, need to use the grinding agent of minor diameter.
Wherein, with respect to the weight of described the first precursor 51, the first grinding agent 11 content that are blended in described the first precursor 51 are below 30 % by weight, and through extruding after-drawing.
The second precursor 52 of described S20 step is on the first precursor 51, be coated with the first bonding agent 21 and make, the material of described the first bonding agent 21 can be used polyurethane, nylon, epoxy resin etc., in the present embodiment, bonding agent by use with the nylon composition of described synthetic resin 14 identical materials, to improve to greatest extent bonding force and to reduce the heterogeneous sense between described synthetic resin 14.
The 3rd precursor 53 of described S30 step is for fix the second grinding agent 12 on the second precursor 52, in the present embodiment, described the second grinding agent 12 is used the material identical with the first grinding agent 11, but also can use the grinding agent of other kinds different from the present embodiment.
In addition, also can with S30 step, finish the manufacture of described brush silk, when finishing the manufacture of described brush silk with S30 step, the gross weight % of described grinding agent can be 20 % by weight to 90 % by weight of described brush silk weight.
In the present embodiment, after described S30 step, append the grinding force that step improves brush silk.
In described S40 step, on described the 3rd precursor 53, be coated with the second bonding agent 22 and manufacture the 4th precursor 54, in described S50 step, utilize fabric 41 to be wound around the outer surface of described the 4th precursor 56, make described fabric 41 impregnated in described the second bonding agent 56, thereby be woven in the outer surface of described the 4th precursor 54.Now, when described fabric 41 does not have thorough impregnation in bonding agent, after finishing, braiding can be coated with again described the second bonding agent.
In the present embodiment, the material of described the second bonding agent 22 is identical with the material of described the first bonding agent 21, but also can use the bonding agent of other materials different from the present embodiment.
In the present embodiment, described fabric 41 has been used the fabric of synthetic resin material, can use polyvinyl chloride, polyethylene, polystyrene, polypropylene, polyvinylidene chloride etc.
Described fabric 41 is wound around described the 4th precursor 54 and impregnated in described the second bonding agent 22 in described S40 step, in the process of solidifying at described the second bonding agent 22, is solidificated on described the 4th precursor 54 together with described the second bonding agent 22, thereby forms one.
At this, described fabric 41 and described the second bonding agent 22 prevent the separated phenomenon of the second bonding agent 12 of described the 3rd precursor 53, improve the engaging force of described the second grinding agent 12 simultaneously.
In the present embodiment, described fabric 41 is to weave in orthogonal mode.
On the other hand, with the present embodiment differently, can repeat described S20 step and S30 step, by repeating described S20 step and S30 step, improve the % by weight of the grinding agent of brush silk 50.
Therefore, in the brush silk 50 of manufacturing by above step, the % by weight of described grinding agent can be 20 % by weight to 90 % by weight of described brush silk weight, 30 % by weight to 50 % by weight more preferably, now, can increase toughness and elastic force, thereby improve durability, and can reduce to greatest extent the fracture because bending causes repeatedly.
In addition, because the first grinding agent 11 is also contained in described brush silk 50 inside at the first precursor 51, therefore, even if described brush silk 50 wearing and tearing or rupture and come off are contained in inner grinding agent and also continue to play a role.
In addition, described brush silk 50 can independently be adjusted % by weight and the kind that is fixed on the second outside grinding agent 12.Therefore, the first grinding agent 11 that is contained in 51 li of the first precursor is selected the grinding agent that can reduce to greatest extent the elastic force of synthetic resin 14 and the reduction of toughness, and be fixed on the second grinding agent 12 of the first precursor 51 outsides by selecting heat-resisting and anti abrasive grinding agent, thereby can produce the brush silk 50 that multiple toughness is strong, elasticity large and durability improves.
Fig. 5 means the procedure charts of manufacture method of many brush silks of the second embodiment of the present invention, and Fig. 6 is the cross-sectional views of many brush silks of Fig. 5, and Fig. 7 is the longitudinal sections of many brush silks of Fig. 5.
As shown in the figure, the manufacture method of many brush silks of the present embodiment comprises: arrange a plurality of brush silks 50 of manufacturing by described the first embodiment to form the step (S60) of first order brush silk 61; To cover the mode of each brush silk 50 of described first order brush silk 61, be coated with the 3rd bonding agent 23, thereby form the step (S70) of second order brush silk 62; At the 3rd bonding agent 23 of coating on described second order brush silk 62, be coated with and adsorb the 3rd grinding agent 13, thereby forming the 3rd step (S80) of arranging brush silk 63; In absorption, there is the described the 3rd of the 3rd grinding agent 13 to arrange on brush silk 63 and be coated with the 4th bonding agent 24 to form the 4th step (S90) of arranging brush silk 64; With the second fabric 42, weave and be wound around the described the 4th outside of arranging brush silk 64, to manufacture the step (S100) of many brush silks 60.
In the present embodiment, the material of described the 3rd bonding agent 23 and described the 4th bonding agent 24 is identical with the material of described the first bonding agent 21.
In the present embodiment, the material of described the 3rd grinding agent 13 is identical with the material of described the first grinding agent 11.
It is spiral-shaped etc. that first order in described S60 step brush silk 61 can configure a plurality of brushes silks or be twisted into parallel mode.
Same with the process of manufacturing described brush silk, described S70 step by coating adhesive, absorption fixed abrasive, the process of impregnate fabric after coating adhesive again, one brushes thread 60 thereby a plurality of brushes silks 50 can be manufactured to S100 step more.
Compare with single brush silk 50, many brush silks 60 of manufacturing by above-mentioned steps have more excellent durability, and can more independently adjust the % by weight of contained grinding agent.
In the present embodiment, the material of described the second fabric 42 is identical with the material of described the first fabric 41, but in order to strengthen durability and elasticity, also can use other materials.
Below, other formations of the present embodiment are identical with formation and the method for described the first embodiment with method, at this, omit detailed explanation.
Above, with reference to embodiment, be illustrated, still, in thought of the present invention and scope that those skilled in the art records in not departing from claim, can carry out different modifications and change to the present invention.

Claims (9)

1. brush a manufacture method for silk, by by extruding and manufacture after synthetic resin and grinding agent mixing, it is characterized in that, comprising:
Step (S10), the first precursor (51) that contains synthetic resin (14) and the first grinding agent (11) is extruded, wherein, with respect to the weight of described the first precursor (51) after extruding, described the first grinding agent (11) contains 1 % by weight to 30 % by weight;
Step (S20), is coated with the first bonding agent (21) to manufacture the second precursor (52) at the outer surface of described the first precursor (51);
Step (S30), fixes the second grinding agent (12) to manufacture the 3rd precursor (53) at the outer surface that is coated with second precursor (52) of described the first bonding agent (21).
2. the manufacture method of brush silk according to claim 1, is characterized in that, comprising:
Step (S40), the 3rd precursor (53) surface-coated the second bonding agent (22) in described S30 step is to manufacture the 4th precursor (54);
Step (S50), before described the second bonding agent (22) solidifies, is wound around the outer surface of described the 4th precursor (54) with fabric (41), so that described the 4th precursor (54) impregnated in described the second bonding agent (22).
3. the manufacture method of brush silk according to claim 1, is characterized in that,
Described the first grinding agent (11) comprises at least one in diamond dust, hydrocarbon powder, alumina powder, iron powder.
4. the manufacture method of brush silk according to claim 1, is characterized in that,
Also be included in described S10 step and extrude the step after described the first precursor (51), the first precursor (51) being stretched.
5. the manufacture method of brush silk according to claim 2, is characterized in that,
With respect to the weight of the brush silk (50) of manufacturing by described S50 step, the gross weight % of described the first grinding agent (11) and described the second grinding agent (12) is 20 % by weight to 90 % by weight.
6. the manufacture method of brush silk according to claim 2, is characterized in that,
At least one in described the first bonding agent (21) and described the second bonding agent (22) has the material identical with described synthetic resin (14).
7. a manufacture method for the silk of brush more than, is characterized in that, comprising:
Step (S60), a plurality of brush silks (50) that the method by described in any one in claim 1 to 6 is manufactured are arranged, to form first order brush silk (61);
Step (S70), is coated with the 3rd bonding agent (23) to cover the mode of each brush silk (50) of described first order brush silk (61) completely, thereby forms second order brush silk (62);
Step (S80), upper at the 3rd bonding agent (23) of coating on described second order brush silk (62), be coated with and adsorb the 3rd grinding agent (13), thereby form the 3rd, arrange brush silk (63);
Step (S90), has the described the 3rd of the 3rd grinding agent (13) to arrange the upper coating of brush silk (63) the 4th bonding agent (24) in absorption and arranges brush silk (64) to form the 4th;
Step (S100), weaves and is wound around the described the 4th outside of arranging brush silk (64) with the second fabric (42), thereby manufactures many brush silks (60).
8. one kind, brush silk, it is manufactured by method claimed in claim 7 more.
9. brush silk for one kind, it is manufactured by the method described in any one in claim 1 to 6.
CN201380002010.2A 2013-02-05 2013-11-11 Brush filament, many brush filaments and its manufacture method Active CN104093526B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
KR1020130013022A KR101253248B1 (en) 2013-02-05 2013-02-05 Brush, milti-brush and manufacturing method of the same
KR10-2013-0013022 2013-02-05
PCT/KR2013/010164 WO2014123295A1 (en) 2013-02-05 2013-11-11 Brush threads, multi-brush threads and manufacturing method therefor

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CN104093526A true CN104093526A (en) 2014-10-08
CN104093526B CN104093526B (en) 2017-07-07

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JP (1) JP5877912B2 (en)
KR (1) KR101253248B1 (en)
CN (1) CN104093526B (en)
WO (1) WO2014123295A1 (en)

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KR101587415B1 (en) * 2014-05-29 2016-01-22 주식회사 마산 Brush, milti-brush and manufacturing method of the same

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JP2009202298A (en) * 2008-02-28 2009-09-10 Toray Monofilament Co Ltd Brush bristle material for polishing, its manufacturing method and polishing brush

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CN108030228A (en) * 2017-11-29 2018-05-15 浙江大学 A kind of tartar-removing toothbrush silk and preparation method thereof

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CN104093526B (en) 2017-07-07
JP5877912B2 (en) 2016-03-08

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