CN104082338B - A kind of sanitizing composition and application thereof and the method utilizing described sanitizing composition to prepare disinfectant - Google Patents
A kind of sanitizing composition and application thereof and the method utilizing described sanitizing composition to prepare disinfectant Download PDFInfo
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- CN104082338B CN104082338B CN201410333786.9A CN201410333786A CN104082338B CN 104082338 B CN104082338 B CN 104082338B CN 201410333786 A CN201410333786 A CN 201410333786A CN 104082338 B CN104082338 B CN 104082338B
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- ammonium
- sanitizing composition
- sodium
- disinfectant
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- 239000000203 mixture Substances 0.000 title claims abstract description 102
- 239000000645 desinfectant Substances 0.000 title claims abstract description 99
- 238000011012 sanitization Methods 0.000 title claims abstract description 53
- 238000000034 method Methods 0.000 title claims abstract description 18
- 239000000463 material Substances 0.000 claims abstract description 44
- 238000004659 sterilization and disinfection Methods 0.000 claims abstract description 21
- 239000002994 raw material Substances 0.000 claims abstract description 18
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 17
- 150000001875 compounds Chemical class 0.000 claims abstract description 17
- 239000011593 sulfur Substances 0.000 claims abstract description 17
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 17
- SXDBWCPKPHAZSM-UHFFFAOYSA-N bromic acid Chemical compound OBr(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-N 0.000 claims abstract description 16
- SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Inorganic materials [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 claims abstract description 13
- 238000002360 preparation method Methods 0.000 claims abstract description 11
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 84
- XUXNAKZDHHEHPC-UHFFFAOYSA-M sodium bromate Chemical group [Na+].[O-]Br(=O)=O XUXNAKZDHHEHPC-UHFFFAOYSA-M 0.000 claims description 51
- 235000010265 sodium sulphite Nutrition 0.000 claims description 42
- 238000003756 stirring Methods 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- BEOODBYKENEKIC-UHFFFAOYSA-N azanium;bromate Chemical compound [NH4+].[O-]Br(=O)=O BEOODBYKENEKIC-UHFFFAOYSA-N 0.000 claims description 19
- 239000003795 chemical substances by application Substances 0.000 claims description 19
- UYJXRRSPUVSSMN-UHFFFAOYSA-P ammonium sulfide Chemical compound [NH4+].[NH4+].[S-2] UYJXRRSPUVSSMN-UHFFFAOYSA-P 0.000 claims description 17
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 claims description 16
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 claims description 16
- 230000001954 sterilising effect Effects 0.000 claims description 16
- 239000007864 aqueous solution Substances 0.000 claims description 12
- 239000000243 solution Substances 0.000 claims description 10
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 5
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052794 bromium Inorganic materials 0.000 claims description 5
- 239000002574 poison Substances 0.000 claims description 3
- 231100000614 poison Toxicity 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 239000007938 effervescent tablet Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims 1
- 150000003464 sulfur compounds Chemical class 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 6
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 230000000680 avirulence Effects 0.000 abstract 1
- 230000002147 killing effect Effects 0.000 description 63
- 244000063299 Bacillus subtilis Species 0.000 description 27
- 235000014469 Bacillus subtilis Nutrition 0.000 description 27
- 241000222122 Candida albicans Species 0.000 description 24
- 241000588724 Escherichia coli Species 0.000 description 24
- 229940095731 candida albicans Drugs 0.000 description 24
- 241000191967 Staphylococcus aureus Species 0.000 description 23
- 239000012895 dilution Substances 0.000 description 22
- 238000010790 dilution Methods 0.000 description 22
- 239000011550 stock solution Substances 0.000 description 22
- 241000726221 Gemma Species 0.000 description 16
- 241000193830 Bacillus <bacterium> Species 0.000 description 7
- XWNSFEAWWGGSKJ-UHFFFAOYSA-N 4-acetyl-4-methylheptanedinitrile Chemical compound N#CCCC(C)(C(=O)C)CCC#N XWNSFEAWWGGSKJ-UHFFFAOYSA-N 0.000 description 5
- 239000004153 Potassium bromate Substances 0.000 description 5
- 229940094037 potassium bromate Drugs 0.000 description 5
- 235000019396 potassium bromate Nutrition 0.000 description 5
- AOSFMYBATFLTAQ-UHFFFAOYSA-N 1-amino-3-(benzimidazol-1-yl)propan-2-ol Chemical compound C1=CC=C2N(CC(O)CN)C=NC2=C1 AOSFMYBATFLTAQ-UHFFFAOYSA-N 0.000 description 4
- DJEHXEMURTVAOE-UHFFFAOYSA-M potassium bisulfite Chemical compound [K+].OS([O-])=O DJEHXEMURTVAOE-UHFFFAOYSA-M 0.000 description 4
- 239000007788 liquid Substances 0.000 description 3
- 230000000149 penetrating effect Effects 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- 241001478240 Coccus Species 0.000 description 1
- 208000035473 Communicable disease Diseases 0.000 description 1
- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- FGRVOLIFQGXPCT-UHFFFAOYSA-L dipotassium;dioxido-oxo-sulfanylidene-$l^{6}-sulfane Chemical compound [K+].[K+].[O-]S([O-])(=O)=S FGRVOLIFQGXPCT-UHFFFAOYSA-L 0.000 description 1
- FANSKVBLGRZAQA-UHFFFAOYSA-M dipotassium;sulfanide Chemical compound [SH-].[K+].[K+] FANSKVBLGRZAQA-UHFFFAOYSA-M 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 230000003211 malignant effect Effects 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 1
- 235000019252 potassium sulphite Nutrition 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 230000035943 smell Effects 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of sanitizing composition and application thereof and the method utilizing described sanitizing composition to prepare disinfectant, it is made up of component A and B component, described component A amount percentage ratio of shared material in sanitizing composition is M, M is more than or equal to 25% and less than or equal to 75%, described B component amount percentage ratio of shared material in sanitizing composition is N, N=1 M；Described component A is bromate, and described B component is reproducibility sulfur-containing compound.The invention provides a kind of have good decontaminating effect, raw material is easy to get, cheap disinfectant and preparation method thereof, the contained disinfectant of the present invention has broad-spectrum, the most efficiently；Disinfectant good fluidity, temperature applicable range is wide, uses safety, and have no irritating odor generation, less to metal protection, and avirulence remains, and does not cause secondary pollution, is suitable for carrying out disinfection environment, air and thing table.
Description
Technical field
The present invention and chemical industry clean field, disappear described in particularly a kind of sanitizing composition and application thereof and utilization
The method that poison compositions prepares disinfectant.
Background technology
Disinfectant is for killing the pathogen on communication media so that it is reach innoxious requirement.And by cause of disease
It is people's a kind of methods of controlling infectious disease that body is killed outside human body.Along with urban air pollution more and more
Seriously, dirty air has become the hotbed of various malignant bacteria, the gradually aggravation of other environmental pollutions in addition,
Various objects carry the kind of pathogenic bacterium and quantity is more and more, and this just makes people get in daily life
To use disinfectant manyly.But in existing commercially available disinfectant, or strong impulse can be volatilized
Property abnormal smells from the patient and poor stability, action effect are poor, such as Bath disinfectant, or bactericidal effect is inconspicuous or
Poor stability, and in order to use disinfectant in different environment, people are often required to standby several money and disappear
Toxic agent.Along with growth in the living standard, people are badly in need of the broad-spectrum disinfectant of a kind of full effect, can be efficient
Sterilization, low cost, and use safety, not residual toxicity, non-volatile go out penetrating odor, range
Wide disinfectant.
Summary of the invention
For the deficiencies in the prior art, it is an object of the invention to provide a kind of raw material be easy to get, with low cost,
Disinfection Effect is good, use is safe, do not produce unpleasant penetrating odor, do not produce toxic residue and will not
Sanitizing composition causing secondary pollution and application thereof and utilize described sanitizing composition to prepare the side of disinfectant
Method.
The technical scheme is that and be achieved in that: a kind of sanitizing composition, by component A and B component
Composition, described component A amount percentage ratio of shared material in sanitizing composition is that M, M are more than or equal to
25% and less than or equal to 75%, described B component amount percentage ratio of shared material in sanitizing composition is N,
N=1-M；Described component A is bromate, and described B component is reproducibility sulfur-containing compound.
Above-mentioned sanitizing composition, described bromate is the one or in sodium bromate, Potassium bromate. and bromic acid ammonium
More than Zhong.
Above-mentioned sanitizing composition, described reproducibility sulfur-containing compound be sodium sulfite, Potassium acid sulfite,
Ammonium bisulfite, sodium sulfite, potassium sulfite, ammonium sulfite, sodium hydrosulfite, sodium thiosulfate, sulfur generation
One or more in ammonium sulfate, Potassium hyposulfite., Potassium monosulfide., sodium sulfide and ammonium sulfide.
Above-mentioned sanitizing composition, described bromate is sodium bromate and the mixture of bromic acid ammonium, sodium bromate and bromine
The ratio of the amount of the material of acid ammonium is 1:2；Described reproducibility sulfur-containing compound be sodium sulfite, sodium hydrosulfite,
Ammonium hyposulfite. and the mixture of ammonium sulfide, sodium sulfite, sodium hydrosulfite, Ammonium hyposulfite. and ammonium sulfide
The ratio of the amount of material is 1:3:1.3:0.8.
The method utilizing above-mentioned sanitizing composition to prepare disinfectant, comprises the steps:
(1) raw material prepares: the material in sanitizing composition according to described component A and described B component
Amount proportioning weigh described component A respectively and described B component is standby, and to measure weight be described component A
Standby with the water of 10～100000 times of described B component weight sum；
(2) load weighted described component A is placed directly in described B component together with mix；
(3) mixture of mixed described component A and described B component composition joined measure
In water, after stirring, i.e. obtain disinfectant.
Utilize the method that above-mentioned sanitizing composition prepares disinfectant, the preparation method of described disinfectant include as
Lower step:
A () raw material prepares: the material in sanitizing composition according to described component A and described B component
Amount proportioning weigh described component A respectively and described B component is standby, and to measure weight be described component A
Standby with the water of 10～100000 times of described B component weight sum；
B any one in load weighted described component A and described both B component is joined and measures by ()
In good water, then stir；
C another in load weighted described component A and described both B component is added step by () again
B, in () in last obtained solution, can be sterilized after stirring agent.
Utilize the method that above-mentioned sanitizing composition prepares disinfectant, the preparation method of described disinfectant include as
Lower step:
(I) raw material prepares: the material in sanitizing composition according to described component A and described B component
Amount proportioning weighs described component A and described B component is standby；
(II) load weighted described component A is configured to the concentration aqueous solution more than or equal to 10mg/L,
And load weighted described B component is also configured to concentration more than or equal to 10mg/L aqueous solution；
(III) two kinds of aqueous solutions obtained in step (II) are directly mixed, after stirring
Be sterilized agent.
Utilize the method that above-mentioned sanitizing composition prepares disinfectant, the preparation method of described disinfectant include as
Lower step:
I () raw material prepares: the material in sanitizing composition according to described component A and described B component
Amount proportioning weigh described component A and described B component standby；
(ii) load weighted described component A is configured to the concentration aqueous solution more than or equal to 10mg/L,
And load weighted described B component is also configured to the concentration aqueous solution more than or equal to 10mg/L；
(iii) two kinds of aqueous solutions obtained in step (ii) are separately added into or are sprayed to same to be washed
Sterilised object or environment can be sterilized agent.
Utilize the method that above-mentioned sanitizing composition prepares disinfectant, the preparation method of described disinfectant include as
Lower step:
1. according to described component A and described B component, the amount proportioning of the material in sanitizing composition weighs respectively
Described component A and described B component are standby；
2. make effervescent tablet after load weighted described component A and described B component being mixed, obtain sterilization
Agent.
The purposes of above-mentioned sanitizing composition, described sanitizing composition is used for sterilizing.
The invention has the beneficial effects as follows: the invention provides one there is good decontaminating effect, raw material is easy to get,
Cheap and operate easy sanitizing composition and disinfectant preparation method, the contained disinfectant of the present invention is not
Only there is broad-spectrum, and the most efficient；Good fluidity, temperature applicable range is wide, uses safety,
Do not produce unpleasant penetrating odor, less to metal protection, do not produce residual toxicity, do not cause two
Secondary pollution, is suitable for carrying out disinfection environment, air and thing table.
It is cheap and easy to get that the present invention has raw material, and preparation uses technique simple, the raw material of use be bromate and
Reproducibility sulfur-containing compound, utilizes the efficient disinfection composition that redox reaction produces, and is a kind of simple
The disinfectant of efficient wide spectrum is high, effective to disinfection efficiencies such as antibacterial, virus and spore；Make
Disinfectant good fluidity, temperature applicable range is wide, can be used for various water mists decontaminating apparatus.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in further detail.
Embodiment 1
In the present embodiment, described component A selects sodium bromate, and described B component selects sodium sulfite, claims
The sodium bromate of amount 15.1g (0.1mol) and the sodium sulfite of 10.4g (0.1mol) are standby, will weigh
Good sodium bromate mixes together with being placed directly in sodium sulfite, will mixed described component A and
The mixture of described B component composition is dissolved in the water of 1L and stirs and is configured to disinfectant stock solution.Take
The dilution of different multiples is carried out with some parts of disinfectant stock solutions and to it, then molten by the disinfectant after dilution
Liquid is respectively to escherichia coli, staphylococcus aureus, Candida albicans and bacillus subtilis black variety gemma
Carrying out killing test, its result is as follows:
It is analyzed it can be seen that with the sterilization prepared in the present embodiment according to data in above-mentioned table
When escherichia coli, staphylococcus aureus, Candida albicans are killed by agent, decontaminant concentration is the highest,
Reach required time during same killing effect the shortest；By the disinfectant configured in the present embodiment to hay
When bacillus var. niger spores is killed, killing the time the longest, killing effect is the best, and disinfectant
Concentration the highest, same kill in the time, killing effect is the best, when decontaminant concentration is that 3000mg/L (presses
Sodium bromate concentration calculates) time, within five minutes, bacillus subtilis black spore all can be killed.
Embodiment 2
In the present embodiment, described component A selects Potassium bromate., and described B component selects sodium sulfite, claims
The Potassium bromate. of amount 16.7g (0.1mol) and the sodium sulfite of 10.4g (0.1mol) are standby, will weigh
Good Potassium bromate. is dissolved in the water of 1L and stirs, and then adds sodium sulfite and stirs all
Even, it is configured to disinfectant stock solution.Take some parts of disinfectant stock solutions and it carried out the dilution of different multiples,
Then with the disinfectant solution after dilution respectively to escherichia coli, staphylococcus aureus, Candida albicans
Carrying out killing test with bacillus subtilis black variety gemma, its result is as follows:
It is analyzed it can be seen that with the sterilization prepared in the present embodiment according to data in above-mentioned table
When escherichia coli, staphylococcus aureus, Candida albicans are killed by agent, decontaminant concentration is the highest,
Reach required time during same killing effect the shortest；By the disinfectant configured in the present embodiment to hay
When bacillus var. niger spores is killed, killing the time the longest, killing effect is the best, and disinfectant
Concentration the highest, same kill in the time, killing effect is the best, when decontaminant concentration is that 3200mg/L (presses
Potassium bromate. concentration calculates) time, within five minutes, bacillus subtilis black spore all can be killed.
Embodiment 3
In the present embodiment, described component A selects bromic acid ammonium, and described B component selects sodium sulfite, claims
The bromic acid ammonium of amount 14.5g (0.1mol) and the sodium sulfite of 10.4g (0.1mol) are standby, will weigh
Good bromic acid ammonium mixes together with being placed directly in sodium sulfite, will mixed described component A and
The mixture of described B component composition is dissolved in the water of 1L and stirs and is configured to disinfectant stock solution.Take
The dilution of different multiples is carried out with some parts of disinfectant stock solutions and to it, then molten by the disinfectant after dilution
Liquid is respectively to escherichia coli, staphylococcus aureus, Candida albicans and bacillus subtilis black variety gemma
Carrying out killing test, its result is as follows:
It is analyzed it can be seen that with the sterilization prepared in the present embodiment according to data in above-mentioned table
When escherichia coli, staphylococcus aureus, Candida albicans are killed by agent, decontaminant concentration is the highest,
Reach required time during same killing effect the shortest；By the disinfectant configured in the present embodiment to hay
When bacillus var. niger spores is killed, killing the time the longest, killing effect is the best, and disinfectant
Concentration the highest, same kill in the time, killing effect is the best, when decontaminant concentration is that 3000mg/L (presses
Bromic acid ammonium concentration calculates) time, within five minutes, bacillus subtilis black spore all can be killed.
Embodiment 4
In the present embodiment, described component A selects sodium bromate, and described B component selects Potassium acid sulfite, claims
The sodium bromate of amount 15.1g (0.1mol) and the Potassium acid sulfite of 12g (0.1mol) are standby, by weighing well
Sodium bromate be placed directly in Potassium acid sulfite together with mix, by mixed described component A and institute
The mixture stating B component composition is dissolved in the water of 1L and stirs and is configured to disinfectant stock solution.Take
Some parts of disinfectant stock solutions also carry out the dilution of different multiples, then with the disinfectant solution after dilution to it
Respectively escherichia coli, staphylococcus aureus, Candida albicans and bacillus subtilis black variety gemma are entered
Row killing test, its result is as follows:
It is analyzed it can be seen that with the sterilization prepared in the present embodiment according to data in above-mentioned table
When escherichia coli, staphylococcus aureus, Candida albicans are killed by agent, decontaminant concentration is the highest,
Reach required time during same killing effect the shortest；By the disinfectant configured in the present embodiment to hay
When bacillus var. niger spores is killed, killing the time the longest, killing effect is the best, and disinfectant
Concentration the highest, same kill in the time, killing effect is the best, when decontaminant concentration is that 3000mg/L (presses
Sodium bromate concentration calculates) time, within five minutes, bacillus subtilis black spore all can be killed.
Embodiment 5
In the present embodiment, described component A selects sodium bromate, and described B component selects ammonium bisulfite, claims
The sodium bromate of amount 15.1g (0.1mol) and the ammonium bisulfite of 9.8g (0.1mol) are standby, will weigh
Good sodium bromate mixes together with being placed directly in ammonium bisulfite, will mixed described component A and
The mixture of described B component composition is dissolved in the water of 1L and stirs and is configured to disinfectant stock solution.Take
The dilution of different multiples is carried out with some parts of disinfectant stock solutions and to it, then molten by the disinfectant after dilution
Liquid is respectively to escherichia coli, staphylococcus aureus, Candida albicans and bacillus subtilis black variety gemma
Carrying out killing test, its result is as follows:
It is analyzed it can be seen that with the sterilization prepared in the present embodiment according to data in above-mentioned table
When escherichia coli, staphylococcus aureus, Candida albicans are killed by agent, decontaminant concentration is the highest,
Reach required time during same killing effect the shortest；By the disinfectant configured in the present embodiment to hay
When bacillus var. niger spores is killed, killing the time the longest, killing effect is the best, and disinfectant
Concentration the highest, same kill in the time, killing effect is the best, when decontaminant concentration is that 3000mg/L (presses
Sodium bromate concentration calculates) time, within five minutes, bacillus subtilis black spore all can be killed.
Embodiment 6
In the present embodiment, described component A selects sodium bromate, and described B component selects sodium sulfite, weighs
The sodium bromate of 15.1g (0.1mol) and the sodium sulfite of 12.6g (0.1mol) are standby, by load weighted
Sodium bromate mixes together with being placed directly in sodium sulfite, by mixed described component A and described B
The mixture of component composition is dissolved in the water of 1L and stirs and is configured to disinfectant stock solution.Take some
Part disinfectant stock solution also carries out the dilution of different multiples, then with the disinfectant solution after dilution respectively to it
Escherichia coli, staphylococcus aureus, Candida albicans and bacillus subtilis black variety gemma are killed
Going out experiment, its result is as follows:
It is analyzed it can be seen that with the sterilization prepared in the present embodiment according to data in above-mentioned table
When escherichia coli, staphylococcus aureus, Candida albicans are killed by agent, decontaminant concentration is the highest,
Reach required time during same killing effect the shortest；By the disinfectant configured in the present embodiment to hay
When bacillus var. niger spores is killed, killing the time the longest, killing effect is the best, and disinfectant
Concentration the highest, same kill in the time, killing effect is the best, when decontaminant concentration is that 3000mg/L (presses
Sodium bromate concentration calculates) time, within five minutes, bacillus subtilis black spore all can be killed.
Embodiment 7
In the present embodiment, described component A selects sodium bromate, and described B component selects sodium sulfite, claims
The sodium bromate of amount 15.1g (0.1mol) and 3.5g (0.0337mol, the amount percentage ratio of material is 25.2%)
Sodium sulfite standby, load weighted sodium bromate is placed directly in sodium sulfite together with mix,
The mixture of mixed described component A with described B component composition is dissolved in the water of 1L and stirs all
Even it is configured to disinfectant stock solution.Take some parts of disinfectant stock solutions and it carried out the dilution of different multiples,
Then with the disinfectant solution after dilution respectively to escherichia coli, staphylococcus aureus, Candida albicans
Carrying out killing test with bacillus subtilis black variety gemma, its result is as follows:
It is analyzed it can be seen that with the sterilization prepared in the present embodiment according to data in above-mentioned table
When escherichia coli, staphylococcus aureus, Candida albicans are killed by agent, decontaminant concentration is the highest,
Reach required time during same killing effect the shortest, compared with Example 1, (press in decontaminant concentration
Sodium bromate concentration calculates) it is respectively in the case of 750mg/L, 60mg/L, reach same killing effect institute
The time needed is elongated；By the disinfectant configured in the present embodiment, bacillus subtilis black variety gemma is entered
Row when killing, kills the time the longest, and killing effect is the best, and the concentration of disinfectant is the highest, same kills
Going out in the time, killing effect is the best, when decontaminant concentration is 3000mg/L (calculating by sodium bromate concentration)
Time, within five minutes, bacillus subtilis black spore all can be killed.
Embodiment 8
In the present embodiment, described component A selects sodium bromate, and described B component selects sodium sulfite, claims
The sodium bromate of amount 15.1g (0.1mol) and 7g (0.0673mol, the amount percentage ratio of material is 40.23%)
Sodium sulfite standby, load weighted sodium bromate is placed directly in sodium sulfite together with mix,
The mixture of mixed described component A with described B component composition is dissolved in the water of 1L and stirs all
Even it is configured to disinfectant stock solution.Take some parts of disinfectant stock solutions and it carried out the dilution of different multiples,
Then with the disinfectant solution after dilution respectively to escherichia coli, staphylococcus aureus, Candida albicans
Carrying out killing test with bacillus subtilis black variety gemma, its result is as follows:
It is analyzed it can be seen that with the sterilization prepared in the present embodiment according to data in above-mentioned table
When escherichia coli, staphylococcus aureus, Candida albicans are killed by agent, decontaminant concentration is the highest,
Reach required time during same killing effect the shortest, compared with Example 1, (press in decontaminant concentration
Sodium bromate concentration calculates) it is respectively in the case of 750mg/L, 60mg/L, reach same killing effect institute
The time needed is elongated；By the disinfectant configured in the present embodiment, bacillus subtilis black variety gemma is entered
Row when killing, kills the time the longest, and killing effect is the best, and the concentration of disinfectant is the highest, same kills
Going out in the time, killing effect is the best, when decontaminant concentration is 3000mg/L (calculating by sodium bromate concentration)
Time, within five minutes, bacillus subtilis black spore all can be killed.
Embodiment 9
In the present embodiment, described component A selects sodium bromate, and described B component selects sodium sulfite, claims
The sodium bromate of amount 7.5g (0.0497mol, the amount percentage ratio of material is 33.2%) and 10.5g (0.1mol)
Sodium sulfite standby, load weighted sodium bromate is placed directly in sodium sulfite together with mix,
The mixture of mixed described component A with described B component composition is dissolved in the water of 1L and stirs all
Even it is configured to disinfectant stock solution.Take some parts of disinfectant stock solutions and it carried out the dilution of different multiples,
Then with the disinfectant solution after dilution respectively to escherichia coli, staphylococcus aureus, Candida albicans
Carrying out killing test with bacillus subtilis black variety gemma, its result is as follows:
It is analyzed it can be seen that with the sterilization prepared in the present embodiment according to data in above-mentioned table
When escherichia coli, staphylococcus aureus, Candida albicans are killed by agent, decontaminant concentration is the highest,
Reach required time during same killing effect the shortest, compared with Example 1, (press in decontaminant concentration
Sodium bromate concentration calculates) it is respectively in the case of 750mg/L, 60mg/L, reach same killing effect institute
The time needed is elongated；By the disinfectant configured in the present embodiment, bacillus subtilis black variety gemma is entered
Row when killing, kills the time the longest, and killing effect is the best, and the concentration of disinfectant is the highest, same kills
Going out in the time, killing effect is the best, when decontaminant concentration is 3000mg/L (calculating by sodium bromate concentration)
Time, within five minutes, bacillus subtilis black spore all can be killed.
Embodiment 10
In the present embodiment, described component A selects sodium bromate, and described B component selects sodium sulfite, claims
The sodium bromate of amount 10g (0.0662mol, the amount percentage ratio of material is 39.84%) and 10.5g (0.1mol)
Sodium sulfite standby, load weighted sodium bromate is placed directly in sodium sulfite together with mix,
The mixture of mixed described component A with described B component composition is dissolved in the water of 1L and stirs all
Even it is configured to disinfectant stock solution.Take some parts of disinfectant stock solutions and it carried out the dilution of different multiples,
Then with the disinfectant solution after dilution respectively to escherichia coli, staphylococcus aureus, Candida albicans
Carrying out killing test with bacillus subtilis black variety gemma, its result is as follows:
It is analyzed it can be seen that with the sterilization prepared in the present embodiment according to data in above-mentioned table
When escherichia coli, staphylococcus aureus, Candida albicans are killed by agent, decontaminant concentration is the highest,
Reach required time during same killing effect the shortest, compared with Example 1, (press in decontaminant concentration
Sodium bromate concentration calculates) it is respectively in the case of 750mg/L, 60mg/L, reach same killing effect institute
The time needed is elongated；By the disinfectant configured in the present embodiment, bacillus subtilis black variety gemma is entered
Row when killing, kills the time the longest, and killing effect is the best, and the concentration of disinfectant is the highest, same kills
Going out in the time, killing effect is the best, when decontaminant concentration is 3000mg/L (calculating by sodium bromate concentration)
Time, within five minutes, bacillus subtilis black spore all can be killed.
Embodiment 11
In the present embodiment, described component A selects sodium bromate and the mixture of bromic acid ammonium, weighs bromic acid respectively
Sodium 6.0g (0.04mol), bromic acid ammonium 11.7g (0.08mol)；Described B component selection sodium sulfite,
The mixture of sodium hydrosulfite, Ammonium hyposulfite. and ammonium sulfide, weighing sodium sulfite 2.5g (0.02mol) respectively,
Sodium hydrosulfite 10.4g (0.06mol), Ammonium hyposulfite. 3.9g (0.026mol) and ammonium sulfide 1.1g
(0.016mol)。
First load weighted described component A it is dissolved in the water of 1L and stirs, then adding institute
State B component and stir, being configured to disinfectant stock solution.Take some parts of disinfectant stock solutions and it is entered
The dilution of row different multiples, then with the disinfectant solution after dilution respectively to escherichia coli, golden yellow Portugal
Grape coccus, Candida albicans and bacillus subtilis black variety gemma carry out killing test, and its result is as follows:
It is analyzed it can be seen that with the sterilization prepared in the present embodiment according to data in above-mentioned table
When escherichia coli, staphylococcus aureus, Candida albicans are killed by agent, decontaminant concentration is the highest,
Reach required time during same killing effect the shortest；By the disinfectant configured in the present embodiment to hay
When bacillus var. niger spores is killed, killing the time the longest, killing effect is the best, and disinfectant
Concentration the highest, same kill in the time, killing effect is the best, when decontaminant concentration is that 1000mg/L (presses
Solute concentration calculates) time, within three minutes, bacillus subtilis black spore all can be killed.
Find according to the date comprision in embodiment 1-6 and embodiment 7～10, by the present invention
When escherichia coli, staphylococcus aureus and Candida albicans are killed by contained disinfectant, disinfectant
Concentration is more up to the shortest to required time during same killing effect, and when decontaminant concentration is respectively
Disinfectant in the case of 750mg/L, 60mg/L, compared with embodiment 1-6, in embodiment 7～10
To escherichia coli, Staphylococcus aureus in the case of decontaminant concentration is respectively 750mg/L, 60mg/L
When bacterium and Candida albicans kill the killing effect reaching to kill logarithm value more than 5, required when killing
Between elongated, and the sterilization when bacillus subtilis black variety gemma is killed, in embodiment 7～10
There is not significant change in agent required time when reaching same or close killing effect.And embodiment 11
Can be with method phase with the contrast of embodiment 1-10, in embodiment 11, the Disinfection Effect of disinfectant substantially entirety is better than
Embodiment 1-10.
Above-described embodiment is only for clearly demonstrating the invention example, and not to this
The restriction of bright creation detailed description of the invention.For those of ordinary skill in the field, state upper
Can also make other changes in different forms on the basis of bright.Here without also cannot be to all
Embodiment give exhaustive.All extended out within the spirit and principles in the present invention any aobvious and easy
The change seen or variation still in the invention scope of the claims among.
Claims (7)
1. a sanitizing composition, it is characterised in that be made up of component A and B component, described component A is disappearing
In poison compositions, the amount percentage ratio of shared material is that M, M more than or equal to 25% and are less than or equal to 75%,
Described B component amount percentage ratio of shared material in sanitizing composition is N, N=1-M；Described component A
For bromate, described B component is reproducibility sulfur-containing compound；Described bromate is sodium bromate and bromic acid
The mixture of ammonium, the ratio of the amount of the material of sodium bromate and bromic acid ammonium is 1:2；Described reproducibility Containing Sulfur
Compound is the mixture of sodium sulfite, sodium hydrosulfite, Ammonium hyposulfite. and ammonium sulfide, sodium sulfite, guarantor
The ratio of the amount of the material of danger powder, Ammonium hyposulfite. and ammonium sulfide is 1:3:1.3:0.8.
2. utilize the method that the sanitizing composition described in claim 1 prepares disinfectant, it is characterised in that include
Following steps:
(1) raw material prepares: raw material is made up of component A and B component, and described component A is at sanitizing composition
The amount percentage ratio of material shared by is that M, M more than or equal to 25% and are less than or equal to 75%, described B
Component amount percentage ratio of shared material in sanitizing composition is N, N=1-M；Described component A is bromine
Hydrochlorate, described B component is reproducibility sulfur-containing compound；Described bromate is sodium bromate and bromic acid ammonium
Mixture, the ratio of the amount of the material of sodium bromate and bromic acid ammonium is 1:2；Described reproducibility sulfur-containing compound
For the mixture of sodium sulfite, sodium hydrosulfite, Ammonium hyposulfite. and ammonium sulfide, sodium sulfite, sodium hydrosulfite,
The ratio of the amount of the material of Ammonium hyposulfite. and ammonium sulfide is 1:3:1.3:0.8；According to described component A and
The amount proportioning of described B component material in sanitizing composition weighs described component A and described B respectively
Component is standby, and measure that weight is described component A and described B component weight sum 10～100000
Water again is standby；
(2) load weighted described component A is placed directly in described B component together with mix；
(3) mixture of mixed described component A and described B component composition joined measure
In water, after stirring, i.e. obtain disinfectant.
3. utilize the method that the sanitizing composition described in claim 1 prepares disinfectant, it is characterised in that described
The preparation method of disinfectant comprises the steps:
A () raw material prepares: raw material is made up of component A and B component, and described component A is at sanitizing composition
The amount percentage ratio of material shared by is that M, M more than or equal to 25% and are less than or equal to 75%, described B
Component amount percentage ratio of shared material in sanitizing composition is N, N=1-M；Described component A is bromine
Hydrochlorate, described B component is reproducibility sulfur-containing compound；Described bromate is sodium bromate and bromic acid ammonium
Mixture, the ratio of the amount of the material of sodium bromate and bromic acid ammonium is 1:2；Described reproducibility sulfur-containing compound
For the mixture of sodium sulfite, sodium hydrosulfite, Ammonium hyposulfite. and ammonium sulfide, sodium sulfite, sodium hydrosulfite,
The ratio of the amount of the material of Ammonium hyposulfite. and ammonium sulfide is 1:3:1.3:0.8；According to described component A and
The amount proportioning of described B component material in sanitizing composition weighs described component A and described B respectively
Component is standby, and measure that weight is described component A and described B component weight sum 10～100000
Water again is standby；
B any one in load weighted described component A and described both B component is joined and measures by ()
In good water, then stir；
C another in load weighted described component A and described both B component is added step by () again
B, in () in last obtained solution, can be sterilized after stirring agent.
4. utilize the method that the sanitizing composition described in claim 1 prepares disinfectant, it is characterised in that described
The preparation method of disinfectant comprises the steps:
(I) raw material prepares: raw material is made up of component A and B component, and described component A is at sanitizing composition
The amount percentage ratio of material shared by is that M, M more than or equal to 25% and are less than or equal to 75%, described B
Component amount percentage ratio of shared material in sanitizing composition is N, N=1-M；Described component A is bromine
Hydrochlorate, described B component is reproducibility sulfur-containing compound；Described bromate is sodium bromate and bromic acid ammonium
Mixture, the ratio of the amount of the material of sodium bromate and bromic acid ammonium is 1:2；Described reproducibility sulfur-containing compound
For the mixture of sodium sulfite, sodium hydrosulfite, Ammonium hyposulfite. and ammonium sulfide, sodium sulfite, sodium hydrosulfite,
The ratio of the amount of the material of Ammonium hyposulfite. and ammonium sulfide is 1:3:1.3:0.8；According to described component A and
The amount proportioning of described B component material in sanitizing composition weighs described component A and described B component
Standby；
(II) load weighted described component A is configured to the concentration aqueous solution more than or equal to 10mg/L,
And load weighted described B component is also configured to concentration more than or equal to 10mg/L aqueous solution；
(III) two kinds of aqueous solutions obtained in step (II) are directly mixed, after stirring
Be sterilized agent.
5. utilize the method that the sanitizing composition described in claim 1 prepares disinfectant, it is characterised in that described
The preparation method of disinfectant comprises the steps:
I () raw material prepares: raw material is made up of component A and B component, and described component A is at sanitizing composition
The amount percentage ratio of material shared by is that M, M more than or equal to 25% and are less than or equal to 75%, described B
Component amount percentage ratio of shared material in sanitizing composition is N, N=1-M；Described component A is bromine
Hydrochlorate, described B component is reproducibility sulfur-containing compound；Described bromate is sodium bromate and bromic acid ammonium
Mixture, the ratio of the amount of the material of sodium bromate and bromic acid ammonium is 1:2；Described reproducibility sulfur-containing compound
For the mixture of sodium sulfite, sodium hydrosulfite, Ammonium hyposulfite. and ammonium sulfide, sodium sulfite, sodium hydrosulfite,
The ratio of the amount of the material of Ammonium hyposulfite. and ammonium sulfide is 1:3:1.3:0.8；According to described component A and
The amount proportioning of described B component material in sanitizing composition weighs described component A and described B component
Standby；
(ii) load weighted described component A is configured to the concentration aqueous solution more than or equal to 10mg/L,
And load weighted described B component is also configured to the concentration aqueous solution more than or equal to 10mg/L；
(iii) two kinds of aqueous solutions obtained in step (ii) are separately added into or are sprayed to same to be washed
Sterilised object or environment can be sterilized agent.
6. utilize the method that the sanitizing composition described in claim 1 prepares disinfectant, it is characterised in that described
The preparation method of disinfectant comprises the steps:
1. raw material is made up of component A and B component, and described component A is shared material in sanitizing composition
Amount percentage ratio is that M, M more than or equal to 25% and are less than or equal to 75%, and described B component is in sterilization group
In compound, the amount percentage ratio of shared material is N, N=1-M；Described component A is bromate, described B
Component is reproducibility sulfur-containing compound；Described bromate is sodium bromate and the mixture of bromic acid ammonium, bromic acid
The ratio of the amount of the material of sodium and bromic acid ammonium is 1:2；Described reproducibility sulfur-containing compound be sodium sulfite,
The mixture of sodium hydrosulfite, Ammonium hyposulfite. and ammonium sulfide, sodium sulfite, sodium hydrosulfite, Ammonium hyposulfite.
It is 1:3:1.3:0.8 with the ratio of the amount of the material of ammonium sulfide；According to described component A and described B component
The amount proportioning of the material in sanitizing composition weighs described component A respectively and described B component is standby；
2. make effervescent tablet after load weighted described component A and described B component being mixed, obtain disinfectant.
7. the purposes of sanitizing composition described in claim 1, it is characterised in that described sanitizing composition is used for disappearing
Poison.
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