CN104080898A - Fragrance composition for improving breath having smell of cigarettes - Google Patents
Fragrance composition for improving breath having smell of cigarettes Download PDFInfo
- Publication number
- CN104080898A CN104080898A CN201280068203.3A CN201280068203A CN104080898A CN 104080898 A CN104080898 A CN 104080898A CN 201280068203 A CN201280068203 A CN 201280068203A CN 104080898 A CN104080898 A CN 104080898A
- Authority
- CN
- China
- Prior art keywords
- weight
- fragrance component
- acetate
- respect
- integral body
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
- A24B15/34—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances containing a carbocyclic ring other than a six-membered aromatic ring
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
- A24B15/34—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances containing a carbocyclic ring other than a six-membered aromatic ring
- A24B15/345—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances containing a carbocyclic ring other than a six-membered aromatic ring containing condensed rings
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0204—Preliminary operations before the filter rod forming process, e.g. crimping, blooming
- A24D3/0212—Applying additives to filter materials
- A24D3/0216—Applying additives to filter materials the additive being in the form of capsules, beads or the like
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/061—Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/08—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/14—Use of materials for tobacco smoke filters of organic materials as additive
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Fats And Perfumes (AREA)
- Cosmetics (AREA)
- Manufacture Of Tobacco Products (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
A fragrance composition for improving a breath having a smell of cigarettes, comprising a fragrance component (A) and a fragrance component (B), wherein the fragrance component (A) is a component having a steam pressure of 2 Pa or more and less than 210 Pa and a water/octanol partition coefficient of 1.5 to 6.5 inclusive and the fragrance component (B) is a component having a steam pressure of 210 to 10000 Pa inclusive and a water/octanol partition coefficient of -1 to 3 inclusive.
Description
Technical field
The present invention relates to the smelly implication of a kind of cigarette and improve flavor compositions.
Background technology
In the past, smelly in order to remove cigarette, the known technology (with reference to Japanese kokai publication hei 7-250665 communique and TOHKEMY 2009-179708 communique) that supports specific deodorizing composition in tobacco filter or coil paper.But these technology are removes the stink directly being produced by tobacco, is not the technology of improving the smelly implication of cigarette.In fact, only directly use disclosed deodorizing composition in above-mentioned document cannot realize the deodorizing of the smelly implication of cigarette.While improving the smelly implication of cigarette, need to consider that fragrance component is at intraoral desorption.
On the other hand, in recent years, consciousness for implication improves, therefore, just develop relevant implication and improving the technology of spices and reodorant (with reference to TOHKEMY 2005-289918 communique, TOHKEMY 2005-170906 communique, TOHKEMY 2003-175095 communique and the reference of TOHKEMY 2009-190990 communique).In addition, the technology (with reference to TOHKEMY 2004-18431 communique) about covering the spices that comprises the implication that cigarette is smelly is also disclosed.But these implications are improved spices or reodorant is used if directly added, need to add the composition of emitting in a large number strong fragrance, damage tobacco fragrance originally in tobacco.In brief, for the smelly implication of the cigarette adding in tobacco, improve spices, require to show with minute quantity the effect of improving the smelly implication of cigarette.In addition, although also consider after smoking, these implications to be improved spices or reodorant containing the method in entrance, now need to after smoking, operate separately, not preferred.As mentioned above, in the prior art, cannot be when guaranteeing tobacco flavor improve the smelly implication of cigarette of following smoking in such 1 action of abundant real Current smoking.
Summary of the invention
The object of the invention is to, provide a kind of interpolation with small amount can improve the smelly implication of cigarette, and can not damage the smoking article that the smelly implication of cigarette of tobacco fragrance is originally improved flavor compositions and contained such flavor compositions.
The invention provides a kind of smelly implication of cigarette that contains following fragrance component A and fragrance component B and improve flavor compositions.
Fragrance component A: vapour pressure is that 2Pa is above and lower than 210Pa, water/octanol partition ratio is the composition more than 1.5 and below 6.5.
Fragrance component B: vapour pressure is that 210Pa is above and below 10000Pa, water/octanol partition ratio is the composition more than-1 and below 3.
As the fragrance component A using in the present invention, can illustration Geraniol, caryophyllene, geranyl acetate, terpinol, geraniol, citronellyl acetate, citral, menthyl acetate, Karvon, piperitone, agalloch eaglewood ketone, 4 '-methyl acetophenone, piperitone, blatter alcohol, capryl acetate, phellandrene, limonene, ethyl hexanoate, 2-ethanoyl-5-methyl furan, bornyl acetate, 2-decenal, m-dimethoxybenzene, p-dimethyoxy benzene, 2, 4-dimethyl acetophenone, ethyl benzoate, 2-ethyl-1-hexanol, fenchone, 2-hexen-1-ol, acetic acid hexene ester, hexanol, isobornyl acetate, acetic acid agalloch eaglewood ester, 1-methyl-3-methoxyl group-4-isopropyl benzene, methylanisole, nonanone, methyln-hexyl ketone, 1-OCOL, terpinolene, 3, 5, 5-trimethylammonium-1-hexanol, 2, 2, 6-trimethylcyclohexanone.Wherein, preferred Geraniol, caryophyllene, geranyl acetate, terpinol, geraniol, citronellyl acetate, citral, menthyl acetate, Karvon, piperitone, agalloch eaglewood ketone, 4 '-methyl acetophenone, piperitone, blatter alcohol, capryl acetate, phellandrene, limonene, ethyl hexanoate.
As the fragrance component B using in the present invention, can illustration eucalyptol, isoamyl acetate, Ethylisovalerate, ethyl propionate, acetoin, amylalcohol, pentyl formate, n-butyl alcohol, N-BUTYL ACETATE, ethyl butyrate, ethyl lactate, 2-butylene acetoacetic ester, 2-heptanone, hexanal, 2-hexenoic aldehyde, formic acid cis-3-hexene ester, isoamyl formate, isobutyl acetate, isopropylcarbinol, 2-methylfuroate, methyl isovalerate, 5-methyl-3-hexene-2-ketone, 4-methyl-3-amylene-2-ketone, 2-methyltetrahydrofuran-3-ketone, 2 pentanone.Wherein, preferred eucalyptol, isoamyl acetate, Ethylisovalerate, ethyl propionate.
Also can use the natural perfume that contains these compositions to replace above-mentioned fragrance component or together use with above-mentioned fragrance component.As such natural perfume, for example, can enumerate: Spearmint oil, Fructus Piperis peppermint oil, flower garden spearmint oil, spearmint oil, yellow cicada fungus oil, rough sawn Chi Ji thuja oil, basil oil, Costusroot oil, rose-wood oil, rose, pamorusa oil, fragrant citrus, oleum graminis citrati, Herba Verbenae oil, lemon oil, Oleum Pelargonii Graveolentis, perfume tree oil, Michelia champaca oil, sage oil, coriander, jasmine oil, eye-catching Oleum lavandula angustifolia, Oleum lavandula angustifolia, mandarin orange oil, orange flower oil, orange-peel oil, orange oil, flores aurantii, petitgrain bigarade oil, sage oil, thyme oil, the blue ylang-ylang oil of clothing, Oils, bergamot peel, block that oiling, Calamintha oil, oleum anethi, volatile oil extracted from eucalyptus' leaves or twigs, lime oil, Sweet marjoram oil, caraway seed oil, Oils, Apium graveolens, grapefruit oil, pepper, tangerine oil, verbena oil, star aniseed oil, perubalsam oil, Tolu balsam oil, white oil of camphor, cedar wood, oil of chamomile, Oleum Cinnamomi, cloves, davana oil, Sweet fennel oil, trigonella, ginger oil, amaranth, Touch-me-notAction Plant oil, olibanum oil, wintergreen oil, myrcia oil, Oils, Elettaria cardamomum, Rosmarinus officinalis wet goods.
And then the smelly implication of cigarette of the present invention is improved flavor compositions except above-mentioned fragrance component, can also contain other composition.As other such composition, can enumerate: the fragrance component of the aliphatics chain alcohols beyond above-mentioned fragrance component, terpenic series alcohols, terpenic series aldehydes, terpenic series ester class, aliphatic ester, terpenic series ketone, aromatic series ketone, terpenic series hydro carbons, terpenic series ethers, aliphatic ester.
According to other embodiment of the present invention, can provide a kind of smoking article that the smelly implication of above-mentioned cigarette is improved flavor compositions that supports.The smelly implication of cigarette of the present invention is improved flavor compositions can make an addition to tobacco in conventionally add spiced arbitrary operation in tobacco.In addition, the smelly implication of cigarette of the present invention is improved flavor compositions can make an addition to final smoking article (cigarette etc.) with arbitrary concentration, but preferably take with respect to tobacco material 1g the ratio as 0.5mg more than and below 15mg, the more preferably interpolation of the ratio more than 0.5mg and below 5mg with respect to tobacco material 1g.As tobacco material, also can use arbitrary tobacco materials such as tobacco leaf (yellow kind, burley tobaccos kind, east kind etc.), reconstituted tobacco, conventionally, these tobacco materials are used for smoking article with the form of pipe tobacco.Pipe tobacco can be also expanded form.In addition, the smelly implication of cigarette of the present invention is improved arbitrary position that flavor compositions also can make an addition to tobacco material, material product (tobacco filter etc.).
Embodiment
The inventor etc. think, in order to improve the smelly implication of cigarette, flavor compositions need to spue when exhaling.That is, according to the difference of spices, in exist arriving mouthful before volatilization situation and in arriving mouthful after can when exhaling, not spue and remain in the situation in mouth.If spices does not spue when exhaling, even if there is height, cover effect, be also not suitable as the smelly implication of cigarette and improve flavor compositions.
The inventor etc. carry out chemical analysis to a plurality of known fragrance components, measure the release rate L of the fragrance component of smoking in exhaling after 3 minutes.
In expiration release rate L (%) by the fragrance component concentration C ex (area/mL) in exhaling divided by the fragrance component concentration C ms (area/mL) in mainstream smoke and be multiplied by 100 and calculate.Area is for to analyze by GC/MS the peak integral area obtaining.
If find that the value of release rate L in this expiration is more than 0.1%, in the scope of the spices addition of allowing, can guarantee to improve the sufficient spices discharge-amount in the expiration of the smelly implication of cigarette in tobacco design.
In addition, in known above-mentioned expiration, release rate L is that more than 0.1% fragrance component can be categorized as vapour pressure Vp and water/octanol partition ratio P in 2 groups of certain limit.That is, the fragrance component A of 2≤Vp<210 and 1.5≤logP≤6.5 and 210≤Vp≤10000 and-the fragrance component B of 1≤logP≤3.
And then from fragrance component A and fragrance component B, selected implication is improved the king-sized composition of effect (sensory evaluation gimmick aftermentioned) respectively by sensory evaluation.
At this, the prediction such as inventor fragrance component A is with fragrance component B because their physical property is different, and therefore, the behavior in mouth is different, for the smelly implication of cigarette, improves and gives different effects.Particularly, because the vapour pressure of fragrance component B is higher, therefore, prediction has implication to the smelly implication of cigarette and improves effect (hereinafter referred to as " initial effect ") after just smoking.In addition, because the vapour pressure of fragrance component A is lower, therefore, prediction is given long-term implication to the smelly implication of cigarette and is improved effect (hereinafter referred to as " lasting effect ").Table 1 shows the characteristic of fragrance component A and fragrance component B.In addition, the composition not comprising in fragrance component A and fragrance component B, be vapour pressure compared with high and wave loose in smoking way and cannot arrive in mouth compared with hydrophobic composition is many, in addition, although the lower and more hydrophilic composition of vapour pressure can arrive in mouth, but can be dissolved in the moisture in mouth and can from exhale, not spue, therefore, think that cannot give implication improves effect.
[table 1]
Therefore, as described later, prepare respectively fragrance component A only or the combination spice (embodiment) of the combination spice of fragrance component B (comparative example) and fragrance component A and fragrance component B only, the smelly implication of cigarette degree of improvement is carried out to sensory evaluation.Its result is known, with fragrance component A only or only the situation of fragrance component B compare, the combination of fragrance component A and fragrance component B can improve effect to bring into play on a small quantity the smelly implication of sufficient cigarette.
Therefore, the method for selecting that the smelly implication of cigarette in the present invention is improved flavor compositions have the amount in mainstream smoke and the operation that in exhaling, burst size is analyzed and select to exhale in release rate L be the operation of more than 0.1% fragrance component, in described expiration release rate L by the fragrance component concentration C ex (area/mL) in exhaling divided by the fragrance component concentration C ms (area/mL) in mainstream smoke and be multiplied by 100 and calculate.Further preferably also there is following operation: in above-mentioned selected fragrance component, according to the Analyses Methods for Sensory Evaluation Results of the smelly implication odor strength of cigarette, select to have the operation that the smelly implication of cigarette is improved the fragrance component of effect.
And then the weight ratio of known fragrance component A is greater than the situation that the situation of fragrance component B (A>B) and the weight ratio of fragrance component A be less than or equal to fragrance component B (A≤B) and compares, and shows the smelly implication of king-sized cigarette and improves effect.
Thus, can improve the smelly implication of cigarette in the situation that do not damage tobacco fragrance originally.
Below, embodiments of the present invention are described in more detail.
(1) calculation method of release rate in expiration
(1.1) smoking after 3 minutes the release rate L (%) of fragrance component in expiration for by the fragrance component concentration C ex (area/mL) in exhaling divided by the fragrance component concentration C ms (area/mL) in mainstream smoke and be multiplied by 100 values that obtain.
(1.2) method of sampling
(1.2.1) preparation of cigarette
For the cigarette of analyzing, be commercial cigarettes " Seven Stars Lights Box ".Before analyzing spices, by with alcohol dilution spices make an addition in pipe tobacco for testing.Particularly, each solution 10 μ L that mix with the concentration of 100 μ g/10 μ L of 20～30 kinds of fragrance components are made an addition to pipe tobacco.
(1.2.2) trapping of exhaling
Experimenter gargles with water before smoking, cleans oral area.Then, smoking.Smoking interval is made as 30 seconds, smoking compressing number of times is made as 7 times.After smoking, trap tube (linking 2 TENAX-TA) is held in the month to entrance, by pump, with 100mL/min, trapped intraoral head space (expiration spuing).Exhale time of trapping is 1 minute behind 3 minutes of starting point while being made as to finish smoking.After trapping, loose to analyzing the moisture that causes obstacle in order to wave, with 100mL/min circulation nitrogen 4 minutes.
(1.2.3) mainstream smoke trapping
The smoking apparatus trapping mainstream smoke that use consists of mass flow control device and pump.Smoking interval is made as 30 seconds, smoking flow is made as 55mL/2sec.From igniting, till the 3rd compressing, do not trap.The mainstream smoke of the 4th compressing is ventilated in trap tube (TENAX-TA).
(1.3) gas-chromatography/mass analysis (GC/MS)
In having additional the GC/MS that adds thermal desorption system (TDS), cooling injected system (CIS), cryogenic trapping system (CTS), analyze.
(2) the sensory evaluation method of fragrance component A, B
Expiration after smoker's smoking is trapped in the bag of polyester film system, and by smoker self, this bag carried out to sensory evaluation as other stink.The details of evaluation assessment is with reference to the meeting of evaluation of measuring portion of smell fragrance environment association, stink brief appraisal technology standardization research association in " implication examination handbook " first gear division publication and " report of applying flexibly of relevant stink brief appraisal technology ".
(2.1) evaluation assessment
(2.1.1) evaluate the making of cigarette
Cigarette is used commercial cigarettes " Seven Stars Lights Box ".The fragrance component of evaluation object, with after alcohol dilution to 650 μ g/ μ L, is added to 10 μ L in pipe tobacco, for test.
(2.1.2) method of trapping of exhaling in bag
Valuator's water before smoking is gargled, and cleans oral area.Then, to evaluating cigarette, carry out smoking.Smoking interval is made as 30 seconds, smoking compressing number of times is made as 7 times.After smoking, expiration is spued in the bag of the polyester film system of 3L capacity, and airtight with silicon bolt.Exhale time of trapping is behind 30 seconds of starting point and after 3 minutes while being made as to finish smoking.
(2.1.3) sensory evaluation of bag
Valuator (the special valuators in 4 companies) cleans oral area before evaluation.The bolt of the bag that valuator self is trapped takes off, and evaluates the taste of the expiration in bag.By assessment item remember in below.
The effect of covering that cigarette is smelly is carried out to absolute evaluation (point system.0 minute: the taste that does not suppress tobacco.1 minute: the taste that suppresses tobacco.2 minutes: the taste that suppresses tobacco completely.Within 0.5 minute and 1.5 minutes, be respectively centres at different levels).Scoring after 30 seconds of each valuator and after 3 minutes is average, and the scoring using the scoring obtaining as each valuator, is that 0.5 minute above situation is made as " covering effect " by 4 valuators' summation score.And then, by 4 valuators' summation score, be that 4 minutes above situations are made as " having the stronger effect of covering ".In table 2, illustrated and be evaluated as the concrete fragrance component A that " having the effect covered " " has the stronger effect of covering ", B.
[table 2]
| ? | Fragrance component | Vapour pressure (Pa) | Partition ratio | The gross score of scoring | Result |
| A | Karvon | 13.7 | 2.7 | 4.0 | There is the stronger effect of covering |
| A | Caryophyllene | 4.2 | 6.3 | 5.0 | There is the stronger effect of covering |
| A | Citral | 12.2 | 3.5 | 5.5 | There is the stronger effect of covering |
| A | Geraniol | 5.9 | 3.9 | 5.0 | There is the stronger effect of covering |
| A | Ethyl hexanoate | 208.0 | 2.8 | 6.0 | There is the stronger effect of covering |
| A | Geraniol | 4.0 | 3.6 | 4.0 | There is the stronger effect of covering |
| A | Geranyl acetate | 4.4 | 4.0 | 4.0 | There is the stronger effect of covering |
| A | Blatter alcohol | 124.9 | 1.6 | 7.0 | There is the stronger effect of covering |
| A | Capryl acetate | 176.0 | 2.8 | 8.0 | There is the stronger effect of covering |
| A | Linaool | 21.3 | 3.0 | 7.0 | There is the stronger effect of covering |
| A | Menthol | 49.3 | 3.1 | 7.0 | There is the stronger effect of covering |
| A | Menthyl acetate | 12.2 | 4.4 | 4.0 | There is the stronger effect of covering |
| A | 4 '-methyl acetophenone | 29.5 | 2.1 | 5.0 | There is the stronger effect of covering |
| A | Phellandrene | 186.7 | 4.6 | 6.0 | There is the stronger effect of covering |
| A | Piperitone | 13.9 | 2.9 | 6.0 | There is the stronger effect of covering |
| A | Terpinol | 5.6 | 3.0 | 4.5 | There is the stronger effect of covering |
| A | Citronellyl acetate | 7.0 | 4.6 | 5.0 | There is the stronger effect of covering |
| A | Limonene | 206.7 | 4.6 | 5.0 | There is the stronger effect of covering |
| A | 2-ethanoyl-5-methyl furan | 168.0 | 1.5 | 3.5 | Cover effect |
| A | Bornyl acetate | 30.4 | 3.9 | 3.5 | Cover effect |
| A | 2-decenal | 10.4 | 3.6 | 3.5 | Cover effect |
| A | Between dimethyl benzene | 70.4 | 2.2 | 3.0 | Cover effect |
| A | To dimethyl benzene | 11.6 | 2.0 | 3.0 | Cover effect |
| A | 2,4-dimethyl acetophenone | 10.8 | 2.8 | 2.0 | Cover effect |
| A | Ethyl benzoate | 35.6 | 2.6 | 2.0 | Cover effect |
| A | 2-ethyl-1-hexanol | 18.1 | 2.7 | 2.0 | Cover effect |
| A | Fenchone | 96.1 | 3.0 | 1.5 | Cover effect |
| A | 2-hexen-1-ol | 121.5 | 1.6 | 1.5 | Cover effect |
| A | Acetic acid hexene ester | 152.0 | 2.6 | 2.5 | Cover effect |
| A | Hexanol | 123.7 | 2.0 | 0.5 | Cover effect |
| A | Isobornyl acetate | 14.3 | 4.3 | 2.0 | Cover effect |
| A | Acetic acid agalloch eaglewood ester | 14.8 | 3.9 | 2.5 | Cover effect |
| A | 1-methyl-3-methoxyl group-4-isopropyl benzene | 18.4 | 4.1 | 0.5 | Cover effect |
| A | Methylanisole | 152.0 | 2.7 | 2.0 | Cover effect |
| A | Nonanone | 83.2 | 3.1 | 2.5 | Cover effect |
| A | Methyln-hexyl ketone | 180.0 | 2.4 | 2.5 | Cover effect |
| A | 1-OCOL | 31.7 | 2.6 | 3.5 | Cover effect |
| A | Terpinolene | 99.1 | 4.5 | 3.5 | Cover effect |
| A | 3,5,5-trimethylammonium-1-hexanol | 40.0 | 3.1 | 0.5 | Cover effect |
| A | 2,2,6-trimethylcyclohexanone | 189.3 | 2.4 | 1.0 | Cover effect |
| B | Ethylisovalerate | 1106.7 | 2.3 | 5.5 | There is the stronger effect of covering |
| B | Ethyl propionate | 4786.6 | 1.2 | 6.5 | There is the stronger effect of covering |
| B | Eucalyptol | 253.3 | 2.7 | 7.0 | There is the stronger effect of covering |
| B | Isoamyl acetate | 746.7 | 2.3 | 8.0 | There is the stronger effect of covering |
| B | 3-hydroxy-2-butanone | 358.7 | -0.4 | 0.5 | Cover effect |
| B | Amylalcohol | 293.3 | 1.5 | 1.0 | Cover effect |
| B | Pentyl formate | 1310.7 | 1.8 | 0.5 | Cover effect |
| B | N-butyl alcohol | 893.3 | 0.9 | 0.5 | Cover effect |
| B | N-BUTYL ACETATE | 1533.3 | 1.8 | 2.0 | Cover effect |
| B | Ethyl butyrate | 1706.6 | 1.9 | 0.5 | Cover effect |
| B | Ethyl lactate | 500.0 | -0.2 | 2.5 | Cover effect |
| B | 2-butylene acetoacetic ester | 994.7 | 1.6 | 0.5 | Cover effect |
| B | 2-heptanone | 514.7 | 2.0 | 2.0 | Cover effect |
| B | Hexanal | 1506.7 | 1.8 | 0.5 | Cover effect |
| B | 2-hexenoic aldehyde | 880.0 | 1.6 | 2.5 | Cover effect |
| B | Formic acid cis 3-hexene ester | 382.7 | 2.1 | 0.5 | Cover effect |
| B | Isoamyl formate | 2040.0 | 1.7 | 0.5 | Cover effect |
| B | Isobutyl acetate | 2373.3 | 1.8 | 1.5 | Cover effect |
| B | Isopropylcarbinol | 1400.0 | 0.8 | 2.5 | Cover effect |
| B | 2-methylfuroate | 340.0 | 1.0 | 0.5 | Cover effect |
| B | Methyl isovalerate | 1866.6 | 1.8 | 0.5 | Cover effect |
| B | 5-methyl-3-hexene-2-ketone | 1318.7 | 1.7 | 1.5 | Cover effect |
| B | 4-methyl-3-hexene-2-ketone | 1094.7 | 1.4 | 1.5 | Cover effect |
| B | 2-methyltetrahydrofuran-3-ketone | 612.0 | -0.2 | 2.0 | Cover effect |
| B | 2 pentanone | 4720.0 | 0.9 | 1.5 | Cover effect |
(3) stink sensory evaluation method in the mouth of the flavor compositions of embodiment
Expiration after smoker's smoking is trapped in the bag of the polyester film system of 3L capacity, and by smoker self, this bag carried out to sensory evaluation as other stink.The details of evaluation assessment is with reference to the meeting of evaluation of measuring portion of smell fragrance environment association, stink brief appraisal technology standardization research association in " implication examination handbook " first gear division publication and " report of applying flexibly of relevant stink brief appraisal technology ".
(3.1) evaluation assessment
(3.1.1) evaluate the making of cigarette
Cigarette is used commercial cigarettes " Seven Stars Lights Box ".The fragrance component of evaluation object is enclosed to the seamless capsule (gelatin film) of diameter 4mm and by 1 capsule-filling in filter tip.
(3.1.2) method of trapping of exhaling in bag
Valuator's water before smoking is gargled, and cleans oral area.Then, valuator sucks and evaluates cigarette after the capsule in filter tip being crushed with finger before smoking.Smoking interval is made as 30 seconds, smoking compressing number of times is made as 7 times.After smoking, expiration is spued in the bag of the polyester film system of 3L capacity, and airtight with silicon bolt.Exhale time of trapping is behind 30 seconds of starting point and after 3 minutes while being made as to finish smoking.
(3.1.3) sensory evaluation of bag
Valuator (the special valuators in 4 companies) cleans oral area before evaluation.The bolt of the bag that valuator self is trapped takes off, and evaluates the taste of the expiration in bag.Following project is carried out to absolute evaluation (from the point system of 1 minute to 4 minutes.Numerical value is larger, and effect is stronger).
The smelly effect of covering of cigarette of initial effect (after smoking 30 seconds)
The smelly effect of covering of cigarette of lasting effect (after smoking 3 minutes)
The whole smelly implication of cigarette is improved effect
Inhale taste acceptability
Test-results is gathered and is shown in table 3 and table 4.In table 3 and table 4, ◎ represent 4 valuators scoring be equally divided into 3.5 minutes above and 4 minutes following situations, zero represent 4 valuators scoring be equally divided into 2.5 minutes above and lower than situation, the △ of 3.5 minutes, represent 4 valuators scoring be equally divided into 1.5 minutes above and lower than the situation of 2.5 minutes, * average mark of scoring that represents 4 valuators lower than the situation of 1.5 minutes.
In addition, in embodiment 1, the weight that can suitable change makes menthyl acetate with respect to the weight of solution integral body between 550～650 ‰ (permillages), the weight of isoamyl acetate with respect to the weight of solution integral body between 350～450 ‰.In embodiment 2, the weight that can suitable change makes menthyl acetate with respect to the weight of solution integral body between 350～450 ‰, the weight of isoamyl acetate with respect to the weight of solution integral body between 550～650 ‰.In embodiment 3, the weight that can suitable change makes piperitone with respect to the weight of solution integral body between 300～500 ‰, the weight of blatter alcohol with respect to the weight of solution integral body between 300～500 ‰, the weight of eucalyptol with respect to the weight of solution integral body between 130～270 ‰.In embodiment 4, the weight that can suitable change makes caryophyllene with respect to the weight of solution integral body between 1～20 ‰, the weight of geranyl acetate with respect to the weight of solution integral body between 1～20 ‰, the weight of terpinol with respect to the weight of solution integral body between 1～20 ‰, the weight of citral with respect to the weight of solution integral body between 50～100 ‰, the weight of menthyl acetate with respect to the weight of solution integral body between 1～20 ‰, the weight of Karvon with respect to the weight of solution integral body between 180～260 ‰, the weight of piperitone with respect to the weight of solution integral body between 1～20 ‰, the weight of agalloch eaglewood ketone with respect to the weight of solution integral body between 30～50 ‰, the weight of piperitone with respect to the weight of solution integral body between 200～300 ‰, the weight of phellandrene with respect to the weight of solution integral body between 1～20 ‰, the weight of limonene with respect to the weight of solution integral body between 200～340 ‰, the weight of eucalyptol with respect to the weight of solution integral body between 120～180 ‰.In embodiment 5, the weight that can suitable change makes agalloch eaglewood ketone with respect to the weight of solution integral body between 140～200 ‰, the weight of 4 '-methyl acetophenone with respect to the weight of solution integral body between 140～200 ‰, the weight of capryl acetate with respect to the weight of solution integral body between 400～600 ‰, the weight of eucalyptol with respect to the weight of solution integral body between 140～200 ‰.In embodiment 6, the weight that can suitable change makes caryophyllene with respect to the weight of solution integral body between 1～20 ‰, the weight of geranyl acetate with respect to the weight of solution integral body between 1～20 ‰, the weight of terpinol with respect to the weight of solution integral body between 1～20 ‰, the weight of citral with respect to the weight of solution integral body between 30～100 ‰, the weight of menthyl acetate with respect to the weight of solution integral body between 1～20 ‰, the weight of Karvon with respect to the weight of solution integral body between 240～360 ‰, the weight of piperitone with respect to the weight of solution integral body between 1～20 ‰, the weight of agalloch eaglewood ketone with respect to the weight of solution integral body between 20～60 ‰, the weight of piperitone with respect to the weight of solution integral body between 230～330 ‰, the weight of phellandrene with respect to the weight of solution integral body between 1～20 ‰, the weight of limonene with respect to the weight of solution integral body between 150～210 ‰, the weight of eucalyptol with respect to the weight of solution integral body between 120～200 ‰.In embodiment 7, the weight that can suitable change makes caryophyllene with respect to the weight of solution integral body between 25～45 ‰, the weight of geranyl acetate with respect to the weight of solution integral body between 90～130 ‰, the weight of terpinol with respect to the weight of solution integral body between 30～70 ‰, the weight of citronellyl acetate with respect to the weight of solution integral body between 320～460 ‰, the weight of citral with respect to the weight of solution integral body between 40～80 ‰, the weight of menthyl acetate with respect to the weight of solution integral body between 10～30 ‰, the weight of Karvon with respect to the weight of solution integral body between 130～190 ‰, the weight of piperitone with respect to the weight of solution integral body between 1～20 ‰, the weight of agalloch eaglewood ketone with respect to the weight of solution integral body between 1～20 ‰, the weight of piperitone with respect to the weight of solution integral body between 80～120 ‰, the weight of limonene with respect to the weight of solution integral body between 40～80 ‰, the weight of eucalyptol with respect to the weight of solution integral body between 10～40 ‰.In embodiment 8, the weight that can suitable change makes Karvon with respect to the weight of solution integral body between 390～570 ‰, the weight of agalloch eaglewood ketone with respect to the weight of solution integral body between 3～60 ‰, the weight of piperitone with respect to the weight of solution integral body between 240～360 ‰, the weight of eucalyptol with respect to the weight of solution integral body between 30～120 ‰.In embodiment 9, the weight that can suitable change makes caryophyllene with respect to the weight of solution integral body between 1～20 ‰, the weight of geranyl acetate with respect to the weight of solution integral body between 1～20 ‰, the weight of terpinol with respect to the weight of solution integral body between 1～20 ‰, the weight of citral with respect to the weight of solution integral body between 30～100 ‰, the weight of menthyl acetate with respect to the weight of solution integral body between 1～20 ‰, the weight of Karvon with respect to the weight of solution integral body between 110～170 ‰, the weight of piperitone with respect to the weight of solution integral body between 1～20 ‰, the weight of agalloch eaglewood ketone with respect to the weight of solution integral body between 40～80 ‰, the weight of piperitone with respect to the weight of solution integral body between 270～360 ‰, the weight of phellandrene with respect to the weight of solution integral body between 1～20 ‰, the weight of limonene with respect to the weight of solution integral body between 150～210 ‰, the weight of eucalyptol with respect to the weight of solution integral body between 200～280 ‰.In embodiment 10, the weight that can suitable change makes capryl acetate with respect to the weight of solution integral body between 330～550 ‰, the weight of eucalyptol with respect to the weight of solution integral body between 240～320 ‰, the weight of Ethylisovalerate with respect to the weight of solution integral body between 90～140 ‰, the weight of ethyl propionate with respect to the weight of solution integral body between 30～100 ‰.In embodiment 11, the weight that can suitable change makes caryophyllene with respect to the weight of solution integral body between 1～20 ‰, the weight of terpinol with respect to the weight of solution integral body between 1～20 ‰, the weight of menthyl acetate with respect to the weight of solution integral body between 1～20 ‰, the weight of Karvon with respect to the weight of solution integral body between 80～140 ‰, the weight of piperitone with respect to the weight of solution integral body between 1～20 ‰, the weight of agalloch eaglewood ketone with respect to the weight of solution integral body between 80～120 ‰, the weight of piperitone with respect to the weight of solution integral body between 360～520 ‰, the weight of phellandrene with respect to the weight of solution integral body between 1～20 ‰, the weight of limonene with respect to the weight of solution integral body between 1～20 ‰, the weight of eucalyptol with respect to the weight of solution integral body between 270～390 ‰.In embodiment 12, the weight that can suitable change makes menthyl acetate with respect to the weight of solution integral body between 110～170 ‰, the weight of piperitone with respect to the weight of solution integral body between 470～670 ‰, the weight of eucalyptol with respect to the weight of solution integral body between 235～335 ‰.In embodiment 13, the weight that can suitable change makes caryophyllene with respect to the weight of solution integral body between 1～20 ‰, the weight of terpinol with respect to the weight of solution integral body between 1～20 ‰, the weight of menthyl acetate with respect to the weight of solution integral body between 1～20 ‰, the weight of Karvon with respect to the weight of solution integral body between 480～740 ‰, the weight of piperitone with respect to the weight of solution integral body between 1～20 ‰, the weight of agalloch eaglewood ketone with respect to the weight of solution integral body between 10～60 ‰, the weight of piperitone with respect to the weight of solution integral body between 150～220 ‰, the weight of phellandrene with respect to the weight of solution integral body between 1～20 ‰, the weight of limonene with respect to the weight of solution integral body between 10～60 ‰, the weight of eucalyptol with respect to the weight of solution integral body between 80～160 ‰.In embodiment 14, the weight that can suitable change makes Geraniol with respect to the weight of solution integral body between 70～140 ‰, the weight of terpinol with respect to the weight of solution integral body between 120～180 ‰, the weight of geraniol with respect to the weight of solution integral body between 150～210 ‰, the weight of Karvon with respect to the weight of solution integral body between 1～20 ‰, the weight of agalloch eaglewood ketone with respect to the weight of solution integral body between 180～280 ‰, the weight of ethyl hexanoate with respect to the weight of solution integral body between 100～160 ‰, the weight of isoamyl acetate with respect to the weight of solution integral body between 140～220 ‰.In embodiment 15, the weight that can suitable change makes caryophyllene with respect to the weight of solution integral body between 1～20 ‰, the weight of terpinol with respect to the weight of solution integral body between 1～20 ‰, the weight of menthyl acetate with respect to the weight of solution integral body between 1～20 ‰, the weight of Karvon with respect to the weight of solution integral body between 480～740 ‰, the weight of piperitone with respect to the weight of solution integral body between 1～20 ‰, the weight of agalloch eaglewood ketone with respect to the weight of solution integral body between 10～60 ‰, the weight of piperitone with respect to the weight of solution integral body between 230～330 ‰, the weight of phellandrene with respect to the weight of solution integral body between 1～20 ‰, the weight of limonene with respect to the weight of solution integral body between 10～60 ‰, the weight of eucalyptol with respect to the weight of solution integral body between 80～160 ‰.In embodiment 16, the weight that can suitable change makes caryophyllene with respect to the weight of solution integral body between 1～20 ‰, the weight of geranyl acetate with respect to the weight of solution integral body between 150～250 ‰, the weight of terpinol with respect to the weight of solution integral body between 1～20 ‰, the weight of citronellyl acetate with respect to the weight of solution integral body between 130～230 ‰, the weight of menthyl acetate with respect to the weight of solution integral body between 1～20 ‰, the weight of Karvon with respect to the weight of solution integral body between 40～80 ‰, the weight of agalloch eaglewood ketone with respect to the weight of solution integral body between 10～60 ‰, the weight of piperitone with respect to the weight of solution integral body between 130～200 ‰, the weight of limonene with respect to the weight of solution integral body between 40～80 ‰, the weight of eucalyptol with respect to the weight of solution integral body between 80～130 ‰.
By table 3 and the known following content of table 4.
Only fragrance component A or only the smelly implication of arbitrary cigarette of " the initial effect " and " lasting effect " of the situation of fragrance component B (comparative example 1,2) to improve effect all insufficient, therefore, it is also insufficient that the smelly implication of cigarette is as a whole improved effect.In addition, " the initial effect " and " lasting effect " of the situation (embodiment 1-16) of fragrance component A and fragrance component B combination all visible higher implication improved effect, and it is also abundant that the whole smelly implication of cigarette is improved effect.
In addition, compare with the situation (embodiment 2) of A<B, if the weight of fragrance component A is greater than the weight (A>B) (embodiment 1,3-16) of fragrance component B, can obtains the smelly implication of better cigarette and improve effect.The weight ratio of fragrance component A and fragrance component B is preferably 5.5:4.5～9.9:0.1.
And then, in the situation (embodiment 1-16) of fragrance component A and fragrance component B combination, the addition of the flavor compositions of every 1g tobacco material is more than 0.5mg and below 15mg, can obtain the smelly implication of cigarette and improve effect, and then every 1g tobacco material is that the above and 5mg of 0.5mg also can obtain below the smelly implication of cigarette and improves effect.As mentioned above, even for every 1g tobacco material is the so considerably less addition of 0.5mg, also can obtain the smelly implication of sufficient cigarette and improve effect.From the viewpoint of tobacco flavor, consider, also preferred every 1g tobacco material is the such addition of 0.5mg.
Claims (9)
1. the smelly implication of cigarette is improved a flavor compositions, and it contains fragrance component A and fragrance component B,
Fragrance component A: vapour pressure is more than 2Pa and lower than 210Pa, and water/octanol partition ratio is the composition more than 1.5 and below 6.5;
Fragrance component B: vapour pressure is more than 210Pa and below 10000Pa, and water/octanol partition ratio is the composition more than-1 and below 3.
2. the smelly implication of cigarette according to claim 1 is improved flavor compositions, and wherein, described fragrance component A is selected from Geraniol, caryophyllene, geranyl acetate, terpinol, geraniol, citronellyl acetate, citral, menthyl acetate, Karvon, piperitone, agalloch eaglewood ketone, 4 '-methyl acetophenone, piperitone, blatter alcohol, capryl acetate, phellandrene, limonene, ethyl hexanoate, 2-ethanoyl-5-methyl furan, bornyl acetate, 2-decenal, m-dimethoxybenzene, p-dimethyoxy benzene, 2,4-dimethyl acetophenone, ethyl benzoate, 2-ethyl-1-hexanol, fenchone, 2-hexen-1-ol, acetic acid hexene ester, hexanol, isobornyl acetate, acetic acid agalloch eaglewood ester, 1-methyl isophthalic acid-methoxyl group-4-isopropyl benzene, methylanisole, nonanone, methyln-hexyl ketone, 1-OCOL, terpinolene, 3,5,5-trimethylammonium-1-hexanol, in 2,2,6-trimethylcyclohexanone more than a kind, fragrance component B is for being selected from eucalyptol, isoamyl acetate, Ethylisovalerate, ethyl propionate, acetoin, amylalcohol, pentyl formate, n-butyl alcohol, N-BUTYL ACETATE, ethyl butyrate, ethyl lactate, 2-butylene acetoacetic ester, 2-heptanone, hexanal, 2-hexenoic aldehyde, formic acid cis-3-hexene ester, isoamyl formate, isobutyl acetate, isopropylcarbinol, 2-methylfuroate, methyl isovalerate, 5-methyl-3-hexene-2-ketone, 4-methyl-3-amylene-2-ketone, 2-methyltetrahydrofuran-3-ketone, in 2 pentanone more than a kind.
3. the smelly implication of cigarette according to claim 2 is improved flavor compositions, wherein, fragrance component A for be selected from Geraniol, caryophyllene, geranyl acetate, terpinol, geraniol, citronellyl acetate, citral, menthyl acetate, Karvon, piperitone, agalloch eaglewood ketone, 4 '-methyl acetophenone, piperitone, blatter alcohol, capryl acetate, phellandrene, limonene, ethyl hexanoate more than a kind, fragrance component B be selected from eucalyptol, isoamyl acetate, Ethylisovalerate, ethyl propionate more than a kind.
4. according to the smelly implication of the cigarette described in any one in claim 1～3, improve flavor compositions, wherein, the weight of described fragrance component A is greater than the weight of described fragrance component B.
5. the smelly implication of cigarette according to claim 4 is improved flavor compositions, and wherein, the weight ratio of described fragrance component A and described fragrance component B is 5.5:4.5～9.9:0.1.
6. a smoking article, it supports the smelly implication of cigarette described in any one in the requirement 1～5 of having the right and improves flavor compositions.
7. smoking article according to claim 6, wherein, the addition of the flavor compositions of every 1g tobacco material is that 0.5mg is above and below 15mg, and flavor compositions makes an addition to the tobacco material of smoking article, arbitrary position of material product.
8. smoking article according to claim 7, wherein, the addition of the flavor compositions of every 1g tobacco material is that 0.5mg is above and below 5mg.
9. according to the smoking article described in any one in claim 6～8, it is the cigarette with tobacco rod and tobacco filter, and described tobacco filter is filled with has enclosed the capsule that the smelly implication of described cigarette is improved flavor compositions.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811463996.4A CN109480330A (en) | 2012-01-25 | 2012-01-25 | The smelly implication of cigarette improves spice composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/JP2012/051524 WO2013111281A1 (en) | 2012-01-25 | 2012-01-25 | Fragrance composition for improving breath having smell of cigarettes |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811463996.4A Division CN109480330A (en) | 2012-01-25 | 2012-01-25 | The smelly implication of cigarette improves spice composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104080898A true CN104080898A (en) | 2014-10-01 |
Family
ID=48873052
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280068203.3A Pending CN104080898A (en) | 2012-01-25 | 2012-01-25 | Fragrance composition for improving breath having smell of cigarettes |
| CN201811463996.4A Pending CN109480330A (en) | 2012-01-25 | 2012-01-25 | The smelly implication of cigarette improves spice composition |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811463996.4A Pending CN109480330A (en) | 2012-01-25 | 2012-01-25 | The smelly implication of cigarette improves spice composition |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JP5860904B2 (en) |
| KR (2) | KR102033213B1 (en) |
| CN (2) | CN104080898A (en) |
| HK (1) | HK1198258A1 (en) |
| RU (1) | RU2592351C2 (en) |
| UA (1) | UA110881C2 (en) |
| WO (1) | WO2013111281A1 (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106307602A (en) * | 2016-09-12 | 2017-01-11 | 三峡大学 | Electronic cigarette liquid for freshening breath |
| CN107446700A (en) * | 2017-09-14 | 2017-12-08 | 皖西学院 | A kind of flavor compositions for showing Dendrobidium huoshanness fresh flower fragrance and application |
| CN107668771A (en) * | 2017-09-19 | 2018-02-09 | 河南中烟工业有限责任公司 | Fragrant line fennel essence and its application in a kind of ramuscule filter stick |
| CN107802030A (en) * | 2017-09-19 | 2018-03-16 | 河南中烟工业有限责任公司 | Fragrant line lilac compound and its application in a kind of ramuscule filter stick |
| CN109315820A (en) * | 2018-08-10 | 2019-02-12 | 杨福荣 | Cigarette ingredient, preparation method and the cigarette using it |
| CN110144261A (en) * | 2019-04-11 | 2019-08-20 | 杨伟祖 | A kind of cigarette lemon-grass essence |
| CN110452773A (en) * | 2019-07-09 | 2019-11-15 | 河南中烟工业有限责任公司 | A kind of quick-fried pearl fragrant citrus essence and preparation method thereof, quick-fried pearl and cigarette |
| CN110484366A (en) * | 2019-07-09 | 2019-11-22 | 河南中烟工业有限责任公司 | A kind of quick-fried pearl fennel essence and preparation method thereof, quick-fried pearl and cigarette |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8952038B2 (en) * | 2010-03-26 | 2015-02-10 | Philip Morris Usa Inc. | Inhibition of undesired sensory effects by the compound camphor |
| JP6559950B2 (en) * | 2014-12-11 | 2019-08-14 | 大日本除蟲菊株式会社 | Smoke agent composition and method for mitigating irritating odor after using smoke agent |
| JP6888974B2 (en) * | 2016-01-27 | 2021-06-18 | 学校法人近畿大学 | Compounds with CYP2A13 inhibitory activity and CYP2A13 inhibitors |
| KR102549107B1 (en) * | 2018-03-07 | 2023-06-30 | 재단법인대구경북과학기술원 | Evaluation method for similarity in odors using perception of odors |
| CN115379832A (en) * | 2020-03-10 | 2022-11-22 | 学校法人近畿大学 | Agent containing caryophyllene, composition and various uses |
| US20220034866A1 (en) * | 2020-07-28 | 2022-02-03 | Takasago International Corporation | Method for screening of unpleasant odor masking agents |
| CN112063454A (en) * | 2020-09-07 | 2020-12-11 | 泛亚（武汉）食品科技有限公司 | Lotus and mint compound essence suitable for bead blasting for cigarettes and preparation method thereof |
| WO2022091317A1 (en) * | 2020-10-30 | 2022-05-05 | 日本たばこ産業株式会社 | Mouthwash for use in oral cleaning performed with aerosol, cartridge, aerosol generator for oral cleaning, and oral cleaning method |
| US20230372262A1 (en) * | 2020-11-06 | 2023-11-23 | Kinki University | Composition for treating vascular disease, composition for reventing vascular disease, composition for treating hypertension, and composition for preventing hypertension |
| WO2023210481A1 (en) * | 2022-04-28 | 2023-11-02 | 学校法人近畿大学 | Caryophyllene-containing composition |
| GB202211859D0 (en) * | 2022-08-12 | 2022-09-28 | Nicoventures Trading Ltd | Aeroslisable material |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1216233A (en) * | 1997-10-24 | 1999-05-12 | 日本烟草产业株式会社 | Cigarette paper having flavorant which improves sidestream smoke smell, and cigarette |
| CN1473011A (en) * | 2000-11-06 | 2004-02-04 | �ձ��̲ݲ�ҵ��ʽ���� | Deodorant composition for tobacco odor, deodorant for tobacco odor, and cigarette and tobacco package reduced in secondary smoke odor |
| CN1500477A (en) * | 2002-11-13 | 2004-06-02 | 丛繁滋 | Quick result aerosol with plant aroma and its preparation |
| CN1590522A (en) * | 2003-09-05 | 2005-03-09 | 上海百润香精香料有限公司 | Cured tobacco essence |
| CN101558860A (en) * | 2009-05-18 | 2009-10-21 | 广州市凯虹香精香料有限公司 | Compound essence special for betelnut |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04110496U (en) * | 1990-12-25 | 1992-09-25 | テル 鈴木 | flavored tobacco |
| KR940006104B1 (en) * | 1991-07-26 | 1994-07-06 | 주식회사 태평양 | Composition for emitting woodgreen fragrance |
| CN1076844A (en) * | 1992-03-31 | 1993-10-06 | 武汉市一轻工业科学研究所 | Special essence for cigarette |
| US6631722B2 (en) * | 1993-09-30 | 2003-10-14 | British-American Tobacco Company Limited | Tobacco smoke filter elements |
| DE19920147A1 (en) * | 1999-05-03 | 2000-11-09 | Haarmann & Reimer Gmbh | Mint and / or fruit flavor compositions |
| EP1336345B2 (en) * | 2000-11-06 | 2014-01-22 | Japan Tobacco Inc. | Use of perfume compositions as side smoke flow odor reducing agent in a cigarette |
| JP2003190264A (en) * | 2001-12-25 | 2003-07-08 | Kiyomitsu Kawasaki | Aromatic deodorizing composition for environment and aromatic deodorizer for environment containing the aromatic deodorizing composition for environment |
| JP2005013138A (en) * | 2003-06-27 | 2005-01-20 | Kiyomitsu Kawasaki | Method for producing spice flavor |
| WO2005041151A2 (en) * | 2003-10-02 | 2005-05-06 | Vector Tobacco Ltd. | Tobacco product labeling system |
| JP4782478B2 (en) * | 2005-06-07 | 2011-09-28 | 花王株式会社 | Fragrance composition |
| JP2007289221A (en) * | 2006-04-21 | 2007-11-08 | Kao Corp | Deodorant composition |
| US8602036B2 (en) * | 2006-08-03 | 2013-12-10 | Philip Morris Usa Inc. | Smoking articles enhanced to deliver additives incorporated within electrospun microfibers and nonofibers, and related methods |
| ITVA20060056A1 (en) * | 2006-09-06 | 2008-03-07 | Giuseppe Elia | FILTER TO REMOVE TOXIC TOBACCO SMOKE SUBSTANCES |
| US20080253976A1 (en) * | 2007-04-16 | 2008-10-16 | Douglas Craig Scott | Personal Care Compositions Comprising An Antimicrobial Blend of Essential Oils or Constituents Thereof |
| RU2010151986A (en) * | 2008-05-19 | 2012-06-27 | Джапан Тобакко Инк. (Jp) | COVERING FRAGRANCE MATERIAL FOR A CIGARETTE, METHOD FOR PRODUCING IT AND A CIGARETTE |
| WO2009157240A1 (en) * | 2008-06-25 | 2009-12-30 | 日本たばこ産業株式会社 | Smoking article |
| RU2550333C2 (en) * | 2010-05-31 | 2015-05-10 | Джапан Тобакко Инк. | Cigarette filter and cigarette |
| RU107025U1 (en) * | 2011-04-04 | 2011-08-10 | Марсиль Робертович Ахметшин | Capsule Design for Cigarette Filter (OPTIONS) |
-
2012
- 2012-01-25 KR KR1020167025827A patent/KR102033213B1/en active IP Right Grant
- 2012-01-25 RU RU2014134518/12A patent/RU2592351C2/en active
- 2012-01-25 UA UAA201409355A patent/UA110881C2/en unknown
- 2012-01-25 WO PCT/JP2012/051524 patent/WO2013111281A1/en active Application Filing
- 2012-01-25 JP JP2013555043A patent/JP5860904B2/en active Active
- 2012-01-25 KR KR1020147023319A patent/KR20140116531A/en active Application Filing
- 2012-01-25 CN CN201280068203.3A patent/CN104080898A/en active Pending
- 2012-01-25 CN CN201811463996.4A patent/CN109480330A/en active Pending
-
2014
- 2014-11-21 HK HK14111784.1A patent/HK1198258A1/en unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1216233A (en) * | 1997-10-24 | 1999-05-12 | 日本烟草产业株式会社 | Cigarette paper having flavorant which improves sidestream smoke smell, and cigarette |
| CN1473011A (en) * | 2000-11-06 | 2004-02-04 | �ձ��̲ݲ�ҵ��ʽ���� | Deodorant composition for tobacco odor, deodorant for tobacco odor, and cigarette and tobacco package reduced in secondary smoke odor |
| CN1500477A (en) * | 2002-11-13 | 2004-06-02 | 丛繁滋 | Quick result aerosol with plant aroma and its preparation |
| CN1590522A (en) * | 2003-09-05 | 2005-03-09 | 上海百润香精香料有限公司 | Cured tobacco essence |
| CN101558860A (en) * | 2009-05-18 | 2009-10-21 | 广州市凯虹香精香料有限公司 | Compound essence special for betelnut |
Non-Patent Citations (2)
| Title |
|---|
| 于建军: "《卷烟工艺学》", 31 December 2003, 中国农业出版社 * |
| 孙宝国: "《日用化工辞典》", 30 June 2002, 化学工业出版社 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106307602A (en) * | 2016-09-12 | 2017-01-11 | 三峡大学 | Electronic cigarette liquid for freshening breath |
| CN107446700A (en) * | 2017-09-14 | 2017-12-08 | 皖西学院 | A kind of flavor compositions for showing Dendrobidium huoshanness fresh flower fragrance and application |
| CN107668771A (en) * | 2017-09-19 | 2018-02-09 | 河南中烟工业有限责任公司 | Fragrant line fennel essence and its application in a kind of ramuscule filter stick |
| CN107802030A (en) * | 2017-09-19 | 2018-03-16 | 河南中烟工业有限责任公司 | Fragrant line lilac compound and its application in a kind of ramuscule filter stick |
| CN109315820A (en) * | 2018-08-10 | 2019-02-12 | 杨福荣 | Cigarette ingredient, preparation method and the cigarette using it |
| CN110144261A (en) * | 2019-04-11 | 2019-08-20 | 杨伟祖 | A kind of cigarette lemon-grass essence |
| CN110452773A (en) * | 2019-07-09 | 2019-11-15 | 河南中烟工业有限责任公司 | A kind of quick-fried pearl fragrant citrus essence and preparation method thereof, quick-fried pearl and cigarette |
| CN110484366A (en) * | 2019-07-09 | 2019-11-22 | 河南中烟工业有限责任公司 | A kind of quick-fried pearl fennel essence and preparation method thereof, quick-fried pearl and cigarette |
Also Published As
| Publication number | Publication date |
|---|---|
| RU2014134518A (en) | 2016-03-20 |
| HK1198258A1 (en) | 2015-03-20 |
| JP5860904B2 (en) | 2016-02-16 |
| RU2592351C2 (en) | 2016-07-20 |
| CN109480330A (en) | 2019-03-19 |
| KR20160114188A (en) | 2016-10-04 |
| KR102033213B1 (en) | 2019-10-16 |
| JPWO2013111281A1 (en) | 2015-05-11 |
| KR20140116531A (en) | 2014-10-02 |
| WO2013111281A1 (en) | 2013-08-01 |
| UA110881C2 (en) | 2016-02-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104080898A (en) | Fragrance composition for improving breath having smell of cigarettes | |
| US11773344B2 (en) | Terpene-based compositions, processes, methodologies for creation and products thereby | |
| US20190240191A1 (en) | Terpene-Based Compositions, Processes Methodologies | |
| Brattoli et al. | Gas chromatography analysis with olfactometric detection (GC-O) as a useful methodology for chemical characterization of odorous compounds | |
| Bhuiyan et al. | Chemical composition of leaf and seed essential oil of Coriandrum sativum L. from Bangladesh | |
| Oyama-Okubo et al. | Analysis of floral scent compounds and classification by scent quality in tulip cultivars | |
| Bandeira Reidel et al. | Aroma profile of Rubus ulmifolius flowers and fruits during different ontogenetic phases | |
| AĞALAR et al. | The volatile compounds of the elderflowers extract and the essential oil | |
| CN109846075A (en) | A kind of electronic cigarette liquid and preparation method thereof with lemon flavor | |
| JP2023120434A (en) | Aerosolized formulation | |
| CA3106717A1 (en) | Sulfur-containing volatile organic compounds in cannabis | |
| Phi et al. | Evaluation of characteristic aroma compounds of Citrus natsudaidai Hayata (Natsudaidai) cold-pressed peel oil | |
| Minteguiaga et al. | Impact of gas chromatography and mass spectrometry combined with gas chromatography and olfactometry for the sex differentiation of Baccharis articulata by the analysis of volatile compounds | |
| Phi et al. | Characterisation of the odour volatiles in Citrus aurantifolia Persa lime oil from Vietnam | |
| Chung | Volatile compounds of Zanthoxylum piperitum AP DC. | |
| Ayalew et al. | Volatile organic compounds of anchote tuber and leaf extracted using simultaneous steam distillation and solvent extraction | |
| KR102610346B1 (en) | Perfume composition for reproducibly expressing the fragrance of the flower of Actinidia arguta | |
| TWI457437B (en) | Fragrance composition for improving tobacco odor and breath odor | |
| Hosseini et al. | Chemical analysis of essential oils from different populations of Ferulago angulata subsp. carduchorum in Iran | |
| Bertella et al. | Analysis of Bioactive Aroma Compounds in Essential Oils from Algerian Plants: Implications for Potential Antioxidant Applications | |
| Teigland | Characterisation of nonpolar compounds from Electronic cigarette aerosols by GC-MS | |
| JP2020182676A (en) | Deodorant composition | |
| Maldonado et al. | New Essential Oils from Ecuadorian Gynoxys cuicochensis Cuatrec. and Gynoxys sancti-antonii Cuatrec. Chemical Compositions and Enantioselective Analyses | |
| Hale et al. | The Volatile Compounds of the Elderflowers Extract and the Essential Oi Hale Gamze Ağalar, Betül Demirci, Fatih Demirci and Neşe Kırımer | |
| KR102299416B1 (en) | Perfume composition for expressing the fragrance of Chrysanthemum zaqadskii var. latilobum |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| REG | Reference to a national code |
Ref country code: HK Ref legal event code: DE Ref document number: 1198258 Country of ref document: HK |
|
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20141001 |
|
| RJ01 | Rejection of invention patent application after publication | ||
| REG | Reference to a national code |
Ref country code: HK Ref legal event code: WD Ref document number: 1198258 Country of ref document: HK |