CN104072853B - A kind of electric wire sheath material - Google Patents

A kind of electric wire sheath material Download PDF

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Publication number
CN104072853B
CN104072853B CN201410346515.7A CN201410346515A CN104072853B CN 104072853 B CN104072853 B CN 104072853B CN 201410346515 A CN201410346515 A CN 201410346515A CN 104072853 B CN104072853 B CN 104072853B
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China
Prior art keywords
parts
electric wire
sheath material
wire sheath
water
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Expired - Fee Related
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CN201410346515.7A
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Chinese (zh)
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CN104072853A (en
Inventor
单金博
杨延勇
亓立广
张岩
李先栋
李勇
王西华
俞力
刘玉
周广磊
张晓莉
张忠柯
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State Grid Corp of China SGCC
Liaocheng Power Supply Co of State Grid Shandong Electric Power Co Ltd
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State Grid Corp of China SGCC
Liaocheng Power Supply Co of State Grid Shandong Electric Power Co Ltd
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Application filed by State Grid Corp of China SGCC, Liaocheng Power Supply Co of State Grid Shandong Electric Power Co Ltd filed Critical State Grid Corp of China SGCC
Priority to CN201410346515.7A priority Critical patent/CN104072853B/en
Priority to CN201511013267.5A priority patent/CN105504444B/en
Priority to CN201510911689.8A priority patent/CN105295182B8/en
Publication of CN104072853A publication Critical patent/CN104072853A/en
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Publication of CN104072853B publication Critical patent/CN104072853B/en
Expired - Fee Related legal-status Critical Current
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide

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  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Insulated Conductors (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Spectroscopy & Molecular Physics (AREA)

Abstract

The invention belongs to technical field of cables, especially a kind of electric wire sheath material is related to, it is characterized in that counting by weight, it includes following material: polyvinyl resin 70-80 part, polyethylene terephthalate 10-20 part, carbon black 2-2.5 part, antioxidant 0.2-0.6 part, Microcrystalline Wax 1-3 part, titanium dioxide 1-1.6 part, antiaging agent 0.3-0.8 part, uvioresistant stablizer 0.4-0.6 part, plastics toughener 1-2 part, water-proofing powder 0.8-1.8 part.Present invention further teaches its making method.The present invention has following main beneficial effect: the sheath of the cable that starting material non-lipid, cost be low, obtained electric wire sheath material is produced punctures that rate is low, pore quantity is few on sheath cross section; The defective products that production method is simple, product qualified rate is high, formed in product and production process can recycling, can not form the waste of resource, not affect environment.

Description

A kind of electric wire sheath material
Technical field
The invention belongs to technical field of cables, especially relate to a kind of electric wire sheath material.
Background technology
Electric wire is as the basic industry of national economy, its output value has risen the second of national economy at home, it is the maximum industry after automobile industry, domestic at present have electric wire mortar businesses more than 15000, wherein contains the enterprise that pure cables manufacturing enterprise and pure fiber optic cable manufacture enterprise and optical cable and cable all produce.
Cable industry is especially in optical cable industry, and the sheath material that conventional outdoor cable adopts is polyethylene, and conventional is Low Density Polyethylene, medium-density polyethylene, high density polyethylene(HDPE).In the standard of optical cable and cable industry, require bar none the surface of sheath should rounding smooth, all should without eyesight visible bubble, sand holes and crackle on any transverse section.For when there is below sheath metal level, need to adopt electric approach to carry out the integrity test of sheath to sheath, direct voltage or voltage of alternating current is normally adopted to carry out sheath spark test, minimum value is normally adopted to be the volts DS (in units of KV) of 9 times of jacket thickness values and the volts DS being less than 25KV carries out, as jacket thickness be 2mm time, adopt the volts DS of 2 × 9=18KV to carry out spark test; Or adopt the voltage of alternating current (in units of KV, and being virtual value) of 6 times of jacket thickness values and the voltage of alternating current being less than 15KV carries out, as jacket thickness be 2mm time, adopt the voltage of alternating current of 2 × 6=12KV virtual value to carry out spark test; Can not be punctured by trial voltage, carry out when this tests normally online production, arbitrary section of sheath is all tested, have puncture namely defective; Have when puncturing, the cross section of sheath has usually more eyesight visible bubble, sand holes and crackle; Certainly, the cross section of the sheath do not punctured might not be exactly do not have eyesight visible bubble, sand holes and crackle, and likely also have eyesight visible bubble, sand holes and crackle, only eyesight visible bubble, sand holes and crackle are fewer or not obvious.
In prior art, the method for sheath material granulating has two kinds, and a kind of mode is earnestly, on extruder die head with scraper expecting directly to scrape off, then with the particle that air cooling or water cooling scrape off; Another kind of mode is that the material that cold-extruded goes out normally is cut into particle again with after water cooling.Adopt air-cooled mode time fervent, usual production line is longer, is placed on streamline and cools further after scaling off, and this mode production rate is very fast, during to the streamline end, usually just can pack; And during cold cut, although it is less that production unit can be made to take up room, after granulating, need further drying, therefore, need the long period and spend more electric power.Because plastic pellet is after granulating, normally piles and piles ofly to put together, therefore, no matter cold cut or earnestly, all without the abundant dry plastics particle of stream, at dry weather, sheath particle to meet the requirement that optical cable or cable are produced usually, and idol has punch-through; But in yellow plum weather or moisture larger season; due to the existence of the aqueous vapor of local in sheath material surface and sheath material; cause puncturing of sheath when optical, electrical cable usually can be made to manufacture, cause scrapping of whole cable, cause the increase of cost and unnecessary trouble to cable manufacturer.
Cable manufacturing enterprise is in order to avoid puncturing and the generation of cavitations, normally adopt and come partly to solve for the production of the mode of front carrying out one-level or secondary oven dry at sheath material, one-level or secondary are dried and normally before manufacture plastics are put into dryer, 4 hours are dried in 40 ~ 80 DEG C of temperature ranges, this mode can make the moisture content part of particle surface remove, but can not remove the part aqueous vapor of inside particles.
This phenomenon, can be described as the problem that line cable industry cannot overcome at present, therefore, in industry, as long as there is fairly large cable manufacturer, all wishes to find and make the sheath material that sheath does not puncture or breakdown probability reduces greatly, but regrettably there is no effective terms of settlement at present.
Summary of the invention
In order to solve the problem, the object of the invention is to disclose a kind of electric wire sheath material, it realizes by the following technical solutions.
A kind of electric wire sheath material, it is characterized in that counting by weight, it includes following material: polyvinyl resin 70-80 parts, polyethylene terephthalate 10-20 parts, carbon black 2-2.5 parts, antioxidant 0.2-0.6 part, fusing point are 80 ~ 95 DEG C of Microcrystalline Waxes 1-3 parts, titanium dioxide 1-1.6 parts, antiaging agent 0.3-0.8 part, uvioresistant stablizer 0.4-0.6 part, plastics toughener 1-2 parts, water-proofing powder 0.8-1.8 parts.
A kind of electric wire sheath material described above, it is characterized in that counting by weight, it includes following material: polyvinyl resin 70 parts, polyethylene terephthalate 10 parts, carbon black 2 parts, antioxidant 0.2 part, fusing point are 80 ~ 95 DEG C of Microcrystalline Waxes 1 part, titanium dioxide 1 part, antiaging agent 0.3 part, uvioresistant stablizer 0.4 part, plastics toughener 1 part, water-proofing powder 0.8 part.
A kind of electric wire sheath material described above, it is characterized in that counting by weight, it includes following material: polyvinyl resin 75 parts, polyethylene terephthalate 15 parts, carbon black 2.3 parts, antioxidant 0.4 part, fusing point are 80 ~ 95 DEG C of Microcrystalline Waxes 2 parts, titanium dioxide 1.3 parts, antiaging agent 0.6 part, uvioresistant stablizer 0.5 part, plastics toughener 1.5 parts, water-proofing powder 1.4 parts.
A kind of electric wire sheath material described above, it is characterized in that counting by weight, it includes following material: polyvinyl resin 80 parts, polyethylene terephthalate 20 parts, carbon black 2.5 parts, antioxidant 0.6 part, fusing point are 80 ~ 95 DEG C of Microcrystalline Waxes 3 parts, titanium dioxide 1.6 parts, antiaging agent 0.8 part, uvioresistant stablizer 0.6 part, plastics toughener 2 parts, water-proofing powder 1.8 parts.
A kind of electric wire sheath material described above, is characterized in that it obtains as follows: 1. weighing by weight obtains the starting material of following proportioning: polyvinyl resin 70-80 parts, polyethylene terephthalate 10-20 parts, carbon black 2-2.5 parts, antioxidant 0.2-0.6 part, fusing point are 80 ~ 95 DEG C of Microcrystalline Waxes 1-3 parts, titanium dioxide 1-1.6 parts, antiaging agent 0.3-0.8 part, uvioresistant stablizer 0.4-0.6 part, plastics toughener 1-2 parts, water-proofing powder 0.8-1.8 parts; 2. starting material are mixed; 3. put into plastic granulator and carry out extrusion molding stretching; 4. cool to cut again or cut to extrudate and cool again; 5. use drying machine dry; 6. quantitative package forms electric wire sheath material.
A kind of electric wire sheath material described above, is characterized in that described polyvinyl resin is ldpe resin or medium density polyethylene resin or high-density polyethylene resin.
A kind of electric wire sheath material described above, is characterized in that described water-proofing powder be the model that Hebei Renqiu City Chang Xing Chemical Co., Ltd. produces is water-proofing powder or other commercially available water-proofing powder of ZSF-100.
A kind of electric wire sheath material described above, is characterized in that described antioxidant be pentaerythritol tetrathioglycollate or two Lauryl Alcohol ester or two ten four carbon alcohols esters or two octadecanol ester or model is the antioxidant of 1010.
A kind of electric wire sheath material described above, is characterized in that described antiaging agent to be model is commercially available anti-aging agent or the Xylo-Mucine of RD4O1O.
A kind of electric wire sheath material described above, is characterized in that described uvioresistant stablizer be the model that German BASF plastics company limited produces is the photostabilizer ultraviolet-resistant absorbent of UV-329.
A kind of electric wire sheath material described above, it is characterized in that described plastics toughener be commercially available model is DH-1 or DH-2 or DH-3 or DH-4 plastics toughener, for improving the thickness of sheath and the self-adhesive performance of sheath material that electric wire sheath material produces.
Polyethylene terephthalate in the present invention also claims PET, can be brand-new material, and the mineral water bottle of also can be predominant amount composition be PET, like this, can reclaim cheap mineral water bottle in large quantities, carry out utilization of waste material; Greatly can reduce the cost of electric wire sheath material, greatly increase the competitive power of cable enterprise cost.
The present invention has following main beneficial effect: the sheath of the cable that starting material non-lipid, cost be low, obtained electric wire sheath material is produced punctures that rate is low, pore quantity is few on sheath cross section; The defective products that production method is simple, product qualified rate is high, formed in product and production process can recycling, can not form the waste of resource, not affect environment.
Embodiment
embodiment 1
A kind of electric wire sheath material, it is characterized in that counting by weight, it includes following material: polyvinyl resin 70 parts, polyethylene terephthalate 10 parts, carbon black 2 parts, antioxidant 0.2 part, fusing point are 80 ~ 95 DEG C of Microcrystalline Waxes 1 part, titanium dioxide 1 part, antiaging agent 0.3 part, uvioresistant stablizer 0.4 part, plastics toughener 1 part, water-proofing powder 0.8 part; Described a kind of electric wire sheath material, it obtains as follows: 1. weighing by weight obtains the starting material of said ratio; 2. starting material are mixed; 3. put into plastic granulator and carry out extrusion molding stretching; 4. cool to cut again or cut to extrudate and cool again; 5. use drying machine dry; 6. quantitative package forms electric wire sheath material; Described polyvinyl resin is ldpe resin; Described water-proofing powder is the model that Hebei Renqiu City Chang Xing Chemical Co., Ltd. produces is the water-proofing powder of ZSF-100; Described antioxidant to be model be 1010 antioxidant; The commercially available anti-aging agent of described antiaging agent to be model be RD4O1O; Described uvioresistant stablizer is the model that German BASF plastics company limited produces is the photostabilizer ultraviolet-resistant absorbent of UV-329; Described plastics toughener is commercially available model is DH-4 plastics tougheners.
embodiment 2
A kind of electric wire sheath material, it is characterized in that counting by weight, it includes following material: polyvinyl resin 75 parts, polyethylene terephthalate 15 parts, carbon black 2.3 parts, antioxidant 0.4 part, fusing point are 80 ~ 95 DEG C of Microcrystalline Waxes 2 parts, titanium dioxide 1.3 parts, antiaging agent 0.6 part, uvioresistant stablizer 0.5 part, plastics toughener 1.5 parts, water-proofing powder 1.4 parts; Described a kind of electric wire sheath material, it obtains as follows: 1. weighing by weight obtains the starting material of said ratio; 2. starting material are mixed; 3. put into plastic granulator and carry out extrusion molding stretching; 4. cool to cut again or cut to extrudate and cool again; 5. use drying machine dry; 6. quantitative package forms electric wire sheath material; Described polyvinyl resin is medium density polyethylene resin; Described water-proofing powder is the model that Hebei Renqiu City Chang Xing Chemical Co., Ltd. produces is the water-proofing powder of ZSF-100; Described antioxidant is pentaerythritol tetrathioglycollate antioxidant; The commercially available anti-aging agent of described antiaging agent to be model be RD4O1O; Described uvioresistant stablizer is the model that German BASF plastics company limited produces is the photostabilizer ultraviolet-resistant absorbent of UV-329; Described plastics toughener is commercially available model is DH-3 plastics tougheners.
embodiment 3
A kind of electric wire sheath material, it is characterized in that counting by weight, it includes following material: polyvinyl resin 80 parts, polyethylene terephthalate 20 parts, carbon black 2.5 parts, antioxidant 0.6 part, fusing point are 80 ~ 95 DEG C of Microcrystalline Waxes 3 parts, titanium dioxide 1.6 parts, antiaging agent 0.8 part, uvioresistant stablizer 0.6 part, plastics toughener 2 parts, water-proofing powder 1.8 parts; Described a kind of electric wire sheath material, it obtains as follows: 1. weighing by weight obtains the starting material of said ratio; 2. starting material are mixed; 3. put into plastic granulator and carry out extrusion molding stretching; 4. cool to cut again or cut to extrudate and cool again; 5. use drying machine dry; 6. quantitative package forms electric wire sheath material; Described polyvinyl resin is high-density polyethylene resin; Described water-proofing powder is the model that Hebei Renqiu City Chang Xing Chemical Co., Ltd. produces is the water-proofing powder of ZSF-100; Described antioxidant is the antioxidant of two ten four carbon alcohols esters or two octadecanol ester; The commercially available anti-aging agent of described antiaging agent to be model be RD4O1O; Described uvioresistant stablizer is the model that German BASF plastics company limited produces is the photostabilizer ultraviolet-resistant absorbent of UV-329; Described plastics toughener is commercially available model is DH-2 plastics tougheners.
Any one electric wire sheath material described above, it is characterized in that counting by weight, it includes following material: polyvinyl resin 70-80 parts, polyethylene terephthalate 10-20 parts, carbon black 2-2.5 parts, antioxidant 0.2-0.6 part, fusing point are 80 ~ 95 DEG C of Microcrystalline Waxes 1-3 parts, titanium dioxide 1-1.6 parts, antiaging agent 0.3-0.8 part, uvioresistant stablizer 0.4-0.6 part, plastics toughener 1-2 parts, water-proofing powder 0.8-1.8 parts.
Any one electric wire sheath material described above, is characterized in that described polyvinyl resin is ldpe resin or medium density polyethylene resin or high-density polyethylene resin.
Any one electric wire sheath material described above, is characterized in that described water-proofing powder be the model that Hebei Renqiu City Chang Xing Chemical Co., Ltd. produces is water-proofing powder or other commercially available water-proofing powder of ZSF-100.
Any one electric wire sheath material described above, is characterized in that described antioxidant be pentaerythritol tetrathioglycollate or two Lauryl Alcohol ester or two ten four carbon alcohols esters or two octadecanol ester or model is the antioxidant of 1010.
Any one electric wire sheath material described above, is characterized in that described antiaging agent to be model is commercially available anti-aging agent or the Xylo-Mucine of RD4O1O.
Any one electric wire sheath material described above, is characterized in that described uvioresistant stablizer be the model that German BASF plastics company limited produces is the photostabilizer ultraviolet-resistant absorbent of UV-329.
Any one electric wire sheath material described above, it is characterized in that described plastics toughener be commercially available model is DH-1 or DH-2 or DH-3 or DH-4 plastics toughener, for improving the thickness of sheath and the self-adhesive performance of sheath material that electric wire sheath material produces.
Any one electric wire sheath material described above, is characterized in that it obtains as follows: 1. weighing by weight obtains the starting material of following proportioning: polyvinyl resin 70-80 parts, polyethylene terephthalate 10-20 parts, carbon black 2-2.5 parts, antioxidant 0.2-0.6 part, fusing point are 80 ~ 95 DEG C of Microcrystalline Waxes 1-3 parts, titanium dioxide 1-1.6 parts, antiaging agent 0.3-0.8 part, uvioresistant stablizer 0.4-0.6 part, plastics toughener 1-2 parts, water-proofing powder 0.8-1.8 parts; 2. starting material are mixed; 3. put into plastic granulator and carry out extrusion molding stretching; 4. cool to cut again or cut to extrudate and cool again; 5. use drying machine dry; 6. quantitative package forms electric wire sheath material.
Applicant, for the optical cable adopting the electric wire sheath material of above-mentioned formula to produce same model specification, obtains following correlation data; All do not carry out baking material before producing cable jacket, the date manufactured of sheath material is all in 1 month; MDPE type electric wire sheath material 1 of the prior art, MDPE type electric wire sheath material 2 of the prior art are materials of different vendor's supply.
Can find out from upper table, the probability adopting the sheath material of the application to greatly reduce sheath to puncture, makes the product qualified rate of electric wire higher.
The present invention has following main beneficial effect: the sheath of the cable that starting material non-lipid, cost be low, obtained electric wire sheath material is produced punctures that rate is low, pore quantity is few on sheath cross section; The defective products that production method is simple, product qualified rate is high, formed in product and production process can recycling, can not form the waste of resource, not affect environment.
The present invention may be used for the sheath of electric wire, also may be used in the sheath extrusion process of optical cable.
The present invention is not limited to above-mentioned preferred forms, and should be appreciated that design of the present invention can be implemented to use by other various forms, they drop in protection scope of the present invention equally.

Claims (2)

1. an electric wire sheath material, it is characterized in that counting by weight, it includes following material: polyvinyl resin 70-80 parts, polyethylene terephthalate 10-20 parts, carbon black 2-2.5 parts, antioxidant 0.2-0.6 part, fusing point are 80 ~ 95 DEG C of Microcrystalline Waxes 1-3 parts, titanium dioxide 1-1.6 parts, antiaging agent 0.3-0.8 part, uvioresistant stablizer 0.4-0.6 part, plastics toughener 1-2 parts, water-proofing powder 0.8-1.8 parts; Described polyvinyl resin is ldpe resin or medium density polyethylene resin or high-density polyethylene resin; Described water-proofing powder is the model that Hebei Renqiu City Chang Xing Chemical Co., Ltd. produces is the water-proofing powder of ZSF-100; Described antioxidant is pentaerythritol tetrathioglycollate or two Lauryl Alcohol ester or two ten four carbon alcohols esters or two octadecanol ester; Described antiaging agent is Xylo-Mucine; Described uvioresistant stablizer is the model that German BASF plastics company limited produces is the photostabilizer ultraviolet-resistant absorbent of UV-329; Described plastics toughener is commercially available model is DH-1 or DH-2 or DH-3 or DH-4 plastics toughener.
2. a kind of electric wire sheath material according to claim 1, is characterized in that it obtains as follows: 1. weighing by weight part according to claim 1 obtains each starting material; 2. each starting material are mixed; 3. put into plastic granulator and carry out extrusion molding stretching; 4. cool to cut again or cut to extrudate and cool again; 5. use drying machine dry; 6. quantitative package forms electric wire sheath material.
CN201410346515.7A 2014-07-21 2014-07-21 A kind of electric wire sheath material Expired - Fee Related CN104072853B (en)

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CN201410346515.7A CN104072853B (en) 2014-07-21 2014-07-21 A kind of electric wire sheath material
CN201511013267.5A CN105504444B (en) 2014-07-21 2014-07-21 A kind of electric wire protective cover material and its manufacture method
CN201510911689.8A CN105295182B8 (en) 2014-07-21 2014-07-21 A kind of electric wire protective cover material and its manufacture method

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CN104277308A (en) * 2014-10-30 2015-01-14 安徽电信器材贸易工业有限责任公司 Sheath material for seafloor communication optical cable and preparation method thereof
CN105906907A (en) * 2016-05-03 2016-08-31 安徽九华金润铜业有限公司 Sheathing material for liquid level transmitter cable
CN105885167A (en) * 2016-05-03 2016-08-24 安徽九华金润铜业有限公司 Insulation material used for liquid level transmitter cable
CN108274716A (en) * 2018-01-29 2018-07-13 王子华 The manufacturing method of once-combined moulding plastics template
CN108312679A (en) * 2018-01-29 2018-07-24 王子华 Composite plastic template

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CN105504444B (en) 2017-12-08
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CN105295182A (en) 2016-02-03
CN105295182B (en) 2017-07-18
CN105504444A (en) 2016-04-20

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