CN104060767A - Method of industrially preparing steel-continuous-fiber composite bar - Google Patents

Method of industrially preparing steel-continuous-fiber composite bar Download PDF

Info

Publication number
CN104060767A
CN104060767A CN201410274561.0A CN201410274561A CN104060767A CN 104060767 A CN104060767 A CN 104060767A CN 201410274561 A CN201410274561 A CN 201410274561A CN 104060767 A CN104060767 A CN 104060767A
Authority
CN
China
Prior art keywords
bundle
silvalin
inner core
fiber
reinforcing bar
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410274561.0A
Other languages
Chinese (zh)
Inventor
王灵
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sichuan Aerospace Wuyuan Composite Co Ltd
Original Assignee
Sichuan Aerospace Wuyuan Composite Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sichuan Aerospace Wuyuan Composite Co Ltd filed Critical Sichuan Aerospace Wuyuan Composite Co Ltd
Priority to CN201410274561.0A priority Critical patent/CN104060767A/en
Publication of CN104060767A publication Critical patent/CN104060767A/en
Pending legal-status Critical Current

Links

Landscapes

  • Reinforcement Elements For Buildings (AREA)

Abstract

The invention discloses a method of industrially preparing a steel-continuous-fiber composite bar. The method comprises the following steps: sequentially compounding rough fiber yarns and fiber yarn bundles dipped with resin on the surface of a reinforcing steel bar to form the fiber compound bar. The fiber compound bar compounded by the process has a reasonable structure and the fiber yarn bundles used as an enhancing material are fully dipped with resin, so that the inner and outer interfaces have good adhesive performance to effectively satisfy the design strength of the reinforced concrete structure. Meanwhile, the bar further can overcome the deficiencies of high brittleness and high price of existing fiber reinforced plastic (FRP) and is good in actual using effect.

Description

The method of preparation of industrialization steel-continuous fiber composite reinforcing
Technical field
The present invention is the method for preparation of industrialization steel-continuous fiber composite reinforcing, and the manufacture craft of the composite reinforcing reinforcing material that is specifically related to use in reinforced concrete structure, belongs to field of compound material.
Background technology
Reinforced concrete structure (reinforced concrete structure) is a kind of structure by reinforcing bar and concrete constructions, reinforcing bar bearing tension, concrete bears pressure, have firm, durable, fireproof performance is good, save steel and low cost and other advantages than steel work, also be a kind of construction more common in current construction work, be used for various super-high buildings, longspan structure, as the load structure such as bridge, tunnel.In its structure, reinforcing bar is as basic reinforcing material, its combination property is stronger, but there is the shortcomings such as easily corrosion, based on this situation, in recent years, fibre reinforced composites (FRP) are because the characteristic of its high-strength light is used widely gradually, for example, patent documentation CN1936206A(steel-continuous-fiber composite-rib reinforced concrete earthquake-resisting structure) a kind of earthquake resistant structure that uses these fibre reinforced composites (FRP) and concrete binding to form disclosed, but in the time that reality is used, these fibre reinforced composites (FRP) but also exist material fragility strong, the defects such as price height, for this reason, Chinese scholars propose with different fibers mix or fibers encapsulation reinforcing bar to obtain combination property excellent, the advanced composite material (ACM) reinforcing rib that price is low, but at present, research to steel-continuous fiber composite reinforcing (SFCB) is at home and abroad scarcely out of swaddling-clothes, there is no ripe product, certainly, its production technology does not have regularization yet.
Summary of the invention
The object of the present invention is to provide the method for preparation of industrialization steel-continuous fiber composite reinforcing, adopt indented bars as inner core, use successively fiber roving and silvalin bundle to be composited, there is rational structural texture, and the silvalin Shu Caiyong resin using as reinforcing material fully floods, in it, outer boundary all has good adhesive property, can effectively be satisfied with the design strength of reinforced concrete structure, simultaneously, can also overcome existing fibre reinforced composites (FRP) and have the defects such as material fragility is strong, price is high, practical effect is good.
The present invention is achieved through the following technical solutions: the method for preparation of industrialization steel-continuous fiber composite reinforcing, this fibre composite reinforcement has overcome existing fibre reinforced composites (FRP) and has had the defects such as material fragility is strong, price is high, there is stronger combination property, and cheap, in the present invention, the method is the manufacture craft that is compounded in rebar surface and forms fibre composite reinforcement being impregnated with the fiber roving of resin and silvalin Shu Yici, comprises the following steps:
(1) inner core processing: select indented bars as reinforcing bar inner core, adopt sander to remove the monosymmetric longitudinal michinaga rib of this indented bars, make twisted steel material, and use wipes of alcohol wash clean;
(2) hoop Filament-wound Machine: the twisted steel material that adopts fiber roving to make step (1) carries out hoop winding;
(3) row's yarn: the reinforcing bar material that step (2) is made is placed on row's yarn seat, the silvalin bundle that is impregnated with resin is evenly arranged in to the outside of reinforcing bar inner core through arranging yarn device;
(4) curing molding: use draw-gear, the reinforcing bar inner core that above-mentioned steps (3) is made is sent into pulltrusion device and curing oven successively, completes the compound of fibre composite reinforcement.
The present invention is applicable to the industry preparation that diameter is the indented bars of 8~12mm, and therefore, in the present invention, described reinforcing bar inner core adopts the indented bars that diameter is 8~12mm.
To better implement the present invention, on described fiber roving, be coated with and be brushed with resin, described fiber roving carries out hoop winding along the space between twisted steel material salient rib, can be used for filling up the gap between indented bars screw thread, simultaneously, can, in the time that reinforcing bar inner core becomes composite reinforcing with silvalin Shu Fuhe pultrusion, strengthen adhesive property and globality between indented bars and silvalin bundle (longitudinal fiber).
In theory, the fiber roving that this hoop is wound around, in the time of fibre composite reinforcement axially loaded, does not play a role substantially, therefore can adopt continuous fiber cheaply, that is: described fiber roving is basalt fibre or glass fiber.
The dipping method of described silvalin bundle comprises: silvalin bundle is arranged on creel with the form of spindle, the row's of employing creel is introduced the silvalin bundle on spindle to be loaded with in the dipping tank of resin again, after silvalin bundle dipping is abundant, the row's of re-using yarn device is evenly arranged in this silvalin bundle in the outside of reinforcing bar inner core, in the present invention, the dipping of silvalin bundle adopts the method for straight trough dipping, simple to operate, quick.
Further, on described creel, the magnitude setting of spindle is 20~40 orders.
In the present invention, described silvalin bundle is basalt yarn bundle or carbon fiber yarn bundle.
The present invention compared with prior art, has the following advantages and beneficial effect:
(1) the fibre composite reinforcement structure the present invention relates to is reasonable in design, mainly be composited by indented bars, fiber roving and silvalin bundle, and the fiber roving and the silvalin bundle that use as reinforcing material all adopt resin fully to flood, can not only effectively be satisfied with the design strength of reinforced concrete structure, simultaneously, can also overcome existing fibre reinforced composites (FRP) and have the defects such as material fragility is strong, price is high, there is stronger combination property, and cheap, suitablely extensively promote the use of.
(2) the present invention adopts basalt fibre or glass fiber to carry out hoop winding as fiber roving, in theory, the fiber roving that this hoop is wound around, in the time of fibre composite reinforcement axially loaded, does not play a role substantially, therefore can adopt continuous fiber cheaply, cost of production is very cheap.
(3) the present invention is before using fiber roving double thread reinforcing bar inner core to be wound around, also need to carry out sanding operation, mainly due to the existing indented bars both sides of buying on the market all with longitudinal michinaga rib of symmetry, tend to cause the fibre composite reinforcement cross section ovalize structure being composited, for this reason, also need to adopt sander to remove it, simple to operate, quick.
Detailed description of the invention
Below goal of the invention of the present invention, technical scheme and beneficial effect are described in further detail.
Should be noted that, it is all exemplary below describing in detail, be intended for the requested to provide further explanation of the invention, except as otherwise noted, all technology used herein and scientific terminology have the identical meanings of conventionally understanding with general technical staff of the technical field of the invention.
Reinforcing bar is widely used reinforcing material in current reinforced concrete structure (reinforced concrete structure), should possess stronger combination property, but there is the defects such as material fragility is strong, price is high based on existing fibre reinforced composites (FRP), the present invention proposes a kind of method of preparation of industrialization steel-continuous fiber composite reinforcing, this fibre composite reinforcement not only has stronger combination property, and its price is also very cheap.The fibre composite reinforcement the present invention relates to is mainly composited by indented bars, fiber roving and silvalin bundle, there is rational structural texture, and the fiber roving and the silvalin bundle that use as reinforcing material all adopt resin fully to flood, can not only effectively be satisfied with the design strength of reinforced concrete structure, simultaneously, can also overcome existing fibre reinforced composites (FRP) and have the defects such as material fragility is strong, price is high, there is stronger combination property, and cheap, suitablely extensively promote the use of.
Below further describing fibre composite reinforcement of the present invention:
The fibre composite reinforcement the present invention relates to includes following three parts:
A: reinforcing bar inner core: the indented bars that selection diameter is 8~12mm is as reinforcing bar inner core;
B: fiber roving: hoop is wound in the thread pitch of indented bars, in theory, the fiber roving that this hoop is wound around, in the time of fibre composite reinforcement axially loaded, does not play a role, substantially therefore can adopt continuous fiber cheaply, that is: basalt fibre or glass fiber.
C: silvalin bundle: be longitudinally evenly arranged in the outside of reinforcing bar inner core, can select basalt yarn bundle or carbon fiber yarn bundle.
In said structure, fiber roving and silvalin Shu Shangjun are impregnated with resin, in actual fabrication process, can in mixed with resin device, complete the abundant dipping of resin, to reach the working design intensity of reinforced concrete structure, it is very reasonable to design, wherein, resin can be selected epoxy resin, as: Atlac430 epoxy bisphenol-A vinylite.
Enumerate explanation the specific embodiment of the present invention with an exemplary embodiments below, certainly, protection scope of the present invention is not limited to following examples.
This method is the industrial production process of fibre composite reinforcement, is the manufacture craft that is compounded in rebar surface and forms fibre composite reinforcement being impregnated with the fiber roving of resin and silvalin Shu Yici, and in the present embodiment, its preparation method specifically comprises the following steps:
(1) inner core processing: select the indented bars (as: HRB400 type indented bars) of 10mm diameter as reinforcing bar inner core, adopt sander to remove the monosymmetric longitudinal michinaga rib of this indented bars, make twisted steel material, and use wipes of alcohol wash clean, the key property of HRB400 type indented bars is as shown in table 1:
Table 1
Reinforcing bar type Model Yield strength (MPa) Modulus of elasticity (Gpa) Weight (kg/m) Diameter (mm)
Indented bars HRB400 420 200 0.617 10
(2) hoop Filament-wound Machine: select Atlac430 epoxy bisphenol-A vinylite as brushing resin, basalt fibre is brushed, and then the basalt fibre that painting is brushed with to resin is wound around along the space hoop between twisted steel material salient rib, wherein, the material property of Atlac430 epoxy bisphenol-A vinylite is as shown in table 2:
Table 2
Resin Tensile strength (MPa) Stretch modulus (Gpa) Fracture elongation (%) Density (g/m 3
Atlac430 95 3.6 6.1 1.06
(3) impregnation of fibers yarn bundle: carbon fiber yarn bundle is arranged on creel with the form of spindle, then the row's of employing creel introduces carbon fiber yarn bundle on spindle to be loaded with in the dipping tank of resin, carbon fiber yarn bundle can be selected the carbon fiber yarn bundle of 12k, and spindle is set as 40 orders
(4) row's yarn: after silvalin bundle dipping is abundant, the row's of re-using yarn device is evenly arranged in this silvalin bundle in the outside of reinforcing bar inner core, in the present embodiment, the dipping of carbon fiber yarn bundle adopts the method for straight trough dipping, simple to operate, quick.
(5) curing molding: use draw-gear, the reinforcing bar inner core that above-mentioned steps (4) is made is sent into pulltrusion device and isothermal curing stove successively, completes the compound of fibre composite reinforcement.
The fibre composite reinforcement making is tested, and its mechanical characteristic is as shown in table 3:
Table 3
Diameter (mm) Play mould (Gpa) Intensity (MPa)
12 152 588
The fibre composite reinforcement that the present embodiment is made and plain bars and fibre reinforced composites (FRP) carry out comprehensive comparison, as shown in table 4:
Table 4
Tested object Intensity Play mould Ductility Weight Price Corrosion resistance
Reinforcing bar Low High Good Heavy Low Poor
FRP High Lower than reinforcing bar Low Gently High Better
The present embodiment Higher Higher Good Lighter Lower Better
The above, be only preferred embodiment of the present invention, not the present invention done to any pro forma restriction, and any simple modification, equivalent variations that every foundation technical spirit of the present invention is done above embodiment, within all falling into protection scope of the present invention.

Claims (7)

1. the method for preparation of industrialization steel-continuous fiber composite reinforcing, is characterized in that: the method is the manufacture craft that is compounded in rebar surface and forms fibre composite reinforcement being impregnated with the fiber roving of resin and silvalin Shu Yici, comprises the following steps:
(1) inner core processing: select indented bars as reinforcing bar inner core, adopt sander to remove the monosymmetric longitudinal michinaga rib of this indented bars, make twisted steel material, and use wipes of alcohol wash clean;
(2) hoop Filament-wound Machine: the twisted steel material that adopts fiber roving to make step (1) carries out hoop winding;
(3) row's yarn: the reinforcing bar material that step (2) is made is placed on row's yarn seat, the silvalin bundle that is impregnated with resin is evenly arranged in to the outside of reinforcing bar inner core through arranging yarn device;
(4) curing molding: use draw-gear, the reinforcing bar inner core that above-mentioned steps (3) is made is sent into pulltrusion device and curing oven successively, completes the compound of fibre composite reinforcement.
2. the method for preparation of industrialization steel-continuous fiber composite reinforcing according to claim 1, is characterized in that: described reinforcing bar inner core adopts the indented bars that diameter is 8~12mm.
3. the method for preparation of industrialization steel-continuous fiber composite reinforcing according to claim 1, is characterized in that: described fiber roving carries out hoop winding along the space between twisted steel material salient rib.
4. the method for preparation of industrialization steel-continuous fiber composite reinforcing according to claim 1, is characterized in that: described fiber roving is basalt fibre or glass fiber.
5. the method for preparation of industrialization steel-continuous fiber composite reinforcing according to claim 1, it is characterized in that: the dipping method of described silvalin bundle comprises: silvalin bundle is arranged on creel with the form of spindle, the row's of employing creel is introduced the silvalin bundle on spindle to be loaded with in the dipping tank of resin again, after silvalin bundle dipping is abundant, the row's of re-using yarn device is evenly arranged in this silvalin bundle in the outside of reinforcing bar inner core.
6. the method for preparation of industrialization steel-continuous fiber composite reinforcing according to claim 5, is characterized in that: on described creel, the magnitude setting of spindle is 20~40 orders.
7. the method for preparation of industrialization steel-continuous fiber composite reinforcing according to claim 1, is characterized in that: described silvalin bundle is basalt yarn bundle or carbon fiber yarn bundle.
CN201410274561.0A 2014-06-19 2014-06-19 Method of industrially preparing steel-continuous-fiber composite bar Pending CN104060767A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410274561.0A CN104060767A (en) 2014-06-19 2014-06-19 Method of industrially preparing steel-continuous-fiber composite bar

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410274561.0A CN104060767A (en) 2014-06-19 2014-06-19 Method of industrially preparing steel-continuous-fiber composite bar

Publications (1)

Publication Number Publication Date
CN104060767A true CN104060767A (en) 2014-09-24

Family

ID=51548680

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410274561.0A Pending CN104060767A (en) 2014-06-19 2014-06-19 Method of industrially preparing steel-continuous-fiber composite bar

Country Status (1)

Country Link
CN (1) CN104060767A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106498974A (en) * 2016-12-27 2017-03-15 国网江苏省电力公司经济技术研究院 A kind of assembling type base and its installation method for power transmission tower
CN106827589A (en) * 2017-01-22 2017-06-13 北京工业大学 A kind of preparation technology of the FRP section bars arch of embedded shaped steel
CN107160715A (en) * 2017-05-25 2017-09-15 江苏海川新材料科技有限公司 A kind of glass fiber-reinforced polymer production technology
CN107217786A (en) * 2017-05-05 2017-09-29 广东工业大学 Confusion type FRP steel composite reinforcing marine sand concrete beams
CN110079055A (en) * 2019-04-10 2019-08-02 鞍钢建设集团有限公司 A kind of combined type Side fascia environment-friendly and energy-efficient connector and its production method
CN110539505A (en) * 2019-09-19 2019-12-06 中国人民解放军陆军工程大学 Preparation method of SFCB (Small form-factor pluggable) rib
CN112593658A (en) * 2020-12-17 2021-04-02 广东工业大学 Steel-FRP (fiber reinforced plastic) composite bar seawater sea sand concrete beam, design method and preparation method

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005009307A (en) * 2003-06-17 2005-01-13 Korea Inst Of Construction Technology Reinforcing material for hybrid fiber reinforced polymer
CN2732884Y (en) * 2004-01-19 2005-10-12 株式会社汉城補强世界 Reinforcing bar for concrete structures
CN1936206A (en) * 2006-10-24 2007-03-28 东南大学 Steel-continuous-fiber composite-rib reinforced concrete earthquake-resisting structure
CA2596911A1 (en) * 2006-08-11 2008-02-11 Sinoma Science & Technology Co., Ltd. Fiber-reinforced plastic bar
KR100861578B1 (en) * 2008-06-18 2008-10-07 신승수 Frp re-bar for reinforcing concrete structure and its manufacturing method
CN201236420Y (en) * 2008-07-31 2009-05-13 四川航天拓鑫玄武岩实业有限公司 Fibre composite reinforcement material
CN101560816A (en) * 2009-05-15 2009-10-21 同济大学 FRP rib fibre cloth winding coaxial connection method
CN101817227A (en) * 2010-05-11 2010-09-01 南京锋晖复合材料有限公司 Method for processing composite fiber material spiral stirrup
CN103132654A (en) * 2011-07-22 2013-06-05 湖北金力工程复合材料有限公司 FRP reinforcement material end nut and manufacturing method and application thereof
CN203080803U (en) * 2012-12-25 2013-07-24 淮南市金德实业有限公司 Re-processable composite rib
CN103334382A (en) * 2013-07-15 2013-10-02 天津城建大学 High-strength fiber material wedge anchoring device and construction method thereof

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005009307A (en) * 2003-06-17 2005-01-13 Korea Inst Of Construction Technology Reinforcing material for hybrid fiber reinforced polymer
CN2732884Y (en) * 2004-01-19 2005-10-12 株式会社汉城補强世界 Reinforcing bar for concrete structures
CA2596911A1 (en) * 2006-08-11 2008-02-11 Sinoma Science & Technology Co., Ltd. Fiber-reinforced plastic bar
CN1936206A (en) * 2006-10-24 2007-03-28 东南大学 Steel-continuous-fiber composite-rib reinforced concrete earthquake-resisting structure
KR100861578B1 (en) * 2008-06-18 2008-10-07 신승수 Frp re-bar for reinforcing concrete structure and its manufacturing method
CN201236420Y (en) * 2008-07-31 2009-05-13 四川航天拓鑫玄武岩实业有限公司 Fibre composite reinforcement material
CN101560816A (en) * 2009-05-15 2009-10-21 同济大学 FRP rib fibre cloth winding coaxial connection method
CN101817227A (en) * 2010-05-11 2010-09-01 南京锋晖复合材料有限公司 Method for processing composite fiber material spiral stirrup
CN103132654A (en) * 2011-07-22 2013-06-05 湖北金力工程复合材料有限公司 FRP reinforcement material end nut and manufacturing method and application thereof
CN203080803U (en) * 2012-12-25 2013-07-24 淮南市金德实业有限公司 Re-processable composite rib
CN103334382A (en) * 2013-07-15 2013-10-02 天津城建大学 High-strength fiber material wedge anchoring device and construction method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
罗云标 等: "钢-连续纤维复合筋(SFCB)的生产制备研究", 《工程抗震与加固改造》 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106498974A (en) * 2016-12-27 2017-03-15 国网江苏省电力公司经济技术研究院 A kind of assembling type base and its installation method for power transmission tower
CN106827589A (en) * 2017-01-22 2017-06-13 北京工业大学 A kind of preparation technology of the FRP section bars arch of embedded shaped steel
CN107217786A (en) * 2017-05-05 2017-09-29 广东工业大学 Confusion type FRP steel composite reinforcing marine sand concrete beams
CN107160715A (en) * 2017-05-25 2017-09-15 江苏海川新材料科技有限公司 A kind of glass fiber-reinforced polymer production technology
CN110079055A (en) * 2019-04-10 2019-08-02 鞍钢建设集团有限公司 A kind of combined type Side fascia environment-friendly and energy-efficient connector and its production method
CN110539505A (en) * 2019-09-19 2019-12-06 中国人民解放军陆军工程大学 Preparation method of SFCB (Small form-factor pluggable) rib
CN112593658A (en) * 2020-12-17 2021-04-02 广东工业大学 Steel-FRP (fiber reinforced plastic) composite bar seawater sea sand concrete beam, design method and preparation method

Similar Documents

Publication Publication Date Title
CN104060767A (en) Method of industrially preparing steel-continuous-fiber composite bar
CN104060765A (en) Steel-continuous-fiber composite bar and preparation method thereof
CN104085117B (en) A kind of preparation method being applicable to steel-continuous-fiber composite-rib
CN101817227B (en) Method for processing composite fiber material spiral stirrup
CN104060768A (en) Industrial preparation method of steel-continuous-fiber composite bar with rib texture
CN201459947U (en) Fiber reinforced composite material-restraining bending and energy consumption-preventing steel support
CN102279449B (en) Basalt fiber optical cable reinforced core and manufacturing method thereof
CN202108160U (en) Fiber-reinforced resin rib material
CN101575884A (en) Reinforced-fiber composite constraining anti-buckling energy-consumption steel timbering
CN102235095B (en) Preparation method of fiber reinforced polymer sheet
CN103225369A (en) Fiber composite bar with surface having helicitic texture, and making method thereof
CN103132654B (en) FRP reinforcement material end nut and manufacturing method thereof
CN103302906A (en) Ultra-high-modulus polyethylene fiber reinforced plastic rod and manufacturing method thereof
CN104059238A (en) Preparation method of basalt fiber reinforced polymer rebar
CN104060766A (en) Steel-continuous-fiber composite bar for building
CN107100327A (en) The concrete structure and implementation method of a kind of carbon cloth parcel reinforcing bar
CN104480619A (en) Jute biaxial weft knitted fabric reinforced polypropylene composite material and manufacturing method thereof
CN104842569B (en) Composite FRP bar, preparation process and preparation device
CA2596911A1 (en) Fiber-reinforced plastic bar
CN209163221U (en) A kind of FRP pipe composite reinforcing sea sand concrete columns
CN204509978U (en) Adopt the concrete structure that circle FRP constraint concrete core strengthens
CN103526880B (en) Manufacturing method for FRP constraint PVC pipe-steel pipe internal filling concrete fireproof combination column
RU77309U1 (en) BAR FOR CONCRETE REINFORCEMENT
CN104059336A (en) Basalt fiber reinforced polymer rebar and preparation method thereof
CN204826415U (en) A preparation facilities for preparing compound FRP muscle

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C12 Rejection of a patent application after its publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20140924