CN104060031A - Core spun yarn and application thereof, vanadium nitrogen alloyed molten steel and preparation method thereof, and vanadium nitrogen microalloyed steel - Google Patents
Core spun yarn and application thereof, vanadium nitrogen alloyed molten steel and preparation method thereof, and vanadium nitrogen microalloyed steel Download PDFInfo
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Abstract
The invention provides a core spun yarn and application thereof. The core spun yarn comprises a core layer and an outer layer wrapping the core layer, the core layer is a mixture comprising vanadium nitrogen alloy, ferro-silicon nitride, iron alloy and aluminum pills, and the iron alloy is titanium iron alloy and/or niobium iron alloy. The invention provides vanadium nitrogen alloyed molten steel and a preparation method thereof, and the method includes feeding of the core spun yarn into to-be-vanadium and nitrogen alloyed molten steel for vanadium nitrogen alloying. The invention provides vanadium nitrogen microalloyed steel, and the vanadium nitrogen microalloyed steel is casted by the vanadium nitrogen alloyed molten steel. The core spun yarn is used for realizing molten steel vanadium and nitrogen alloying, nitrogen content can be effectively increased without affecting on the vanadium content according to the need, vanadium containing steel with higher nitrogen content can be produced in the need of the molten steel, and the recovery rate of nitrogen is high and stable.
Description
Technical field
The present invention relates to a kind of cored-wire and the application in molten steel VN alloy thereof, and a kind of VN alloy molten steel and preparation method thereof, and a kind of V-N Microalloy Steel.
Background technology
VN alloy is a kind of novel alloy additive, can substitute the production of vanadium iron for microalloyed steel.VN alloy makes an addition to the comprehensive mechanical performances such as intensity, toughness, ductility and the thermal fatigue resistance that can improve steel in steel, and makes steel have good weldability.Reaching under same intensity, adding vanadium nitride and save vanadium add-on 30-40%, and then reduced cost.VN alloy can be used for structure iron, tool steel, and pipe line steel, in reinforcing bar and cast iron.VN alloy is applied in high-strength low-alloy steel can carry out effective vanadium, nitrogen microalloying simultaneously, promotes separating out of carbon in steel, vanadium, nitrogen compound, more effective performance sedimentation strengthening and Grain refinement.
Owing to directly adding the rate of recovery in molten steel lower with block-shape morphology VN alloy, in prior art, be mainly therefore that the method by feed cored-wire in molten steel realizes molten steel vanadium, nitrogen alloying.The method is a block or spherical VN alloy physical method fragmentation, then packs into cored-wire with iron sheet or sheetmetal, and VN alloy forms the sandwich layer of cored-wire, the skin of iron sheet or sheetmetal formation cored-wire; Then above-mentioned cored-wire is fed in the molten steel in ladle by Yarn feeding device, make molten steel vanadium, nitrogen alloying.This kind of method vanadium, the nitrogen alloying element rate of recovery are higher, and vanadium recovery is at 88-95%, and nitrogen recovery is at 70-90%.But this kind of method is applied in the higher kind of some nitrogen content requirements and has some limitations, because the nitrogen content of this kind of core-spun yarn made of vanadium nitride is limited by the ratio of nitrogen in vanadium-nitrogen alloy and vanadium, in currently available products, VN alloy has VN12, VN14 and tri-trades mark of VN16 conventionally, generally the ratio of these three trade mark nitrogen and vanadium 12:78 (N:V) respectively; 14:78 (N:V); 16:78 (N:V).Can find out that the ratio of nitrogen and vanadium is up to the 16:78 of VN16, in alloy, contain 16% N, contain 78% vanadium.
Therefore, if produce nitrogen content higher containing vanadium steel, must a large amount of vanadium nitride of corresponding feeding, the consequent is that the content of vanadium in steel also rolls up.And vanadium is more valuable metallic element, be unnecessary for the production low cost reducing containing vanadium steel.
Summary of the invention
The technical problem to be solved in the present invention is to provide one and can be used in that to produce nitrogen content higher, and the rate of recovery of nitrogen high and stable containing the cored-wire of vanadium steel.
For realizing aforementioned object, according to a first aspect of the invention, the invention provides a kind of cored-wire, this cored-wire comprises: the skin of sandwich layer and the described sandwich layer of parcel, wherein, described sandwich layer is the mixture that contains VN alloy, ferro-silicon nitride, iron alloy and aluminum shot, and described iron alloy is ferro-titanium and/or ferrocolumbium.
According to a second aspect of the invention, the invention provides the application of cored-wire of the present invention in preparation VN alloy molten steel.
According to a third aspect of the invention we, the invention provides a kind of preparation method of VN alloy molten steel, the method comprises: cored-wire of the present invention is fed in the molten steel for the treatment of VN alloy and carries out VN alloy.
According to a forth aspect of the invention, the invention provides the VN alloy molten steel preparing according to the preparation method of VN alloy molten steel of the present invention.
According to a fifth aspect of the invention, the invention provides a kind of V-N Microalloy Steel, wherein, this V-N Microalloy Steel is formed by VN alloy molten steel casting of the present invention.
Cored-wire of the present invention, for realizing the alloying of molten steel vanadium and nitrogen, can effectively increase nitrogen content and not affect content of vanadium according to needs, can in the situation that molten steel needs, produce nitrogen content higher containing vanadium steel, and the rate of recovery of nitrogen is high and stable.And it is high to adopt cored-wire of the present invention to carry out the V-N Microalloy Steel yield strength and the tensile strength that after VN alloy molten steel casting that molten steel VN alloy obtains, obtain.
Other features and advantages of the present invention are described in detail the embodiment part subsequently.
Brief description of the drawings
Accompanying drawing is to be used to provide a further understanding of the present invention, and forms a part for specification sheets, is used from explanation the present invention, but is not construed as limiting the invention with embodiment one below.In the accompanying drawings:
Fig. 1 is the cross section view of cored-wire of the present invention.
Description of reference numerals
1 sandwich layer 2 skins
Embodiment
Below the specific embodiment of the present invention is elaborated.Should be understood that, embodiment described herein only, for description and interpretation the present invention, is not limited to the present invention.
As shown in Figure 1, the invention provides a kind of cored-wire, this cored-wire comprises: the skin 2 of sandwich layer 1 and the described sandwich layer 1 of parcel, wherein, the mixture of described sandwich layer 1 for containing VN alloy, ferro-silicon nitride, iron alloy and aluminum shot, described iron alloy is ferro-titanium and/or ferrocolumbium.
According to cored-wire of the present invention, on the one hand by add ferro-silicon nitride in sandwich layer, can improve the nitrogen content of unit sandwich layer, be beneficial to produce nitrogen content higher containing vanadium steel, for example produce containing vanadium 0.05 % by weight, more than nitrogenous 0.015 % by weight non-hardened and tempered steel, thereby can avoid the excessive phenomenon that adds noble metal vanadium to occur, reduce production cost.On the other hand, ferro-silicon nitride add the use properties that does not affect cored-wire, and the rate of recovery of nitrogen is high and stable in preparation VN alloy molten steel, and further, because described sandwich layer of the present invention is the mixture that contains VN alloy, ferro-silicon nitride, iron alloy and aluminum shot, make to adopt cored-wire of the present invention to carry out the V-N Microalloy Steel yield strength and the tensile strength that after VN alloy molten steel casting that molten steel VN alloy obtains, obtain high.
According to cored-wire of the present invention, in preferred described mixture, the content of VN alloy is 50-94 % by weight, and the content of ferro-silicon nitride is 4-15 % by weight, and the content of iron alloy is 1-25 % by weight, and the content of aluminum shot is 1-25 % by weight.Adopt aforementioned cored-wire to carry out molten steel VN alloy, nitrogen recovery is high and stable, and the V-N Microalloy Steel yield strength and the tensile strength that after the VN alloy molten steel casting obtaining, obtain are high.
According to cored-wire of the present invention, in preferred described VN alloy, N content is 10-18 % by weight, and V content is 76-82 % by weight, and all the other are Fe and inevitable other impurity element.Aforementioned VN alloy can be for example that VN12(V content is 76.0-82.0 % by weight for the trade mark, N content is 10.0-14.0 % by weight, all the other are Fe and inevitable other impurity element), VN14(V content is 76.0-82.0 % by weight, N content is 12.0-16.0 % by weight, and all the other are Fe and inevitable other impurity element), (V content is 76.0-82.0 % by weight to the VN alloy of VN16, N content is 14.0-18.0 % by weight, and all the other are Fe and inevitable other impurity element).Adopt aforementioned cored-wire to carry out molten steel VN alloy, nitrogen recovery is high and stable, and the V-N Microalloy Steel yield strength and the tensile strength that after the VN alloy molten steel casting obtaining, obtain are high.
According to cored-wire of the present invention, the main component of described ferro-silicon nitride is Si
3n
4, follow the ferrosilicon of minute quantity free iron, not nitrogenize and the inevitable mixture of some other impurity element composition.For the present invention, in preferred described ferro-silicon nitride, N content is 32-39 % by weight, and Si content is 48-58 % by weight, and all the other are a small amount of Fe and inevitable other impurity element.Adopt aforementioned cored-wire to carry out molten steel VN alloy, nitrogen recovery is high and stable, and the V-N Microalloy Steel yield strength obtaining after the VN alloy molten steel casting obtaining is high and tensile strength is high.
According to cored-wire of the present invention, preferred described iron alloy is the hybrid alloys of ferrocolumbium and ferro-titanium, further preferred, and the weight ratio of ferrocolumbium and ferro-titanium is 1-10:1.Adopt the cored-wire of aforementioned preferred iron alloy to carry out molten steel VN alloy, nitrogen recovery is high and stable, and the V-N Microalloy Steel yield strength obtaining after the VN alloy molten steel casting obtaining is high and tensile strength is high.
According to cored-wire of the present invention, in preferred described ferrocolumbium, Nb+Ta content is 60-80 % by weight, all the other are Fe and inevitable other impurity element, aforementioned ferrocolumbium can be for example that FeNb60(Nb+Ta content is 60.0-70.0 % by weight for the trade mark, Ta content≤0.3 % by weight, all the other are Fe and inevitable other impurity element), FeNb70(Nb+Ta content is 70.0-80.0 % by weight, all the other be Fe and inevitable other impurity element) ferrocolumbium.Adopt aforementioned cored-wire to carry out molten steel VN alloy, nitrogen recovery is high and stable, and the V-N Microalloy Steel yield strength and the tensile strength that after the VN alloy molten steel casting obtaining, obtain are high.
According to cored-wire of the present invention, in preferred described ferro-titanium, Ti content is 25-45 % by weight, all the other are Fe and inevitable other impurity element, aforementioned ferro-titanium can be for example that FeTi30(Ti content is 25.0-35.0 % by weight for the trade mark, all the other are Fe and inevitable other impurity element), the trade mark is that FeTi40(Ti content is 35.0-45.0 % by weight, all the other be Fe and inevitable other impurity element) ferro-titanium.Adopt aforementioned cored-wire to carry out molten steel VN alloy, nitrogen recovery is high and stable, and the V-N Microalloy Steel yield strength and the tensile strength that after the VN alloy molten steel casting obtaining, obtain are high.
According to cored-wire of the present invention, Al content >=95 % by weight in preferred described aluminum shot, all the other are inevitable other impurity element.
According to cored-wire of the present invention, fuse into fast in molten steel for the ease of VN alloy, ferro-silicon nitride, iron alloy and aluminum shot, also be convenient to the making of the sandwich layer of cored-wire, simultaneously in order to improve yield strength and the tensile strength of V-N Microalloy Steel, the mixture that contains VN alloy, ferro-silicon nitride, iron alloy and aluminum shot is preferably powder form, more preferably the grain diameter of described powder, below 5mm, is preferably below 2mm, the following or 2-5mm of 3mm.
According to cored-wire of the present invention, the described skin of preferred described cored-wire is iron sheet or sheetmetal.
The present invention is to the material of described iron sheet or sheetmetal without particular requirement, and it can be the routine selection of this area, and the present invention is not described in detail at this.
The cored-wire with aforementioned component of the present invention all can be realized object of the present invention, and its preparation method can be that the routine of this area is selected, for example, can carry out as follows:
VN alloy, ferro-silicon nitride, iron alloy and aluminum shot are ground to form to powder, then use crust (thereby forming skin of the present invention) for example can be wrapped to form cored-wire for iron sheet or sheetmetal.
In the present invention, the diameter of cored-wire can be that the routine of this area is selected, and for the present invention, preferably the external diameter of cored-wire is 10-20mm.
The invention provides the application of a kind of cored-wire of the present invention in preparation VN alloy molten steel.
The preparation method who the invention provides a kind of VN alloy molten steel, the method comprises: cored-wire of the present invention is fed in the molten steel for the treatment of VN alloy and carries out VN alloy.
According to the preparation method of VN alloy molten steel of the present invention, feed fast in molten steel in order to be conducive to cored-wire, simultaneously in order to improve yield strength and the tensile strength of V-N Microalloy Steel, preferably carrying out in VN alloy process, under dynamic condition, carry out VN alloy, dynamic condition can be by rocking ladle or rotating and realize, for example can be in cored-wire feeds the molten steel in ladle by Yarn feeding device in, ladle is rocked.
According to the preparation method of VN alloy molten steel of the present invention, wherein, carrying out in VN alloy process, preferably in cored-wire is fed to the molten steel in ladle by Yarn feeding device in, to the contact area winding-up rare gas element of cored-wire and molten steel.
In the present invention, rare gas element can be that the routine of this area is selected, for example, can be nitrogen and/or argon gas.
According to the preparation method of VN alloy molten steel of the present invention, by to cored-wire and molten steel contact area winding-up rare gas element, can improve on the one hand the mobility of the slag in this region, can improve yield strength and the tensile strength of V-N Microalloy Steel simultaneously, can prevent that on the other hand the slag beyond this region from collecting towards this zone flows, especially ladle is rocked in process, the slag in other region is likely towards cored-wire Flow Structure Nearby, by near the rare gas element of jetting cored-wire, can effectively ensure the quick feeding of cored-wire.
According to the preparation method of VN alloy molten steel of the present invention, wherein, preferably the speed of cored-wire feeding is 3-10 meter per second.
According to the preparation method of VN alloy molten steel of the present invention, the molten steel for the treatment of VN alloy described in is preferably the molten steel of carbon silicomanganese.
According to one of the present invention preferred embodiment, treat that the temperature of the molten steel of VN alloy is 1500-1600 DEG C described in preferably.
The invention provides the VN alloy molten steel obtaining according to the preparation method of VN alloy molten steel of the present invention.
The invention provides a kind of V-N Microalloy Steel, wherein, this V-N Microalloy Steel is formed by VN alloy molten steel casting of the present invention.
Below in conjunction with embodiment, the present invention is further described, but can not therefore limit the scope of the invention.
In the present invention, nitrogen content records as follows: molten steel is directly got the more than 10 pole sample of φ, and the cooling post-treatment of sample to be tested becomes
oxygen nitrogen instrument roundlet rod standard, on oxygen nitrogen instrument, measure nitrogen content, the concrete measuring method of nitrogen is pressed GB/T20124(iron and steel, the mensuration of nitrogen content, rare gas element melting heat inducing defecation by enema and suppository) requirement carry out.
Nitrogen recovery is by measuring the forward and backward nitrogen content of molten steel feeding cored-wire, the total nitrogen of bringing in conjunction with cored-wire again, by calculating, be specially: the total nitrogen that nitrogen recovery=(nitrogen content before the nitrogen content-molten steel feeding cored-wire after molten steel feeding cored-wire) × tap/cored-wire is brought into.
Content of vanadium records as follows: molten steel is directly got the cake sample of φ 30 × 10mm left and right, after sample to be tested is cooling at any one plane emery wheel scale removal, and polish flat, on spark discharge Atomic Emission SpectrometerAES, by GB/T4336(carbon steel and middle-low alloy steel spark source atomic emission spectrometry analytical procedure) requirement test.
In the present invention, tensile property is according to GB/T228(metallic substance tensile testing at ambient temperature) carry out, detect respectively yield strength ReL, tensile strength Rm.
In the present invention, the powder of target particles particle diameter can will be sieved and be obtained by standard sieve after crushing material.
Embodiment 1
A kind of cored-wire A1(external diameter is 12mm), comprise the skin of sandwich layer and parcel sandwich layer, described sandwich layer is by VN alloy, ferro-silicon nitride, powder (grain diameter is that 2mm the is following) composition of iron alloy and aluminum shot, the outer crust of making for cold rolled strip (trade mark St12), wherein, in powder, contain VN alloy (VN16, content of vanadium 78 % by weight, N content 16 % by weight): 94 % by weight, (N content is 36 % by weight to ferro-silicon nitride, Si content is 52 % by weight): 4 % by weight, iron alloy: 1 % by weight, (aluminium content is 96 % by weight to aluminum shot, all the other are inevitable other impurity element): 1 % by weight, wherein, iron alloy is the hybrid alloys of ferrocolumbium and ferro-titanium, wherein, the weight ratio of ferrocolumbium and ferro-titanium is 1:1, ferrocolumbium is that FeNb60(Nb+Ta content is 61 % by weight, Ta content is 0.2 % by weight, all the other are Fe and inevitable other impurity element), ferro-titanium is that FeTi40(Ti content is 40 % by weight, all the other are Fe and inevitable other impurity element).
Embodiment 2
A kind of cored-wire A2(external diameter is 12mm), comprise the skin of sandwich layer and parcel sandwich layer, described sandwich layer is by VN alloy, ferro-silicon nitride, powder (grain diameter is that 3mm the is following) composition of iron alloy and aluminum shot, the outer crust of making for cold rolled strip (trade mark St12), wherein, in powder, contain VN alloy (VN16, content of vanadium 78 % by weight, N content 16 % by weight): 51 % by weight, (N content is 36 % by weight to ferro-silicon nitride, Si content is 52 % by weight): 9 % by weight, iron alloy: 15 % by weight, (aluminium content is 96 % by weight to aluminum shot, all the other are inevitable other impurity element): 25 % by weight, wherein, iron alloy is the hybrid alloys of ferrocolumbium and ferro-titanium, wherein, the weight ratio of ferrocolumbium and ferro-titanium is 5:1, ferrocolumbium is that FeNb60(Nb+Ta content is 61 % by weight, Ta content is 0.2 % by weight, all the other are Fe and inevitable other impurity element), ferro-titanium is that FeTi40(Ti content is 40 % by weight, all the other are Fe and inevitable other impurity element).
Embodiment 3
A kind of cored-wire A3(external diameter is 13mm), comprise the skin of sandwich layer and parcel sandwich layer, described sandwich layer is by VN alloy, ferro-silicon nitride, powder (grain diameter is that 3mm the is following) composition of iron alloy and aluminum shot, the outer crust of making for cold rolled strip (trade mark St12), wherein, in powder, contain VN alloy (VN16, content of vanadium 78 % by weight, N content 16 % by weight): 51 % by weight, (N content is 36 % by weight to ferro-silicon nitride, Si content is 52 % by weight): 9 % by weight, iron alloy: 25 % by weight, (aluminium content is 96 % by weight to aluminum shot, all the other are inevitable other impurity element): 15 % by weight, wherein, iron alloy is the hybrid alloys of ferrocolumbium and ferro-titanium, wherein, the weight ratio of ferrocolumbium and ferro-titanium is 10:1, ferrocolumbium is that FeNb60(Nb+Ta content is 61 % by weight, Ta content is 0.2 % by weight, all the other are Fe and inevitable other impurity element), ferro-titanium is that FeTi40(Ti content is 40 % by weight, all the other are Fe and inevitable other impurity element).
Embodiment 4
A kind of cored-wire A4(external diameter is 13mm), comprise the skin of sandwich layer and parcel sandwich layer, described sandwich layer is by VN alloy, ferro-silicon nitride, powder (grain diameter is that 5mm the is following) composition of iron alloy and aluminum shot, the outer crust of making for cold rolled strip (trade mark St12), wherein, in powder, contain VN alloy (VN16, content of vanadium 78 % by weight, N content 16 % by weight): 75 % by weight, (N content is 36 % by weight to ferro-silicon nitride, Si content is 52 % by weight): 15 % by weight, iron alloy: 1 % by weight, (aluminium content is 96 % by weight to aluminum shot, all the other are inevitable other impurity element): 9 % by weight, wherein, iron alloy is the hybrid alloys of ferrocolumbium and ferro-titanium, wherein, the weight ratio of ferrocolumbium and ferro-titanium is 3:1, ferrocolumbium is that FeNb60(Nb+Ta content is 61 % by weight, Ta content is 0.2 % by weight, all the other are Fe and inevitable other impurity element), ferro-titanium is that FeTi40(Ti content is 40 % by weight, all the other are Fe and inevitable other impurity element).
Embodiment 5
Identical with the cored-wire of embodiment 1, different, in cored-wire A5, the weight ratio of ferrocolumbium and ferro-titanium is 0.1:1.
Embodiment 6
Identical with the cored-wire of embodiment 1, different, in cored-wire A6, iron alloy is independent ferrocolumbium.
Embodiment 7
Identical with the cored-wire of embodiment 1, different, in cored-wire A7, iron alloy is independent ferro-titanium.
Comparative example 1
Identical with the cored-wire of embodiment 4, different, the sandwich layer of cored-wire D1 is the VN16 alloy of vanadium nitride powder of 100 % by weight.
Preparation example
Ton LF stove refining furnace+6 machine 6 flows and on billet caster, produces C content 0.34-0.38 % by weight 120 tons of converter+120 to adopt cored-wire A1-A7, Mn content 1.45-1.70 % by weight, Si content 0.25-0.45 % by weight, content of vanadium 0.05-0.08 % by weight, nitrogen content is not less than the 36Mn2VN steel of 0.0050 % by weight, specifically carries out as follows:
First in converter, add 140 tons of molten iron, utilize the function of the de-C of Converter Oxigen Blowing, molten iron is just smelt to molten steel, and the C in molten steel taps in ladle when just refining is to 0.08 % by weight, and now actual tap is 133 tons (in the first refining process of converter, the raw material of approximately 5 % by weight is burnt).In tapping process to add FeSi, FeMn alloy and hard coal to carry out Si, Mn in molten steel and C element alloyed, after alloying, in molten steel, C content is 0.35 % by weight, Mn content is 1.50 % by weight, Si content is 0.30 % by weight, V content is 0.005 % by weight, now in molten steel, sample, after the sample of taking-up is cooling, be reprocessed into
oxygen nitrogen instrument roundlet rod standard, the nitrogen content of measuring on oxygen nitrogen instrument in molten steel is 0.0050 % by weight.
Molten steel starts electrically heated after arriving LF stove, in the time that being heated to 1575 DEG C, liquid steel temperature stops heating, feed cored-wire by feeding wire machine and also rock ladle simultaneously, contact area winding-up rare gas element (rare gas element is nitrogen) to cored-wire and molten steel simultaneously, to prepare the VN alloy molten steel of required vanadium nitrogen content, the nitrogen recovery (the results are shown in Table 1) of this process; Then flow on billet caster and VN alloy molten steel casting become to 280mm × 380mm strand at 6 machines 6, after rolling, become a useful person for
, the wall thickness finished product weldless steel tube that is 5mm, its nitrogen content and content of vanadium, yield strength and tensile strength are in table 1.
Preparation comparative example
Method according to preparation example is prepared Finished Steel, different, uses cored-wire D1 to be prepared.
Table 1
In table 1, be all at C content, Mn content, the contrast of performance data and the contrast of nitrogen recovery of each Finished Steel under the identical condition of Si content.
Data by table 1 can be found out, cored-wire of the present invention is for realizing the alloying of molten steel vanadium and nitrogen, can effectively increase nitrogen content and not affect content of vanadium according to needs, can in the situation that molten steel needs, produce nitrogen content higher containing vanadium steel, and the rate of recovery of nitrogen is stable.And it is high to adopt cored-wire of the present invention to carry out the V-N Microalloy Steel yield strength and the tensile strength that after VN alloy molten steel casting that molten steel VN alloy obtains, obtain, for example contrast preparation comparative example 2 is known with the result of preparation example 4, for obtaining the suitable Finished Steel of fundamental property, adopt the required content of vanadium of steel that cored-wire alloying of the present invention obtains greatly to reduce, this greatly reduces production cost undoubtedly; And for example contrast preparation comparative example 1 is known with the result of preparation example 4, adopts the steel that cored-wire alloying of the present invention obtains not increasing under the prerequisite of content of vanadium, can greatly increase nitrogen content, and the Finished Steel yield strength and the tensile strength that obtain is higher.
More than describe the preferred embodiment of the present invention in detail; but the present invention is not limited to the detail in above-mentioned embodiment, within the scope of technical conceive of the present invention; can carry out multiple simple variant to technical scheme of the present invention, these simple variant all belong to protection scope of the present invention.
It should be noted that in addition each the concrete technical characterictic described in above-mentioned embodiment, in reconcilable situation, can combine by any suitable mode.
In addition, also can carry out arbitrary combination between various embodiment of the present invention, as long as it is without prejudice to thought of the present invention, it should be considered as content disclosed in this invention equally.
Claims (13)
1. a cored-wire, this cored-wire comprises: the skin of sandwich layer and the described sandwich layer of parcel, it is characterized in that, described sandwich layer is the mixture that contains VN alloy, ferro-silicon nitride, iron alloy and aluminum shot, described iron alloy is ferro-titanium and/or ferrocolumbium.
2. cored-wire according to claim 1, wherein, in described mixture, the content of VN alloy is 50-94 % by weight, and the content of ferro-silicon nitride is 4-15 % by weight, and the content of iron alloy is 1-25 % by weight, and the content of aluminum shot is 1-25 % by weight.
3. cored-wire according to claim 1 and 2, wherein, in described VN alloy, N content is 10-18 % by weight, and V content is 76-82 % by weight, and all the other are Fe and inevitable other impurity element.
4. cored-wire according to claim 1 and 2, wherein, in described ferro-silicon nitride, N content is 32-39 % by weight, and Si content is 48-58 % by weight, and all the other are a small amount of Fe and inevitable other impurity element.
5. cored-wire according to claim 1 and 2, wherein, described iron alloy is the hybrid alloys of ferrocolumbium and ferro-titanium, and the weight ratio of described ferrocolumbium and ferro-titanium is 1-10:1.
6. cored-wire according to claim 1 and 2, wherein, aluminium content >=95 % by weight in described aluminum shot, all the other are inevitable other impurity element.
7. cored-wire according to claim 1 and 2, wherein, described mixture is powder form, and the grain diameter of described powder is below 5mm, and the described skin of cored-wire is iron sheet or sheetmetal.
8. the application of the cored-wire described in any one in preparation VN alloy molten steel in claim 1-7.
9. a preparation method for VN alloy molten steel, the method comprises: the cored-wire described in any one in claim 1-7 is fed in the molten steel for the treatment of VN alloy and carries out VN alloy.
10. preparation method according to claim 9, wherein, described in treat VN alloy molten steel be the molten steel of carbon silicomanganese, and described in treat that the temperature of the molten steel of VN alloy is 1500-1600 DEG C.
11. according to the preparation method described in claim 9 or 10, wherein, carries out VN alloy under dynamic condition, and when cored-wire feeds in the molten steel for the treatment of VN alloy, to the contact area winding-up rare gas element of cored-wire and described molten steel.
The VN alloy molten steel that method in 12. claim 9-11 described in any one obtains.
13. 1 kinds of V-N Microalloy Steels, is characterized in that, this V-N Microalloy Steel is formed by the VN alloy molten steel casting described in claim 12.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105132789A (en) * | 2015-09-01 | 2015-12-09 | 安阳荣达铸业有限公司 | Composite vanadium and nitrogen additive and preparing method thereof |
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