CN104046019A - High-strength polyamide resin alloy material for processing safety toe cap - Google Patents
High-strength polyamide resin alloy material for processing safety toe cap Download PDFInfo
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- CN104046019A CN104046019A CN201410310645.5A CN201410310645A CN104046019A CN 104046019 A CN104046019 A CN 104046019A CN 201410310645 A CN201410310645 A CN 201410310645A CN 104046019 A CN104046019 A CN 104046019A
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- polyamide resin
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B23/00—Uppers; Boot legs; Stiffeners; Other single parts of footwear
- A43B23/08—Heel stiffeners; Toe stiffeners
- A43B23/16—Heel stiffeners; Toe stiffeners made of impregnated fabrics, plastics or the like
- A43B23/17—Heel stiffeners; Toe stiffeners made of impregnated fabrics, plastics or the like made of plastics
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
- C08J2377/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
- C08J2377/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention relates to a high-strength polyamide resin alloy material for processing a safety toe cap, belongs to the field of high polymer alloys, and particularly relates to a high-strength polyamide resin alloy material for processing a safety toe cap. The material is prepared from the following components in parts by weight: 60-90 parts of polyamide resin, 3-10 parts of elastomers, 1-8 parts of polyolefin, 4-20 parts of stem grafting bodies, 1-5 parts of functional masterbatch, 1-3 parts of white master batch, 0.2-0.5 part of main antioxidant and 0.1-0.5 part of assistant antioxidant, wherein the functional masterbatch comprises the following components in percentage by weight: 60-90% of at least one of polyamide resin (PA66), nylon resin and vinyl-butene copolymer, 3-15% of chiral organic and inorganic hybrid mesoporous material, 5-10% of lubricant, 1-12% of epoxy resin and 1-8% of inorganic fillers. According to the high-strength polyamide resin alloy material provided by the invention, based on excellent properties such as original mechanical property and wear resistance, the flowability and the toughness are improved, so that the high strength polyamide resin alloy material can better satisfy injection moulding, the subsequent processing treatment and the using requirements of the safety toe cap.
Description
[technical field]
The present invention relates to polyamide resin alloy material, belong to high polymer alloy field, specifically a kind of for process safety toe-cap high strength polyamide resin alloy material.
[background technology]
Polyamide resin has the performance of a lot of excellences, such as mechanical property, resistance toheat, dimensional stability, oil resistance etc., is widely used in the fields such as electronic apparatus, automobile component, electric device.Although existing polyamide resin material has had excellent mechanical property, resistance toheat, but its mobility, toughness are undesirable, thereby in the time that polyamide resin material is used to process safety toe-cap, injection moulding, the following process that cannot well meet safety toes are processed and service requirements.Therefore, if can keep on the basis of the excellent properties such as mechanical property, resistance toheat of polyamide resin material, its mobility, toughness are improved, injection moulding, the following process that can well meet safety toes are processed and service requirements, will have very important significance again.
[summary of the invention]
Object of the present invention is exactly will solve above-mentioned deficiency and provide a kind of for process safety toe-cap high strength polyamide resin alloy material, can keep on the basis of the excellent properties such as original mechanical property, resistance toheat, its mobility, toughness are improved, thereby the injection moulding, following process that can well meet safety toes are processed and service requirements.
Design is a kind of for process safety toe-cap high strength polyamide resin alloy material for achieving the above object, calculates according to parts by weight, is made up of following component:
Described polyamide resin is the mixture of a kind of in nylon 6 or nylon 66 or two kinds, and the relative viscosity of described nylon 6 is 2.43 ± 0.03, and the relative viscosity of described nylon 66 is 2.67 ± 0.03.
Described elastomerics is one or several the mixture in polyhutadiene, chloroprene rubber, polyisoprene rubber, using trans-polyisoprene, styrene-butadiene rubber(SBR), HSBR, hydrogenation nitrile rubber, ethylene-propylene rubber(EPR), ethylene copolymer.
Described polyolefine is one or several the mixture in polyethylene, polypropylene, poly 1-butene, poly(4-methyl-1-pentene), ethylene-propylene copolymer, ethylene-butene copolymer.
Described grafting body is that the grafts of described grafting body is the one or more kinds of mixtures in MALEIC ANHYDRIDE, benzoyl oxide, Tetra hydro Phthalic anhydride, diacetyl oxide, propionic anhydride, citric acid taking one or more the mixture in polyamide resin (PA66), ethylene-butene copolymer as base material.
Described functional agglomerate comprises the component of following weight percent:
Described chirality organic inorganic hybridization mesoporous material is taking C-Si key as main chain, has a meso-hole structure material;
Described lubricant is at least one in paraffin class, lipid acid and ester class thereof, fatty acid amide, silicoorganic compound;
Described epoxy resin is at least one in bisphenol A type epoxy resin, phenol aldehyde type epoxy resin;
Described inorganic filler is at least one in mesoporous silicon oxide, mesoporous TiO 2, nano imvite, superfine talcum powder.
Described functional agglomerate is taking at least one in polyamide resin, nylon resin, ethylene-butene copolymer as base material; Be written into taking C-Si key as main chain, there is the chirality organic inorganic hybridization mesoporous material of meso-hole structure, by at least one in paraffin class, lipid acid and ester class thereof, fatty acid amide, silicoorganic compound, at least one in bisphenol A type epoxy resin, phenol aldehyde type epoxy resin, be written into inorganic filler, described inorganic filler is that at least one in mesoporous silicon oxide, mesoporous TiO 2, nano imvite, superfine talcum powder forms jointly simultaneously.
The preparation technology of described functional agglomerate is: utilize twin screw, temperature is controlled under 200～260 DEG C of conditions and melt extrudes, and twin screw rotating speed is 260～300RPM, and vacuum tightness is 0.5～0.8MPa.
Described primary antioxidant is the mixture of a kind of in 3,5-di-tert-butyl-hydroxy phenyl propionic acid stearyl alcohol ester, β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid stearyl alcohol ester or two kinds.
Described auxiliary antioxidant is the mixture of a kind of in two (2,4-di-t-butyl) pentaerythritol diphosphites, three (2,4-di-tert-butyl-phenyl) phosphorous acid esters or two kinds.
The present invention is by being used in conjunction with polyamide resin, elastomerics, polyolefine, grafting body, functional agglomerate, white master batch, primary antioxidant, auxiliary antioxidant, the usage ratio of the above-mentioned each component of reasonably optimizing simultaneously, polyamide resin alloy material can be kept on the basis of the excellent properties such as original mechanical property, resistance toheat, and its mobility, toughness are improved, thereby the injection moulding, following process that can well meet safety toes are processed and service requirements.
[embodiment]
Below in conjunction with embodiment and comparative example, the present invention is done to following further illustrating:
Comparative example 1
86.7 parts of polyamide resins (PA66) add from the first weight-loss type feeder mouth, 8 parts of elastomericss, 1 part of polyolefine, 1 part of white master batch, 0.2 part of primary antioxidant and 0.1 part of auxiliary antioxidant add from the second weightless feeder mouth after mixed through too high, then through twin screw extruder plasticizing, melting, extrude, tie rod, cooling, pelletizing.Pellet is at 110 DEG C of dry 2h of gas blower drying oven, and then test bars or goods are prepared in injection moulding.
Embodiment 1
60 parts of polyamide resins (PA66) and 4 parts of grafting bodies add from the first weight-loss type feeder mouth, 3 parts of elastomericss, 1 part of polyolefine, 1 part of functional agglomerate, 1 part of white master batch, 0.2 part of primary antioxidant and 0.1 part of auxiliary antioxidant add from the second weightless feeder mouth after mixed through too high, then through twin screw extruder plasticizing, melting, extrude, tie rod, cooling, pelletizing.Pellet is at 110 DEG C of dry 2h of gas blower drying oven, and then test bars or goods are prepared in injection moulding.
Embodiment 2
71.7 parts of polyamide resins (PA66) and 20 parts of grafting bodies add from the first weight-loss type feeder mouth, 8 parts of elastomericss, 4 parts of polyolefine, 4 parts of functional agglomerates, 2 parts of white master batches, 0.3 part of primary antioxidant and 0.25 part of auxiliary antioxidant add from the second weightless feeder mouth after mixed through too high, then through twin screw extruder plasticizing, melting, extrude, tie rod, cooling, pelletizing.Pellet is at 110 DEG C of dry 2h of gas blower drying oven, and then test bars or goods are prepared in injection moulding.
Embodiment 3
82 parts of polyamide resins (PA66) and 10 parts of grafting bodies add from the first weight-loss type feeder mouth, 8 parts of elastomericss, 7 parts of polyolefine, 4 parts of functional agglomerates, 2 parts of white master batches, 0.4 part of primary antioxidant and 0.3 part of auxiliary antioxidant add from the second weightless feeder mouth after mixed through too high, then through twin screw extruder plasticizing, melting, extrude, tie rod, cooling, pelletizing.Pellet is at 110 DEG C of dry 2h of gas blower drying oven, and then test bars or goods are prepared in injection moulding.
Embodiment 4
90 parts of polyamide resins (PA66) and 15 parts of grafting bodies add from the first weight-loss type feeder mouth, 10 parts of elastomericss, 8 parts of polyolefine, 5 parts of functional agglomerates, 3 parts of white master batches, 0.5 part of primary antioxidant and 0.5 part of auxiliary antioxidant add from the second weightless feeder mouth after mixed through too high, then through twin screw extruder plasticizing, melting, extrude, tie rod, cooling, pelletizing.Pellet is at 110 DEG C of dry 2h of gas blower drying oven, and then test bars or goods are prepared in injection moulding.
Table 1 is the raw material weight umber proportioning of comparative example 1, embodiment 1～4:
| Component | Comparative example 1 | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Polyamide resin | 86.7 | 60 | 71.7 | 82 | 90 |
| Elastomerics | 8 | 3 | 8 | 8 | 10 |
| Polyolefine | 1 | 1 | 4 | 7 | 8 |
| Grafting body | / | 4 | 20 | 10 | 15 |
| Functional agglomerate | / | 1 | 4 | 4 | 5 |
| White master batch | 1 | 1 | 2 | 2 | 3 |
| Primary antioxidant | 0.2 | 0.2 | 0.3 | 0.4 | 0.5 |
| Auxiliary antioxidant | 0.1 | 0.1 | 0.25 | 0.3 | 0.5 |
Table 1
Table 2 is composition properties test result in comparative example 1 and embodiment 1～4:
Table 2
The present invention tests the performance of composition in and comparative example routine with Evaluation operation by the following method:
(1) tensile strength
Described tensile strength is pressed ASTM D-638 test.
(2) elongation at break
Described tensile strength is pressed ASTM D-638 test.
(3) flexural strength
Described flexural strength is pressed ASTM D-790 test.
(4) modulus in flexure
Described flexural strength is pressed ASTM D-790 test.
(5) Izod notch shock
Described Izod notch shock is pressed ASTM D-256 test.
(6) heat-drawn wire
Described heat-drawn wire is hit by ASTM D-648 and is tested.
(7) mobility
Certain thickness spiral of Archimedes cavity plate is carried out to the injection moulding test of produced polyamide resin (PA66) alloy material.Injection moulding wall thickness is 2mm, and width is 5mm, and injection temperature is 260～280 DEG C, and injection pressure is 90～110MPa, and be 10s cooling time, and dwell pressure is 60～90MPa, and the dwell time is 5～10s.
(8) hundred lattice experiments
The goods of injection formed, after on-line spray, are dried, after 24 hours, take out goods, be cooled to room temperature, allow the rear sub-box that marks 5mm × 5mm with guarded blade utility knife on product surface, with adhesive tape sticking on surface, after cementing, tear rapidly adhesive tape off, see that whether paint after spraying is by adhesive tape stick-down, if there is no stick-down, be considered as hundred lattice stand the tests, vice versa.
The invention provides a kind of for process safety toe-cap high strength polyamide resin alloy material, in its component, polyamide resin is the mixture of a kind of in nylon 6 or nylon 66 or two kinds, and the relative viscosity of nylon 6 is 2.43 ± 0.03, and the relative viscosity of nylon 66 is 2.67 ± 0.03; Elastomerics is one or several the mixture in polyhutadiene, chloroprene rubber, polyisoprene rubber, using trans-polyisoprene, styrene-butadiene rubber(SBR), HSBR, hydrogenation nitrile rubber, ethylene-propylene rubber(EPR), ethylene copolymer; Polyolefine is one or several the mixture in polyethylene, polypropylene, poly 1-butene, poly(4-methyl-1-pentene), ethylene-propylene copolymer, ethylene-butene copolymer; Grafting body is that the grafts of grafting body is the one or more kinds of mixtures in MALEIC ANHYDRIDE, benzoyl oxide, Tetra hydro Phthalic anhydride, diacetyl oxide, propionic anhydride, citric acid taking one or more the mixture in polyamide resin (PA66), ethylene-butene copolymer as base material; Primary antioxidant is the mixture of a kind of in 3,5-di-tert-butyl-hydroxy phenyl propionic acid stearyl alcohol ester, β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid stearyl alcohol ester or two kinds; Auxiliary antioxidant is the mixture of a kind of in two (2,4-di-t-butyl) pentaerythritol diphosphites, three (2,4-di-tert-butyl-phenyl) phosphorous acid esters or two kinds.
In the present invention, functional agglomerate is made up of the component of following weight percent: in (1) polyamide resin (PA66), nylon resin, ethylene-butene copolymer at least one 60%; Chirality organic inorganic hybridization mesoporous material 15%; Lubricant 10%; Epoxy resin 12%; Inorganic filler 3%.(2) in polyamide resin (PA66), nylon resin, ethylene-butene copolymer at least one 90%; Chirality organic inorganic hybridization mesoporous material 3%; Lubricant 5%; Epoxy resin 1%; Inorganic filler 1%.(3) in polyamide resin (PA66), nylon resin, ethylene-butene copolymer at least one 75%; Chirality organic inorganic hybridization mesoporous material 6%; Lubricant 8%; Epoxy resin 3%; Inorganic filler 8%.
Wherein, chirality organic inorganic hybridization mesoporous material is taking C-Si key as main chain, has a meso-hole structure material; Lubricant is at least one in paraffin class, lipid acid and ester class thereof, fatty acid amide, silicoorganic compound; Epoxy resin is at least one in bisphenol A type epoxy resin, phenol aldehyde type epoxy resin; Inorganic filler is at least one in mesoporous silicon oxide, mesoporous TiO 2, nano imvite, superfine talcum powder.
This functional agglomerate is taking at least one in polyamide resin, nylon resin, ethylene-butene copolymer as base material; Be written into taking C-Si key as main chain, there is the chirality organic inorganic hybridization mesoporous material of meso-hole structure, by at least one in paraffin class, lipid acid and ester class thereof, fatty acid amide, silicoorganic compound, at least one in bisphenol A type epoxy resin, phenol aldehyde type epoxy resin, be written into inorganic filler, inorganic filler is that at least one in mesoporous silicon oxide, mesoporous TiO 2, nano imvite, superfine talcum powder forms jointly simultaneously.Its preparation technology is: utilize twin screw, temperature is controlled under 200～260 DEG C of conditions and melt extrudes, and twin screw rotating speed is 260～300RPM, and vacuum tightness is 0.5～0.8MPa.
In the present invention, the manufacturer of each raw material is:
The present invention is not subject to the restriction of above-mentioned embodiment, and other any do not deviate from change, the modification done under spirit of the present invention and principle, substitutes, combination, simplify, and all should be equivalent substitute mode, within being included in protection scope of the present invention.
Claims (10)
1. for a process safety toe-cap high strength polyamide resin alloy material, it is characterized in that, calculate according to parts by weight, formed by following component:
2. polyamide resin alloy material as claimed in claim 1, it is characterized in that: described polyamide resin is the mixture of a kind of in nylon 6 or nylon 66 or two kinds, the relative viscosity of described nylon 6 is 2.43 ± 0.03, and the relative viscosity of described nylon 66 is 2.67 ± 0.03.
3. polyamide resin alloy material as claimed in claim 1, is characterized in that: described elastomerics is one or several the mixture in polyhutadiene, chloroprene rubber, polyisoprene rubber, using trans-polyisoprene, styrene-butadiene rubber(SBR), HSBR, hydrogenation nitrile rubber, ethylene-propylene rubber(EPR), ethylene copolymer.
4. polyamide resin alloy material as claimed in claim 1, is characterized in that: described polyolefine is one or several the mixture in polyethylene, polypropylene, poly 1-butene, poly(4-methyl-1-pentene), ethylene-propylene copolymer, ethylene-butene copolymer.
5. polyamide resin alloy material as claimed in claim 1, it is characterized in that: described grafting body is that the grafts of described grafting body is the one or more kinds of mixtures in MALEIC ANHYDRIDE, benzoyl oxide, Tetra hydro Phthalic anhydride, diacetyl oxide, propionic anhydride, citric acid taking one or more the mixture in polyamide resin (PA66), ethylene-butene copolymer as base material.
6. polyamide resin alloy material as claimed in claim 1, is characterized in that, described functional agglomerate comprises the component of following weight percent:
Described chirality organic inorganic hybridization mesoporous material is taking C-Si key as main chain, has a meso-hole structure material;
Described lubricant is at least one in paraffin class, lipid acid and ester class thereof, fatty acid amide, silicoorganic compound;
Described epoxy resin is at least one in bisphenol A type epoxy resin, phenol aldehyde type epoxy resin;
Described inorganic filler is at least one in mesoporous silicon oxide, mesoporous TiO 2, nano imvite, superfine talcum powder.
7. polyamide resin alloy material as claimed in claim 6, is characterized in that: described functional agglomerate is taking at least one in polyamide resin, nylon resin, ethylene-butene copolymer as base material; Be written into taking C-Si key as main chain, there is the chirality organic inorganic hybridization mesoporous material of meso-hole structure, by at least one in paraffin class, lipid acid and ester class thereof, fatty acid amide, silicoorganic compound, at least one in bisphenol A type epoxy resin, phenol aldehyde type epoxy resin, be written into inorganic filler, described inorganic filler is that at least one in mesoporous silicon oxide, mesoporous TiO 2, nano imvite, superfine talcum powder forms jointly simultaneously.
8. polyamide resin alloy material as claimed in claim 6, it is characterized in that, the preparation technology of described functional agglomerate is: utilize twin screw, temperature is controlled under 200～260 DEG C of conditions and melt extrudes, twin screw rotating speed is 260～300RPM, and vacuum tightness is 0.5～0.8MPa.
9. polyamide resin alloy material as claimed in claim 1, it is characterized in that: described primary antioxidant is 3, the mixture of a kind of in 5-di-tert-butyl-hydroxy phenyl propionic acid stearyl alcohol ester, β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid stearyl alcohol ester or two kinds.
10. polyamide resin alloy material as claimed in claim 1, it is characterized in that: described auxiliary antioxidant is two (2,4-di-t-butyl) mixture of a kind of in pentaerythritol diphosphites, three (2,4-di-tert-butyl-phenyl) phosphorous acid ester or two kinds.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410310645.5A CN104046019A (en) | 2014-07-01 | 2014-07-01 | High-strength polyamide resin alloy material for processing safety toe cap |
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| CN201410310645.5A CN104046019A (en) | 2014-07-01 | 2014-07-01 | High-strength polyamide resin alloy material for processing safety toe cap |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104292829A (en) * | 2014-10-31 | 2015-01-21 | 上海梓辰实业有限公司 | Polyamide resin alloy material for processing of lining housing of coffee maker |
| CN104312142A (en) * | 2014-11-07 | 2015-01-28 | 上海梓辰实业有限公司 | Polyamide resin alloy material for processing base of electric tool |
| CN104387765A (en) * | 2014-10-31 | 2015-03-04 | 上海梓辰实业有限公司 | Polyamide resin alloy material for machining ground brush of dust collector |
| CN104382284A (en) * | 2014-11-25 | 2015-03-04 | 东莞华固复合材料科技有限公司 | New type nanocomposite safety shoe cap manufacturing method and shoe cap product thereof |
| CN105440667A (en) * | 2015-12-16 | 2016-03-30 | 安徽都邦电器有限公司 | High strength heatproof nylon pipe |
| CN110358290A (en) * | 2019-06-27 | 2019-10-22 | 苍南县鑫洋新材料有限公司 | A kind of nylon material of modification |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101870811A (en) * | 2009-11-04 | 2010-10-27 | 深圳市科聚新材料有限公司 | Cold-resistance super tough nylon polyolefin alloy and preparation method thereof |
| US20120052993A1 (en) * | 2006-03-24 | 2012-03-01 | Applied Nanotech Holdings, Inc. | Nylon based composites |
| CN103073771A (en) * | 2012-12-28 | 2013-05-01 | 东莞市普凯塑料科技有限公司 | Ultraviolet shielding, anti-bacterial and anti-fouling multifunctional color masterbatch and preparation method thereof |
| CN103382301A (en) * | 2013-07-03 | 2013-11-06 | 苏州市沃特新材料科技有限公司 | Polyphenyl ether alloy material and preparation method thereof |
-
2014
- 2014-07-01 CN CN201410310645.5A patent/CN104046019A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120052993A1 (en) * | 2006-03-24 | 2012-03-01 | Applied Nanotech Holdings, Inc. | Nylon based composites |
| CN101870811A (en) * | 2009-11-04 | 2010-10-27 | 深圳市科聚新材料有限公司 | Cold-resistance super tough nylon polyolefin alloy and preparation method thereof |
| CN103073771A (en) * | 2012-12-28 | 2013-05-01 | 东莞市普凯塑料科技有限公司 | Ultraviolet shielding, anti-bacterial and anti-fouling multifunctional color masterbatch and preparation method thereof |
| CN103382301A (en) * | 2013-07-03 | 2013-11-06 | 苏州市沃特新材料科技有限公司 | Polyphenyl ether alloy material and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104292829A (en) * | 2014-10-31 | 2015-01-21 | 上海梓辰实业有限公司 | Polyamide resin alloy material for processing of lining housing of coffee maker |
| CN104387765A (en) * | 2014-10-31 | 2015-03-04 | 上海梓辰实业有限公司 | Polyamide resin alloy material for machining ground brush of dust collector |
| CN104312142A (en) * | 2014-11-07 | 2015-01-28 | 上海梓辰实业有限公司 | Polyamide resin alloy material for processing base of electric tool |
| CN104382284A (en) * | 2014-11-25 | 2015-03-04 | 东莞华固复合材料科技有限公司 | New type nanocomposite safety shoe cap manufacturing method and shoe cap product thereof |
| CN105440667A (en) * | 2015-12-16 | 2016-03-30 | 安徽都邦电器有限公司 | High strength heatproof nylon pipe |
| CN110358290A (en) * | 2019-06-27 | 2019-10-22 | 苍南县鑫洋新材料有限公司 | A kind of nylon material of modification |
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Application publication date: 20140917 |