CN1040458A - Be coated with the electric light of light absorbing zone - Google Patents

Be coated with the electric light of light absorbing zone Download PDF

Info

Publication number
CN1040458A
CN1040458A CN89105638A CN89105638A CN1040458A CN 1040458 A CN1040458 A CN 1040458A CN 89105638 A CN89105638 A CN 89105638A CN 89105638 A CN89105638 A CN 89105638A CN 1040458 A CN1040458 A CN 1040458A
Authority
CN
China
Prior art keywords
light
electric light
coated
coating
colouring agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN89105638A
Other languages
Chinese (zh)
Inventor
克劳斯·舍勒
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Koninklijke Philips NV
Original Assignee
Philips Gloeilampenfabrieken NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Philips Gloeilampenfabrieken NV filed Critical Philips Gloeilampenfabrieken NV
Publication of CN1040458A publication Critical patent/CN1040458A/en
Pending legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00—Gas-discharge or vapour-discharge lamps
    • H01J61/02—Details
    • H01J61/30—Vessels; Containers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01K—ELECTRIC INCANDESCENT LAMPS
    • H01K1/00—Details
    • H01K1/28—Envelopes; Vessels
    • H01K1/32—Envelopes; Vessels provided with coatings on the walls; Vessels or coatings thereon characterised by the material thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J5/00—Details relating to vessels or to leading-in conductors common to two or more basic types of discharge tubes or lamps
    • H01J5/02—Vessels; Containers; Shields associated therewith; Vacuum locks
    • H01J5/08—Vessels; Containers; Shields associated therewith; Vacuum locks provided with coatings on the walls thereof; Selection of materials for the coatings
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01K—ELECTRIC INCANDESCENT LAMPS
    • H01K9/00—Lamps having two or more incandescent bodies separately heated
    • H01K9/08—Lamps having two or more incandescent bodies separately heated to provide selectively different light effects, e.g. for automobile headlamp

Landscapes

  • Vessels And Coating Films For Discharge Lamps (AREA)
  • Non-Portable Lighting Devices Or Systems Thereof (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Common Detailed Techniques For Electron Tubes Or Discharge Tubes (AREA)
  • Glass Compositions (AREA)
  • Paints Or Removers (AREA)

Abstract

Be coated with the electric light of light absorbing zone (7), described absorbed layer (7) is partly to be arranged on the electric light shell (1), and comprises the manganese dioxide (MnO as colouring agent 2), magnesium oxide and titanium dioxide, they all are included in and contain in the silicon adhesive.

Description

Be coated with the electric light of light absorbing zone
The present invention relates to the electric light that its housing parts is laid with a light-absorbing coating, this coating is included in iron oxide and the manganese dioxide as colouring agent that contains in the silicon adhesive to be contained.This contains silicon adhesive and generally includes a kind of organo-silicon compound, and when heating, this silicon compound just is converted to silicon dioxide.So this silicon dioxide just is used as a kind of beading thing of bonding described colouring agent.
With regard to various electric lights, the light-absorbing coating on the lamp housing is commonly used to cover part emission light.Therefore this lamp housing is a shadowed layer.This class electric light (for example) has the halogen incandescent lamp as the car lighting lamp, or high-pressure discharge lamp; The latter's configurable one outside lamp housing.Described light-absorbing coating can be coated on outside or the interior lamp housing.Because this type of electric light will bear high heat, so their shell contains hard glass or quartz glass usually.Described light-absorbing coating should be able to be corrosion-resistant, can bond to described lamp housing and the anti-zoned trace of energy securely.
By this class known lamp that the No.1422491 British patent is learnt, described colouring agent comprises iron oxide, cobalt oxide and manganese dioxide.People in a short time from then on consider with cobalt oxide (COO), yet because it has been not suitable for being used for the electric light coating for the carcinogen event.
The electric light of being learnt by British patent 1334329 has same shortcoming, and its shell coating comprises as the cobalt oxide of colouring agent and carbonyl iron.
In the electric light according to No1909394 Germany patent, it is pigment coated to be provided with the silester that contains as the silicon of mineral black.This pigment can only make with the sizable technology of difficulty, and too transparent consequently bright inadequately.
The light-absorbing coating that electric light had that discloses by No. 2837280 prospectus in Germany comprises carbonyl iron and silica flour and does not have siliceous adhesive.This coating is fired under 530 ℃ of high temperature and is formed.Yet have now found that: this pigment can only be used for certain several shells top shape and can only use a kind of impregnation technology of complexity.
Therefore, the objective of the invention is for a kind of electric light with a kind of like this light-absorbing coating is provided, this coating can form and bonding good with simple technology mode, and this coating is enough to shading and without cobalt oxide.
According to the present invention, promptly can reach above purpose, because described coating contains the titanium dioxide as additional colorant by the described the sort of electric light of this paper section of beginning.
The inventor is surprised to find that: can show the opacity of improving this coating by adding this titanium dioxide as white.
According to another embodiment of the present invention, described colouring agent can be present in the starting mixt of following column weight amount proportioning:
Magnetic iron ore (FeO, Fe 2O 3) 14 to 20%
Manganese dioxide 8 to 16%
Carbonyl iron 14 to 21%
Titanium dioxide 5 to 12%
In one embodiment of the invention, starting mixt comprises the silester as adhesive, therefore obtains firm adhesive coatings.
One embodiment of the present of invention are now more fully described with reference to the accompanying drawings.
This illustrates the end view as the halogen incandescent lamp of car lighting lamp.
The halogen incandescent lamp of a 12V 55W is as a kind of parabolic reflector of car lighting lamp.This lamp has the shell 1 of a quartz or hard glass system.Be provided with two helical heaters 2 and 3 in this shell 1, wherein main filament 2 is placed in the focus of parabolic reflector, and inclination filament 3 is partly centered on by a sloping baffle 4.Housing 1 is filled with a kind of inert gas and a kind of halogen compounds, so that this lamp can obtain a tungsten halogen cycle (tungston-halogen circulation) during operation.Lamp housing 1 places on the base 5 that has flange connector 6.
The top 7 that has the lamp housing 1 of evacuation tube seal head 8 is placed on the lateral surface that is covered with light-absorbing coating 9.This coating comprises magnetic iron ore, manganese dioxide, carbonyl iron and the titanium dioxide as colouring agent, and these colouring agents all are included in a kind of containing in the silicon adhesive.Coating 9 can comprise following starting mixt:
The amount material
430 gram titanium dioxide
690 grams, four manganese oxide
70 gram sodium metaphosphates
1900 milliliters of ethyl silicate aqueous solution
150 milliliter of one fourth fat glycol ether
80 milliliters of ethylene glycol
500 milliliter of 96% denatured ethyl alcohol
930 gram carbonyl iron EN8
(Bay ferrox Bayer synthesizes oxygen to 900 gram magnetic iron ores
Changing Inland Steel produces)
These all substances with about 3kg of frangible sphere of 13mm diameter are sent into one 51 type porcelain ball mill (51 porcelain ball mill) together also ground 18 hours on the pressure roller with per minute 16 commentaries on classics rotations within it.Then, allowing the mixture worn into have by one widely sieves for the woven wire of 0.1mm mesh.So this mixture is just available at any time.
The top 7 of lamp housing 1 is immersed in this mixture, makes it dry and through heat-treated then, that is, the shell of coating 7 heats in a drying oven, is added to the 12V voltage source simultaneously and makes their work on these lamps.Then, utilize ring-type blowtorch (ring burners) to be heated under certain temperature of (＞1000 ℃) at the top 7 of melanism, make them be the red heat attitude with oxidizing flame.During such heat treatment, ethyl silicate is changed into iron oxide and is burnt so that described coating is glued fast to shell within it.The thickness of this coating 9 is about 0.005mm.
The transparence value that the electric light of making thus is covered with the top of black coating almost is equivalent to the resulting result of a large amount of pigment of its twice dipping.

Claims (3)

1, is coated with the electric light of light-absorbing coating, described coating is partly to be coated on shell and to be included in a kind of magnesium oxide and manganese dioxide as colouring agent that contains in the silicon adhesive to be contained, and it is characterized in that: described coating comprises the titanium dioxide as auxiliary colorant.
2, electric light as claimed in claim 1 is characterized in that: described colouring agent is present in the starting mixt of being made up of following weight proportion:
Magnetic iron ore 14 to 20%
Manganese dioxide 8 to 16%
Carbonyl iron 14 to 21%
Titanium dioxide 5 to 12%
3, electric light as claimed in claim 1 or 2 is characterized in that: described starting mixt comprises the ethyl silicate as adhesive.
CN89105638A 1988-08-12 1989-08-09 Be coated with the electric light of light absorbing zone Pending CN1040458A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3827451A DE3827451C1 (en) 1988-08-12 1988-08-12
DEP3827451.5 1988-08-12

Publications (1)

Publication Number Publication Date
CN1040458A true CN1040458A (en) 1990-03-14

Family

ID=6360758

Family Applications (1)

Application Number Title Priority Date Filing Date
CN89105638A Pending CN1040458A (en) 1988-08-12 1989-08-09 Be coated with the electric light of light absorbing zone

Country Status (7)

Country Link
EP (1) EP0354620A1 (en)
JP (1) JPH0287456A (en)
KR (1) KR900003957A (en)
CN (1) CN1040458A (en)
DD (1) DD284097A5 (en)
DE (1) DE3827451C1 (en)
HU (1) HU201422B (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1296966C (en) * 1998-03-26 2007-01-24 皇家菲利浦电子有限公司 Electric lamp
CN100383910C (en) * 1999-09-13 2008-04-23 皇家菲利浦电子有限公司 Electric lamp
CN100437892C (en) * 2000-08-18 2008-11-26 皇家菲利浦电子有限公司 Halogen incandescent lamp for motor vehicles
CN101536142B (en) * 2006-11-09 2010-12-22 皇家飞利浦电子股份有限公司 Electric lamp with light-absorbing coating, precursor suspension for such a coating and method of making such a lamp

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4108316A1 (en) * 1991-03-14 1992-09-17 Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh ELECTRIC LAMP BASED ON ONE SIDE
DE69503466T2 (en) * 1994-11-10 1999-03-04 Philips Patentverwaltung ELECTRIC LAMP
DE19941531A1 (en) * 1999-09-01 2001-03-08 Philips Corp Intellectual Pty Colored signal light with iron oxide pigment coated lamp
KR20040039355A (en) 2001-09-13 2004-05-10 코닌클리즈케 필립스 일렉트로닉스 엔.브이. Electric lamp, lamp vessel provided with a light-absorbing coating as well as a method of preparing a light-absorbing coating
WO2014206432A1 (en) 2013-06-28 2014-12-31 Trumpf Laser- Und Systemtechnik Gmbh Process for machining, in particular for mechanical welding, and control apparatus for a setting device of a process gas feed

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2034987A (en) * 1931-06-12 1936-03-24 Morita Kikujiro Process for coating glass sheets
DE1063773B (en) * 1957-12-10 1959-08-20 Jenaer Glaswerk Schott & Gen Process for producing thin, light-absorbing layers on solid, radiation-permeable or radiation-reflecting substrates, in particular glass
DE2136012A1 (en) * 1971-07-19 1973-02-01 Patra Patent Treuhand ELECTRIC LAMP WITH LIGHT COVERING COVER
DE2363812C3 (en) * 1973-01-15 1980-07-10 Veb Narva, Ddr 1017 Berlin Thermally heavy-duty, opaque coating for lamp bulbs
DE2837280A1 (en) * 1978-08-25 1980-03-06 Patra Patent Treuhand ELECTRIC LAMP WITH LIGHT COVERING COVER
US4288713A (en) * 1979-11-23 1981-09-08 Gte Products Corporation Lamp having opaque coating

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1296966C (en) * 1998-03-26 2007-01-24 皇家菲利浦电子有限公司 Electric lamp
CN100383910C (en) * 1999-09-13 2008-04-23 皇家菲利浦电子有限公司 Electric lamp
CN100437892C (en) * 2000-08-18 2008-11-26 皇家菲利浦电子有限公司 Halogen incandescent lamp for motor vehicles
CN101536142B (en) * 2006-11-09 2010-12-22 皇家飞利浦电子股份有限公司 Electric lamp with light-absorbing coating, precursor suspension for such a coating and method of making such a lamp

Also Published As

Publication number Publication date
JPH0287456A (en) 1990-03-28
KR900003957A (en) 1990-03-27
HUT50533A (en) 1990-02-28
DE3827451C1 (en) 1989-10-12
EP0354620A1 (en) 1990-02-14
DD284097A5 (en) 1990-10-31
HU201422B (en) 1990-10-28

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C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C01 Deemed withdrawal of patent application (patent law 1993)
WD01 Invention patent application deemed withdrawn after publication