CN104031713A - Manufacturing method of pollution-free coal with high combustion value by household garbage - Google Patents
Manufacturing method of pollution-free coal with high combustion value by household garbage Download PDFInfo
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- CN104031713A CN104031713A CN201410293336.1A CN201410293336A CN104031713A CN 104031713 A CN104031713 A CN 104031713A CN 201410293336 A CN201410293336 A CN 201410293336A CN 104031713 A CN104031713 A CN 104031713A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/46—Solid fuels essentially based on materials of non-mineral origin on sewage, house, or town refuse
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
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- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Combustion & Propulsion (AREA)
- Processing Of Solid Wastes (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
Abstract
The invention relates to a manufacturing method of pollution-free coal with a high combustion value by household garbage. The manufacturing method specifically comprises the following steps: S1, conveying garbage from dispersing points to a garbage storage area; S2, conveying the garbage from the garbage storage area to a reaction kettle automatically or manually, and completely sealing the reaction kettle; S3, introducing steam into the reaction kettle and dynamically controlling time-dependent temperature and pressure of the garbage to form a carbonized mixture; S4, reducing the temperature and pressure in the reaction kettle and discharging liquefied water and gases formed in reaction; and S5, pouring the carbonized mixture formed in the step 3 into a screening device which screens incombustible matters out of the carbonized mixture, and finally obtaining the carbide. The manufacturing method provided by the invention is pollution-free in processing process and low in processing cost, and the prepared garbage coal is high in combustion value and low in emission.
Description
Technical field
The invention belongs to Prediction for Solid Waste Treatment Technology field, be specifically related to a kind of manufacture method of utilizing domestic refuse to manufacture high, the free of contamination coal of fuel value.
Background technology
According to data, China's domestic waste average growth rate per annum is 8%-10%, and within 2013, domestic waste reaches 2.6 hundred million tons, also nearly hundred million tons of the annual domestic refuses in rural area, and the domestic refuse growing with each passing day has become the significant problem of puzzlement Economic development and environmental improvement.To this, country and local governments at various levels pay much attention to, in recent years China has newly put into effect a series of new policy and new planning, refuse treatment problem is made to policy and practicality is set forth comprehensively, particularly " 12 " period, country formulates great planning to field of Environment Protection and waste management, for China's domestic rubbish disposal project provides important development opportunity.Meanwhile, " 18 is large " clearly proposed the contents such as " conservation culture ", " beautiful China ", " economizing on resources ", " protection of the environment ", and this has created very large development space also to refuse treatment industry.The master file that relates at present refuse treatment has:
1. on April 19th, 2012; the General Office of the State Council has printed and distributed " planning of " 12 " national application of city life garbage harmless treatment Facilities Construction " (Office of the State Council is sent out [2012] No. 23); this planning is worked out by State Development and Reform Commission, house town and country construction portion, Environmental Protection Department three ministries and commissions' combination weaves; target, main task and the safeguards of having illustrated whole nation application of city life garbage harmless treatment in " 12 " period Facilities Construction, specify the focus of government work.The programmatic document that Zhe Shi China Municipal Solid-state Garbage-disposal Facilities is built, 2,636 hundred million yuan of planning construction gross investments.
2. on June 16th, 2012, State Council has printed and distributed " " 12 " energy-conserving and environment-protective industrial development planning " (No. [2012] 19, promulgated by the State Council), relate to the content of the aspects such as technical equipment, energy-conserving product, energy-conserving and environment-protective service, renewable resource utilization, the associated viscera of the aspects such as kitchen castoff recycling and refuse treatment particularly in major fields, are mentioned specially.
3. on July 9th, 2012, State Council has printed and distributed " " 12 " national strategy new industry development program " (No. [2012] 28, promulgated by the State Council), proposes the advanced environmental protection industry of development, promotes rubbish and Hazardous wastes and processes the contents such as disposal; Development resource recycle industry, gives priority to the waste and old commodity recovery system supporting with modern technique, the contents such as kitchen castoff, agriculture and forestry organic waste material, waste textile and waste or used plastics goods recycling.
4. on August 6th, 2012, State Council has printed and distributed " notice of planning about " 12 " of printing and distributing energy-saving and emission-reduction " (No. [2012] 40, promulgated by the State Council), proposes to strengthen town environment infrastructure construction; Implement rural area cleaning project, encourage categorized consumer waste to collect and decrement harmless treatment on the spot, select economical, be suitable for, safe processing disposal technology, raising rubbish processing to be harmless level, urban-rural integration refuse treatment pattern is progressively promoted in the rural area of cities and towns periphery and environmental sensitive area; Accelerate the construction of domestic rubbish disposal disposal facility in cities and towns, strengthening percolate is disposed; Reinforcement policy is implemented and guiding, encourages to adopt Energy Management Contract to implement reducing energy consumption, promotes environmental protection facility socialization, the specialized runnings such as town sewage, refuse treatment and enterprise pollution improvement.
5. on October 8th, 2012, Environmental Protection Department, National Development and Reform Committee, Ministry of Industry and Information, four ministries and commissions of the Ministry of Health combine and have printed and distributed " " 12 " Hazardous Wastes Management control program " (No. [2012] 123, environment-development), propose to carry out Hazardous wastes investigation, try to explore Hazardous wastes source decrement, plan as a whole to advance dangerous waste incineration, landfills etc. centrally dispose Facilities Construction, scientific development Hazardous wastes utilizes and service industry, strengthening relating to heavy metal Hazardous wastes innoxious use disposes, advance clinical waste harmlessness disposing, promoting non-industrial source and the utilization of left over by history Hazardous wastes disposes, promote operation management and state of the art, strengthen the 9 large tasks such as Hazardous wastes supervisory system construction.
According to above-mentioned these public documents, can gem-purely see, refuse treatment has become the technical field that country attaches great importance to, but we also see that technology of garbage disposal also exists a lot of deficiencies, drawback and technological gap up till now simultaneously.
Make a general survey of other countries of the world, the very severe problem of the same existence of refuse treatment, especially developing country and relative poor and backward country, sanitary fill is as serious in mountain, environmental pollution etc., and problem becomes increasingly conspicuous, and needs the method treating refuse of employing science, efficient, environmental protection badly.
Waste disposal method mainly comprises burning disposal, sanitary landfill, sorting compost at present.Burning disposal and sanitary landfill, not only than great, are also the gesture of rising gradually, and the atrophy gradually of sorting compost, on the other hand, country is having little effect aspect publicity and propelling refuse classification processing, and this all makes refuse treatment difficulty strengthen.More outstanding, in prior art, all be there is to many defects in focusing on of rubbish, continue to cause secondary pollution to environment, the addressing of garbage burning factory more causes negative impact to social stability.Mainly there is following defect and problem in conventional garbage treatment process:
(1) burning disposal
1, gaseous emission, causes secondary pollution
Adopt the treating refuse of burning mode, conventionally need to add auxiliary fuel, such as the coal of 5-10%, not only increase cost, increase the discharge of carbon monoxide, sulfurous gas simultaneously, in burning, produced especially multiple obnoxious flavour in addition, environment has been caused to secondary pollution.Wherein to environmental influence the most outstanding be Dioxins, the toxicity of Dioxins is very large, is 130 times of prussiate, 900 times of arsenic, has the title of " poison in century ".Meanwhile, the problem that garbage burning factory all exists whole plant area to stink to high heaven, also has very significantly impact to the conventional air ambient of periphery.Exactly because incineration treatment of garbage has very serious impact to surrounding enviroment, having there is the Mass disturbance of a lot of mass protest government building waste incineration projects in the areas such as recent China Foshan, Zhejiang Hangzhou, affects very severe.
2, combustionresidue, still needs to take up an area landfill
Burning disposal rubbish can produce the combustionresidue of 20%-25%, and prior art is normally by extrusion molding landfill after residue harmless treatment, and this still will take a large amount of soils.Owing to containing heavy metal and other objectionable impuritiess in residue, treatment technology requirement is high, treatment facility is complicated, processing cost is high, if some incineration plant fully residue carry out harmless treatment or process not thorough, this will cause serious pollution can to again soil, underground water.
3, great number investment, economy return is very micro-
Burning disposal rubbish needs great number investment, the incineration plant that the treating refuse of 1 year is 300,000 tons need to invest 3.2 hundred million-3.5 hundred million, be mainly used in buying the equipment of large-area soil, complexity,, technical sophistication large in particular for the facility investment of harmless treatment emission gases and combustionresidue, generally will reach 50% of total investment for construction, this causes, and project cost is high, return period is long, reduced the economic benefit of the project implementation.More having indivedual enterprises is that the investment that interests reduce these treatment facilities does not by fair means or foul reach the effect of harmless treatment, brings very big hidden danger to surrounding enviroment and common people's health.
(2) sanitary landfill
Garbage loading embeading its by by stacking in refuse collecting or directly placing into the soil, rubbish is not carried out to harmless treatment, residual the hidden danger such as a large amount of bacteriums, virus, heavy metal contamination are imbedded underground in the lump; Its garbage leaching liquid can permanent ground contamination groundwater resource, and in seashore is built landfill yard in some areas, work the mischief to coastal waters water and marine organisms.Garbage loading embeading is not only wasted the required land resources of a large amount of landfills, and the environmental pollution causing, because Land pollution has disguise, hysteresis quality, and there is accumulation property, ununiformity, the most important thing is to have difficult reversibility, substantially be the process that can not reverse completely such as heavy metal hard degradation causes Land pollution, organic pollutant also needs the long period to degrade, and this all brings infinite future trouble to descendants.Current many developed countries prohibite landfill waste.The competent authorities at different levels of the Chinese government and technical specialist all think that this kind of mode treating refuse can not be lasting, but not yet find one prevent the pollution of the environment, the processing mode of high-efficient simple is replaced this type of processing mode again.
(3) sorting compost
Garbage sorting compost is the ability of decomposing by microorganism, and the organic substance decomposing in rubbish is become to inorganic nutrients, after compost treatment, becomes farm crop fertilizer, and inorganic metal object wherein and glass, fragment of brick etc. are carried out to landfill, and rubber plastic etc. reclaim; But consumer garbage compost amount is large, and the content of nitrogen and phosphorous is low, life-time service easily causes soil compaction and groundwater quality to degenerate, and also has following distinct issues: 1, odor pollution simultaneously; 2, working cost is too high; 3, technology is immature; 4, factory management is bad etc., so garbage sorting composting technology is still immature at present.
To prior art, retrieval is found, patent name is " using rubbish, stalk and mud to manufacture the method for environment-friendly renewable coal ", application number is 201310672617.3 Chinese invention patent, in this patent, rubbish, stalk, mud are made to environment-friendly renewable coal by weight mixing in mixer, but the course of processing adopts physical method raw material disposal not to be had to the variation of matter, the coal combustion value of its generation is low, pre-treatment link in manufacture method needs manual sorting, classification simultaneously, making method tradition, is difficult to Industry Promotion and sizable application; Patent name is " Novel household garbage environment-friendly renewable coal manufacture method and products thereof ", application number is China's invention of 201210076821.4, utilize domestic refuse to prepare reclaimed coal, but need to add a large amount of chemical auxiliary materials in preparation, cause serious secondary pollution to environment; In addition, also there is the example taking rubbish as fuel power generation function, coal gas processed etc. in China, but investment is large, cost is high, harmless treatment imperfection, forms secondary pollution, and some need to mix a large amount of raw coal or coal liquid, finally causes losing more than gain.
To sum up, also there is no the method for a real science, efficient, pollution-free treating refuse in prior art, more not having can be by rubbish in low cost, pollution-free situation, generates that fuel value is high, the production technology of the coal of non-secondary pollution.
Summary of the invention
For defect of the prior art, the object of this invention is to provide a kind of manufacture method of utilizing domestic refuse to manufacture high, the free of contamination coal of fuel value, dynamically control by rubbish being carried out to time dependent temperature pressure in reactor, domestic refuse is transformed to coal-forming.The related operation of whole method is to carry out in the reactor of a sealing, and equipment used level of automation is high, after a upper operation completes, according to dynamic state of parameters monitoring, can automatically enter subsequent processing.Process for processing cost of the present invention is low, process of manufacture is pollution-free, and the rubbish coal fuel value making high, discharge low.
The present invention is achieved by the following technical solutions:
The invention provides a kind of manufacture method of utilizing domestic refuse to manufacture high, the free of contamination coal of fuel value, concrete steps comprise:
Step 1: rubbish is transported to waste deposit district from each spaced point;
Step 2: rubbish is delivered to reactor from waste deposit district by automatic or manual mode, and reactor is sealed completely;
Step 3: import steam in reactor, and rubbish is carried out to time dependent temperature pressure and dynamically control, form carbonization mixture;
Step 4: reduce temperature and pressure in reactor, discharge liquefaction water, gas that reaction forms;
Step 5: the carbonization mixture that step 3 is formed is poured screening plant into, filters out incombustible material in carbonization mixture, and finally obtain carbide by screening plant.
Preferably, the district of waste deposit described in step 1, it is provided with flase floor for the loading end of placing rubbish, and flase floor goes out the liquid of rubbish for drop, in necessary situation, can push the clean effect of drop that strengthens liquid by pressurizing device;
Preferably, the district of waste deposit described in step 1, is complete seal cavity, in this complete seal cavity by modes such as spray, purifications to the rubbish processing that eliminates the unusual smell, can ensure whole output zone odorless.
Preferably, rubbish described in step 2 carries out preliminary screening by modes such as vibrations, magnetic to rubbish in carrying by automatic or manual mode, removes the rubbish such as part metals, pottery or fragment of brick;
Preferably, described in step 2, rubbish is delivered to reactor by automatic or manual mode from waste deposit district, wherein rubbish is carried and is specifically referred to: first rubbish is placed in reaction box, then reaction box is pushed to reactor by track, the holding rubbish by reaction box, can better load rubbish, so that treating refuse in order in batches, simultaneously, the quantity of reaction box can be several according to the capacity setting of reactor, the bottom of reaction box and the bottom of reactor are provided with the scroll wheel and the track that mutually agree with, are convenient to reaction box turnover reactor.
Preferably, described in step 3, rubbish is carried out to time dependent temperature pressure and dynamically control, temperature span is 150 DEG C-500 DEG C, and pressure span is 15bar-35bar, and the general reaction time is 2h-7h, and time segment is dynamically controlled specific as follows:
Before general reaction, in the time period of 1/4-1/3, temperature span is 150 DEG C-250 DEG C, and pressure span is: 15bar-25bar;
After general reaction, in the time period of 2/4-1/3, temperature span is 200 DEG C-500 DEG C, and pressure span is: 20bar-35bar;
In the middle of general reaction, in the time period of 1/4-1/3, temperature span is 150 DEG C-300 DEG C, and pressure span is: 18bar-25bar.
In technique scheme, reacting kettle inner pressure and the dynamic change of temperature temporal evolution, make rubbish that efficient carburizing reagent occur.
Preferably, in step 3, in temperature and pressure, in rubbish, add catalyzer dynamically controlling in reaction vessel, catalyzer uses following free of contamination material one of them or multiple combination: zinc oxide, celestite powder, mullite powder, snake stone flour, montmorillonite powder, granite powder, bentonite in powder, golden red stone flour, gasoline and butane 1:1 mixture, marble flour, cryolite powder, talcum powder, colliery powder, carbonate sodium, kaolin powder, sepiolite powder, iron ore powder, silica powder, diatomite in powder, bauxitic clay powder, attapulgite powder, ground phosphate rock, Graphite Powder 99, containing poly-lithium silicate salt, sylvite, bucky-ball, clay powder.
Preferably, the carbonization mixture forming in step 3, carries out pouring in screening plant after drying and processing to this carbonization mixture again, and bake out temperature is: 20 DEG C-130 DEG C.
Preferably, described in step 4, reduce temperature and pressure in reactor, specifically: the temperature in described reactor is down to 30 DEG C-150 DEG C, and pressure drop is to standard atmospheric pressure.
Preferably, described in step 4, discharge the liquefaction water that reaction forms, specifically by liquefaction water by strainer harmless treatment and enter water reservoir or sewage network.
Preferably, described in step 4, discharge the gas that reaction forms, specifically by gas by strainer harmless treatment discharged to atmosphere.
Preferably, described in step 5, filter out incombustible material in carbonization mixture by screening plant, specifically by modes such as vibrations, magnetic, carbonization mixture is screened.
Preferably, in step 5, before or after carbonization mixture is carried out to Screening Treatment, carbonization mixture is carried out to pulverization process, after pulverization process, form coal dust, before Screening Treatment, carbonization mixture is carried out to pulverization process in this way, the coal dust forming liking pulverizing of Screening Treatment; After Screening Treatment, carbonization mixture is carried out to pulverization process in this way, the object of Screening Treatment is the block carbonization mixture of High Temperature High Pressure carbonizing treatment.
Preferably, described coal dust, its granular size is: 20 μ m-1500 μ m.
Preferably, described coal dust, is processed into coal dust by shaped device the moulded coal of setting shape according to customer demand.
Preferably, described moulded coal, is specially coal briquette, briquet, coal rod or honeycomb briquette etc.
Preferably, described when pulverized coal forming is processed, humidity is: 5%-30%, pressure is: 20MPa-100MPa.
Compared with prior art, the present invention has following beneficial effect:
(1) operational path of the present invention is rationally advanced, and low to refuse classification requirement, nearly all domestic refuse all can be processed;
(2) preparation method's used level of automation of the present invention is high, after a upper operation completes, according to dynamic state of parameters monitoring, can automatically enter subsequent processing, therefore running cost economy meets innoxious, resource utilization, the industrialized development direction of refuse treatment very much;
(3) the whole production system of the present invention is discharged without foul smell, can surrounding environment not pollute; High temperature in production process in reactor can effectively be killed the germ in rubbish; The liquefaction water, the gas that in production process, form, only need by simple water treating equipment and gas purifying equipment, can form and can meet water and gas national standard, that can discharge, can not produce secondary pollution;
(4) to produce the coal combustion value obtaining higher in the present invention, and according to different rubbish kinds, fuel value is 4500-6500 kilocalorie;
(5) in production process of the present invention, carbonization mixture obtains carbide by screening and is about 90% of described carbonization mixture, the present invention utilizes rubbish to produce the utilization ratio of coal dust far above the additive method of prior art, be that whole production process can be carbide by most garbage conversions, and only have the material of less not carbonaceous component to discharge by screening;
(6) coal that the present invention generates, the discharge after burning is taking a small amount of carbonic acid gas as main, and combustion product gases quantity discharged is than the low 50%-60% of common bituminous coal;
(7) coal dust that the present invention generates, can be used as the raw material of carbon fertilizer, thereby has further widened the purposes that refuse reclamation is utilized;
(8) the required infusion of financial resources of the construction project of the inventive method is few, return is fast, because technique is simple, equipment is also without complex appts, so build the producing coal with garbage equipment of 300,000 tons of year treating refuse and the factory that forms a complete production network, approximately needing to drop into 5,000 ten thousand yuans, approximately two years payback periods, is 15% left and right of equal treatment capacity garbage burning factory investment;
(9) technical solution of the present invention is reasonable, equipment advanced person, and required area of mill site is little, builds the factory of 300,000 tons of year treating refuse, only needs the soil of 100 mu of left and right, and the garbage burning factory of building equal treatment capacity needs 400-500 mu;
(10) economy of the present invention, efficiently environmental issue and energy problem are organically combined, on industrialization height, solve social enviroment protection problem, meet national policy guidance completely, the market requirement is very huge simultaneously, according to current rubbish increment, at least need to build the garbage burning factory of 300,000 tons of scales of family more than 1000, with this technology building Lai Jizhimei processing plant, before 2016, at least can build at home 100 left and right, so this project implementation is the strong propelling to national environmental protection policy, also be the practicing to Chinese dream, there is important social effect.
Brief description of the drawings
By reading the detailed description of non-limiting example being done with reference to the following drawings, it is more obvious that other features, objects and advantages of the present invention will become:
Fig. 1 is the production scheme of patent of the present invention;
The device systems structural representation of Fig. 2 for using in patent production of the present invention;
Wherein, waste deposit storehouse or waste deposit hole 1, reaction box 2, reactor 3, gas storage case 4, by gas filter 5, vapour generator 6, liquid water receptacle 7, water reservoir or sewage network 8, drying unit 9, screening plant 10, shaped device 11.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.Following examples will contribute to those skilled in the art further to understand the present invention, but not limit in any form the present invention.It should be pointed out that to those skilled in the art, without departing from the inventive concept of the premise, can also make some distortion and improvement.These all belong to protection scope of the present invention.
embodiment 1
As shown in Figure 1, the present embodiment provides a kind of manufacture method of utilizing domestic refuse to manufacture high, the free of contamination coal of fuel value, as shown in Figure 2, is to realize the required device systems of this manufacture method.
The manufacture method of the present embodiment, concrete steps comprise:
Step 1: collect and deposit rubbish, specifically incite somebody to action: rubbish is transported to waste deposit storehouse or waste deposit hole 1 from each spaced point;
Step 2: rubbish is put into reaction box 2, and reaction box is pushed to reactor 3: by rubbish by automatic or manual mode from waste deposit storehouse or waste deposit hole 1 be delivered to reaction box 2, then reaction box 2 is pushed to reactor 3 by track, and reactor 3 is sealed completely;
Step 3: import steam, automatically control reactor and react: have vapour generator 6 to produce steam, and import steam in reactor 3, and rubbish is carried out to time dependent temperature pressure and dynamically control, form carbonization mixture;
Step 4: reduce temperature and pressure in reactor, and discharge liquefaction water, gas that reaction forms, the liquefaction water of generation is stored in liquid water receptacle 7, is disposed to water reservoir or sewage network 8 by strainer; The atmosphere storage generating, in gas storage case 4, forms purified gas by gas filter 5;
Step 5: reaction box is pulled out from reactor 3, and the carbonization mixture that step 3 is formed is poured screening plant into, filters out incombustible material in carbonization mixture, and finally obtain carbide by screening plant.
In the present embodiment, the district of waste deposit described in step 1, it is provided with flase floor for the loading end of placing rubbish, and flase floor goes out the liquid of rubbish for drop;
In the present embodiment, rubbish described in step 2 carries out preliminary screening by modes such as vibrations, magnetic to rubbish in carrying by automatic or manual mode, removes the rubbish such as part metals, pottery or fragment of brick;
In the present embodiment, in step 2 by rubbish by automatic transmission mode from waste deposit storehouse or waste deposit hole 1 be delivered to reaction box 2, specifically reaction box is pushed in reactor by automatic transmission track.
In the present embodiment, described in step 3, rubbish is carried out to time dependent temperature pressure and dynamically control, the general reaction time is 2 hours, and time segment is dynamically controlled specific as follows:
In the time period of general reaction front 1/4, temperature is 150 DEG C, and pressure is: 15bar;
In the middle of general reaction, in 2/4 time period, temperature is 200 DEG C, and pressure is: 20bar;
After general reaction, in 1/4 time period, temperature is 150 DEG C, and pressure is: 18bar.
In the present embodiment, in step 3, in temperature and pressure, in rubbish, add catalyzer dynamically controlling in reaction vessel, catalyzer use following substances one of them or multiple combination: zinc oxide, celestite powder, mullite powder, snake stone flour, montmorillonite powder, granite powder, bentonite in powder, golden red stone flour, gasoline and butane 1:1 mixture.
In the present embodiment, the carbonization mixture forming in step 3, is undertaken pouring in screening plant 10 after drying and processing by drying unit 9 to this carbonization mixture again, and bake out temperature is: 20 DEG C.
In the present embodiment, described in step 4, reduce temperature and pressure in reactor, specifically: the temperature in described reactor is down to 30 DEG C, and pressure drop is to standard atmospheric pressure.
In the present embodiment, described in step 4, discharge the liquefaction water that reaction forms, specifically by liquefaction water by strainer harmless treatment and enter water reservoir or sewage network.
In the present embodiment, described in step 4, discharge the gas that reaction forms, specifically by gas by strainer harmless treatment discharged to atmosphere.
In the present embodiment, described in step 5, filter out incombustible material in carbonization mixture by screening plant, specifically by modes such as vibrations, magnetic, carbonization mixture is screened;
In the present embodiment, in step 5, before or after carbonization mixture is carried out to Screening Treatment, carbonization mixture is carried out to pulverization process, after pulverization process, form coal dust, before Screening Treatment, carbonization mixture is carried out to pulverization process in this way, the coal dust forming liking pulverizing of Screening Treatment; After Screening Treatment, carbonization mixture is carried out to pulverization process in this way, the object of Screening Treatment is the block carbonization mixture of High Temperature High Pressure carbonizing treatment.Because the process links of pulverization process can regulate, so in accompanying drawing 1 and accompanying drawing 2, do not draw and pulverize corresponding operation and equipment, in accompanying drawing, not embodying corresponding content does not affect understanding and the realization of the technical program.
In the present embodiment, described coal dust, its granular size is: 1500 μ m.
In the present embodiment, described coal dust, is processed into coal dust by shaped device 11 moulded coal of setting shape according to customer demand.
In the present embodiment, described moulded coal, is specially coal briquette, briquet, coal rod or honeycomb briquette.
In the present embodiment, described when pulverized coal forming is processed, humidity is: 5%, and pressure is: 20MPa.
embodiment 2
Total preparation of the present embodiment is identical with embodiment 1, relates to different parameters and limits as follows:
In the present embodiment, described in step 3, rubbish is carried out to time dependent temperature pressure and dynamically control, the general reaction time is 7 hours, and time segment is dynamically controlled specific as follows:
In the time period of general reaction front 1/3, temperature is 250 DEG C, and pressure is: 25bar;
In the middle of general reaction, in 1/3 time period, temperature is 500 DEG C, and pressure is: 35bar;
After general reaction, in 1/3 time period, temperature is 300 DEG C, and pressure is: 25bar.
In the present embodiment, in step 3, in temperature and pressure, in rubbish, add catalyzer dynamically controlling in reaction vessel, catalyzer use following substances one of them or multiple combination: marble flour, cryolite powder, talcum powder, colliery powder, carbonate sodium, kaolin powder, sepiolite powder, iron ore powder.
In the present embodiment, the carbonization mixture forming in step 3, carries out pouring in screening plant after drying and processing to this carbonization mixture again, and bake out temperature is: 130 DEG C.
In the present embodiment, described in step 4, reduce temperature and pressure in reactor, specifically: the temperature in described reactor is down to 150 DEG C, and pressure drop is to standard atmospheric pressure.
In the present embodiment, described coal dust, its granular size is: 20 μ m.
In the present embodiment, described when pulverized coal forming is processed, humidity is: 30%, and pressure is: 100MPa.
embodiment 3
Total preparation of the present embodiment is identical with embodiment 1, relates to different parameters and limits as follows:
In the present embodiment, described in step 3, rubbish is carried out to time dependent temperature pressure and dynamically control, the general reaction time is 5 hours, and time segment is dynamically controlled specific as follows:
In the time period of general reaction front 1/4, temperature is 180 DEG C, and pressure is: 20bar;
In the middle of general reaction, in 2/4 time period, temperature is 300 DEG C, and pressure is: 30bar;
After general reaction, in 1/4 time period, temperature is 200 DEG C, and pressure is: 23bar.
In the present embodiment, in step 3, add catalyzer dynamically controlling in reaction vessel in temperature and pressure in rubbish, catalyzer uses following substances one of them or multiple combination: silica powder, diatomite in powder, bauxitic clay powder, attapulgite powder, ground phosphate rock, Graphite Powder 99, contain poly-lithium silicate salt, sylvite, bucky-ball, clay powder.
In the present embodiment, the carbonization mixture forming in step 3, carries out pouring in screening plant after drying and processing to this carbonization mixture again, and bake out temperature is: 100 DEG C.
In the present embodiment, described in step 4, reduce temperature and pressure in reactor, specifically: the temperature in described reactor is down to 45 DEG C, and pressure drop is to standard atmospheric pressure.
In the present embodiment, described coal dust, its granular size is: 500 μ m.
In the present embodiment, described when pulverized coal forming is processed, humidity is: 20%, and pressure is: 80MPa.
Above specific embodiments of the invention are described.It will be appreciated that, the present invention is not limited to above-mentioned specific implementations, and those skilled in the art can make various distortion or amendment within the scope of the claims, and this does not affect flesh and blood of the present invention.
Claims (17)
1. utilize domestic refuse to manufacture a manufacture method for high, the free of contamination coal of fuel value, concrete steps comprise:
Step 1: rubbish is transported to waste deposit district from each spaced point;
Step 2: rubbish is delivered to reactor from waste deposit district by automatic or manual mode, and reactor is sealed completely;
Step 3: import steam in reactor, and rubbish is carried out to time dependent temperature pressure and dynamically control, form carbonization mixture;
Step 4: reduce temperature and pressure in reactor, discharge liquefaction water, gas that reaction forms;
Step 5: the carbonization mixture that step 3 is formed is poured screening plant into, filters out incombustible material in carbonization mixture, and finally obtain carbide by screening plant.
2. the manufacture method of utilizing domestic refuse to manufacture high, the free of contamination coal of fuel value according to claim 1, it is characterized in that, the district of waste deposit described in step 1, it is provided with flase floor for the loading end of placing rubbish, and flase floor goes out the liquid of rubbish for drop.
3. the manufacture method of utilizing domestic refuse to manufacture high, the free of contamination coal of fuel value according to claim 1, it is characterized in that, the district of waste deposit described in step 1, is complete seal cavity, in this complete seal cavity by spray or purification style to the rubbish processing that eliminates the unusual smell.
4. the manufacture method of utilizing domestic refuse to manufacture high, the free of contamination coal of fuel value according to claim 1, it is characterized in that, during rubbish described in step 2 is carried by automatic or manual mode, mode by vibrations or magnetic is carried out preliminary screening to rubbish, removes part metals, pottery or fragment of brick rubbish.
5. the manufacture method of utilizing domestic refuse to manufacture high, the free of contamination coal of fuel value according to claim 1, it is characterized in that, described in step 2, rubbish is delivered to reactor by automatic or manual mode from waste deposit district, wherein rubbish is carried and is specifically referred to: first rubbish is placed in reaction box, then reaction box is pushed to reactor by track.
6. the manufacture method of utilizing domestic refuse to manufacture high, the free of contamination coal of fuel value according to claim 1, it is characterized in that, described in step 3, rubbish being carried out to time dependent temperature pressure dynamically controls, temperature span is 150 DEG C-500 DEG C, pressure span is 15bar-35bar, the general reaction time is 2h-7h, and time segment is dynamically controlled specific as follows:
Before general reaction, in the time period of 1/4-1/3, temperature span is 150 DEG C-250 DEG C, and pressure span is: 15bar-25bar;
After general reaction, in the time period of 2/4-1/3, temperature span is 200 DEG C-500 DEG C, and pressure span is: 20bar-35bar;
In the middle of general reaction, in the time period of 1/4-1/3, temperature span is 150 DEG C-300 DEG C, and pressure span is: 18bar-25bar.
7. the domestic refuse manufacture fuel value of utilizing according to claim 1 is high, the manufacture method of free of contamination coal, it is characterized in that, in step 3, in temperature and pressure, in rubbish, add catalyzer dynamically controlling in reaction vessel, catalyzer uses following substances one of them or multiple combination: zinc oxide, celestite powder, mullite powder, snake stone flour, montmorillonite powder, granite powder, bentonite in powder, golden red stone flour, gasoline and butane 1:1 mixture, marble flour, cryolite powder, talcum powder, colliery powder, carbonate sodium, kaolin powder, sepiolite powder, iron ore powder, silica powder, diatomite in powder, bauxitic clay powder, attapulgite powder, ground phosphate rock, Graphite Powder 99, containing poly-lithium silicate salt, sylvite, bucky-ball, clay powder.
8. the manufacture method of utilizing domestic refuse to manufacture high, the free of contamination coal of fuel value according to claim 1, it is characterized in that, the carbonization mixture forming in step 3, carries out pouring in screening plant after drying and processing to this carbonization mixture again, and bake out temperature is: 20 DEG C-130 DEG C.
9. the manufacture method of utilizing domestic refuse to manufacture high, the free of contamination coal of fuel value according to claim 1, it is characterized in that, described in step 4, reduce temperature and pressure in reactor, specifically: the temperature in described reactor is down to 30 DEG C-150 DEG C, and pressure drop is to standard atmospheric pressure.
10. the manufacture method of utilizing domestic refuse to manufacture high, the free of contamination coal of fuel value according to claim 1, it is characterized in that, described in step 4, discharge the liquefaction water that reaction forms, specifically by liquefaction water by strainer harmless treatment and enter water reservoir or sewage network.
11. manufacture method of utilizing domestic refuse to manufacture high, the free of contamination coal of fuel value according to claim 1, is characterized in that, discharge the gas that reaction forms described in step 4, specifically by gas by strainer harmless treatment and discharged to atmosphere.
12. manufacture method of utilizing domestic refuse to manufacture high, the free of contamination coal of fuel value according to claim 1, it is characterized in that, described in step 5, filter out incombustible material in carbonization mixture by screening plant, specifically by the mode of vibrations or magnetic, carbonization mixture is screened.
13. manufacture method of utilizing domestic refuse to manufacture high, the free of contamination coal of fuel value according to claim 1, it is characterized in that, in step 5, before or after carbonization mixture is carried out to Screening Treatment, carbonization mixture is carried out to pulverization process, after pulverization process, form coal dust.
14. manufacture method of utilizing domestic refuse to manufacture high, the free of contamination coal of fuel value according to claim 13, is characterized in that, described coal dust, and its granular size is: 20 μ m-1500 μ m.
15. manufacture method of utilizing domestic refuse to manufacture high, the free of contamination coal of fuel value according to claim 13, is characterized in that, described coal dust is processed into coal dust by shaped device the moulded coal of setting shape according to customer demand.
16. manufacture method of utilizing domestic refuse to manufacture high, the free of contamination coal of fuel value according to claim 15, is characterized in that described moulded coal is specially coal briquette, briquet, coal rod or honeycomb briquette.
17. manufacture method of utilizing domestic refuse to manufacture high, the free of contamination coal of fuel value according to claim 15, is characterized in that, described when pulverized coal forming is processed, humidity is: 5%-30%, pressure is: 20MPa-100MPa.
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410293336.1A CN104031713A (en) | 2014-06-25 | 2014-06-25 | Manufacturing method of pollution-free coal with high combustion value by household garbage |
| PCT/CN2014/081469 WO2015196502A1 (en) | 2014-06-25 | 2014-07-02 | Method for manufacturing high-calorific-value, non-polluting coal from household garbage |
| CN201420575439.2U CN204325226U (en) | 2014-06-25 | 2014-09-30 | Rubbish carbonization reaction system |
| CN201410520612.3A CN104403716B (en) | 2014-06-25 | 2014-09-30 | Method for producing biomass fuels by using garbage |
| CN201410522166.XA CN104263388B (en) | 2014-06-25 | 2014-09-30 | Rubbish carbonization reaction system |
| PCT/CN2014/092669 WO2016049978A1 (en) | 2014-06-25 | 2014-12-01 | Garbage carbonization reaction system |
| PCT/CN2014/092668 WO2015196732A1 (en) | 2014-06-25 | 2014-12-01 | Method for manufacturing biomass fuel from garbage |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410293336.1A CN104031713A (en) | 2014-06-25 | 2014-06-25 | Manufacturing method of pollution-free coal with high combustion value by household garbage |
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| Publication Number | Publication Date |
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| CN104031713A true CN104031713A (en) | 2014-09-10 |
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| CN201410293336.1A Pending CN104031713A (en) | 2014-06-25 | 2014-06-25 | Manufacturing method of pollution-free coal with high combustion value by household garbage |
| CN201410520612.3A Expired - Fee Related CN104403716B (en) | 2014-06-25 | 2014-09-30 | Method for producing biomass fuels by using garbage |
| CN201410522166.XA Active CN104263388B (en) | 2014-06-25 | 2014-09-30 | Rubbish carbonization reaction system |
| CN201420575439.2U Active CN204325226U (en) | 2014-06-25 | 2014-09-30 | Rubbish carbonization reaction system |
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| CN201410520612.3A Expired - Fee Related CN104403716B (en) | 2014-06-25 | 2014-09-30 | Method for producing biomass fuels by using garbage |
| CN201410522166.XA Active CN104263388B (en) | 2014-06-25 | 2014-09-30 | Rubbish carbonization reaction system |
| CN201420575439.2U Active CN204325226U (en) | 2014-06-25 | 2014-09-30 | Rubbish carbonization reaction system |
Country Status (2)
| Country | Link |
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| CN (4) | CN104031713A (en) |
| WO (3) | WO2015196502A1 (en) |
Cited By (5)
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| WO2015196732A1 (en) * | 2014-06-25 | 2015-12-30 | 沙嫣 | Method for manufacturing biomass fuel from garbage |
| CN105219471A (en) * | 2015-10-17 | 2016-01-06 | 明光市龙腾矿物有限公司 | A kind of containing sepiolite composite biomass fuel and preparation method thereof |
| CN106867616A (en) * | 2017-03-22 | 2017-06-20 | 合肥浦尔菲电线科技有限公司 | A kind of Novel environment-friendlymaterial material and preparation method thereof |
| CN110716479A (en) * | 2019-11-13 | 2020-01-21 | 河北星鼎机械设备制造有限公司 | Control method of garbage anaerobic carbonization system |
| CN114011841A (en) * | 2021-09-23 | 2022-02-08 | 中铁市政环境建设有限公司 | Distributed garbage carbonization treatment system |
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| CN105296046B (en) * | 2015-10-17 | 2017-12-08 | 明光市龙腾矿物有限公司 | A kind of biomass fuel containing calcareous shale |
| CN105598137B (en) * | 2016-02-22 | 2017-09-12 | 长沙雷邦环保科技有限公司 | A kind of solid waste integrated synthesis processing unit |
| CN109294600B (en) * | 2018-12-06 | 2024-01-23 | 黑龙江省能源环境研究院 | Multi-bin vertical biomass carbonization experiment furnace and application method thereof |
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| JP2000104082A (en) * | 1998-09-30 | 2000-04-11 | Kawasaki Steel Corp | Method and apparatus for producing refuse derived solid fuel |
| KR20010110384A (en) * | 2001-11-17 | 2001-12-13 | 남학진 | The Method of Recycling Wastes for Carbonizing Fuel |
| JP2006206856A (en) * | 2005-01-31 | 2006-08-10 | Kenji Yamane | Manufacturing method of carbide and carbide manufacturing unit |
| CN1915544A (en) * | 2005-08-15 | 2007-02-21 | 萧良英 | Synthesis method for treating household garbage in city |
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| CN104031713A (en) * | 2014-06-25 | 2014-09-10 | 沙嫣 | Manufacturing method of pollution-free coal with high combustion value by household garbage |
-
2014
- 2014-06-25 CN CN201410293336.1A patent/CN104031713A/en active Pending
- 2014-07-02 WO PCT/CN2014/081469 patent/WO2015196502A1/en active Application Filing
- 2014-09-30 CN CN201410520612.3A patent/CN104403716B/en not_active Expired - Fee Related
- 2014-09-30 CN CN201410522166.XA patent/CN104263388B/en active Active
- 2014-09-30 CN CN201420575439.2U patent/CN204325226U/en active Active
- 2014-12-01 WO PCT/CN2014/092668 patent/WO2015196732A1/en active Application Filing
- 2014-12-01 WO PCT/CN2014/092669 patent/WO2016049978A1/en active Application Filing
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015196732A1 (en) * | 2014-06-25 | 2015-12-30 | 沙嫣 | Method for manufacturing biomass fuel from garbage |
| WO2016049978A1 (en) * | 2014-06-25 | 2016-04-07 | 沙嫣 | Garbage carbonization reaction system |
| CN105219471A (en) * | 2015-10-17 | 2016-01-06 | 明光市龙腾矿物有限公司 | A kind of containing sepiolite composite biomass fuel and preparation method thereof |
| CN106867616A (en) * | 2017-03-22 | 2017-06-20 | 合肥浦尔菲电线科技有限公司 | A kind of Novel environment-friendlymaterial material and preparation method thereof |
| CN110716479A (en) * | 2019-11-13 | 2020-01-21 | 河北星鼎机械设备制造有限公司 | Control method of garbage anaerobic carbonization system |
| CN110716479B (en) * | 2019-11-13 | 2022-06-03 | 河北星鼎机械设备制造有限公司 | Control method of garbage anaerobic carbonization system |
| CN114011841A (en) * | 2021-09-23 | 2022-02-08 | 中铁市政环境建设有限公司 | Distributed garbage carbonization treatment system |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104263388B (en) | 2016-08-17 |
| CN104263388A (en) | 2015-01-07 |
| CN204325226U (en) | 2015-05-13 |
| CN104403716B (en) | 2017-01-18 |
| WO2016049978A1 (en) | 2016-04-07 |
| CN104403716A (en) | 2015-03-11 |
| WO2015196732A1 (en) | 2015-12-30 |
| WO2015196502A1 (en) | 2015-12-30 |
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