CN104031631B - Mud acid cross-linking agent and preparation method thereof - Google Patents
Mud acid cross-linking agent and preparation method thereof Download PDFInfo
- Publication number
- CN104031631B CN104031631B CN201410277220.9A CN201410277220A CN104031631B CN 104031631 B CN104031631 B CN 104031631B CN 201410277220 A CN201410277220 A CN 201410277220A CN 104031631 B CN104031631 B CN 104031631B
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- parts
- phenol
- water
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- catalyst
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Links
- 239000002253 acid Substances 0.000 title claims abstract description 72
- 239000003431 cross linking reagent Substances 0.000 title claims abstract description 52
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 104
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 71
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 54
- 239000003054 catalyst Substances 0.000 claims abstract description 52
- 239000005011 phenolic resin Substances 0.000 claims abstract description 52
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 41
- JHHZLHWJQPUNKB-UHFFFAOYSA-N pyrrolidin-3-ol Chemical compound OC1CCNC1 JHHZLHWJQPUNKB-UHFFFAOYSA-N 0.000 claims abstract description 31
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 26
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 23
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims abstract description 15
- 238000006243 chemical reaction Methods 0.000 claims description 49
- 238000003756 stirring Methods 0.000 claims description 43
- 238000010792 warming Methods 0.000 claims description 28
- 239000007788 liquid Substances 0.000 claims description 16
- 239000002994 raw material Substances 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- 239000003292 glue Substances 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 150000001299 aldehydes Chemical class 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 230000036632 reaction speed Effects 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 2
- 230000003044 adaptive effect Effects 0.000 abstract 1
- 229940015043 glyoxal Drugs 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 63
- 238000004132 cross linking Methods 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 239000011435 rock Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical compound N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 229920006322 acrylamide copolymer Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 229910052925 anhydrite Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000001455 metallic ions Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003129 oil well Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/62—Compositions for forming crevices or fractures
- C09K8/72—Eroding chemicals, e.g. acids
- C09K8/74—Eroding chemicals, e.g. acids combined with additives added for specific purposes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/84—Compositions based on water or polar solvents
- C09K8/86—Compositions based on water or polar solvents containing organic compounds
- C09K8/88—Compositions based on water or polar solvents containing organic compounds macromolecular compounds
- C09K8/887—Compositions based on water or polar solvents containing organic compounds macromolecular compounds containing cross-linking agents
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Abstract
Description
Cross-linking agent | Temperature (DEG C) | Dosage (%) | Crosslinking time (s) | Cross-linked state |
Cross-linking agent a | 60 | 3.0 | 140 | Can hang |
Cross-linking agent b | 60 | 3.0 | 155 | Can hang |
Cross-linking agent c | 60 | 3.0 | 142 | Can hang |
Cross-linking agent d | 60 | 3.0 | 150 | Can hang |
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410277220.9A CN104031631B (en) | 2014-06-16 | 2014-06-16 | Mud acid cross-linking agent and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410277220.9A CN104031631B (en) | 2014-06-16 | 2014-06-16 | Mud acid cross-linking agent and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
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CN104031631A CN104031631A (en) | 2014-09-10 |
CN104031631B true CN104031631B (en) | 2017-01-25 |
Family
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Family Applications (1)
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CN201410277220.9A Expired - Fee Related CN104031631B (en) | 2014-06-16 | 2014-06-16 | Mud acid cross-linking agent and preparation method thereof |
Country Status (1)
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CN (1) | CN104031631B (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106398672A (en) * | 2016-09-07 | 2017-02-15 | 中国石油化工股份有限公司 | Preparation method of water soluble phenolic resin crosslinking agent for temporary plugging steering acidizing |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101602838A (en) * | 2009-07-10 | 2009-12-16 | 北京林业大学 | A kind of preparation method who is used for the wood pyrolysis oil modified phenolic resin of wood-based plate |
CN102952533A (en) * | 2012-11-20 | 2013-03-06 | 西南石油大学 | Composite cross-linked polymer weak gel oil displacement agent and preparation method thereof |
CN102965093A (en) * | 2012-11-21 | 2013-03-13 | 中国海洋石油总公司 | Composite crosslinking deep profile control agent for oil reservoir deep profile control and preparation method thereof |
EP2617779A1 (en) * | 2012-01-20 | 2013-07-24 | JETBEST Corporation | Low odor environmentally-friendly nano-pigment inkjet ink composition |
CN102093871B (en) * | 2009-12-09 | 2013-09-04 | 中国石油天然气股份有限公司 | Cross-linking acid cross-linking agent and preparation method thereof |
CN103554830A (en) * | 2013-10-25 | 2014-02-05 | 林百川 | Phenolic foam material with low coefficient of thermal conductivity and preparation method thereof |
CN103790560A (en) * | 2012-11-02 | 2014-05-14 | 西安交大京盛科技发展有限公司 | Fractured reservoir profile control process |
-
2014
- 2014-06-16 CN CN201410277220.9A patent/CN104031631B/en not_active Expired - Fee Related
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101602838A (en) * | 2009-07-10 | 2009-12-16 | 北京林业大学 | A kind of preparation method who is used for the wood pyrolysis oil modified phenolic resin of wood-based plate |
CN102093871B (en) * | 2009-12-09 | 2013-09-04 | 中国石油天然气股份有限公司 | Cross-linking acid cross-linking agent and preparation method thereof |
EP2617779A1 (en) * | 2012-01-20 | 2013-07-24 | JETBEST Corporation | Low odor environmentally-friendly nano-pigment inkjet ink composition |
CN103790560A (en) * | 2012-11-02 | 2014-05-14 | 西安交大京盛科技发展有限公司 | Fractured reservoir profile control process |
CN102952533A (en) * | 2012-11-20 | 2013-03-06 | 西南石油大学 | Composite cross-linked polymer weak gel oil displacement agent and preparation method thereof |
CN102965093A (en) * | 2012-11-21 | 2013-03-13 | 中国海洋石油总公司 | Composite crosslinking deep profile control agent for oil reservoir deep profile control and preparation method thereof |
CN103554830A (en) * | 2013-10-25 | 2014-02-05 | 林百川 | Phenolic foam material with low coefficient of thermal conductivity and preparation method thereof |
Non-Patent Citations (1)
Title |
---|
硼酚醛树脂及其塑料的合成制备研究进展;杨莹 等;《工程塑料应用》;20120930;87-89 * |
Also Published As
Publication number | Publication date |
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CN104031631A (en) | 2014-09-10 |
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C06 | Publication | ||
PB01 | Publication | ||
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
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TR01 | Transfer of patent right |
Effective date of registration: 20201021 Address after: 102200 No. 204, 2nd Floor, Beijing Shidacuigong Conference Center, College of Petroleum University, Zhenreservoir Road, Changping District, Beijing Patentee after: BEIJING SEALAND INSTITUTE OF ENERGY RESEARCH Patentee after: Qinghai Guorong energy and environment Co.,Ltd. Address before: 102200, Beijing Changping District science and Technology Park, super Road, 35 Chemical University (Beijing) science and Technology Park, building 305 Patentee before: BEIJING SEALAND INSTITUTE OF ENERGY RESEARCH Patentee before: XINXIANG XUANTAI INDUSTRY Co.,Ltd. |
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TR01 | Transfer of patent right |
Effective date of registration: 20210407 Address after: 102200 No.204, 2nd floor, shidacui palace Conference Center, petroleum university, Shuiku Road, Chengcheng Town, Changping District, Beijing Patentee after: BEIJING SEALAND INSTITUTE OF ENERGY RESEARCH Address before: 102200 No.204, 2nd floor, shidacui palace Conference Center, petroleum university, Shuiku Road, Chengcheng Town, Changping District, Beijing Patentee before: BEIJING SEALAND INSTITUTE OF ENERGY RESEARCH Patentee before: Qinghai Guorong energy and environment Co.,Ltd. |
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TR01 | Transfer of patent right |
Effective date of registration: 20220401 Address after: 571155 Guanshu, Mission Hills Resort, Longqiao Town, Longhua District, Haikou City, Hainan Province Patentee after: Zhang Chunyu Address before: 102200 No.204, 2nd floor, shidacui palace Conference Center, petroleum university, Shuiku Road, Chengcheng Town, Changping District, Beijing Patentee before: BEIJING SEALAND INSTITUTE OF ENERGY RESEARCH |
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CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20170125 |
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CF01 | Termination of patent right due to non-payment of annual fee |