CN104031455B - Car paints fire retardant - Google Patents
Car paints fire retardant Download PDFInfo
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- CN104031455B CN104031455B CN201410288977.8A CN201410288977A CN104031455B CN 104031455 B CN104031455 B CN 104031455B CN 201410288977 A CN201410288977 A CN 201410288977A CN 104031455 B CN104031455 B CN 104031455B
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- methyl
- fire
- car paints
- triethyl ammonium
- fire retardant
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 29
- 239000003973 paint Substances 0.000 title claims abstract description 25
- ZOJBYZNEUISWFT-UHFFFAOYSA-N allyl isothiocyanate Chemical compound C=CCN=C=S ZOJBYZNEUISWFT-UHFFFAOYSA-N 0.000 claims abstract description 27
- CFAKWWQIUFSQFU-UHFFFAOYSA-N 2-hydroxy-3-methylcyclopent-2-en-1-one Chemical compound CC1=C(O)C(=O)CC1 CFAKWWQIUFSQFU-UHFFFAOYSA-N 0.000 claims abstract description 23
- YUFRRMZSSPQMOS-UHFFFAOYSA-N 2-(2-aminoethyldisulfanyl)ethanamine;hydron;dichloride Chemical compound Cl.Cl.NCCSSCCN YUFRRMZSSPQMOS-UHFFFAOYSA-N 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- -1 2,3-dimercapto-1-propyl Chemical group 0.000 claims abstract description 11
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 claims abstract description 11
- LHTVMBMETNGEAN-UHFFFAOYSA-N pent-1-en-1-ol Chemical compound CCCC=CO LHTVMBMETNGEAN-UHFFFAOYSA-N 0.000 claims abstract description 11
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims abstract description 11
- CRWMOJJERCTMAI-UHFFFAOYSA-N tetraethylazanium triiodide Chemical compound [I-](I)I.C(C)[N+](CC)(CC)CC CRWMOJJERCTMAI-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 230000006378 damage Effects 0.000 abstract description 6
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 5
- 208000027418 Wounds and injury Diseases 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 208000014674 injury Diseases 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 239000000470 constituent Substances 0.000 abstract description 2
- 230000003993 interaction Effects 0.000 abstract description 2
- 238000010422 painting Methods 0.000 abstract description 2
- 238000003756 stirring Methods 0.000 description 16
- 230000000052 comparative effect Effects 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 7
- 230000007812 deficiency Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000002828 fuel tank Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to car paints fire retardant, belong to fire-retardant articles for use field.It is prepared from by following raw material: water, 2,3-dimercapto-1-propyl alcohol, 2-[two (the 2-triethyl ammonium oxyethyl group) phenoxy group of 2,6-] ethyl triethyl ammonium triiodide, 3,6-dioxa-1,8-octamethylenediamine tetraacethyl, two Cystamine HCL 95s, 2-hydroxy-3-methyl-2-cyclopentene-1-one, 2-methyl-5-oxo ring penta-1-enol propionic ester, N-(2,6-dioxo-3-piperidyl)-phthalic imidine, allyl mustard oil.This car paints fire retardant, utilizes the interaction between related chemical constituents, influences each other, and coordinates the use of car paints, effectively prevent from painting catching fire of dirt settling, stop fire spread to expand, there is splendid flame retardant effect, greatly reduce loss of life and personal injury and property damage.
Description
Technical field
The present invention relates to a kind of car paints fire retardant, belong to fire-retardant articles for use technical field.
Background technology
Automobile is the modern transport facility the most widely used, and each unit has automobile, and individual to have the quantity of automobile also increasing.On automobile except fuel tank, oil circuit, miscellaneous part such as tire, inside fitting facility etc. are also combustiblematerialss, fire, but automobile is flowing object, once presence of fire, difficulty of putting out a fire to save life and property is larger.Thus, the vehicle material of a kind of effective prevention automobile fire residence expansion is very necessary.
Summary of the invention
The object of the invention is to solve the deficiency that car paints that above-mentioned prior art exists cannot be fire-retardant, a kind of car paints fire retardant of good flame retardation effect is provided.
Car paints fire retardant, special character is to be prepared from by the raw material of following weight: 80 parts, water, 2, 3-dimercapto-1-propyl alcohol 22-25 part, 2-[2, two (the 2-triethyl ammonium oxyethyl group) phenoxy group of 6-] ethyl triethyl ammonium triiodide 18-20 part, 3, 6-dioxa-1, 8-octamethylenediamine tetraacethyl 30-32 part, two Cystamine HCL 95 12-15 parts, 2-hydroxy-3-methyl-2-cyclopentene-1-one 14-16 part, 2-methyl-5-oxo ring penta-1-enol propionic ester 12-15 part, N-(2, 6-dioxo-3-piperidyl)-phthalic imidine 4-6 part, allyl mustard oil 1-2 part.
Preparation method of the present invention: add pure water, add 2,3-dimercapto-1-propyl alcohol, 2-[two (the 2-triethyl ammonium oxyethyl group) phenoxy group of 2,6-] ethyl triethyl ammonium triiodide while stirring, continue to be stirred to and be uniformly dispersed, be then heated to 55-65 DEG C; Slowly add 3,6-dioxa-1,8-octamethylenediamine tetraacethyl, stir and make it to dissolve; After add two Cystamine HCL 95s successively, 2-hydroxy-3-methyl-2-cyclopentene-1-one, 2-methyl-5-oxo ring penta-1-enol propionic ester, N-(2,6-dioxo-3-piperidyl)-phthalic imidine, allyl mustard oil, stirs; Be cooled to 30-35 DEG C, stir and leave standstill 20 minutes, namely obtain this car paints fire retardant.
This car paints fire retardant, utilizes the interaction between related chemical constituents, influences each other, and coordinates the use of car paints, effectively prevent from painting catching fire of dirt settling, stop fire spread to expand, there is splendid flame retardant effect, greatly reduce loss of life and personal injury and property damage.
Embodiment
Below provide the specific embodiment of the present invention, be used for being further described the present invention.In the present invention, if no special instructions, each raw material all in working substance content for 100%.
In following examples and comparative example, raw material introduction:
2,3-dimercapto-1-propyl alcohol, CAS accession number is: 59-52-9;
2-[two (the 2-triethyl ammonium oxyethyl group) phenoxy group of 2,6-] ethyl triethyl ammonium triiodide, CAS accession number is: 65-29-2;
3,6-dioxa-1,8-octamethylenediamine tetraacethyl, CAS accession number is: 67-42-5;
Two Cystamine HCL 95s, CAS accession number is: 56-17-7;
2-hydroxy-3-methyl-2-cyclopentene-1-one, CAS accession number is: 80-71-7;
2-methyl-5-oxo ring penta-1-enol propionic ester, CAS accession number is: 87-55-8;
N-(2,6-dioxo-3-piperidyl)-phthalic imidine, CAS accession number is: 50-35-1;
Allyl mustard oil, CAS accession number is: 57-06-7.
Embodiment 1
Weigh: water 80kg, 2,3-dimercapto-1-propyl alcohol 22kg, 2-[two (the 2-triethyl ammonium oxyethyl group) phenoxy group of 2,6-] ethyl triethyl ammonium triiodide 20kg, 3,6-dioxa-1,8-octamethylenediamine tetraacethyl 31kg, two Cystamine HCL 95 12kg, 2-hydroxy-3-methyl-2-cyclopentene-1-one 15kg, 2-methyl-5-oxo ring penta-1-enol propionic ester 15kg, N-(2,6-dioxo-3-piperidyl)-phthalic imidine 4kg, allyl mustard oil 1kg.
The preparation method of the present embodiment car paints fire retardant: add pure water, add 2 while stirring, 3-dimercapto-1-propyl alcohol, 2-[2, two (the 2-triethyl ammonium oxyethyl group) phenoxy group of 6-] ethyl triethyl ammonium triiodide, continue to be stirred to and be uniformly dispersed, be then heated to 55-65 DEG C; Slowly add 3,6-dioxa-1,8-octamethylenediamine tetraacethyl, stir and make it to dissolve; After add two Cystamine HCL 95s successively, 2-hydroxy-3-methyl-2-cyclopentene-1-one, 2-methyl-5-oxo ring penta-1-enol propionic ester, N-(2,6-dioxo-3-piperidyl)-phthalic imidine, allyl mustard oil, stirs; Be cooled to 30-35 DEG C, stir and leave standstill 20 minutes, namely obtain this car paints fire retardant.
Embodiment 2
Weigh: water 80kg, 2,3-dimercapto-1-propyl alcohol 25kg, 2-[two (the 2-triethyl ammonium oxyethyl group) phenoxy group of 2,6-] ethyl triethyl ammonium triiodide 18kg, 3,6-dioxa-1,8-octamethylenediamine tetraacethyl 32kg, two Cystamine HCL 95 15kg, 2-hydroxy-3-methyl-2-cyclopentene-1-one 16kg, 2-methyl-5-oxo ring penta-1-enol propionic ester 14kg, N-(2,6-dioxo-3-piperidyl)-phthalic imidine 6kg, allyl mustard oil 2kg.
The preparation method of the present embodiment car paints fire retardant is with embodiment 1.
Embodiment 3
Weigh: water 80kg, 2,3-dimercapto-1-propyl alcohol 23kg, 2-[two (the 2-triethyl ammonium oxyethyl group) phenoxy group of 2,6-] ethyl triethyl ammonium triiodide 19kg, 3,6-dioxa-1,8-octamethylenediamine tetraacethyl 30kg, two Cystamine HCL 95 13kg, 2-hydroxy-3-methyl-2-cyclopentene-1-one 14kg, 2-methyl-5-oxo ring penta-1-enol propionic ester 12kg, N-(2,6-dioxo-3-piperidyl)-phthalic imidine 5kg, allyl mustard oil 1.5kg.
The preparation method of the present embodiment car paints fire retardant is with embodiment 1.
Comparative example 1
Weigh: water 80kg, 2,3-dimercapto-1-propyl alcohol 22kg, 2-[two (the 2-triethyl ammonium oxyethyl group) phenoxy group of 2,6-] ethyl triethyl ammonium triiodide 20kg, 3,6-dioxa-1,8-octamethylenediamine tetraacethyl 31kg, two Cystamine HCL 95 12kg, 2-methyl-5-oxo ring penta-1-enol propionic ester 15kg, allyl mustard oil 1kg.
The preparation method of this comparative example car paints fire retardant: add pure water, add 2 while stirring, 3-dimercapto-1-propyl alcohol, 2-[2, two (the 2-triethyl ammonium oxyethyl group) phenoxy group of 6-] ethyl triethyl ammonium triiodide, continue to be stirred to and be uniformly dispersed, be then heated to 55-65 DEG C; Slowly add 3,6-dioxa-1,8-octamethylenediamine tetraacethyl, stir and make it to dissolve; After add two Cystamine HCL 95s successively, 2-methyl-5-oxo ring penta-1-enol propionic ester, allyl mustard oil, stirs; Be cooled to 30-35 DEG C, stir and leave standstill 20 minutes, namely obtain this car paints fire retardant.
Comparative example 2
Weigh: water 80kg, 2,3-dimercapto-1-propyl alcohol 22kg, 3,6-dioxa-1,8-octamethylenediamine tetraacethyl 31kg, two Cystamine HCL 95 12kg, 2-hydroxy-3-methyl-2-cyclopentene-1-one 15kg, N-(2,6-dioxo-3-piperidyl)-phthalic imidine 4kg, allyl mustard oil 1kg.
The preparation method of this comparative example car paints fire retardant: add pure water, adds 2,3-dimercapto-1-propyl alcohol while stirring, continues to be stirred to be uniformly dispersed, and is then heated to 55-65 DEG C; Slowly add 3,6-dioxa-1,8-octamethylenediamine tetraacethyl, stir and make it to dissolve; After add two Cystamine HCL 95s successively, 2-hydroxy-3-methyl-2-cyclopentene-1-one, N-(2,6-dioxo-3-piperidyl)-phthalic imidine, allyl mustard oil, stirs; Be cooled to 30-35 DEG C, stir and leave standstill 20 minutes, namely obtain this car paints fire retardant.
Test case
Test embodiment and comparative example, concrete data are in table 1.
The flame retardant properties test chart of car paints fire retardant
| UL-94 flame retardant rating, (1.6mm) | LOI，% | |
| Embodiment 1 | VO | 32.1 |
| Embodiment 2 | VO | 30.4 |
| Embodiment 3 | VO | 31.2 |
| Comparative example 1 | VO | 22.3 |
| Comparative example 2 | NR | 9.5 |
Thermotolerance and the flame retardant resistance of car paints fire retardant of the present invention are better, and preparation technology is simple, and product cost is low, the good combination property of product.When car paints is constructed, use this car paints fire retardant simultaneously, effectively prevent the diffusion of automobile fire residence from spreading, put out a fire in time, reduce loss of life and personal injury and property damage.
Claims (1)
1. car paints fire retardant, it is characterized in that being prepared from by the raw material of following weight: 80 parts, water, 2, 3-dimercapto-1-propyl alcohol 22-25 part, 2-[2, two (the 2-triethyl ammonium oxyethyl group) phenoxy group of 6-] ethyl triethyl ammonium triiodide 18-20 part, 3, 6-dioxa-1, 8-octamethylenediamine tetraacethyl 30-32 part, two Cystamine HCL 95 12-15 parts, 2-hydroxy-3-methyl-2-cyclopentene-1-one 14-16 part, 2-methyl-5-oxo ring penta-1-enol propionic ester 12-15 part, N-(2, 6-dioxo-3-piperidyl)-phthalic imidine 4-6 part, allyl mustard oil 1-2 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410288977.8A CN104031455B (en) | 2014-06-25 | 2014-06-25 | Car paints fire retardant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410288977.8A CN104031455B (en) | 2014-06-25 | 2014-06-25 | Car paints fire retardant |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104031455A CN104031455A (en) | 2014-09-10 |
| CN104031455B true CN104031455B (en) | 2015-11-11 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410288977.8A Active CN104031455B (en) | 2014-06-25 | 2014-06-25 | Car paints fire retardant |
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| Country | Link |
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| CN (1) | CN104031455B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104312234B (en) * | 2014-09-29 | 2016-03-23 | 滁州斯迈特复合材料有限公司 | Computer main board fire retardant |
| CN105348878A (en) * | 2015-12-11 | 2016-02-24 | 滁州斯迈特复合材料有限公司 | Water-proofing agent for water tower |
| CN108047787A (en) * | 2017-12-15 | 2018-05-18 | 芜湖华烨新材料有限公司 | A kind of fire retardant canvas |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101602682A (en) * | 2009-07-20 | 2009-12-16 | 北京化工大学 | Light-initiated/halogen-free flame retardants and its production and application |
| CN101818069A (en) * | 2010-04-02 | 2010-09-01 | 南京师范大学 | Method for preparing monophosphonate and biphosphonate mixed fire retardant |
| CN103772740A (en) * | 2014-01-16 | 2014-05-07 | 寿光卫东化工有限公司 | Phosphorus-containing flame retardant and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004224960A (en) * | 2003-01-24 | 2004-08-12 | Dainippon Ink & Chem Inc | Flame retardant paint composition and flame retardant base material having coating film of the composition |
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2014
- 2014-06-25 CN CN201410288977.8A patent/CN104031455B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101602682A (en) * | 2009-07-20 | 2009-12-16 | 北京化工大学 | Light-initiated/halogen-free flame retardants and its production and application |
| CN101818069A (en) * | 2010-04-02 | 2010-09-01 | 南京师范大学 | Method for preparing monophosphonate and biphosphonate mixed fire retardant |
| CN103772740A (en) * | 2014-01-16 | 2014-05-07 | 寿光卫东化工有限公司 | Phosphorus-containing flame retardant and preparation method thereof |
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| Publication number | Publication date |
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| CN104031455A (en) | 2014-09-10 |
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Address after: 239000 Weier Road, Zone C, Lai'an Industrial Park, Chuzhou City, Anhui Province Patentee after: Anhui smart new material Co.,Ltd. Address before: 239000 Weier Road, Zone C, Lai'an Industrial Park, Chuzhou City, Anhui Province Patentee before: Anhui simaite new materials Co.,Ltd. |
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Address after: 239000 Weier Road, Zone C, Lai'an Industrial Park, Chuzhou City, Anhui Province Patentee after: Anhui simaite new materials Co.,Ltd. Address before: 239000 Wei'Er Road, Zone C, industrial park, Lai'an county, Chuzhou City, Anhui Province Patentee before: CHUZHOU SMET COMPOUND MATERIALS Co.,Ltd. |
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| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Flame Retardant for Automotive Paint Effective date of registration: 20220901 Granted publication date: 20151111 Pledgee: Industrial and Commercial Bank of China Co.,Ltd. Lai'an Sub branch Pledgor: Anhui smart new material Co.,Ltd. Registration number: Y2022980014283 |
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| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Granted publication date: 20151111 Pledgee: Industrial and Commercial Bank of China Co.,Ltd. Lai'an Sub branch Pledgor: Anhui smart new material Co.,Ltd. Registration number: Y2022980014283 |