CN103985567B - 一种超级电容器电池 - Google Patents
一种超级电容器电池 Download PDFInfo
- Publication number
- CN103985567B CN103985567B CN201410206846.0A CN201410206846A CN103985567B CN 103985567 B CN103985567 B CN 103985567B CN 201410206846 A CN201410206846 A CN 201410206846A CN 103985567 B CN103985567 B CN 103985567B
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- Prior art keywords
- lithium
- electrolyte
- electrode
- titanium
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- 239000003792 electrolyte Substances 0.000 claims abstract description 90
- 229910001069 Ti alloy Inorganic materials 0.000 claims abstract description 46
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000010936 titanium Substances 0.000 claims abstract description 40
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 35
- 239000004734 Polyphenylene sulfide Substances 0.000 claims abstract description 32
- 229920000069 polyphenylene sulfide Polymers 0.000 claims abstract description 32
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 25
- 229910001386 lithium phosphate Inorganic materials 0.000 claims abstract description 24
- TWQULNDIKKJZPH-UHFFFAOYSA-K trilithium;phosphate Chemical compound [Li+].[Li+].[Li+].[O-]P([O-])([O-])=O TWQULNDIKKJZPH-UHFFFAOYSA-K 0.000 claims abstract description 24
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 claims abstract description 22
- 229910001486 lithium perchlorate Inorganic materials 0.000 claims abstract description 22
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 21
- GFLFKGYNEFFWTR-UHFFFAOYSA-N lithium;2-(methylamino)butanoic acid Chemical compound [Li].CCC(NC)C(O)=O GFLFKGYNEFFWTR-UHFFFAOYSA-N 0.000 claims abstract description 20
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 12
- 239000004020 conductor Substances 0.000 claims abstract description 9
- 239000000835 fiber Substances 0.000 claims abstract description 8
- 238000003466 welding Methods 0.000 claims abstract description 7
- 239000012528 membrane Substances 0.000 claims abstract description 5
- 239000010409 thin film Substances 0.000 claims abstract description 4
- 239000010408 film Substances 0.000 claims description 50
- 230000004888 barrier function Effects 0.000 claims description 45
- 239000003990 capacitor Substances 0.000 claims description 35
- 229920006269 PPS film Polymers 0.000 claims description 30
- 239000000843 powder Substances 0.000 claims description 26
- GLNWILHOFOBOFD-UHFFFAOYSA-N lithium sulfide Chemical class [Li+].[Li+].[S-2] GLNWILHOFOBOFD-UHFFFAOYSA-N 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 16
- 230000005611 electricity Effects 0.000 claims description 13
- 239000004033 plastic Substances 0.000 claims description 13
- 230000008569 process Effects 0.000 claims description 13
- 238000004804 winding Methods 0.000 claims description 6
- 230000008859 change Effects 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- RISRGKINPSVAJP-UHFFFAOYSA-N [Li].C(CCC)(=O)O Chemical compound [Li].C(CCC)(=O)O RISRGKINPSVAJP-UHFFFAOYSA-N 0.000 claims description 2
- 238000005538 encapsulation Methods 0.000 claims description 2
- 238000007731 hot pressing Methods 0.000 claims description 2
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 239000005864 Sulphur Substances 0.000 claims 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims 1
- LTYMSROWYAPPGB-UHFFFAOYSA-N diphenyl sulfide Chemical compound C=1C=CC=CC=1SC1=CC=CC=C1 LTYMSROWYAPPGB-UHFFFAOYSA-N 0.000 claims 1
- 230000000754 repressing effect Effects 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- 239000000243 solution Substances 0.000 abstract description 9
- 230000007797 corrosion Effects 0.000 abstract description 7
- 238000005260 corrosion Methods 0.000 abstract description 7
- 239000005022 packaging material Substances 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 238000001746 injection moulding Methods 0.000 abstract description 2
- 229920001021 polysulfide Polymers 0.000 abstract 1
- 239000005077 polysulfide Substances 0.000 abstract 1
- 150000008117 polysulfides Polymers 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 8
- 208000027418 Wounds and injury Diseases 0.000 description 7
- 239000002253 acid Substances 0.000 description 7
- 229910052782 aluminium Inorganic materials 0.000 description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- 230000018109 developmental process Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000011263 electroactive material Substances 0.000 description 4
- 239000007772 electrode material Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 230000005684 electric field Effects 0.000 description 3
- 230000036961 partial effect Effects 0.000 description 3
- -1 polypropylene Polymers 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000004146 energy storage Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 230000033116 oxidation-reduction process Effects 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 239000005030 aluminium foil Substances 0.000 description 1
- 230000009194 climbing Effects 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- XQHAGELNRSUUGU-UHFFFAOYSA-M lithium chlorate Chemical compound [Li+].[O-]Cl(=O)=O XQHAGELNRSUUGU-UHFFFAOYSA-M 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000128 polypyrrole Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010301 surface-oxidation reaction Methods 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- 238000004758 underpotential deposition Methods 0.000 description 1
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- Electric Double-Layer Capacitors Or The Like (AREA)
Abstract
Description
Claims (4)
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CN201410206846.0A CN103985567B (zh) | 2014-05-16 | 2014-05-16 | 一种超级电容器电池 |
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CN201410206846.0A CN103985567B (zh) | 2014-05-16 | 2014-05-16 | 一种超级电容器电池 |
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CN103985567A CN103985567A (zh) | 2014-08-13 |
CN103985567B true CN103985567B (zh) | 2017-05-10 |
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CN201410206846.0A Expired - Fee Related CN103985567B (zh) | 2014-05-16 | 2014-05-16 | 一种超级电容器电池 |
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Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106504908B (zh) * | 2015-09-07 | 2018-09-04 | 中国科学院大连化学物理研究所 | 一种锂硫混合超级电容器用自支撑电极及其制备和应用 |
CN112310557B (zh) * | 2020-11-03 | 2022-12-23 | 天津工业大学 | 一种基于粘流改性技术的聚苯硫醚基隔膜的制备方法 |
CN112606781B (zh) * | 2020-12-28 | 2023-03-31 | 卢浩义 | 电子控制型起动电池及其控制和应用方法 |
CN114783781B (zh) * | 2022-05-30 | 2023-07-21 | 武汉楚能电子有限公司 | 一种基于碳化硅单元层材料的混合超级电容器 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101113240A (zh) * | 2007-08-23 | 2008-01-30 | 深圳市科聚新材料有限公司 | 一种高导热聚苯硫醚复合材料及其制备方法 |
CN102637529A (zh) * | 2011-02-11 | 2012-08-15 | 张泽森 | 纳米碳化硅用于超级电容器电极材料 |
WO2013126490A1 (en) * | 2012-02-21 | 2013-08-29 | Arkema Inc. | Aqueous polyvinylidene fluoride composition |
CN103360767A (zh) * | 2013-06-24 | 2013-10-23 | 成都市永益泵业有限公司 | 一种基于聚苯硫醚和碳化硅复合材料、制备工艺及其用途 |
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2014
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101113240A (zh) * | 2007-08-23 | 2008-01-30 | 深圳市科聚新材料有限公司 | 一种高导热聚苯硫醚复合材料及其制备方法 |
CN102637529A (zh) * | 2011-02-11 | 2012-08-15 | 张泽森 | 纳米碳化硅用于超级电容器电极材料 |
WO2013126490A1 (en) * | 2012-02-21 | 2013-08-29 | Arkema Inc. | Aqueous polyvinylidene fluoride composition |
CN103360767A (zh) * | 2013-06-24 | 2013-10-23 | 成都市永益泵业有限公司 | 一种基于聚苯硫醚和碳化硅复合材料、制备工艺及其用途 |
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CN103985567A (zh) | 2014-08-13 |
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Effective date of registration: 20201112 Address after: No.99 Taizhou Road, Guangling District, Yangzhou City, Jiangsu Province Patentee after: Yangzhou Dongguan Investment Development Co.,Ltd. Address before: 610031 Sichuan Province, Chengdu City Street No. 2 Chengdu electronic high lift four floor apartment No. 1 Patentee before: Song Dayu |
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Effective date of registration: 20230420 Address after: D210-1, Block D, No. 43 Taizhou Road, Dongguan Street, Guangling District, Yangzhou City, Jiangsu Province, 225000 Patentee after: Yangzhou Rongkeran Technology Co.,Ltd. Address before: No.99 Taizhou Road, Guangling District, Yangzhou City, Jiangsu Province 225004 Patentee before: Yangzhou Dongguan Investment Development Co.,Ltd. |
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CF01 | Termination of patent right due to non-payment of annual fee | ||
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Granted publication date: 20170510 |