CN103981770B - A kind of gasoline filter filter paper and preparation method thereof - Google Patents

A kind of gasoline filter filter paper and preparation method thereof Download PDF

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CN103981770B
CN103981770B CN201410138688.XA CN201410138688A CN103981770B CN 103981770 B CN103981770 B CN 103981770B CN 201410138688 A CN201410138688 A CN 201410138688A CN 103981770 B CN103981770 B CN 103981770B
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agricultural crop
crop straw
modified
coupling agent
filter paper
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CN103981770A (en
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薛卉慧
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Anhui Fengyang Guofeng Ecological Technology Materials Co., Ltd.
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BENGBU FENGCHI FILTER CO LTD
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Abstract

The invention discloses a kind of gasoline filter filter paper and preparation method thereof, the weight portion of its constitutive material is: jute pulp 60 70, bamboo pulp fiber 35 45, polyester fiber 20 25, phenolic resin 10 15, charcoal powder 12 15, modified agricultural crop straw 13 15, Pulvis Talci 10 12, modified coupling agent 46, sodium polymethacrylate 13, antioxidant 1010 0.2 0.4, Nekal BX 78 24, ammonium chloride 13, sodium borate 0.5 1.5, sodium laurylsulfate 0.8 1.5 and chlorinated paraffin 24;The filter paper environmental protection science of the present invention, composition of raw materials is reasonable, each group partition inter-capacitive is good, the modified agricultural crop straw performance of the adsorbent of preparation is stable, has the absorbability of wide spectrum to Organic substance, and the modified coupling agent used can make to be formed between slurry to combine closely, filter paper material performance is made to be improved, viscosity is reduced, and every mechanical property is more preferable, has effects such as preferably drawing high intensity, elongation at break, shock strength.

Description

A kind of gasoline filter filter paper and preparation method thereof
Technical field
The present invention relates to a kind of gasoline filter filter paper and preparation method thereof, belong to automobile filter field.
Background technology
Cleaner is the important spare part of electromotor, it act as filtering the microgranules such as the dust entered in the air of electromotor, diesel oil, machine oil and mechanical admixture, to reduce Cylinder Liner Piston Ring in Engine, crankshaft link rod motion pair and the abrasion of high-pressure oil pump plunger matching parts, optimize the combustion process of electromotor, reduce the discharge of the organic pollutions such as carbon monoxide;Along with improving constantly of filtering requirement, any filter paper being made up of single fiber is all increasingly difficult to the requirement in satisfied use, so being arisen at the historic moment by the filter paper of multiple fiber combinations, during filter paper produces, conventional fiber has wood fibre, chemical fibre, glass fibre etc..
Summary of the invention
It is an object of the invention to provide a kind of gasoline filter filter paper and preparation method thereof,
The present invention adopts the following technical scheme that:
Gasoline filter filter paper, the weight portion of its constitutive material is: jute pulp 60-70, bamboo pulp fiber 35-45, polyester fiber 20-25, phenolic resin 10-15, charcoal powder 12-15, modified agricultural crop straw 13-15, Pulvis Talci 10-12, modified coupling agent 4-6, sodium polymethacrylate 1-3, antioxidant 1010 0.2-0.4, Nekal BX-78 2-4, ammonium chloride 1-3, sodium borate 0.5-1.5, sodium laurylsulfate 0.8-1.5 and chlorinated paraffin 2-4.
Gasoline filter filter paper, the weight portion of its constitutive material is: jute pulp 65, bamboo pulp fiber 40, polyester fiber 22, phenolic resin 12, charcoal powder 14, modified agricultural crop straw 14, Pulvis Talci 11, modified coupling agent 5, sodium polymethacrylate 2, antioxidant 1010 0.3, Nekal BX-78 3, ammonium chloride 2, sodium borate 1, sodium laurylsulfate 1.2 and chlorinated paraffin 3.
The preparation method of gasoline filter filter paper, comprises the following steps:
(1) preparation of modified coupling agent: MTMS is added in dehydrated alcohol, described MTMS and dehydrated alcohol are according to quality and volume ratio 1:3-5, it is subsequently adding the N of the polyacrylamide of the 1.0-2.0% of MTMS quality, 1.5-2.0%, N '-methylene-bisacrylamide and the N of 0.2-0.3%, N- Diisopropylethylamine;The temperature of reaction is 40-60 DEG C, and the time of described reaction is 10-12h, obtains reactant liquor;After reaction, reactant liquor is first disperseed 2-3 hour under the conditions of ultrasonic electric power 350W, disperse 3-5 hour under the conditions of ultrasonic electric power 250W the most again, the most available;
(2) preparation of modified agricultural crop straw:
A () weighs agricultural crop straw by constitutive material formula, grind, and the mass fraction adding 10-15 times amount is 5~10%NaOH solution, activates 3~5h, cross leaching filtering residue under the temperature conditions of 60~80 DEG C;
B () adds the pure water of 5-10 times amount in the filtering residue of step (a), then add the 0.6-0.7% Dodecyl trimethyl ammonium chloride of agricultural crop straw powder quality, 1.2-1.5% Silane coupling agent KH550 and 3-5% potassium permanganate;Stir reaction 2-3h, filters, dries;
C agricultural crop straw powder that step (b) is dried by () adds in the Hyperbranched Polymer with Terminal Amido solution that concentration is 40-50g/L;Described agricultural crop straw powder is 1:40-50 with quality and the volume ratio of Hyperbranched Polymer with Terminal Amido solution, it is subsequently adding 0.1-0.2% catalyst n, N-dimethyl butylamine, stirs hybrid reaction 10-12h, filter and clean 3-5 time with deionized water, obtain after lyophilization;
(3) mix bamboo pulp fiber, polyester fiber, phenolic resin and charcoal powder the most by weight, be then placed in pulper size degradation, obtain the slurry that solid content is 4-6%, add Nekal BX-78, stir and continue size degradation and obtain mixed slurry;
(4) adding in jute pulp by the mixed slurry of the modified coupling agent of step (1), the modified agricultural crop straw of step (2) and step (3), heated and stirred is uniform, controls temperature 50-70 DEG C;
(5) in the compound of step (4), add other residue constitutive materials, after fluffer is discongested, then defibrination, after defibrination, gained slurry is sized mixing through adding water, and according to conventional paper technology copy paper to solid content 3-5%, molding is squeezed, is drying to obtain.
Beneficial effects of the present invention:
The filter paper environmental protection science of the present invention, composition of raw materials is reasonable, each group partition inter-capacitive is good, the modified agricultural crop straw performance of the adsorbent of preparation is stable, has the absorbability of wide spectrum to Organic substance, and the modified coupling agent used can make to be formed between slurry to combine closely, filter paper material performance is made to be improved, viscosity is reduced, and every mechanical property is more preferable, has effects such as preferably drawing high intensity, elongation at break, shock strength.
Detailed description of the invention
Embodiment 1: gasoline filter filter paper, the weight portion (jin) of its constitutive material is: jute pulp 65, bamboo pulp fiber 40, polyester fiber 22, phenolic resin 12, charcoal powder 14, modified agricultural crop straw 14, Pulvis Talci 11, modified coupling agent 5, sodium polymethacrylate 2, antioxidant 1010 0.3, Nekal BX-78 3, ammonium chloride 2, sodium borate 1, sodium laurylsulfate 1.2 and chlorinated paraffin 3.
The preparation method of gasoline filter filter paper, comprises the following steps:
(1) preparation of modified coupling agent: MTMS is added in dehydrated alcohol, described MTMS and dehydrated alcohol are according to quality and volume ratio 1:4, be subsequently adding MTMS quality 1.5% polyacrylamide, the N of 1.8%, N '-methylene-bisacrylamide and the N of 0.25%, N- Diisopropylethylamine;The temperature of reaction is 50 DEG C, and the time of described reaction is 10-12h, obtains reactant liquor;After reaction, reactant liquor is first disperseed 2-3 hour under the conditions of ultrasonic electric power 350W, disperse 3-5 hour under the conditions of ultrasonic electric power 250W the most again, the most available;
(2) preparation of modified agricultural crop straw:
A () weighs agricultural crop straw by constitutive material formula, grind, and the mass fraction adding 12 times amount is 10%NaOH solution, activates 4h, cross leaching filtering residue under the temperature conditions of 70 DEG C;
B () adds the pure water of 5-10 times amount in the filtering residue of step (a), then add 0.65% Dodecyl trimethyl ammonium chloride of agricultural crop straw powder quality, 1.3% Silane coupling agent KH550 and 4% potassium permanganate;Stir reaction 2-3h, filters, dries;
C agricultural crop straw powder that step (b) is dried by () adds in the Hyperbranched Polymer with Terminal Amido solution that concentration is 45g/L;Described agricultural crop straw powder is 1:45 with quality and the volume ratio of Hyperbranched Polymer with Terminal Amido solution, is subsequently adding 0.15% catalyst n, N-dimethyl butylamine, stirs hybrid reaction 10-12h, filters and also cleans 3-5 time with deionized water, obtains after lyophilization;
(3) mix bamboo pulp fiber, polyester fiber, phenolic resin and charcoal powder the most by weight, be then placed in pulper size degradation, obtain the slurry that solid content is 5%, add Nekal BX-78, stir and continue size degradation and obtain mixed slurry;
(4) adding in jute pulp by the mixed slurry of the modified coupling agent of step (1), the modified agricultural crop straw of step (2) and step (3), heated and stirred is uniform, controls temperature 60 C;
(5) in the compound of step (4), add other residue constitutive materials, after fluffer is discongested, then defibrination, after defibrination, gained slurry is sized mixing through adding water, and according to conventional paper technology copy paper to solid content 4%, molding is squeezed, is drying to obtain.
The performance of filter paper that above-described embodiment prepares: grammes per square metre: 125g/cm2;Bursting strength: 310Kpa;Air permeability: 488ml/10cm2 min;Its maximum diameter of hole 48-54 μm, average pore size 34-38 μm, become paper air permeability at 80-85L/m2.S between.

Claims (2)

1. a gasoline filter filter paper, it is characterised in that the weight portion of its constitutive material is: jute pulp 60-70, bamboo pulp fiber 35-45, polyester fiber 20-25, phenolic resin 10-15, charcoal powder 12-15, modified agricultural crop straw 13-15, Pulvis Talci 10-12, modified coupling agent 4-6, sodium polymethacrylate 1-3, antioxidant 1010 0.2-0.4, Nekal BX-78 2-4, ammonium chloride 1-3, sodium borate 0.5-1.5, sodium laurylsulfate 0.8-1.5 and chlorinated paraffin 2-4;
The preparation method of described gasoline filter filter paper comprises the following steps:
(1) preparation of modified coupling agent: MTMS is added in dehydrated alcohol, described MTMS and dehydrated alcohol are according to quality and volume ratio 1:3-5, it is subsequently adding the N of the polyacrylamide of the 1.0-2.0% of MTMS quality, 1.5-2.0%, N '-methylene-bisacrylamide and the N of 0.2-0.3%, N-diisopropylethylamine;The temperature of reaction is 40-60 DEG C, and the time of described reaction is 10-12h, obtains reactant liquor;After reaction, reactant liquor is first disperseed 2-3 hour under the conditions of ultrasonic electric power 350W, disperse 3-5 hour under the conditions of ultrasonic electric power 250W the most again, the most available;
(2) preparation of modified agricultural crop straw:
A () weighs agricultural crop straw by constitutive material formula, grind, and the mass fraction adding 10-15 times amount is 5~10%NaOH solution, activates 3~5h, cross leaching filtering residue under the temperature conditions of 60~80 DEG C;
B () adds the pure water of 5-10 times amount in the filtering residue of step (a), then add the 0.6-0.7% Dodecyl trimethyl ammonium chloride of agricultural crop straw powder quality, 1.2-1.5% Silane coupling agent KH550 and 3-5% potassium permanganate;Stir reaction 2-3h, filters, dries;
C agricultural crop straw powder that step (b) is dried by () adds in the Hyperbranched Polymer with Terminal Amido solution that concentration is 40-50g/L;Described agricultural crop straw powder is 1:40-50 with quality and the volume ratio of Hyperbranched Polymer with Terminal Amido solution, it is subsequently adding 0.1-0.2% catalyst n, N-dimethyl butylamine, stirs hybrid reaction 10-12h, filter and clean 3-5 time with deionized water, obtain after lyophilization;
(3) mix bamboo pulp fiber, polyester fiber, phenolic resin and charcoal powder the most by weight, be then placed in pulper size degradation, obtain the slurry that solid content is 4-6%, add Nekal BX-78, stir and continue size degradation and obtain mixed slurry;
(4) adding in jute pulp by the mixed slurry of the modified coupling agent of step (1), the modified agricultural crop straw of step (2) and step (3), heated and stirred is uniform, controls temperature 50-70 DEG C;
(5) in the compound of step (4), add other residue constitutive materials, after fluffer is discongested, then defibrination, after defibrination, gained slurry is sized mixing through adding water, and according to conventional paper technology copy paper to solid content 3-5%, molding is squeezed, is drying to obtain.
Gasoline filter filter paper the most according to claim 1, it is characterised in that the weight portion of its constitutive material is: jute pulp 65, bamboo pulp fiber 40, polyester fiber 22, phenolic resin 12, charcoal powder 14, modified agricultural crop straw 14, Pulvis Talci 11, modified coupling agent 5, sodium polymethacrylate 2, antioxidant 1010 0.3, Nekal BX-78 3, ammonium chloride 2, sodium borate 1, sodium laurylsulfate 1.2 and chlorinated paraffin 3.
CN201410138688.XA 2014-04-09 2014-04-09 A kind of gasoline filter filter paper and preparation method thereof Active CN103981770B (en)

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CN105568769A (en) * 2016-02-25 2016-05-11 杭州特种纸业有限公司 Diesel filter paper and preparation method thereof
CN105735037A (en) * 2016-02-25 2016-07-06 杭州特种纸业有限公司 Thermosetting air filter paper and preparation method thereof
CN105937193A (en) * 2016-04-26 2016-09-14 杭州特种纸业有限公司 Nano engine and air filter paper and preparation method thereof
CN105951524A (en) * 2016-04-26 2016-09-21 杭州特种纸业有限公司 Nano machine oil filter paper and preparation method thereof
CN105926344A (en) * 2016-04-26 2016-09-07 杭州特种纸业有限公司 Nanometer quantitative filter paper and production method thereof
CN105780595A (en) * 2016-04-26 2016-07-20 杭州特种纸业有限公司 Nanometer air filter paper and preparation method thereof
CN109295797A (en) * 2018-09-26 2019-02-01 扬州市祥华新材料科技有限公司 A kind of preparation method for punching high tenacity paper
CN115300985B (en) * 2022-06-17 2023-11-24 华电电力科学研究院有限公司 Efficient acid removal regeneration treatment method for oil for power equipment
CN115726221B (en) * 2022-11-22 2023-07-21 杭州特种纸业有限公司 Medium-speed quantitative filter paper and preparation method thereof

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CN102877373A (en) * 2012-09-25 2013-01-16 蚌埠凤凰滤清器有限责任公司 Preparation method for modified nacrite-containing filter paper for fuel filter
CN102899970A (en) * 2012-09-25 2013-01-30 蚌埠凤凰滤清器有限责任公司 Preparation process of reed pulp filter paper

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CN1594731A (en) * 2003-09-10 2005-03-16 王家君 Fine fiber reinforced paper
CN102877368A (en) * 2012-09-20 2013-01-16 蚌埠凤凰滤清器有限责任公司 High temperature resistant flame retardant filter paper used for diesel filter and preparation method thereof
CN102877373A (en) * 2012-09-25 2013-01-16 蚌埠凤凰滤清器有限责任公司 Preparation method for modified nacrite-containing filter paper for fuel filter
CN102899970A (en) * 2012-09-25 2013-01-30 蚌埠凤凰滤清器有限责任公司 Preparation process of reed pulp filter paper

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Denomination of invention: A filter paper for gasoline filter and its preparation method

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