CN103977571B - A kind of plasticine of easy cleaning - Google Patents
A kind of plasticine of easy cleaning Download PDFInfo
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- CN103977571B CN103977571B CN201410221380.1A CN201410221380A CN103977571B CN 103977571 B CN103977571 B CN 103977571B CN 201410221380 A CN201410221380 A CN 201410221380A CN 103977571 B CN103977571 B CN 103977571B
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Abstract
The present invention relates to a kind of plasticine of easy cleaning, described plasticine is made up of the component of following weight percent: filler 15 ~ 75%, emulsifying agent 10 ~ 65%, oil phase 2 ~ 40%, surplus is water, and described plasticine can also comprise the additive that weight percentage is 0.2 ~ 2.5%.Containing a certain amount of emulsifying agent in instant component, not only the chemical substance effectively solved in plasticine can stick on skin, nail, hair and be difficult to the problems such as cleaning, but also there is good endurance, toughness high; Meanwhile, for dirty plasticine, the foul of its surface adhesion can be easy to be cleaned up.
Description
Technical field
The present invention relates to a kind of plasticine, especially relate to a kind of plasticine of easy cleaning.
Background technology
Plasticine is a kind of recreational stronger toy, can develop the imagination of children, cultivates manipulative ability and the creativity of children.Plasticine conventional at present mainly contains traditional oil-soluble plasticine, starch based plasticine and soft clay class plasticine, its main component is mud based on high score subclass material, wax class, ester class, starch, talcum powder etc., although these materials itself are nontoxic, but these materials are very easily attached on skin, nail, hair, and being difficult to cleaning, Long Term Contact easily produces excitant to skin.Therefore, the easy cleaning improving plasticine directly can improve the security of plasticine, the health of further child protection.
In addition, it is not good to there is toughness in current a lot of plasticine, and as plasticine glues hand, or quality is really up to the mark, feel is not good, and a lot of plasticine, after the use several months, also there will be dry and cracked, hardening phenomenon, all can affect the recreational of plasticine.
US Patent No. 6444728 provides a kind of use polyoxyethylene (PolyethyleneOxide, the scheme of hand degree is glued in plasticity when PEO) strengthening plasticine moulding and toughness, minimizing, and the plasticine of this scheme has tack-free, the plurality of advantages such as toughness is good, smooth surface, not yielding, good hand touch, workability are strong.But, described polyoxyethylene be a kind ofly relatively not easily to obtain, chemical material that cost is high.
Chinese patent CN101768314A discloses a kind of water-solubility plasticine composition and preparation method thereof, includes: polyvinyl alcohol, vinyl acetate resin, water, maltose, maltitol and particle diameter are the cenosphere of 5-100 μm.The toughness of plasticine is increased by adding macromolecular material polyvinyl alcohol (PVA), its cardinal principle is the texture utilizing the principle of macromolecular material molecular weight great Yi thickening to improve plasticine, but polyvinyl alcohol has certain spread effect to eyes and skin, and for the embedding plasticine being attached to the ground such as nail, hair, the shortcoming of difficult washing still can be there is.
Along with the development of household chemicals science, the shortcoming how solving not strong, the difficult washing of plasticine durability is current important topic.
Summary of the invention
In order to overcome the defect existed in prior art, the invention provides that a kind of good endurance, toughness are high, the plasticine of easy cleaning.
A plasticine for easy cleaning, described plasticine is made up of the component of following weight percent: filler 15 ~ 75%, emulsifying agent 10 ~ 65%, oil phase 2 ~ 40%, and surplus is water;
Described filler is one of the following or two or more any combination: diatomite, clay, talcum powder, starch, calcium carbonate;
Described emulsifying agent is one of the following or two or more any combination: methyl sodiosul foaliphatate, aliphatic acid, soap, tristerin, alkyl benzene sulphonate, sodium alkyl benzene sulfonate, sodium sulfate of polyethenoxy ether of fatty alcohol, aliphatic acid polyethenoxy ether ammonium sulfate, aliphatic acid polyethenoxy ether, lauryl sodium sulfate, lauric acid diethyl amide;
Described oil phase is one of the following or two or more any combination: olive oil, soybean oil, peanut oil, corn oil, SIMMONDSIA CHINENSIS SEED OIL, apricot kernel oil, grape-kernel oil, rose hip oil, apricot persic oil, wheat-germ oil, macadamia nut oil, Avocado Oil, fish oil, cocoa butter, shea butter, glycerine.
As preferably, described plasticine also comprises the additive that weight percentage is 0.2 ~ 2.5%, and described additive is one of the following or two or more any combination: pigment, anticorrisive agent, flavouring agent.
As preferably, described plasticine is made up of the component of following weight percent: filler 30 ~ 50%, emulsifying agent 20 ~ 45%, oil phase 5 ~ 30%, additive 1 ~ 2%, and surplus is water.
Generally, the addition of water is less than 10%, the mass dryness fraction making plasticine can keep suitable, is convenient to plasticine and carries out moulding.
As preferably, described pigment is one of following: beta carotene, carthamin yellow, lac color, cacao pigment, Tea Green Pigment, indigo arnotto, anticorrisive agent is propolis, shitosan or Tea Polyphenols, and flavouring agent is one of following: peach flavor, essence for organi juice, blackberry essence, strawberry essence, flavoring pineapple essence, flavoring apple essence, lychee flavor, mango essence, lemon extract.
As preferably, the weight percentage that described filler is added with emulsifying agent is 60 ~ 90%.
As preferably, add a certain amount of sodium sulphate or sodium chloride in described filler, the weight ratio of described sodium sulphate or sodium chloride and filler is 1:1.5 ~ 7.5.
As preferably, described filler comprises starch and talcum powder, and described starch and talcous weight ratio are 4.9 ~ 5.1:1.
As preferably, described filler comprises diatomite and clay, and the weight ratio of diatomite and clay is 4.8 ~ 5.1:1; Described emulsifying agent comprises methyl sodiosul foaliphatate and stearic acid, and described methyl sodiosul foaliphatate and stearic weight ratio are 8.7 ~ 9.1:1.
As preferably, described plasticine is made up of the component of following weight percent: starch 39.1%, talcum powder 7.8%, lauryl sodium sulfate 39.1%, olive oil 6.5%, beta carotene 0.52%, shitosan 0.26%, flavoring apple essence 0.26%, surplus are water.
As preferably, described plasticine is made up of the component of following weight percent: diatomite 29.9%, clay 6.0%, methyl sodiosul foaliphatate 26.9%, stearic acid 3.0%, soybean oil 24.0%, Tea Green Pigment 0.6%, propolis 0.6%, surplus are water.
Containing a certain amount of emulsifying agent in plasticine component of the present invention, the present invention can by the emulsifying ability of material internal emulsifying agent, play the effect of " self-emulsifying ", the material of the not easy cleaning namely in plasticine, as basic mud (filler, oil, water semi-finished product after certain technique) etc., can emulsified dose of attachment, be wrapped to form hydrophilic " particle ", be easy to be dissolved or dispersed in water after meeting water, be easy to cleaning.Plasticine of the present invention can not use other washing agent, and direct washing just can remove residual plasticine, and through contrasting with conventional clean mode, the present invention's washing is more thorough, and residual quantity is less, and more quick and easy.
In addition, the plasticine being playing dirty or surface adhesion are had to the plasticine of the fouls such as dust, the foul of its surface adhesion can be easy to be cleaned up.
Plasticine hot strength of the present invention is relatively higher, durability is better, this is mainly because the basestocks in traditional plasticine mostly is physical mixed, namely some solvents are added simply in basic mud, even can there is oil phase substance and aqueous phase substance in system simultaneously, plasticine as early stage mostly is wax and clay, for increasing its texture and pliability, a certain proportion of water and oil can be added, and wax and the affinity of clay to water poor, can not be scattered in aqueous phase completely equably, so in process, its mixing can be caused uneven, the water that plasticine in use exposes can therefore and volatilization run off, this causes plasticine long rear appearance service time dry and cracked, hardening key factor.And the present invention adopts " self-emulsifying " mode, emulsified dose of hydrone wraps up, and not easily scatters and disappears, and improves the durability of plasticine; Inconsistent oil/water two-phase reduces surface tension by emulsifying agent in addition, can more easily mix, and is conducive to the dispersed of each component of plasticine, improves the toughness of plasticine.
The present invention not only the chemical substance effectively solved in plasticine can stick on skin, nail, hair and is difficult to the problems such as cleaning, but also has good endurance, toughness high; Meanwhile, for dirty plasticine, the foul of its surface adhesion can be easy to be cleaned up.
Detailed description of the invention
Below in conjunction with specific embodiment, the invention will be further described, but protection scope of the present invention is not limited to this.
Embodiment 1
A kind of plasticine of easy cleaning, described plasticine is made up of the component of following weight percent: starch 39.1%, talcum powder 7.8%, lauryl sodium sulfate 39.1%, olive oil 6.5%, beta carotene 0.52%, shitosan 0.26%, flavoring apple essence 0.26%, surplus are water, fully stirs and can obtain plasticine.Gained plasticine performance indications are as shown in table 1:
Commercially available for difference plasticine sample and plasticine sample of the present invention are placed in climatic chamber, and control temperature is 25 DEG C, and humidity is 40%RH, carries out durability experiment, the results are shown in Table 1:
Table 1 durability test result
| Title | Test result |
| External import plasticine (water base) | To place after 10 days in the pasty state, moisture absorption phenomenon is obvious |
| Domestic plasticine I(is water base) | Place dry and cracked after 7 days, sclerosis |
| Domestic plasticine II(oil base) | Place dry and cracked after 21 days, sclerosis |
| Plasticine of the present invention | Place 21 days rear surfaces and occur a small amount of crackle, dry and cracked after 35 days, but unhardened |
According to the display of table 1 data, plasticine of the present invention performance in durability test is more excellent.
The inconsistent oil/water two-phase of the present invention reduces surface tension by emulsifying agent, more easily can mix, be conducive to the dispersed of each component of plasticine, improves the toughness of plasticine.
Commercially available for difference plasticine sample and plasticine sample of the present invention are done Mechanics Performance Testing, take 2 ~ 3g sample, make the pillars of long (2cm) × wide (0.5cm) × height (0.5cm), two ends are clamped gently with test clamp, carry out the test of hot strength and elongation at break with general-purpose mechanics tester, the results are shown in Table 2:
Table 2 hot strength and elongation at break test result
| Title | Hot strength (MPa) | Elongation at break (%) |
| External import plasticine (water base) | 3.42 | 264.23 |
| Domestic plasticine I(is water base) | 2.43 | 144.52 |
| Domestic plasticine II(oil base) | 2.74 | 262.41 |
| Plasticine of the present invention | 3.51 | 320.81 |
According to the display of table 2 data, plasticine of the present invention performance in the test of hot strength and elongation at break is more excellent.The present invention adopts " self-emulsifying " mode, and emulsified dose of hydrone wraps up, and not easily scatters and disappears, and improves the durability of plasticine, and the present invention's plasticine hot strength made of filling a prescription is relatively higher, and durability is better.
Plasticine of the present invention can not use other washing agent, and direct washing just can remove residual plasticine, and through contrasting with conventional clean mode, the present invention's washing is more thorough, and residual quantity is less, and more quick and easy; Meanwhile, other fouls cleaning the different part of health can also be used for, the object that object for appreciation limit, children limit reaches cleaning can be realized, in cleaning process, increase enjoyment; In addition, the plasticine of the fouls such as dust is had to be easy to clean for surface adhesion.
Embodiment 2
A kind of plasticine of easy cleaning, described plasticine is made up of the component of following weight percent: clay 29.9%, sodium sulphate 15%, methyl sodiosul foaliphatate 26.9%, olive oil 18%, indigo arnotto 0.6%, lemon extract 0.6%, surplus are water, can obtain plasticine after fully stirring.Gained plasticine performance indications are as shown in table 3:
Table 3
| Project | Index |
| Durability (my god) | ≥30 |
| Hot strength (MPa) | 3.45 |
| Elongation at break (%) | 303.62 |
According to table 3 data display, plasticine of the present invention in the test of durability, hot strength and elongation at break, show more excellent performance.
Embodiment 3
A kind of plasticine of easy cleaning, described plasticine is made up of the component of following weight percent: diatomite 29.9%, clay 6.0%, methyl sodiosul foaliphatate 26.9%, stearic acid 3.0%, soybean oil 24.0%, Tea Green Pigment 0.6%, propolis 0.6%, surplus are water, can obtain plasticine after fully stirring.Gained plasticine performance indications are as shown in table 4:
Table 4
| Project | Index |
| Durability (my god) | ≥30 |
| Hot strength (MPa) | 3.48 |
| Elongation at break (%) | 308.40 |
According to table 4 data display, plasticine of the present invention in the test of durability, hot strength and elongation at break, show more excellent performance.
Embodiment 4
A kind of plasticine of easy cleaning, described plasticine is made up of the component of following weight percent: diatomite 27.6%, starch 15%, sodium chloride 5.9%, sodium sulfate of polyethenoxy ether of fatty alcohol 32.3%, SIMMONDSIA CHINENSIS SEED OIL 6.2%, grape-kernel oil 5.8%, cacao pigment 0.6%, peach flavor 0.4%, Tea Polyphenols 0.4%, surplus are water, can obtain plasticine after fully stirring.Gained plasticine performance indications are as shown in table 5:
Table 5
| Project | Index |
| Durability (my god) | ≥30 |
| Hot strength (MPa) | 3.50 |
| Elongation at break (%) | 318.73 |
According to table 5 data display, plasticine of the present invention in the test of durability, hot strength and elongation at break, show more excellent performance.
Embodiment 5
A plasticine for easy cleaning, described plasticine is made up of the component of following weight percent: diatomite 31.8%, DBSA 23.6%, lauric acid diethyl amide 10.3%, Avocado Oil 16.2%, cocoa butter 10.8%, carthamin yellow 1.3%, surplus are water.Gained plasticine performance indications are as shown in table 6:
Table 6
| Project | Index |
| Durability (my god) | ≥30 |
| Hot strength (MPa) | 3.49 |
| Elongation at break (%) | 311.30 |
According to table 6 data display, plasticine of the present invention in the test of durability, hot strength and elongation at break, show more excellent performance.
Embodiment 6
A plasticine for easy cleaning, described plasticine is made up of the component of following weight percent: starch 44.5%, glycerin monostearate 32.8%, rose hip oil 25.1%, lac color 0.8%, flavoring pineapple essence 0.3%, surplus are water.Gained plasticine performance indications are as shown in table 7:
Table 7
| Project | Index |
| Durability (my god) | ≥30 |
| Hot strength (MPa) | 3.39 |
| Elongation at break (%) | 301.92 |
According to the display of table 7 data, plasticine of the present invention in the test of durability and elongation at break, show more excellent performance, and its hot strength is also and in no way inferior.
Embodiment 7
A plasticine for easy cleaning, described plasticine is made up of the component of following weight percent: diatomite 38.7%, starch 22.3%, calcium carbonate 12.5%, stearic acid polyoxyethylene ether 12.8%, macadamia nut oil 5.7%, β-Tea Green Pigment 0.3%, surplus are water.Gained plasticine performance indications are as shown in table 8:
Table 8
| Project | Index |
| Durability (my god) | ≥30 |
| Hot strength (MPa) | 2.98 |
| Elongation at break (%) | 297.32 |
According to the display of table 8 data, plasticine of the present invention in the test of durability and elongation at break, show more excellent performance.
Embodiment 8
A plasticine for easy cleaning, described plasticine is made up of the component of following weight percent: starch 19.8%, tristerin 58.7%, shea butter 8.3%, glycerine 5.9%, beta carotene 1.3%, shitosan 0.6%, surplus are water.Gained plasticine performance indications are as shown in table 9:
Table 9
| Project | Index |
| Durability (my god) | ≥30 |
| Hot strength (MPa) | 3.12 |
| Elongation at break (%) | 287.53 |
According to the display of table 9 data, plasticine of the present invention in the test of durability and elongation at break, show more excellent performance, and its hot strength is also and in no way inferior.
Embodiment 9
A plasticine for easy cleaning, described plasticine is made up of the component of following weight percent: clay 25.3%, talcum powder 19.6%, odium stearate 23.7%, neopelex 5.7%, SIMMONDSIA CHINENSIS SEED OIL 18.8%, carthamin yellow 0.4%, surplus are water.Gained plasticine performance indications are as shown in table 10:
Table 10
| Project | Index |
| Durability (my god) | ≥30 |
| Hot strength (MPa) | 3.50 |
| Elongation at break (%) | 305.77 |
Containing a certain amount of emulsifying agent in plasticine component of the present invention, can by the emulsifying ability of material internal emulsifying agent, play the effect of " self-emulsifying ", not only the chemical substance effectively solved in plasticine can stick on skin, nail, hair and be difficult to the problems such as cleaning, but also there is good endurance, toughness high; Meanwhile, for dirty plasticine, the foul of its surface adhesion can be easy to be cleaned up; Can also be used for other fouls cleaning the different part of health, can realize the object of object for appreciation limit, limit cleaning, especially children increase enjoyment in cleaning process.
Claims (10)
1. a plasticine for easy cleaning, is characterized in that: described plasticine is made up of the component of following weight percent: filler 15 ~ 75%, emulsifying agent 10 ~ 65%, oil phase 2 ~ 40%, and surplus is water;
Described filler is one of the following or two or more any combination: diatomite, clay, talcum powder, starch, calcium carbonate;
Described emulsifying agent is one of the following or two or more any combination: methyl sodiosul foaliphatate, aliphatic acid, soap, tristerin, alkyl benzene sulphonate, sodium alkyl benzene sulfonate, sodium sulfate of polyethenoxy ether of fatty alcohol, aliphatic acid polyethenoxy ether ammonium sulfate, aliphatic acid polyethenoxy ether, lauryl sodium sulfate, lauric acid diethyl amide;
Described oil phase is one of the following or two or more any combination: olive oil, soybean oil, peanut oil, corn oil, SIMMONDSIA CHINENSIS SEED OIL, apricot kernel oil, grape-kernel oil, rose hip oil, apricot persic oil, wheat-germ oil, macadamia nut oil, Avocado Oil, fish oil, cocoa butter, shea butter, glycerine.
2. the plasticine of easy cleaning according to claim 1, it is characterized in that: described plasticine also comprises the additive that weight percentage is 0.2 ~ 2.5%, described additive is one of the following or two or more any combination: pigment, anticorrisive agent, flavouring agent.
3. the plasticine of easy cleaning according to claim 2, is characterized in that: described plasticine is made up of the component of following weight percent: filler 30 ~ 50%, emulsifying agent 20 ~ 45%, oil phase 5 ~ 30%, additive 1 ~ 2%, and surplus is water.
4. the plasticine of easy cleaning according to claim 2, it is characterized in that: described pigment is one of following: beta carotene, carthamin yellow, lac color, cacao pigment, Tea Green Pigment, indigo arnotto, anticorrisive agent is propolis, shitosan or Tea Polyphenols, and flavouring agent is one of following: peach flavor, essence for organi juice, blackberry essence, strawberry essence, flavoring pineapple essence, flavoring apple essence, lychee flavor, mango essence, lemon extract.
5. the plasticine of the easy cleaning according to claim 1 or 3, is characterized in that: the weight percentage that described filler is added with emulsifying agent is 60 ~ 90%.
6. the plasticine of the easy cleaning according to claim 1 or 3, is characterized in that: add a certain amount of sodium sulphate or sodium chloride in described filler, and the weight ratio of described sodium sulphate or sodium chloride and filler is 1:1.5 ~ 7.5.
7. the plasticine of the easy cleaning according to claim 1 or 3, is characterized in that: described filler comprises starch and talcum powder, and described starch and talcous weight ratio are 4.9 ~ 5.1:1.
8. the plasticine of the easy cleaning according to claim 1 or 3, is characterized in that: described filler comprises diatomite and clay, and the weight ratio of diatomite and clay is 4.8 ~ 5.1:1; Described emulsifying agent comprises methyl sodiosul foaliphatate and stearic acid, and described methyl sodiosul foaliphatate and stearic weight ratio are 8.7 ~ 9.1:1.
9. the plasticine of easy cleaning according to claim 7, is characterized in that: described plasticine is made up of the component of following weight percent: starch 39.1%, talcum powder 7.8%, lauryl sodium sulfate 39.1%, olive oil 6.5%, beta carotene 0.52%, shitosan 0.26%, flavoring apple essence 0.26%, surplus are water.
10. the plasticine of easy cleaning according to claim 8, is characterized in that: described plasticine is made up of the component of following weight percent: diatomite 29.9%, clay 6.0%, methyl sodiosul foaliphatate 26.9%, stearic acid 3.0%, soybean oil 24.0%, Tea Green Pigment 0.6%, propolis 0.6%, surplus are water.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410221380.1A CN103977571B (en) | 2014-05-23 | 2014-05-23 | A kind of plasticine of easy cleaning |
| JP2015103437A JP2015223516A (en) | 2014-05-23 | 2015-05-21 | Plasticine capable of being cleaned easily |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410221380.1A CN103977571B (en) | 2014-05-23 | 2014-05-23 | A kind of plasticine of easy cleaning |
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| CN103977571A CN103977571A (en) | 2014-08-13 |
| CN103977571B true CN103977571B (en) | 2016-03-23 |
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| CN (1) | CN103977571B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104436695A (en) * | 2014-11-25 | 2015-03-25 | 张家港保税区冠祥贸易有限公司 | Silly putty and manufacturing method thereof |
| CN107325565A (en) * | 2016-08-28 | 2017-11-07 | 如皋长江科技产业有限公司 | A kind of plasticine capable of washing |
| CN108192151A (en) * | 2018-02-07 | 2018-06-22 | 陕西杨凌陕特农业发展有限公司 | A kind of plasticine prepared with bee honey residue and preparation method thereof |
| CN111167133A (en) * | 2020-01-08 | 2020-05-19 | 衢州贝蒙文教用品制造有限公司 | Boron-free clay and preparation method thereof |
| CN111393090A (en) * | 2020-04-24 | 2020-07-10 | 张澜馨 | Nontoxic crystal mud and preparation method thereof |
| CN112759302B (en) * | 2020-12-20 | 2022-10-28 | 湖北威霆汇彩科技有限公司 | Multifunctional chalk paste |
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| Publication number | Publication date |
|---|---|
| JP2015223516A (en) | 2015-12-14 |
| CN103977571A (en) | 2014-08-13 |
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