CN103952245A - Natural detergent and preparation method and application thereof - Google Patents
Natural detergent and preparation method and application thereof Download PDFInfo
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- CN103952245A CN103952245A CN201410168468.1A CN201410168468A CN103952245A CN 103952245 A CN103952245 A CN 103952245A CN 201410168468 A CN201410168468 A CN 201410168468A CN 103952245 A CN103952245 A CN 103952245A
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Abstract
The invention discloses a natural detergent and a preparation method and application thereof. The soapberry natural detergent comprises the following components in percentage by weight: 4%-8% soapberry extractives, 2%-5.5% of tea saponin, 1%-2.8% of glycerol, 2%-7.8% of sodium citrate, 1.2%-3.6% of sodium carbonate, 1.5%-3.6% of carboxymethyl cellulose and the balance of water. The soapberry natural detergent disclosed by the invention has the advantages of no stimulation, no toxicity, rapidness and thoroughness in biodegradation, environment protection, sustainable development and the like by adopting the soapberry and the tea saponin as main components; raw materials, namely the soapberry and the tea saponin are convenient and easy to obtain; the soapberry natural detergent is rich and exquisite in foam, has the effects of bacteria growth inhibition, disinfection and the like, achieves a submissive effect by being matched with the glycerol, is regulated in pH value by being matched with the sodium carbonate, further exerts the detersive synergistic effect of the soapberry extractives and the tea saponin, is outstandingly enhanced in detersive capacity and can be widely applied to oil stain washing or fabric washing.
Description
Technical field
The present invention relates to natural detergent technical field, is especially openly a kind of Seed of Chinese Soapberry natural detergent and its preparation method and application.
Background technology
Sanitising agent is the articles for washing forming with various tensio-active agents and multiple additive compound.Along with the enhancing of people to environment protection and individual autoprotection consciousness, take natural matter as basic Green Cleanser non-stimulated because having, nontoxic; Biological degradation rapidly, thoroughly; The advantages such as compatibility is good, Sustainable development, are subject to the welcome in market day by day, have a extensive future.
Seed of Chinese Soapberry is one of best natural washing raw material of cleaning capacity, and early stage Seed of Chinese Soapberry is widely used in clean decontamination.Patent CN102943008A discloses the clean facial soap of a kind of Seed of Chinese Soapberry, comprises Seed of Chinese Soapberry extraction liquid, sweet oil, tea oil, wheatgerm oil, essential oil, vitamin-E, lily extracting solution, witch hazel extracting solution, rose extracting solution, sodium soap.Patent CN102940603A discloses a kind of Seed of Chinese Soapberry bathing agents, comprises Seed of Chinese Soapberry extracting solution, sweet oil, milk, Semen Coicis extracting solution, essential oil, deionized water.Patent CN103122287A discloses the full nutrition handmade soap of a kind of Seed of Chinese Soapberry, the mass fraction of its component and each component is: 1.75 parts of Seed of Chinese Soapberry pancebrins, 1.5 parts, sweet oil, 2.5 parts of plam oils, 1 part of Oleum Cocois, 0.75 part, sodium hydroxide, also can add Seed of Chinese Soapberry shell powder 0.1-0.2 part or Seed of Chinese Soapberry medicinal extract 0.1-0.3 part.But the Seed of Chinese Soapberry sanitising agent of above-mentioned patent, its main component comprises the component that olive wet goods cost is comparatively expensive, and its cost of manufacture is higher, and the clean effect of Seed of Chinese Soapberry and other components does not have synergy, and whole clean effect need further raising.
Patent CN102559422A discloses a kind of sanitising agent containing Seed of Chinese Soapberry fruit or pulp, comprise sanitising agent and refining Seed of Chinese Soapberry fruit or the pulp of process, Seed of Chinese Soapberry fruit or pulp after refining: sanitising agent and refining after Seed of Chinese Soapberry fruit or the weight ratio of pulp be 0.5/30-3/30, Seed of Chinese Soapberry fruit after described refining or pulp refer to first Seed of Chinese Soapberry fruit are carried out to drying treatment, again by the Seed of Chinese Soapberry pulp of Seed of Chinese Soapberry fruit or removal kind of benevolence, with ethanolic soln or aqueous isopropanol, clean, or take out after immersing ethanolic soln or aqueous isopropanol, and make it dry.This Seed of Chinese Soapberry sanitising agent only utilizes natural Seed of Chinese Soapberry fruit or the not perishable characteristic of pulp, and the effect that sapindoside can constantly disengage during use, but its clean effect is mainly subject to the restriction of sanitising agent itself, whole clean effect still needs further to be improved.Patent CN103555437A discloses a kind of tea saponin washing composition, comprises by the component of following quality percentage composition: tea dregs of rice powder 50-70%; Tea saponin 15-20%; Seed of Chinese Soapberry fruit peel powder 10-20%; Plant perfume 3-5%; Described plant perfume is the dried powder of Flower of Japanese Camellia, sweet osmanthus or Flower of Arabian Jasmine.It uses tea dregs of rice powder, tea saponin and the Seed of Chinese Soapberry fruit peel powder of pure natural as the main component of washing composition, and its washing effect is fine, produces abundant foam during use, and the residue after washing greasy dirt is easily degraded.But effective decontamination composition of Seed of Chinese Soapberry exists with the form of Seed of Chinese Soapberry fruit peel powder, be difficult to bring into play effect completely within the short period of time of washing, the composite effect of failing to make full use of Seed of Chinese Soapberry, tea saponin is to significantly improve the ability of its decontamination.
Summary of the invention
The object of the present invention is to provide a kind of natural detergent, its adopt Seed of Chinese Soapberry extract and tea saponin composite, and be equipped with glycerine and play submissive effect, be equipped with sodium carbonate and regulate its pH value, further bring into play the synergistic effect of Seed of Chinese Soapberry extract and tea saponin decontamination.
Another object of the present invention is to provide a kind of natural detergent method of preparing, and it is main component that the method adopts low value natural product, and starting material are conveniently easy to get, and technological process is simple, and cost of manufacture is cheap, is applicable to industrialization and produces.
Another object of the present invention is to provide the application of a kind of natural detergent aspect decontamination.
The invention provides a kind of natural detergent, comprise the component of following weight percent: Seed of Chinese Soapberry extract 4-8wt%, tea saponin 2-5.5wt%, glycerine 1-2.8wt%, Trisodium Citrate 2-7.8wt%, sodium carbonate 1.2-3.6wt%, the water of carboxymethyl cellulose 1.5-3.6wt% and surplus.Wherein, natural phant Seed of Chinese Soapberry mainly originate in China Yangtze valley and on the south wide geographic area, wide material sources, the use of Chang Zuowei washing among the people; In Seed of Chinese Soapberry, contain abundant glucosides class material, be mainly triterpene saponin (I) and sesquiterpene glucosides class (II), they all have very strong surface-active action, are natural nonionic surface active agent.Tea saponin has another name called TS, is the class candy glucoside compound extracting in tea tree seed, is a kind of well behaved natural surface active agent, can be widely used in light industry, chemical industry.
Preferably, described natural detergent comprises the component of following weight percent: Seed of Chinese Soapberry extract 6-8wt%, tea saponin 3.5-5.5wt%, glycerine 1.5-2.8wt%, Trisodium Citrate 5-7.8wt%, sodium carbonate 2-3.6wt%, the water of carboxymethyl cellulose 1.5-3.6wt% and surplus.
Preferably, described Seed of Chinese Soapberry extract is that Seed of Chinese Soapberry fruit removes the ethanol extraction after seed.
Preferably, described tea saponin is the ethanol extraction of the residue after the oil expression of tea seed.
Preferably, for increasing the fragrant fragrance of sanitising agent, described natural detergent also comprises that weight percent is essence or the natural plant pefume of 0.05-0.2wt%.Wherein, essence is that it is a kind of synthetic flavour, has been widely used in manufacture food, makeup, articles for washing etc. by the imitation fruit of synthetic and the concentrated perfume oil of natural perfume smell.Preferably, described plant perfume is one or more in the dried powder of Flower of Japanese Camellia, sweet osmanthus or Flower of Arabian Jasmine.
The main component of Seed of Chinese Soapberry ethanol extraction has sapindoside (sapindussaponin), fatty oil, protein, is a kind of plant fruit juice that can be used for cleaning skin, fiber clothing, belongs to nonionic surface active agent.Seed of Chinese Soapberry triterpene saponin, having confirmed to act on human body skin has antibacterial, sterilization and anti-inflammatory effect; In addition, Seed of Chinese Soapberry contains the useful multivitamin of human body and amino acid, as: 10 multiple amino acids such as reducing sugar, lipid acid, grease, oleic acid, carotenoid, nicotinic acid, riboflavin, protein, vitamins C, vitamin A, vitamins B and Methionin, tyrosine, phenylalanine, L-glutamic acid, glycine and Histidine.The juice pH value of Seed of Chinese Soapberry, between 5-7, is nature acidity, and foam is abundant, and feel is fine and smooth, strong detergency.
The basal component of tea saponin by triterpenoid saponin, structure sugar, structure is sour forms, belong to nonionic surface active agent, can produce persistence foam, foaming power is not affected by water hardness, tea saponin and Seed of Chinese Soapberry extract are composite, for example, in the scope adapting in pH=5.7 left and right (pH is between 5.5 to 6), can significantly improve clean clean effect.
Glycerine, glycerol, as tenderizer and viscosity modifier, makes sanitising agent feel finer and smoother soft.Carboxymethyl cellulose, as sticky dose, forms the clear solution with certain viscosity.Trisodium Citrate, substitute traditional tripoly phosphate sodium STPP as the auxiliary agent of non-toxic detergent, it has safety non-toxic performance, have biological degradability, have complexing of metal ion ability, fabulous solubility property, especially, have good pH regulator and shock-absorbing capacity, cost is lower with respect to tripoly phosphate sodium STPP simultaneously.Sodium carbonate, itself has certain soil removability, the pH value of adjustable sanitising agent, and the decontamination synergistic effect after making Seed of Chinese Soapberry ethanol extraction and tea saponin composite is fully played, and significantly strengthens clean effect.
The present invention also provides a kind of method of preparing natural detergent, comprises the steps:
Step 1, prepares Seed of Chinese Soapberry ethanol extraction and tea saponin;
Step 2: add in the water of 50-60 ℃ after glycerine, Trisodium Citrate and sodium carbonate stirring and dissolving, add Seed of Chinese Soapberry ethanol extraction and tea saponin mix and blend, then add essence or spices mixes, make natural detergent; Wherein each weight percentages of components is: Seed of Chinese Soapberry extract 4-8wt%, tea saponin 2-5.5wt%, glycerine 1-2.8wt%, Trisodium Citrate 2-7.8wt%, sodium carbonate 1.2-3.6wt%, the water of carboxymethyl cellulose 2.5-3.6wt% and surplus.Aqueous temperature is controlled in the temperature range of 50-60 ℃, is convenient to the quick dissolving of Trisodium Citrate and sodium carbonate, and improves its meltage, be convenient to the pH value of maintenance cleaner system in suitable scope.
Preferably, wherein each weight percentages of components is: Seed of Chinese Soapberry extract 6-8wt%, tea saponin 3.5-5.5wt%, glycerine 1.5-2.8wt%, Trisodium Citrate 5-7.8wt%, sodium carbonate 2-3.6wt%, the water of carboxymethyl cellulose 1.5-3.6wt% and surplus.
Preferably, the step of preparing Seed of Chinese Soapberry ethanol extraction in described step 1 is: Seed of Chinese Soapberry fruit goes after seed, adopts alcohol steep and alcohol precipitation, filters, and evaporation concentration, makes Seed of Chinese Soapberry ethanol extraction.Preferably, Seed of Chinese Soapberry fruit goes after seed, adopts the alcohol steep of 50-70wt% repeatedly, then carries out alcohol precipitation with dehydrated alcohol, and standing rear filtration, by filtrate evaporation concentration, makes Seed of Chinese Soapberry ethanol extraction.
Preferably, the step of preparing tea saponin in described step 1 is: the residue after tea seed oil expression, add the ethanol of 70-85wt%, and supersound process, centrifugation, filters, underpressure distillation, crystallization, makes tea saponin.
The invention provides the application of a kind of natural detergent in greasy dirt washing or fabric washing.
Beneficial effect of the present invention has:
1, natural detergent employing Seed of Chinese Soapberry of the present invention and tea saponin are main component, it has non-stimulated, nontoxic, biological degradation rapidly, thoroughly, the advantage such as protection of the environment, Sustainable development, meanwhile, the raw material of Seed of Chinese Soapberry, tea saponin is conveniently easy to get, in addition, its foam is abundant fine and smooth, has the effects such as bacteria growing inhibiting, sterilization;
2, its to take Seed of Chinese Soapberry extract and tea saponin be main component, and be equipped with glycerine and play submissive effect, be equipped with sodium carbonate and regulate its pH value, further bring into play the synergistic effect of Seed of Chinese Soapberry extract and tea saponin decontamination, its soil removability significantly strengthens.
Below in conjunction with the drawings and specific embodiments, the present invention will be further described.
Accompanying drawing explanation
Fig. 1 is natural detergent preparation method's of the present invention schema.
Embodiment
By specific embodiments of the invention given below and comparing embodiment, can further be well understood to the present invention, but they not limitation of the invention.The part not describing in detail in specific embodiment and comparing embodiment is to adopt prior art, known technology means and industry standard to obtain.Except as otherwise noted, the percentage ratio adopting in the present invention is weight percentage.
embodiment 1
Incorporated by reference to the step shown in Fig. 1, by the component formula of table 1, prepare natural detergent:
(1) prepare Seed of Chinese Soapberry ethanol extraction:
Seed of Chinese Soapberry fruit washs with clear water, removes seed, and placement is dried, and adds 60% ethanol, after lixiviate 3 times, with dehydrated alcohol, carries out alcohol precipitation, and standing 24h filters.By filtrate evaporation concentration, obtain Seed of Chinese Soapberry ethanol extraction.
Wherein, Seed of Chinese Soapberry in Guangdong, there is plantation in Fujian, Guangxi, Jiangxi, Zhejiang more, productive rate is high, not only natural, soil removability is strong, and environment protection is had to certain effect.
(2) prepare tea saponin:
Utilize the rear remaining residue of tea seed oil expression, add 80% ethanol, with ultrasonic frequency 25kHz, process after 10-20min, centrifugation, filters, and removes impurity, and underpressure distillation, obtains saponin(e liquid, and crystallization makes tea saponin.
Wherein, China can reach more than 400 ten thousand tons by the grouts after the oil expression of tea seed every year, if can make full use of, from wherein extracting tea saponin, comprehensive utilization, can turn waste into wealth, and increases tea grower's income.
(3) prepare natural detergent:
In the distilled water of 50-60 ℃, add glycerine 1.5wt%, Trisodium Citrate 5wt%, sodium carbonate 2wt%, carboxymethyl cellulose 2.5wt%, after stirring and dissolving, adds Seed of Chinese Soapberry ethanol extraction 6wt%, tea saponin 3.5wt%, fully stirring, splashes into essence or spices 0.2wt% mixes, and makes natural detergent.
Wherein, sanitising agent employing tea saponin and Seed of Chinese Soapberry extract are composite, and add Trisodium Citrate and sodium carbonate, regulating its pH value is 5.7 left and right, and there is good pH shock-absorbing capacity, and make its composite generation work in coordination with synergistic effect, significantly improve cleaning effect, and can produce persistence foam, foaming power is not affected by water hardness.
embodiment 2
The implementation process of this embodiment is identical with embodiment 1, and the adjustment of its formula refers to table 1.
embodiment 3
The implementation process of this embodiment is identical with embodiment 1, and the adjustment of its formula refers to table 1.
comparative example 1
A tea saponin washing composition, comprises the tea dregs of rice powder 60%, tea saponin 18%, Seed of Chinese Soapberry fruit peel powder 19%, the plant perfume powder 3% that by quality percentage composition, form, and plant perfume is Flower of Japanese Camellia powder.The preparation method of described tea saponin washing composition:
Step 01: the tea dregs of rice of group component and Seed of Chinese Soapberry pericarp are ground into respectively to 200 object fine powders;
Step 02: tea dregs of rice powder and Seed of Chinese Soapberry fruit peel powder after step 01 is pulverized mix, then add the tea saponin powder of group component, are uniformly mixed 5 minutes;
Step 03: be added into plant perfume powder in the powder making in step 02, be uniformly mixed.
The preparation method of described Seed of Chinese Soapberry fruit peel powder is as follows:
Step 101: by the Seed of Chinese Soapberry pericarp after fresh winning, fruit stone separation, by the Impurity removal in separated Seed of Chinese Soapberry pericarp, cleaning up post-drying to water ratio is 20%,
Step 102: the Seed of Chinese Soapberry pericarp after post-drying is placed in vacuum chamber, and be set as-0.07Mpa of vacuum tightness in case, passes into steam heating, and vapor pressure is 0.4Mpa, and steam heating time is 20 minutes;
Step 103: the Seed of Chinese Soapberry pericarp after steam heating is carried out to vacuum dehydrating at lower temperature at 40 ℃ of temperature, and dry rear water ratio is 5%.
comparative example 2
The implementation process of this comparative example is identical with embodiment 1, and the adjustment of formula rate refers to table 1.
comparative example 3
The implementation process of this comparative example is identical with embodiment 1, and the adjustment of formula rate refers to table 1.
comparative example 4
The process of this comparative example is substantially the same manner as Example 1, and the adjustment of formula rate refers to table 1.
Table 1 formula
| Component | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 2 | Comparative example 3 | Comparative example 4 |
| Seed of Chinese Soapberry extract | 6％ | 4％ | 8％ | 6％ | - | 6％ |
| Tea saponin | 3.5％ | 5.5％ | 2％ | - | 3.5％ | 3.5％ |
| Glycerine | 1.5％ | 1％ | 2.8％ | 1.5％ | 1.5％ | 1.5％ |
| Trisodium Citrate | 5％ | 2％ | 7.8％ | 5％ | 5％ | 1％ |
| Sodium carbonate | 2％ | 3.6％ | 1.2％ | 2％ | 2％ | - |
| Carboxymethyl cellulose | 2.5％ | 1.5％ | 3.6％ | 2.5％ | 2.5％ | 2.5％ |
| Essence | 0.2％ | 0.05％ | - | 0.2％ | 0.15％ | 0.2％ |
| Water | 79.3％ | 82.35％ | 74.6％ | 82.8％ | 85.35％ | 85.3％ |
The evaluation of table 2 clean effect
| ? | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 | Embodiment 4 |
| Foaming power | 160mm | 165mm | 160mm | 150mm | 90mm | 50mm | 80mm |
| Dishwashing detergent | Effective | Effective | Effective | Effect is better | Effect is general | Effect is general | Effect is better |
| Fabric washing | Effective | Effective | Effective | Effect is better | Effect is general | Effect is general | Effect is better |
Table 2 has provided the decontamination effect evaluation result of the sanitising agent that embodiment 1 to 3 and comparative example 1 to 4 make; Wherein, the test of foaming power is carried out by national standard GT/T13173.6-91.Therefrom can find out, adopt adopt Seed of Chinese Soapberry extract and tea saponin composite, and be equipped with glycerine and play submissive effect, be equipped with sodium carbonate and regulate its pH value in suitable scope, its foaming power and clean effect are significantly strengthened.
application Example 1
The natural detergent that embodiment 1 is made is applied to the greasy dirt washing of restaurant tableware, and its foaming effect is good, and clean effect is good, does not hinder hand.
application Example 2
The natural detergent that embodiment 3 is made is applied to the washing of the work clothes of garage man, and its foaming effect is good, and clean effect is good, does not hinder hand.
Above disclosed is only the preferred embodiments of the present invention, certainly can not limit with this interest field of the present invention, and the equivalent variations of therefore doing according to the present patent application the scope of the claims, still belongs to the scope that the present invention is contained.
Claims (10)
1. a natural detergent, is characterized in that: the component that comprises following weight percent: Seed of Chinese Soapberry extract 4-8wt%, tea saponin 2-5.5wt%, glycerine 1-2.8wt%, Trisodium Citrate 2-7.8wt%, sodium carbonate 1.2-3.6wt%, the water of carboxymethyl cellulose 1.5-3.6wt% and surplus.
2. natural detergent according to claim 1, it is characterized in that: the component that comprises following weight percent: Seed of Chinese Soapberry extract 6-8wt%, tea saponin 3.5-5.5wt%, glycerine 1.5-2.8wt%, Trisodium Citrate 5-7.8wt%, sodium carbonate 2-3.6wt%, the water of carboxymethyl cellulose 1.5-3.6wt% and surplus.
3. natural detergent according to claim 1 and 2, is characterized in that: Seed of Chinese Soapberry extract is that Seed of Chinese Soapberry fruit removes the ethanol extraction after seed.
4. natural detergent according to claim 1 and 2, is characterized in that: described tea saponin is the ethanol extraction of the residue after the oil expression of tea seed.
5. according to the natural detergent described in claim 3 or 4, it is characterized in that: also comprise that weight percent is essence or the natural plant pefume of 0.05-0.2wt%.
6. a method of preparing natural detergent, is characterized in that: comprise the steps:
Step 1, prepares Seed of Chinese Soapberry ethanol extraction and tea saponin;
Step 2: add in the water of 50-60 ℃ after glycerine, Trisodium Citrate and sodium carbonate stirring and dissolving, add Seed of Chinese Soapberry ethanol extraction and tea saponin mix and blend, then add essence or spices mixes, make natural detergent; Wherein each weight percentages of components is: Seed of Chinese Soapberry extract 4-8wt%, tea saponin 2-5.5wt%, glycerine 1-2.8wt%, Trisodium Citrate 2-7.8wt%, sodium carbonate 1.2-3.6wt%, the water of carboxymethyl cellulose 2.5-3.6wt% and surplus.
7. method according to claim 6, is characterized in that: the step of preparing Seed of Chinese Soapberry ethanol extraction in described step 1 is: Seed of Chinese Soapberry fruit goes after seed, adopts alcohol steep and alcohol precipitation, filters, and evaporation concentration, makes Seed of Chinese Soapberry ethanol extraction.
8. method according to claim 7, is characterized in that: Seed of Chinese Soapberry fruit goes after seed, adopts the alcohol steep of 50-70wt% repeatedly, then carries out alcohol precipitation with dehydrated alcohol, and standing rear filtration, by filtrate evaporation concentration, makes Seed of Chinese Soapberry ethanol extraction.
9. method according to claim 6, is characterized in that: the step of preparing tea saponin in described step 1 is: the residue after the oil expression of tea seed, add the ethanol of 70-85wt%, and supersound process, centrifugation, filters, underpressure distillation, crystallization, makes tea saponin.
10. the application being in the suds according to the natural detergent described in any one in claim 1 to 5.
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| CN106085611A (en) * | 2016-06-03 | 2016-11-09 | 潘星辑 | A kind of cleaning agent containing tea saponin and preparation method thereof |
| CN106010807A (en) * | 2016-06-08 | 2016-10-12 | 宋介珍 | Multienzyme cleaning compound for stubborn stains on medical instrument |
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| CN112877148A (en) * | 2021-01-19 | 2021-06-01 | 北京圣永制药有限公司 | Bacteriostatic laundry detergent containing natural plant components |
| CN113493725A (en) * | 2021-06-21 | 2021-10-12 | 广东菁萃生物科技有限公司 | Mild non-irritating nursing handmade soap and preparation method thereof |
| CN113493724A (en) * | 2021-06-22 | 2021-10-12 | 广东菁萃生物科技有限公司 | Efficient decontamination laundry detergent and preparation method thereof |
| CN113493724B (en) * | 2021-06-22 | 2023-05-09 | 广东菁萃生物科技有限公司 | Efficient decontamination laundry detergent and preparation method thereof |
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Application publication date: 20140730 |