CN103937268A - Rubber gasket containing nano mica powder - Google Patents

Rubber gasket containing nano mica powder Download PDF

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Publication number
CN103937268A
CN103937268A CN201410197908.6A CN201410197908A CN103937268A CN 103937268 A CN103937268 A CN 103937268A CN 201410197908 A CN201410197908 A CN 201410197908A CN 103937268 A CN103937268 A CN 103937268A
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CN
China
Prior art keywords
parts
mica powder
nano mica
rubber
rubber gasket
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410197908.6A
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Chinese (zh)
Inventor
凌巧
钱胜利
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI MENGLING PRECISION ELECTRONIC Co Ltd
Original Assignee
ANHUI MENGLING PRECISION ELECTRONIC Co Ltd
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Publication date
Application filed by ANHUI MENGLING PRECISION ELECTRONIC Co Ltd filed Critical ANHUI MENGLING PRECISION ELECTRONIC Co Ltd
Priority to CN201410197908.6A priority Critical patent/CN103937268A/en
Publication of CN103937268A publication Critical patent/CN103937268A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a rubber gasket containing nano mica powder. The rubber gasket is prepared from the following raw materials in parts by weight: 80-120 parts of methyl vinyl silicone rubber, 20-30 parts of ethylene-propylene-diene monomer, 2.2-2.5 parts of hexafluorobisphenol A, 1.5-1.8 parts of benzyltriphenylphosphonium chloride, 7-9 parts of toluene diisocyanate, 6-8 parts of dicumyl peroxide, 8-10 parts of nano mica powder, 5-8 parts of nano bentonite, 8-12 parts of polyamide wax micropowder, 12-15 parts of fast extruding furnace black N660, 3-5 parts of paraffin oil, 2.2-2.4 parts of sulfur, 6-8 parts of zinc oxide, 3-4 parts of stearic acid, 1.5-2.5 parts of siloxane and 5-7 parts of modified tree ash. The rubber gasket has excellent overall performances such as wear resistance, high-temperature resistance, acid-base resistance, corrosion resistance, radiation resistance and the like, simultaneously has self-lubricating performance and impermeability, excellent insulating performance, good impact elasticity and long service life and is widely applied to various electronic and electrical devices.

Description

A kind of rubber sheet gasket that contains nano mica powder
Technical field
The present invention relates to gasket materials field, relate in particular to a kind of rubber sheet gasket that contains nano mica powder.
Background technology
Pad is two mechanical seals between object, because machining surface can not be perfect, uses packing ring can fill up irregularity.Pad is normally made by flaky material, as rubber, metal, cork, felt, glass fibre or plastic polymer etc.Along with scientific and technological development, pad is more and more extensive, meanwhile, also more and more higher to the performance requriements of pad for the application on electron device, such as shockproof, waterproof, ventilative, corrosion-resistant, weather-resistant, resistance to elevated temperatures.But use at present the over-all propertieies such as work-ing life of pad prepared by single-material and durability, high thermal resistance, weatherability to be difficult to reach requirement, some pads need often to change and detect, and to production, have brought inconvenience.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, a kind of rubber sheet gasket that contains nano mica powder is provided, material prescription is reasonable, there is the over-all propertieies such as excellent wear resistance, high temperature resistant, acid and alkali-resistance, corrosion-resistant, radiation hardness, insulating property are good, and shock elasticity is good, long service life.
The present invention adopts following technical scheme to achieve these goals:
A kind of rubber sheet gasket that contains nano mica powder, it is to be made by the raw material of following weight parts: methyl vinyl silicone rubber 80-120 part, terpolymer EP rubber 20-30 part, hexafluoro bisphenol-a 2.2-2.5 part, BPP 1.5-1.8 part, toluene di-iso-cyanide ester 7-9 part, oxidation diisopropylbenzene(DIPB) 6-8 part, nano mica powder 8-10 part, nano-bentonite 5-8 part, polyamide wax micropowder 8-12 part, fast extrusion carbon black N66012-15 part, paraffin oil 3-5 part, sulphur 2.2-2.4 part, zinc oxide 6-8 part, stearic acid 3-4 part, siloxanes 1.5-2.5 part, modification trees ashes 5-7 part.
Described modification trees ashes are prepared by following methods: the hydrochloric acid soln that is first 8-10% by trees ashes by concentration soaked after 5 hours, with deionized water wash, to neutral, dry; Then in the trees ashes of drying, add be equivalent to its weight 5-6% nano-sized carbon, 2-3% 2,4, the aluminium hydroxide of the tributyl citrate of 6-trisphenol, 1-2%, the ferrocene of 1-2%, 3-5%, under 5300-5500 rev/min, stir after 40 minutes, after ovendry power is broken into and crosses 100 mesh sieves after powder and get final product.
The described rubber sheet gasket that contains nano mica powder, preparation method is: Fluoride for Raw Material rubber and polyvinyl chloride, curing Dibenzo thiazole, bismaleimides, two Lauryl Alcohol ester are mixed, add melting 1-2 hour in smelting furnace, temperature is controlled at 180-220 ℃, add again surplus stock mix and blend, mixing 2-3 hour at 120-150 ℃, last compression moulding, is cut into finished product.
Compared with the prior art, beneficial effect of the present invention is as follows:
Rubber sheet gasket of the present invention is by adding nano mica powder and modification trees ashes, elasticity and toughness, heat resistance, acid-proof alkaline and the corrosion resistance nature of material have effectively been increased, material prescription of the present invention is reasonable, there is the over-all propertieies such as excellent wear resistance, high temperature resistant, acid and alkali-resistance, corrosion-resistant, radiation hardness, have self lubricity and gas tightness, insulating property are good simultaneously, and shock elasticity is good, long service life, can be widely used in various electronic electric equipments.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment:
A rubber sheet gasket that contains nano mica powder, it is to be made by the raw material of following weight parts: 100 parts of methyl vinyl silicone rubbers, 30 parts of terpolymer EP rubbers, 2.5 parts of hexafluoro bisphenol-as, 1.6 parts of BPP, 8 parts of toluene di-iso-cyanide esters, 7 parts of diisopropylbenzene(DIPB)s of oxidation, 10 parts, nano mica powder, 7 parts of nano-bentonites, 10 parts of polyamide wax micropowders, extrude carbon black N66013 part, 4 parts of paraffin oils, 2.3 parts, sulphur, 7 parts, zinc oxide, 4 parts of stearic acid, 2 parts of siloxanes, 6 parts, modification trees ashes soon.
Wherein, described modification trees ashes are prepared by following methods: the hydrochloric acid soln that is first 10% by trees ashes by concentration soaked after 5 hours, with deionized water wash, to neutral, dry; Then in the trees ashes of drying, add be equivalent to its weight 6% nano-sized carbon, 2% 2,4,6-trisphenol, 2% tributyl citrate, 2% ferrocene, 3% aluminium hydroxide stirred after 40 minutes under 5500 revs/min, after ovendry power is broken into and crosses 100 mesh sieves after powder and get final product.
The described rubber sheet gasket that contains nano mica powder, preparation method is: Fluoride for Raw Material rubber and polyvinyl chloride, curing Dibenzo thiazole, bismaleimides, two Lauryl Alcohol ester are mixed, add the interior melting of smelting furnace 2 hours, temperature is controlled at 200 ℃, add again surplus stock mix and blend, at 150 ℃ mixing 3 hours, last compression moulding, was cut into finished product.
The salient features of the rubber sheet gasket that the present embodiment prepares is as following table:

Claims (3)

1. a rubber sheet gasket that contains nano mica powder, it is characterized in that: it is to be made by the raw material of following weight parts: methyl vinyl silicone rubber 80-120 part, terpolymer EP rubber 20-30 part, hexafluoro bisphenol-a 2.2-2.5 part, BPP 1.5-1.8 part, toluene di-iso-cyanide ester 7-9 part, oxidation diisopropylbenzene(DIPB) 6-8 part, nano mica powder 8-10 part, nano-bentonite 5-8 part, polyamide wax micropowder 8-12 part, fast extrusion carbon black N66012-15 part, paraffin oil 3-5 part, sulphur 2.2-2.4 part, zinc oxide 6-8 part, stearic acid 3-4 part, siloxanes 1.5-2.5 part, modification trees ashes 5-7 part.
2. the rubber sheet gasket that contains nano mica powder according to claim 1, it is characterized in that: described modification trees ashes are prepared by following methods: the hydrochloric acid soln that is first 8-10% by trees ashes by concentration soaked after 5 hours, with deionized water wash, to neutral, dry; Then in the trees ashes of drying, add be equivalent to its weight 5-6% nano-sized carbon, 2-3% 2,4, the aluminium hydroxide of the tributyl citrate of 6-trisphenol, 1-2%, the ferrocene of 1-2%, 3-5%, under 5300-5500 rev/min, stir after 40 minutes, after ovendry power is broken into and crosses 100 mesh sieves after powder and get final product.
3. the rubber sheet gasket that contains nano mica powder according to claim 1, it is characterized in that: preparation method is: Fluoride for Raw Material rubber and polyvinyl chloride, curing Dibenzo thiazole, bismaleimides, two Lauryl Alcohol ester are mixed, add melting 1-2 hour in smelting furnace, temperature is controlled at 180-220 ℃, add again surplus stock mix and blend, mixing 2-3 hour at 120-150 ℃, last compression moulding, is cut into finished product.
CN201410197908.6A 2014-05-12 2014-05-12 Rubber gasket containing nano mica powder Pending CN103937268A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410197908.6A CN103937268A (en) 2014-05-12 2014-05-12 Rubber gasket containing nano mica powder

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410197908.6A CN103937268A (en) 2014-05-12 2014-05-12 Rubber gasket containing nano mica powder

Publications (1)

Publication Number Publication Date
CN103937268A true CN103937268A (en) 2014-07-23

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106349710A (en) * 2016-08-30 2017-01-25 宁波通冠电气自动化设备有限公司 Insulated seal ring material for anti-aging respirator and preparation method thereof
CN107142807A (en) * 2015-08-11 2017-09-08 孙欣 A kind of low temperature resistant fast spreading road
CN108219230A (en) * 2018-01-04 2018-06-29 无锡宝通科技股份有限公司 A kind of thermal resistance and acid-alkali resistance conveyer belt coating rubber and preparation method thereof
CN110483839A (en) * 2019-07-15 2019-11-22 安徽伊法拉电力科技有限公司 A kind of temperature resistant silicon rubber cable attachment is with modified micaceous and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0456557A1 (en) * 1990-05-07 1991-11-13 Shin-Etsu Chemical Co., Ltd. Foamable silicone rubber composition
CN102952477A (en) * 2012-10-27 2013-03-06 蚌埠凤凰滤清器有限责任公司 Filter adhesive film containing nano barite powder
CN103509217A (en) * 2013-09-05 2014-01-15 安徽省科林电子有限公司 High-resilience transformer sealing gasket and preparation method thereof
CN103613933A (en) * 2013-10-28 2014-03-05 青岛嘉利福环保科技有限公司 High temperature resistant fluorinated silicone rubber pad

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0456557A1 (en) * 1990-05-07 1991-11-13 Shin-Etsu Chemical Co., Ltd. Foamable silicone rubber composition
CN102952477A (en) * 2012-10-27 2013-03-06 蚌埠凤凰滤清器有限责任公司 Filter adhesive film containing nano barite powder
CN103509217A (en) * 2013-09-05 2014-01-15 安徽省科林电子有限公司 High-resilience transformer sealing gasket and preparation method thereof
CN103613933A (en) * 2013-10-28 2014-03-05 青岛嘉利福环保科技有限公司 High temperature resistant fluorinated silicone rubber pad

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107142807A (en) * 2015-08-11 2017-09-08 孙欣 A kind of low temperature resistant fast spreading road
CN106349710A (en) * 2016-08-30 2017-01-25 宁波通冠电气自动化设备有限公司 Insulated seal ring material for anti-aging respirator and preparation method thereof
CN108219230A (en) * 2018-01-04 2018-06-29 无锡宝通科技股份有限公司 A kind of thermal resistance and acid-alkali resistance conveyer belt coating rubber and preparation method thereof
CN110483839A (en) * 2019-07-15 2019-11-22 安徽伊法拉电力科技有限公司 A kind of temperature resistant silicon rubber cable attachment is with modified micaceous and preparation method thereof

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Application publication date: 20140723