CN103937216A - Shell powder modified polyphenyl ether material for auto plastic parts - Google Patents
Shell powder modified polyphenyl ether material for auto plastic parts Download PDFInfo
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- CN103937216A CN103937216A CN201410156942.9A CN201410156942A CN103937216A CN 103937216 A CN103937216 A CN 103937216A CN 201410156942 A CN201410156942 A CN 201410156942A CN 103937216 A CN103937216 A CN 103937216A
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- parts
- polyphenyl ether
- powder
- oyster shell
- plastic parts
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Abstract
The invention belongs to the field of a high polymer material, and particularly relates to a shell powder modified polyphenyl ether material for auto plastic parts. The material is prepared from the following raw materials in parts by weight: 100 parts of polyphenyl ether, 10-12 parts of shell powder, 3-5 parts of seaweed gel, 12-16 parts of zinc borate, 2-4 parts of basic magnesium carbonate, 1-2 parts of anti-aging agent MB, 1-3 parts of vinyl tri(beta-methoxyethoxy) silane, 1.8-2.5 parts of silane coupling agent KH550, 2-3 parts of feldspar powder, 5-7 parts of itaconate, 3-4 parts of zinc stearate and 12-15 parts of assistant. The polyphenyl ether is modified by using the raw materials such as the shell powder, zinc borate, the feldspar powder and the like, so that the material has good processing performance and mechanical performance, and the prepared material is firm and wearable, high-temperature ageing resistant, environment-friendly and flame retardant, impact resistant, long in service life, safe and reliable, and can be widely applied to fabrication of various auto plastic parts.
Description
Technical field
The invention belongs to polymeric material field, be specifically related to a kind of automotive plastic parts oyster shell whiting modified polyphenyl ether material and preparation method thereof.
Background technology
Polyphenylene oxide (PPO) is one of five large-engineering plastics, has excellent physical and mechanical properties, thermotolerance and electrical apparatus insulation, and its water absorbability is low, creep resistance is excellent.Be widely used in the fields such as automobile component.PPO is Non-crystallizable polymer, and its melt viscosity is very large, and mobility is very poor, and the words of not modification cannot be used owing to not processing substantially.
In order to improve the performance of polyphenylene oxide (PPO) material, widen materials'use scope, need to improve polyphenylene oxide (PPO) material prescription, material is carried out to modification, can be widely used in each position of automobile.
Summary of the invention
The object of the invention is to, a kind of automotive plastic parts oyster shell whiting modified polyphenyl ether material is provided, promoted the performance of traditional polyphenyl ether material, make it possess good mechanical property, can adapt to specific environment for use, to achieve these goals, the technical solution used in the present invention is as follows:
A kind of automotive plastic parts oyster shell whiting modified polyphenyl ether material, it is characterized in that, material of the present invention is made up of the raw material of following weight part: polyphenylene oxide 100, oyster shell whiting 10-12, seaweed gel 3-5, zinc borate 12-16, magnesium basic carbonate 2-4, antioxidant MB 1-2, vinyl three ('beta '-methoxy oxyethyl group) silane 1-3, Silane coupling agent KH550 1.8-2.5, feldspar in powder 2-3, itaconic ester 5-7, Zinic stearas 3-4, auxiliary agent 12-15.
Described auxiliary agent is made up of the raw material of following weight part: clay 300-320, limestone powder 3-4, jade powder 20-24, tri (propylene glycol) diacrylate 3-4, ZrO
21-2, SnO
21-2, B
2o
35-7, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2-3, aluminium hydroxide 8-10, Syzygium aromaticum stem oil 1-2, polyisobutene 1-2; Preparation method puts into calcining furnace by clay to calcine 3-4 hour at 710-740 DEG C, cooling, puts into 10-12% hydrochloric acid soln and soaks 1-2 hour, filter and take out, clean and dry with clear water, be ground into 200-400 order powder, mix with other remaining component, grinding distribution is even, to obtain final product.
Described a kind of automotive plastic parts oyster shell whiting modified polyphenyl ether material, its preparation method is: polyphenylene oxide, oyster shell whiting, itaconic ester, Zinic stearas are mixed, be heated to 250-280 DEG C, to polyphenylene oxide melting, stir 5-8 minute, add again seaweed gel, zinc borate, magnesium basic carbonate, antioxidant MB, vinyl three ('beta '-methoxy oxyethyl group) silane, stir 4-5 minute, finally add other remaining component, stir after 5-8 minute, send into extruding pelletization in twin screw extruder, to obtain final product.
The present invention utilizes the raw material polyphenylene ether such as oyster shell whiting, zinc borate, feldspar in powder to carry out modification, make it have good processing characteristics and mechanical property, the material of preparation is firm wear-resisting, heat resistant, environmental protection flame retardant, shock-resistant, long service life, can meet specific environment for use condition, market application foreground is wide.
Embodiment
Embodiment
The present embodiment material is made up of the raw material of following weight part: polyphenylene oxide 100, oyster shell whiting 12, seaweed gel 5, zinc borate 16, magnesium basic carbonate 4, antioxidant MB 2, vinyl three ('beta '-methoxy oxyethyl group) silane 3, Silane coupling agent KH550 2.3, feldspar in powder 3, itaconic ester 7, Zinic stearas 4, auxiliary agent 15.Described polyphenylene oxide is selected the polyphenylene oxide resin of viscosity within the scope of 0.35 ~ 0.65Pas.
Described auxiliary agent is made up of the raw material of following weight part: clay 300, limestone powder 4, jade powder 20, tri (propylene glycol) diacrylate 3, ZrO
22, SnO
21, B
2o
35, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 3, aluminium hydroxide 8, Syzygium aromaticum stem oil 2, polyisobutene 2; Preparation method puts into calcining furnace by clay at 740 DEG C, to calcine 4 hours, cooling, puts into 12% hydrochloric acid soln and soaks 2 hours, filters and takes out, and cleans and dries with clear water, is ground into 400 order powder, mixes with other remaining component, and grinding distribution is even, to obtain final product.
Described a kind of automotive plastic parts oyster shell whiting modified polyphenyl ether material, its preparation method is: polyphenylene oxide, oyster shell whiting, itaconic ester, Zinic stearas are mixed, be heated to 260 DEG C, to polyphenylene oxide melting, stir 8 minutes, add again seaweed gel, zinc borate, magnesium basic carbonate, antioxidant MB, vinyl three ('beta '-methoxy oxyethyl group) silane, stir 5 minutes, finally add other remaining component, stir after 8 minutes, send into extruding pelletization in twin screw extruder, to obtain final product.
The performance of material of the present invention: melt flow index is 15-19.3g/10min at 280 DEG C, notched Izod impact strength is 10.1-13.2kJ/m2, tensile strength is 72.1-79.3MPa, flexural strength 138.0-147.9MPa, modulus in flexure is 2665.3-2851.7MPa, and heat-drawn wire is 122.2-127.6 DEG C.
Claims (2)
1. an automotive plastic parts oyster shell whiting modified polyphenyl ether material, it is characterized in that, this material is made up of the raw material of following weight part: polyphenylene oxide 100, oyster shell whiting 10-12, seaweed gel 3-5, zinc borate 12-16, magnesium basic carbonate 2-4, antioxidant MB 1-2, vinyl three ('beta '-methoxy oxyethyl group) silane 1-3, Silane coupling agent KH550 1.8-2.5, feldspar in powder 2-3, itaconic ester 5-7, Zinic stearas 3-4, auxiliary agent 12-15;
Described auxiliary agent is made up of the raw material of following weight part: clay 300-320, limestone powder 3-4, jade powder 20-24, tri (propylene glycol) diacrylate 3-4, ZrO
21-2, SnO
21-2, B
2o
35-7, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2-3, aluminium hydroxide 8-10, Syzygium aromaticum stem oil 1-2, polyisobutene 1-2; Preparation method puts into calcining furnace by clay to calcine 3-4 hour at 710-740 DEG C, cooling, puts into 10-12% hydrochloric acid soln and soaks 1-2 hour, filter and take out, clean and dry with clear water, be ground into 200-400 order powder, mix with other remaining component, grinding distribution is even, to obtain final product.
2. a kind of automotive plastic parts oyster shell whiting modified polyphenyl ether material as claimed in claim 1, its manufacture craft is: polyphenylene oxide, oyster shell whiting, itaconic ester, Zinic stearas are mixed, be heated to 250-280 DEG C, to polyphenylene oxide melting, stir 5-8 minute, add again seaweed gel, zinc borate, magnesium basic carbonate, antioxidant MB, vinyl three ('beta '-methoxy oxyethyl group) silane, stir 4-5 minute, finally add other remaining component, stir after 5-8 minute, send into extruding pelletization in twin screw extruder, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410156942.9A CN103937216A (en) | 2014-04-18 | 2014-04-18 | Shell powder modified polyphenyl ether material for auto plastic parts |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410156942.9A CN103937216A (en) | 2014-04-18 | 2014-04-18 | Shell powder modified polyphenyl ether material for auto plastic parts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103937216A true CN103937216A (en) | 2014-07-23 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410156942.9A Pending CN103937216A (en) | 2014-04-18 | 2014-04-18 | Shell powder modified polyphenyl ether material for auto plastic parts |
Country Status (1)
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104479240A (en) * | 2014-11-07 | 2015-04-01 | 安徽省三乐门窗幕墙工程有限公司 | Door-window plastic-steel section material added with shell powder and preparation method thereof |
| CN106189068A (en) * | 2016-07-07 | 2016-12-07 | 绵阳高新区三阳塑胶有限责任公司 | A kind of preparation method of flame retardant plastics |
Citations (5)
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|---|---|---|---|---|
| CN1605601A (en) * | 2003-12-05 | 2005-04-13 | 吴全德 | High efficiency polyphenylether composition and its application |
| CN102796362A (en) * | 2011-05-24 | 2012-11-28 | 比亚迪股份有限公司 | Polyphenylether material and preparation method thereof |
| CN103289352A (en) * | 2012-02-24 | 2013-09-11 | 青岛海信电器股份有限公司 | Highlight antiflaming polyphenyl ether alloy material and television front shell comprising same |
| CN103642223A (en) * | 2013-11-18 | 2014-03-19 | 安徽宜万丰电器有限公司 | Anti-ultraviolet ageing-resistant modified nylon 66 material for automobile plastic members |
| CN103665841A (en) * | 2013-11-18 | 2014-03-26 | 安徽宜万丰电器有限公司 | Antistatic waterproof modified nylon 12 material for automobile plastic part |
-
2014
- 2014-04-18 CN CN201410156942.9A patent/CN103937216A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1605601A (en) * | 2003-12-05 | 2005-04-13 | 吴全德 | High efficiency polyphenylether composition and its application |
| CN102796362A (en) * | 2011-05-24 | 2012-11-28 | 比亚迪股份有限公司 | Polyphenylether material and preparation method thereof |
| CN103289352A (en) * | 2012-02-24 | 2013-09-11 | 青岛海信电器股份有限公司 | Highlight antiflaming polyphenyl ether alloy material and television front shell comprising same |
| CN103642223A (en) * | 2013-11-18 | 2014-03-19 | 安徽宜万丰电器有限公司 | Anti-ultraviolet ageing-resistant modified nylon 66 material for automobile plastic members |
| CN103665841A (en) * | 2013-11-18 | 2014-03-26 | 安徽宜万丰电器有限公司 | Antistatic waterproof modified nylon 12 material for automobile plastic part |
Non-Patent Citations (1)
| Title |
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| 齐贵亮: "《塑料压延成型实用技术》", 31 May 2013, article "填充剂", pages: 52-59 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104479240A (en) * | 2014-11-07 | 2015-04-01 | 安徽省三乐门窗幕墙工程有限公司 | Door-window plastic-steel section material added with shell powder and preparation method thereof |
| CN104479240B (en) * | 2014-11-07 | 2016-03-30 | 安徽省三乐门窗幕墙工程有限公司 | A kind of plastic-steel door window section bar adding oyster shell whiting and preparation method thereof |
| CN106189068A (en) * | 2016-07-07 | 2016-12-07 | 绵阳高新区三阳塑胶有限责任公司 | A kind of preparation method of flame retardant plastics |
| CN106189068B (en) * | 2016-07-07 | 2017-02-08 | 绵阳高新区三阳塑胶有限责任公司 | Flame-retardant plastic preparation method |
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Application publication date: 20140723 |