CN103930270A - 叠层式窗玻璃的冷弯 - Google Patents

叠层式窗玻璃的冷弯 Download PDF

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Publication number
CN103930270A
CN103930270A CN201280056794.2A CN201280056794A CN103930270A CN 103930270 A CN103930270 A CN 103930270A CN 201280056794 A CN201280056794 A CN 201280056794A CN 103930270 A CN103930270 A CN 103930270A
Authority
CN
China
Prior art keywords
panel
technique
interlayer
glass
glass pane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201280056794.2A
Other languages
English (en)
Inventor
F.勒瓦瑟尔
R.德库尔塞勒
C.斯维德斯基
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saint Gobain Glass France SAS
Compagnie de Saint Gobain SA
Original Assignee
Saint Gobain Glass France SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saint Gobain Glass France SAS filed Critical Saint Gobain Glass France SAS
Publication of CN103930270A publication Critical patent/CN103930270A/zh
Pending legal-status Critical Current

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Classifications

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    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10036Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
    • B32B17/10045Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets with at least one intermediate layer consisting of a glass sheet
    • B32B17/10055Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets with at least one intermediate layer consisting of a glass sheet with at least one intermediate air space
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B23/00Re-forming shaped glass
    • C03B23/02Re-forming glass sheets
    • C03B23/023Re-forming glass sheets by bending
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23PMETAL-WORKING NOT OTHERWISE PROVIDED FOR; COMBINED OPERATIONS; UNIVERSAL MACHINE TOOLS
    • B23P11/00Connecting or disconnecting metal parts or objects by metal-working techniques not otherwise provided for 
    • B23P11/02Connecting or disconnecting metal parts or objects by metal-working techniques not otherwise provided for  by first expanding and then shrinking or vice versa, e.g. by using pressure fluids; by making force fits
    • B23P11/025Connecting or disconnecting metal parts or objects by metal-working techniques not otherwise provided for  by first expanding and then shrinking or vice versa, e.g. by using pressure fluids; by making force fits by using heat or cold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C53/00Shaping by bending, folding, twisting, straightening or flattening; Apparatus therefor
    • B29C53/02Bending or folding
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    • B32B17/10165Functional features of the laminated safety glass or glazing
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    • Y10T29/49826Assembling or joining
    • Y10T29/49863Assembling or joining with prestressing of part
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Abstract

本发明涉及用于制备弯曲的窗玻璃模块的工艺,该模块包括金属构架和面板,面板包括叠层式窗玻璃,叠层式窗玻璃包括由聚合材料制成的夹层分开的玻璃基材,在叠层式窗玻璃已经组装好之后通过力弯曲所述面板,该力使所述面板获得金属构架的形状,且然后通过保持器件使所述面板保持该形状,在夹层处于30℃至80℃之间的温度下时执行所述弯曲。本发明减小了弯曲所需的力,以及由聚合材料制成的夹层与玻璃基材之间的剪切应力,这降低了脱层的风险。

Description

叠层式窗玻璃的冷弯
技术领域
本发明涉及一种用于包括叠层式窗玻璃的面板的冷弯的工艺。
背景技术
叠层式窗玻璃包括由聚合材料制成的夹层分开的若干玻璃基材。如果由以下类型的一层或多层适当覆盖,则玻璃基材包括单个无机玻璃片材:抗反射、日光防护、抗磨损等。
平的叠层式窗玻璃的制备得到良好控制。弯曲的窗玻璃的制备问题更大,且随着给予的曲率增大而更成问题。如果曲率很高,则可能需要在玻璃为软的时(大体上大于500℃)对玻璃片材进行预先的热弯。如果窗玻璃的曲率不是很大,则能够构想出在其制造结束之后的冷弯。表述"冷弯"大体上意味着小于200℃,在该温度下,玻璃不是软的。
EP 282 468教导了包括经回火玻璃基材的叠层式窗玻璃的80℃至140℃之间的弯曲。80℃至140℃之间的加热用于软化叠层式窗玻璃的夹层PVB。
现在已经发现,高于80℃的冷弯导致由聚合材料制成的夹层的不可接受的老化,这由细气泡(但气泡肉眼可见)的形成反映,且此外,有利的是可能在30℃至80℃之间执行冷弯,以减小弯曲所需的负载,且还减小由聚合材料制成的夹层与玻璃基材之间的剪切应力,且因此减小脱层的风险。
发明内容
本发明涉及一种用于在30℃至80℃之间弯曲包括叠层式窗玻璃的面板的工艺。高于40℃的温度是特别令人满意的。低于75℃的温度一般是适合的。40℃至75℃之间的温度范围特别适合。为了执行该工艺,实际上,首先加热平的面板直到夹层达到建议的温度范围(弯曲温度),且然后弯曲面板。作为优选,面板加热到高于由聚合材料制成的夹层的玻璃态转化温度。玻璃态转化温度由利用运动学测定的粘性分析来确定。加热到高于玻璃态转化温度的事实有益于弯曲期间聚合材料的蠕变,这具有的结果在于,在所述材料与玻璃基材之间的界面处的永久的剪切应力减小。由聚合材料制成的夹层具体可为聚乙烯醇缩丁醛(称为"PVB")、乙烯/醋酸乙烯酯或离聚物树脂膜,具体是由DuPont销售的SentryGlas。对于离聚物树脂的情况,优选的是将面板加热到大于45℃。
面板的冷弯导致面板的叠层式窗玻璃的冷弯。面板可包括除叠层式窗玻璃之外的另一个构件,如,平行于叠层式窗玻璃的片材。具体而言,面板可为叠层式窗玻璃自身。
为了将面板加热至30℃至80℃之间,能够通过使加热元件(例如,如,加热毯)与面板并列来很容易地操作。具体可使用由Vulcanic出售的加热毯。能够利用加热元件简单地覆盖面板,直到获得期望的温度,且进行弯曲。能够在弯曲其间使加热元件与面板并列。能够由加热元件来开始面板的加热,同时执行刚刚已经加热的另一个面板的弯曲。当然,本领域的技术人员知道随着窗玻璃的性质及其大小(主面和厚度)的变化如何找出关于各个操作的加热、持续时间和速率状况,以便优化该过程。
根据本发明的工艺适用于包括叠层式窗玻璃的面板的冷弯。具体而言,存在于面板中的所有玻璃片材可为经回火的。本发明特别适用于由叠层式窗玻璃构成的面板的冷弯,该窗玻璃包括由聚合材料制成的夹层分开的两个经回火玻璃片材。
具体而言,本发明特别用于制备必须配合到其窗玻璃必须看起来是弯曲的建筑物上的窗玻璃。这些建筑物(特别是由商业街区的高耸建筑物构成的类型)可具有特别大胆的形状,且可需要制备具有一定形状的弯曲面板,对于同一个建筑物,该形状可一个与另一个不同。
因此,本发明涉及用于制备弯曲的窗玻璃模块的工艺,该模块包括金属构架和面板,面板包括叠层式窗玻璃,窗玻璃包括由聚合材料制成的夹层分开的玻璃基材,在叠层式窗玻璃已经组装好之后通过力弯曲面板,该力使面板获得金属构架的形状,且然后通过保持器件使面板保持该形状,在夹层处于30℃至80℃之间的温度下时执行弯曲。
模块制造成包括包含叠层式窗玻璃的面板,以及能够保持冷弯面板的形状且因此用作模具的金属构架。该金属构架大体上由钢或挤制铝制成。为此,可具体通过将其置于加热毯上来将面板预热至30℃至80℃,然后使其与金属构架接触,且在一个或多个点处对面板施加力,以便使其获得构架的形状。例如,施加的力的范围可为每个接触点高达200kg。可使用系杆、液压千斤顶、配重或机器人以便执行面板的这样变形。根据待保持的曲率半径,通过保持器件如夹具,或通过粘合剂来使面板在构架上保持形状。当然,如果涉及粘合剂连结,则在除去面板施加到构架上的力之前需要等待一些时间来使粘合剂良好设置(通过聚合、交联等)。例如,适合的结构粘合剂为由Dow Corning在标号DC 3362下出售的硅树脂类型。如果待保持的曲率很高,则使用夹具可能很重要。借助于本发明,其自身的弯曲操作(开始变形与面板的变形结束之间)可较快,具体是在10到120秒之间。
在构成面板的玻璃片材中生成不可接受的应力时,不可执行面板的"冷"变形。因此,建筑行业中的未经回火的玻璃的允许的最大永久应力为10MPa。建筑行业中的经回火的玻璃的允许的最大永久应力为40MPa。根据在面板上给予的曲率,因此可能有利的是使用组装在叠层式窗玻璃中的经回火玻璃片材。
具体而言,面板可沿两个不同的方向同时地弯曲(扭曲玻璃)。
本发明所涉及的面板可较大,因为它们可具有面积为大约3m2,且甚至大约4m2,且甚至大于5m2的主面。应当注意的是,面板(以及片材或窗玻璃)包括两个主面和边缘。
在弯曲期间建议不超过使用中的窗玻璃的最大可接受应力。已经发现,限制弯曲的幅度的最关键的因素为由聚合材料制成的夹层和与其并列的玻璃基材之间的界面处的剪切应力。作为优选,弯曲叠层式窗玻璃,使得在20℃下该应力小于3MPa,且优选为小于2MPa,且更优选为小于1.5MPa。根据本发明,当聚合材料制成的夹层加热到大约30℃时,在弯曲期间经历的界面处的剪切应力比在环境温度下降时在使用中可经历的剪切应力低得多。这是为何在执行弯曲之前建议通过常规测试来确定预期弯曲在20℃下是否不会超过由聚合材料制成的夹层与玻璃基材之间的界面处的剪切应力。该专家评定可由也形成本发明的主题的方法很简单地执行。根据该方法,可通过在叠层式窗玻璃的主面中的一个上使偏振膜与叠层式窗玻璃并列来显示这些剪切应力。在将该偏振膜定位在叠层式窗玻璃的样品上之后,通过在一侧上拉动一个玻璃基材且在另一侧上拉动另一个玻璃基材来执行抗拉测试。应力的出现由透射的色泽反映。色泽随应力的强度变化。因此,其足以指出颜色视情况对应于允许的最大应力(3MPa或2MPa或1.5MPa或1MPa或其它)。这样校准可仅利用仅一个偏振膜与叠层式窗玻璃的主面并列来执行。在此情况下,色泽应当以大约45°的观察角来观察(窗玻璃的法线与观察方向之间的角)。还能够将膜置于叠层式窗玻璃的各个主面上,在此情况下,可以以任何观察角来显示应力。在执行校准之后(对于由聚合材料制成的夹层和所述夹层的给定厚度),可容易地在窗玻璃的生产中,通过将偏振膜附连到窗玻璃的主面上或附连两个偏振膜(在窗玻璃的各个主面上各一个)而确认未超过最大剪切应力。因此,本发明还涉及一种工艺,根据该工艺,在根据本发明弯曲夹层且使夹层回到20℃的温度之后,通过将偏振膜施加到面板的主面上且然后显示透射通过面板和膜的颜色来评估由聚合材料制成的夹层和与其并列的位于聚合材料的任一侧上的玻璃基材之间的界面处的剪切应力的状态。该颜色随后可与预先执行的校准的颜色相比较,以便评估由聚合材料制成的夹层与所述玻璃基底之间的界面的剪切应力,且根据该比较的结果,确定模块是否符合规格,即是说,验证或弃置模块。
附图说明
图1呈现了使得能够将变形施加到窗玻璃上且测量经历的应力的装置。
图2呈现了随由图1中的装置施加到窗玻璃上的偏转变化的在两种温度情况(20℃和70℃)中测量的力的绝对值的和。
图3示出了在施加变形的两种温度情况(20℃和70℃)中的力的绝对值的和随时间的变化。 
具体实施方式
经回火的叠层式窗玻璃通过组合2个经回火的整体窗玻璃来制成,各个窗玻璃处于120Mpa的表皮的压缩下,各个窗玻璃均具有1938×876×8 mm的大小,具有4个PVB夹层(PVB厚度为4乘0.38mm)。窗玻璃随后经历如图1中呈现的变形。窗玻璃1的固定宽度2和固定长度3得到保持,且通过方向向下的垂直向量对如图1中呈现的未保持固定的侧部施加位移。这在使组装好的窗玻璃在一种情况下到达20℃的温度而在另一种情况下到达70℃的温度之后执行。置于施加位移的系杆下方的力传感器4使得能够测量施加在窗玻璃的外周的不同点处的力。在一些点处,力为张力,而在其它点处,力为压缩力,以便合力为零。因此,由窗玻璃承受的负载通过对力的绝对值求和来评定。图2呈现了在两个温度情况下测量且随偏转变化的力的绝对值的和。可以看到的是,在70℃下加热使得能够将负载减小大约30%。图3示出了随时间变化的力的绝对值的和的变化,已经知道,对于预热至70℃的测试,窗玻璃立即放回到20℃下的环境空气中。已经根据时间显示70℃至20℃之间的窗玻璃的温度下降。看到的是,如果在20℃下窗玻璃变形与在70℃下变形且回到20℃相比较,则在预热至70℃的情况下合力保持很低,保持了30%的节省且甚至得到改善。在预热至70℃的情况下,夹层因此在老化方面更好,分层的趋势更小,且变白的趋势更小。

Claims (14)

1. 一种用于制备弯曲的窗玻璃模块的工艺,所述窗玻璃模块包括金属构架和面板,所述面板包括叠层式窗玻璃,所述叠层式窗玻璃包括由聚合材料制成的夹层分开的玻璃基材,在所述叠层式窗玻璃已经组装好之后通过力弯曲所述面板,所述力使所述面板获得所述金属构架的形状,且然后通过保持器件使所述面板保持此形状,其特征在于,在所述夹层处于30℃至80℃之间的温度下时执行所述弯曲。
2. 根据前述权利要求所述的工艺,其特征在于,在夹层处于大于40℃的温度下时执行所述弯曲。
3. 根据前述权利要求中任一项所述的工艺,其特征在于,在所述夹层处于小于75℃的温度下时执行所述弯曲。
4. 根据前述权利要求中任一项所述的工艺,其特征在于,所述夹层在所述弯曲期间处于大于其玻璃态转化温度的温度下。
5. 根据前述权利要求中任一项所述的工艺,其特征在于,所述夹层为PVB。
6. 根据前述权利要求中任一项所述的工艺,其特征在于,至少一个玻璃基材包括经回火玻璃片材。
7. 根据前述权利要求中任一项所述的工艺,其特征在于,所述面板的所有玻璃基材的所有玻璃片材为经回火的。
8. 根据前述权利要求中任一项所述的工艺,其特征在于,通过使加热元件与所述面板并列来加热所述面板。
9. 根据前述权利要求所述的工艺,其特征在于,所述加热元件为加热毯。
10. 根据前述权利要求中任一项所述的工艺,其特征在于,沿两个不同方向同时地弯曲所述面板。
11. 根据前述权利要求中任一项所述的工艺,其特征在于,所述弯曲持续10秒至12秒。
12. 根据前述权利要求中任一项所述的工艺,其特征在于,弯曲所述面板,以便由聚合材料制成的所述夹层与同所述夹层并列的所述玻璃基材之间的界面处的剪切应力在20℃下小于3MPa。
13. 根据前述权利要求中任一项所述的工艺,其特征在于,所述面板具有面积大于3m2,实际上甚至大于4m2,实际上甚至大约5m2的主面。
14. 根据前述权利要求中任一项所述的工艺,其特征在于,在弯曲所述夹层且使所述夹层回到20℃的温度之后,通过将偏振膜施加到所述面板的主面上且然后显示透射通过所述面板和所述膜的颜色来评估由聚合材料制成的所述夹层与所述玻璃基材之间的界面处的剪切应力的状态。
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JP7274480B2 (ja) 2017-11-30 2023-05-16 コーニング インコーポレイテッド 曲面ミラーを成形する真空成形装置、システム及び方法
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