CN103904319B - A kind of preparation method of power type nickel-cobalt lithium manganate cathode material - Google Patents
A kind of preparation method of power type nickel-cobalt lithium manganate cathode material Download PDFInfo
- Publication number
- CN103904319B CN103904319B CN201410076330.9A CN201410076330A CN103904319B CN 103904319 B CN103904319 B CN 103904319B CN 201410076330 A CN201410076330 A CN 201410076330A CN 103904319 B CN103904319 B CN 103904319B
- Authority
- CN
- China
- Prior art keywords
- preparation
- nickel
- solution
- shower nozzle
- cobalt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- HFCVPDYCRZVZDF-UHFFFAOYSA-N [Li+].[Co+2].[Ni+2].[O-][Mn]([O-])(=O)=O Chemical compound [Li+].[Co+2].[Ni+2].[O-][Mn]([O-])(=O)=O HFCVPDYCRZVZDF-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 239000010406 cathode material Substances 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 31
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 30
- 238000000197 pyrolysis Methods 0.000 claims abstract description 26
- 238000005469 granulation Methods 0.000 claims abstract description 19
- 230000003179 granulation Effects 0.000 claims abstract description 19
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000011812 mixed powder Substances 0.000 claims abstract description 16
- 239000011572 manganese Substances 0.000 claims abstract description 9
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 7
- 239000010941 cobalt Substances 0.000 claims abstract description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 7
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 7
- 239000003960 organic solvent Substances 0.000 claims abstract description 6
- 239000002245 particle Substances 0.000 claims description 17
- 238000000889 atomisation Methods 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 7
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 claims description 6
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 6
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims description 6
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 5
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 claims description 4
- KDSNLYIMUZNERS-UHFFFAOYSA-N 2-methylpropanamine Chemical compound CC(C)CN KDSNLYIMUZNERS-UHFFFAOYSA-N 0.000 claims description 4
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 claims description 4
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 claims description 4
- 229930016911 cinnamic acid Natural products 0.000 claims description 4
- 235000013985 cinnamic acid Nutrition 0.000 claims description 4
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 claims description 4
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims description 4
- 239000005711 Benzoic acid Substances 0.000 claims description 3
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims description 3
- UWHCKJMYHZGTIT-UHFFFAOYSA-N Tetraethylene glycol, Natural products OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 235000010233 benzoic acid Nutrition 0.000 claims description 3
- 229940015043 glyoxal Drugs 0.000 claims description 3
- 229910021645 metal ion Inorganic materials 0.000 claims description 3
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 claims description 3
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical class CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims description 2
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 2
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 2
- AMIMRNSIRUDHCM-UHFFFAOYSA-N Isopropylaldehyde Chemical compound CC(C)C=O AMIMRNSIRUDHCM-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- UXVMRCQQPJIQGC-UHFFFAOYSA-N n,n,n',n'-tetrakis(ethenyl)ethane-1,2-diamine Chemical group C=CN(C=C)CCN(C=C)C=C UXVMRCQQPJIQGC-UHFFFAOYSA-N 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 10
- 238000005245 sintering Methods 0.000 abstract description 9
- 238000000034 method Methods 0.000 abstract description 6
- 238000003756 stirring Methods 0.000 description 20
- 238000002156 mixing Methods 0.000 description 13
- OVAQODDUFGFVPR-UHFFFAOYSA-N lithium cobalt(2+) dioxido(dioxo)manganese Chemical compound [Li+].[Mn](=O)(=O)([O-])[O-].[Co+2] OVAQODDUFGFVPR-UHFFFAOYSA-N 0.000 description 10
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000012298 atmosphere Substances 0.000 description 6
- 235000013495 cobalt Nutrition 0.000 description 6
- XIXADJRWDQXREU-UHFFFAOYSA-M lithium acetate Chemical compound [Li+].CC([O-])=O XIXADJRWDQXREU-UHFFFAOYSA-M 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- YNQRWVCLAIUHHI-UHFFFAOYSA-L dilithium;oxalate Chemical compound [Li+].[Li+].[O-]C(=O)C([O-])=O YNQRWVCLAIUHHI-UHFFFAOYSA-L 0.000 description 5
- MQRWBMAEBQOWAF-UHFFFAOYSA-N acetic acid;nickel Chemical compound [Ni].CC(O)=O.CC(O)=O MQRWBMAEBQOWAF-UHFFFAOYSA-N 0.000 description 4
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 4
- 229940071125 manganese acetate Drugs 0.000 description 4
- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 description 4
- 229940078494 nickel acetate Drugs 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 230000036571 hydration Effects 0.000 description 3
- 238000006703 hydration reaction Methods 0.000 description 3
- IPJKJLXEVHOKSE-UHFFFAOYSA-L manganese dihydroxide Chemical compound [OH-].[OH-].[Mn+2] IPJKJLXEVHOKSE-UHFFFAOYSA-L 0.000 description 3
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 238000010532 solid phase synthesis reaction Methods 0.000 description 3
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 2
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 238000000975 co-precipitation Methods 0.000 description 2
- MULYSYXKGICWJF-UHFFFAOYSA-L cobalt(2+);oxalate Chemical compound [Co+2].[O-]C(=O)C([O-])=O MULYSYXKGICWJF-UHFFFAOYSA-L 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- QQHJDPROMQRDLA-UHFFFAOYSA-N hexadecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCC(O)=O QQHJDPROMQRDLA-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 229910001416 lithium ion Inorganic materials 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- RGVLTEMOWXGQOS-UHFFFAOYSA-L manganese(2+);oxalate Chemical compound [Mn+2].[O-]C(=O)C([O-])=O RGVLTEMOWXGQOS-UHFFFAOYSA-L 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- DOLZKNFSRCEOFV-UHFFFAOYSA-L nickel(2+);oxalate Chemical compound [Ni+2].[O-]C(=O)C([O-])=O DOLZKNFSRCEOFV-UHFFFAOYSA-L 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- OAVRWNUUOUXDFH-UHFFFAOYSA-H 2-hydroxypropane-1,2,3-tricarboxylate;manganese(2+) Chemical compound [Mn+2].[Mn+2].[Mn+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O OAVRWNUUOUXDFH-UHFFFAOYSA-H 0.000 description 1
- VAIVGJYVKZVQAA-UHFFFAOYSA-N 2-hydroxypropane-1,2,3-tricarboxylic acid;nickel Chemical compound [Ni].OC(=O)CC(O)(C(O)=O)CC(O)=O VAIVGJYVKZVQAA-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 229910002097 Lithium manganese(III,IV) oxide Inorganic materials 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000004087 circulation Effects 0.000 description 1
- 150000001868 cobalt Chemical class 0.000 description 1
- 229940011182 cobalt acetate Drugs 0.000 description 1
- QXOLLBTXUCQAEQ-UHFFFAOYSA-N cobalt;2-hydroxypropane-1,2,3-tricarboxylic acid Chemical compound [Co].OC(=O)CC(O)(C(O)=O)CC(O)=O QXOLLBTXUCQAEQ-UHFFFAOYSA-N 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- QHGJSLXSVXVKHZ-UHFFFAOYSA-N dilithium;dioxido(dioxo)manganese Chemical compound [Li+].[Li+].[O-][Mn]([O-])(=O)=O QHGJSLXSVXVKHZ-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229940071264 lithium citrate Drugs 0.000 description 1
- WJSIUCDMWSDDCE-UHFFFAOYSA-K lithium citrate (anhydrous) Chemical compound [Li+].[Li+].[Li+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O WJSIUCDMWSDDCE-UHFFFAOYSA-K 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 235000014872 manganese citrate Nutrition 0.000 description 1
- 239000011564 manganese citrate Substances 0.000 description 1
- 229940097206 manganese citrate Drugs 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- 150000002885 octadecanoids Chemical class 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007581 slurry coating method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/40—Nickelates
- C01G53/42—Nickelates containing alkali metals, e.g. LiNiO2
- C01G53/44—Nickelates containing alkali metals, e.g. LiNiO2 containing manganese
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/30—Particle morphology extending in three dimensions
- C01P2004/32—Spheres
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/11—Powder tap density
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Abstract
The invention discloses a kind of preparation method of power type nickel-cobalt lithium manganate cathode material, first part lithium source and nickel, cobalt, manganese source are dissolved in organic solvent, again by water-soluble for another part lithium source, simultaneously by two shower nozzle pyrolysis oven granulation, and mix in stove, then high temperature sintering is carried out to mixed-powder, obtain nickel-cobalt lithium manganate cathode material.NH is not produced in this preparation process
4 +, Na
+plasma, greatly reduces the pollution to environment, gained nickel-cobalt lithium manganate material good sphericity, distributed components, and tap density is high, have excellent cyclical stability, and first discharge specific capacity significantly improves in charge and discharge cycles process.
Description
Technical field
The invention belongs to cell positive material preparing technical field, particularly a kind of preparation method of power type nickel-cobalt lithium manganate cathode material.
Background technology
China's " energy-conservation with new-energy automobile industrial development planning (2012-2020) " electric automobile cumulative sale reached 500,000 by 2015, and the year two thousand twenty reaches 5,000,000.Under the guidance of national policy, electrokinetic cell industry obtains develop rapidly.Because of lithium ion battery, to have fail safe good, and electric discharge specific energy is high, and the advantages such as the discharge and recharge life-span is long, pollution-free be it is believed that it is one of the most promising electrokinetic cell.
Positive electrode directly determines the performance of lithium ion battery.Nickel-cobalt lithium manganate cathode material adopts relatively inexpensive nickel and manganese to instead of cobalts a large amount of in cobalt acid lithium, thus it has obviously advantage in reducing costs, simultaneously because of considerable charge/discharge capacity and excellent cyclical stability, the production of nickel-cobalt lithium manganate cathode material and use increasingly extensive, demonstrates huge market prospects.
The pattern of nickle cobalt lithium manganate self and the performance of size to electrical property play an important role.Research shows, sphere material particle can make material have larger tap density and useful life.In addition, excellent nickel-cobalt lithium manganate material must have suitable size and narrower particle size distribution, and is the bead of non-agglomerated.Routine prepares the coprecipitation of spherical nickel-cobalt LiMn2O4, owing to adopting the alkali lye such as ammoniacal liquor or NaOH to precipitate in technical process, and NH
4 +, Na
+plasma easily pollutes water body and context.And coprecipitation causes being difficult to obtain stable and that stoichiometric proportion is fixing coprecipitate in same system because of the difference of the solubility product of nickel, cobalt, hydroxide that each element of manganese is corresponding.The conventional solid phase method adopted, need to pulverize material before sintering in its technical process, batch mixing, although and through long-time grinding before roasting, lithium salts, nickel salt and cobalt salt are all difficult to reach other even contact of molecular level, and poor its stable electrochemical property that causes of the uniformity of material is not high.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, a kind of preparation method of power type nickel-cobalt lithium manganate cathode material is provided.
The technical solution used in the present invention is:
A preparation method for power type nickel-cobalt lithium manganate cathode material, comprises the following steps:
(1) by lithium source, nickel source, cobalt source, manganese source Li:Ni:Co:Mn=x:y:z:(1-y-z in molar ratio) be dissolved in organic solvent, add appropriate viscosity-controlling agent, mix, obtain solution I; Wherein, 0.1≤x≤0.3,0.1≤y≤0.9,0.1≤z≤0.5, y+z<1;
(2) by water-soluble for the lithium source of (1.0 ~ 1.1)-x, add appropriate viscosity-controlling agent, mix, obtain solution II;
(3) the shower nozzle A, the solution II that solution I are passed through two shower nozzle pyrolysis oven carry out press atomization granulation by shower nozzle B simultaneously, obtain the mixed-powder in presoma and lithium source;
(4) mixed-powder that step (3) obtains is sintered 5 ~ 20h at 600 ~ 1000 DEG C of temperature, obtain nickel-cobalt lithium manganate cathode material.
Preferably, step (1) described organic solvent is the carbon number of molten condition is the straight-chain carboxylic acid of 12 ~ 18.
Preferably, in solution I, concentration of metal ions is 0.5 ~ 3mol/L.
Preferably, in solution II, lithium concentration is 1 ~ 5mol/L.
Preferably, step (1) described viscosity-controlling agent is at least one in triethylamine, glyoxal, glutaraldehyde, benzaldehyde, benzoic acid, isobutylaldehyde, cinnamic acid, cinnamic acid; Step (2) described viscosity-controlling agent is at least one in ethylene glycol, glycerol, triethanolamine, ethylenediamine, tetraethylene glycol, ethylenimine, acetamide, dibutyl ethers, isobutyl amine, 2-butanone, propylamine, 2-propyl alcohol.
Preferably, in solution I, the concentration of viscosity-controlling agent is 1 ~ 5 g/L.
Preferably, in solution II, the concentration of viscosity-controlling agent is 2 ~ 10g/L.
Preferably, in step (3), the operating pressure controlling shower nozzle A is 0.1 ~ 0.6MPa, and charging rate is 500 ~ 5000mL/h; The operating pressure controlling shower nozzle B is 0.05 ~ 0.3MPa, and charging rate is 300 ~ 2050mL/h.
Preferably, in step (3), controlling prilling temperature in pyrolysis oven stove is 400 ~ 600 DEG C.
Preferably, be divided into dryer section, pyrolysis section, burning zone, after-flame section and cooling section from top to bottom, blast hot-air in after-flame section in pyrolysis oven stove, make the obtained particle of step (3) be in tumbling state, particle is 1 ~ 5min at residing time in furnace.
Preferably, described lithium source is at least one in lithium acetate, lithium oxalate, lithium citrate, lithium hydroxide; Described nickel source is at least one in nickel acetate, nickel oxalate, citric acid nickel, nickel hydroxide; Described cobalt source is at least one in cobalt acetate, cobalt oxalate, citric acid cobalt, cobalt hydroxide; Described manganese source is at least one in manganese acetate, manganese oxalate, manganese citrate, manganous hydroxide.
The invention has the beneficial effects as follows:
1, the present invention adopts melting carboxylic acid as solvent, and carboxylic acid solvent has solvent, compounding ingredient, surfactant triple role concurrently simultaneously, makes the mixing that each metal ion species is uniform and stable in the liquid phase, and water also can be avoided the hydrolysis of slaine.The structures such as carboxylic acid solvent's molecule and intermolecular formation hydrogen bond association, make to be wound around point between molecule and increase, the intermolecular forces of molecule strengthens, and therefore, the nickle cobalt lithium manganate that sintering is obtained has larger tap density.
2, part lithium source mixes with nickel, cobalt, manganese source solution by the present invention, and each component mixes at atomic level, and lithium source will be evenly distributed in precursor solution; The precursor solution including lithium source sprays from the shower nozzle A of two shower nozzle pyrolysis oven, and another part lithium source solution sprays from shower nozzle B, mixes with it, obtain the Homogeneous phase mixing powder in presoma and lithium source under air-flow drives; High temperature sintering is carried out to mixed-powder, after organic solvent at high temperature burns, gives granular precursor loose structure, be conducive to the Li making molten lithium source
2o fully diffuses into presoma inside from hole, material composition is distributed more even.Lithium source is introduced in two steps, optimizes material composition distribution further, is more preferably measured and compare chemicals after sintering.
3, the present invention adopts two shower nozzle pyrolysis oven simultaneously to presoma and the granulation of lithium source, and the drive by air-flow in stove mixes, and the mixing method avoiding conventional ball mill may destroy the defect of the spherical porous structure of presoma.
4, do not adopt the alkali such as ammoniacal liquor or NaOH to precipitate in technical process of the present invention, do not produce NH in traditional handicraft
4 +, Na
+plasma, to the pollution of water, greatly reduces the pollution to environment.Gained nickle cobalt lithium manganate product yield is high, good sphericity, and tap density is high, have excellent cyclical stability, and first discharge specific capacity significantly improves in charge and discharge cycles process.
Accompanying drawing explanation
Fig. 1 is the SEM figure of nickel-cobalt lithium manganate cathode material;
Fig. 2 is the charging and discharging curve figure of nickel-cobalt lithium manganate cathode material assembled battery;
Fig. 3 is the cycle performance figure of nickel-cobalt lithium manganate cathode material assembled battery.
Embodiment
Below in conjunction with specific embodiment, set forth content of the present invention further.
embodiment 1
A preparation method for power type nickle cobalt lithium manganate, comprises following concrete steps:
(1) lithium acetate, nickel acetate, four hydration cobalt acetates, manganese acetate being joined volume by quality 6.60g, 17.68g, 124.54g, 69.2g is respectively dissolve in the dodecylic acid of 50 DEG C of 2.2L, stir 2h mixing, then 2.2g triethylamine is added dropwise to while stirring, continue to stir 3h mixing, obtain solution I;
(2) 59.39g lithium acetate is dissolved in 0.9L water, adds 1.8g ethylene glycol, stir 1h mixing, obtain solution II;
(3) solution I is carried out press atomization granulation at the shower nozzle A of two shower nozzle pyrolysis oven, controlled pressure is 0.6MPa, and charging rate is 5000mL/h, simultaneously, solution II is carried out press atomization granulation at the shower nozzle B of two shower nozzle pyrolysis oven, and controlled pressure is 0.3MPa, and charging rate is 2050mL/h; The baffle plate that a block length is adjustable is had between shower nozzle A, B, dryer section, pyrolysis section, burning zone, after-flame section and cooling section is divided into from top to bottom in stove, blast hot-air in after-flame section, obtained particle is in tumbling state, and controls that prilling temperature in stove is 400 DEG C, particle stops 5min in stove; Granulation completes, and obtains presoma and lithium source mixed-powder;
(4) presoma step (3) obtained and lithium source mixed-powder are placed in Muffle furnace and sinter in atmosphere, and 600 DEG C of Isothermal sinter 20h, obtain power type nickel-cobalt lithium manganate cathode material.
embodiment 2
A preparation method for power type nickle cobalt lithium manganate, comprises following concrete steps:
(1) lithium acetate, nickel acetate, four hydration cobalt acetates, manganese acetate being joined volume by quality 6.60g, 17.68g, 124.54g, 69.2g is respectively dissolve in the tetracosandioic acid of 135 DEG C of 1.5L, stir 2h mixing, then 3.0g glyoxal is added dropwise to while stirring, continue to stir 3h mixing, obtain solution I;
(2) 59.39g lithium acetate is dissolved in 0.6L water, adds 2.0g glycerol, stir 1h mixing, obtain solution II;
(3) solution I is carried out press atomization granulation at the shower nozzle A of two shower nozzle pyrolysis oven, controlled pressure is 0.5MPa, and charging rate is 4000mL/h, simultaneously, solution II is carried out press atomization granulation at the shower nozzle B of two shower nozzle pyrolysis oven, and controlled pressure is 0.2MPa, and charging rate is 1600mL/h; The baffle plate that a block length is adjustable is had between shower nozzle A, B, dryer section, pyrolysis section, burning zone, after-flame section and cooling section is divided into from top to bottom in stove, blast hot-air in after-flame section, obtained particle is in tumbling state, and controls that prilling temperature in stove is 450 DEG C, particle stops 4min in stove; Granulation completes, and obtains presoma and lithium source mixed-powder;
(4) presoma step (3) obtained and lithium source mixed-powder are placed in Muffle furnace and sinter in atmosphere, and 700 DEG C of Isothermal sinter 15h, obtain power type nickel-cobalt lithium manganate cathode material.
embodiment 3
A preparation method for power type nickle cobalt lithium manganate, comprises following concrete steps:
(1) lithium oxalate, nickel oxalate, cobalt oxalate, manganese oxalate being joined volume by quality 19.19g, 48.90g, 48.97g, 47.65g is respectively dissolve in the hexadecanoic acid of 65 DEG C of 0.8L, stir 3h, then be added dropwise to 2.4g glutaraldehyde while stirring, continue to stir 2h, obtain solution I;
(2) 76.78g lithium oxalate is dissolved in 0.267L water, adds 1.33g triethanolamine, stir 2h mixing, obtain solution II;
(3) solution I is carried out press atomization granulation at the shower nozzle A of two shower nozzle pyrolysis oven, controlled pressure is 0.3MPa, and charging rate is 3000mL/h; Meanwhile, solution II is carried out press atomization granulation at the shower nozzle B of two shower nozzle pyrolysis oven, controlled pressure is 0.15MPa, and charging rate is 1000mL/h; Be divided into dryer section, pyrolysis section, burning zone, after-flame section and cooling section in stove from top to bottom, blast hot-air in after-flame section, obtained particle is in tumbling state, and controls that prilling temperature in stove is 500 DEG C, particle stops 3min in stove; Granulation completes, and obtains presoma and lithium source mixed-powder;
(4) presoma step (3) obtained and lithium source mixed-powder are placed in Muffle furnace and sinter in atmosphere, and 800 DEG C of sintering 10h, obtain power type nickel-cobalt lithium manganate cathode material.
embodiment 4
A preparation method for power type nickle cobalt lithium manganate, comprises following concrete steps:
(1) lithium hydroxide, nickel hydroxide, cobalt hydroxide, manganous hydroxide being joined volume by quality 7.18g, 74.17g, 9.29g, 8.89g is respectively dissolve in the hexadecandioic acid (hexadecane diacid) of 130 DEG C of 0.6L, stir 4h, then 2.5g benzaldehyde is added dropwise to while stirring, continue to stir 1h, obtain solution I;
(2) 76.78g lithium oxalate is dissolved in 0.3L water, adds 2.25g ethylenediamine, stir 2h mixing, obtain solution II;
(3) solution I is carried out press atomization granulation at the shower nozzle A of two shower nozzle pyrolysis oven, controlled pressure is 0.2MPa, and charging rate is 1500mL/h, simultaneously, solution II is carried out press atomization granulation at the shower nozzle B of two shower nozzle pyrolysis oven, and controlled pressure is 0.1MPa, and charging rate is 750mL/h; Be divided into dryer section, pyrolysis section, burning zone, after-flame section and cooling section in stove from top to bottom, blast hot-air in after-flame section, obtained particle is in tumbling state, and controls that prilling temperature in stove is 550 DEG C, particle stops 1min in stove; Granulation completes, and obtains presoma and lithium source mixed-powder;
(4) presoma step (3) obtained and lithium source mixed-powder are placed in Muffle furnace and sinter in atmosphere, and 900 DEG C of sintering 8h, obtain power type nickel-cobalt lithium manganate cathode material.
embodiment 5
A preparation method for power type nickle cobalt lithium manganate, comprises following concrete steps:
(1) lithium hydroxide, nickel hydroxide, cobalt hydroxide, manganous hydroxide being joined volume by quality 7.18g, 74.17g, 9.29g, 8.89g is respectively dissolve in the octadecanoid acid of 85 DEG C of 0.433L, stir 5h, then 2.17g benzoic acid is added dropwise to while stirring, continue to stir 1h, obtain solution I;
(2) 76.78g lithium oxalate is dissolved in 0.267L water, adds 1.34g tetraethylene glycol, stir 2h mixing, obtain solution II;
(3) solution I is carried out press atomization granulation at the shower nozzle A of two shower nozzle pyrolysis oven, controlled pressure is 0.1MPa, and charging rate is 500mL/h, simultaneously, solution II is carried out press atomization granulation at the shower nozzle B of two shower nozzle pyrolysis oven, and controlled pressure is 0.05MPa, and charging rate is 300mL/h; Be divided into dryer section, pyrolysis section, burning zone, after-flame section and cooling section in stove from top to bottom, blast hot-air in after-flame section, obtained particle is in tumbling state, and controls that prilling temperature in stove is 600 DEG C, particle stops 1min in stove; Granulation completes, and obtains presoma and lithium source mixed-powder;
(4) presoma step (3) obtained and lithium source mixed-powder are placed in Muffle furnace and sinter in atmosphere, and 1000 DEG C of sintering 5h, obtain power type nickel-cobalt lithium manganate cathode material.
comparative example
Take 65.99g lithium acetate respectively, 58.93g nickel acetate, 82.03g four hydration cobalt acetates, 57.67g manganese acetate, add 200mL absolute ethyl alcohol and make dispersant, with planetary ball mill ball milling 2h, the powder obtained is placed in Muffle furnace after drying and sinters in atmosphere by 105 DEG C, baking oven, sintering temperature is 600 DEG C, constant temperature 20h.Obtain nickle cobalt lithium manganate comparative sample.
performance Detection:
1, Fig. 1 is the SEM figure that embodiment 1 obtains nickel-cobalt lithium manganate cathode material, can find out, gained sample is spherical in rule, pattern rule, good dispersion, particle size consistency is good, and domain size distribution is between 6 ~ 12 μm, the bulk density of material can not only be improved, increase the volume energy density of battery, and significantly can improve the processing characteristics in slurry coating, electrode production process.The SEM figure of nickel-cobalt lithium manganate cathode material prepared by other embodiments and embodiment 1 are without bigger difference.
2, respectively with the obtained nickle cobalt lithium manganate of embodiment 3 and comparative example for positive pole, take lithium metal as negative pole, be assembled into battery, carry out discharge test first with 1C multiplying power, result is as shown in Figure 2.Result shows, and under 1C multiplying power, the first discharge specific capacity of nickel-cobalt lithium manganate cathode material prepared by embodiment 3 is than the height of common solid phase method, and the specific capacity of embodiment 3 is 151.9mAh/g, and the specific capacity of comparative example only has 136.2mAh/g.
100 charge and discharge cycles tests are carried out, as shown in Figure 3 with 1C multiplying power.Result shows, and the specific capacity of nickel-cobalt lithium manganate cathode material prepared by embodiment 3 is after 100 circulations, and than the height of common solid phase method, the capability retention of embodiment 3 is 90.7%, and the capability retention of comparative example only has 82.4%.
Claims (9)
1. a preparation method for power type nickel-cobalt lithium manganate cathode material, is characterized in that, comprises the following steps:
(1) by lithium source, nickel source, cobalt source, manganese source Li:Ni:Co:Mn=x:y:z:(1-y-z in molar ratio) be dissolved in organic solvent, add appropriate viscosity-controlling agent, mix, obtain solution I; Wherein, 0.1≤x≤0.3,0.1≤y≤0.9,0.1≤z≤0.5, y+z<1; Organic solvent is the carbon number of molten condition is the straight-chain carboxylic acid of 12 ~ 18;
(2) by water-soluble for the lithium source of (1.0 ~ 1.1)-x, add appropriate viscosity-controlling agent, mix, obtain solution II;
(3) the shower nozzle A, the solution II that solution I are passed through two shower nozzle pyrolysis oven carry out press atomization granulation by shower nozzle B simultaneously, obtain the mixed-powder in presoma and lithium source;
(4) mixed-powder that step (3) obtains is sintered 5 ~ 20h at 600 ~ 1000 DEG C of temperature, obtain nickel-cobalt lithium manganate cathode material.
2. preparation method according to claim 1, is characterized in that: in solution I, concentration of metal ions is 0.5 ~ 3mol/L.
3. preparation method according to claim 1, is characterized in that: in solution II, lithium concentration is 1 ~ 5mol/L.
4. preparation method according to claim 1, is characterized in that: step (1) described viscosity-controlling agent is at least one in triethylamine, glyoxal, glutaraldehyde, benzaldehyde, benzoic acid, isobutylaldehyde, cinnamic acid, cinnamic acid; Step (2) described viscosity-controlling agent is at least one in ethylene glycol, glycerol, triethanolamine, ethylenediamine, tetraethylene glycol, ethylenimine, acetamide, dibutyl ethers, isobutyl amine, 2-butanone, propylamine, 2-propyl alcohol.
5. the preparation method according to claim 1 or 4, is characterized in that: in solution I, the concentration of viscosity-controlling agent is 1 ~ 5g/L.
6. the preparation method according to claim 1 or 4, is characterized in that: in solution II, the concentration of viscosity-controlling agent is 2 ~ 10g/L.
7. preparation method according to claim 1, is characterized in that: in step (3), and the operating pressure controlling shower nozzle A is 0.1 ~ 0.6MPa, and charging rate is 500 ~ 5000mL/h; The operating pressure controlling shower nozzle B is 0.05 ~ 0.3MPa, and charging rate is 300 ~ 2050mL/h.
8. preparation method according to claim 1, is characterized in that: in step (3), and controlling prilling temperature in pyrolysis oven stove is 400 ~ 600 DEG C.
9. the preparation method according to claim 1,7 or 8, it is characterized in that: in pyrolysis oven stove, be divided into dryer section, pyrolysis section, burning zone, after-flame section and cooling section from top to bottom, hot-air is blasted in after-flame section, make the obtained particle of step (3) be in tumbling state, particle is 1 ~ 5min at residing time in furnace.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410076330.9A CN103904319B (en) | 2014-03-04 | 2014-03-04 | A kind of preparation method of power type nickel-cobalt lithium manganate cathode material |
| PCT/CN2015/072620 WO2015131745A1 (en) | 2014-03-04 | 2015-02-10 | Method for preparation of power-type nickel cobalt manganate lithium positive electrode material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410076330.9A CN103904319B (en) | 2014-03-04 | 2014-03-04 | A kind of preparation method of power type nickel-cobalt lithium manganate cathode material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103904319A CN103904319A (en) | 2014-07-02 |
| CN103904319B true CN103904319B (en) | 2015-10-07 |
Family
ID=50995543
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410076330.9A Active CN103904319B (en) | 2014-03-04 | 2014-03-04 | A kind of preparation method of power type nickel-cobalt lithium manganate cathode material |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN103904319B (en) |
| WO (1) | WO2015131745A1 (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103904319B (en) * | 2014-03-04 | 2015-10-07 | 广东邦普循环科技有限公司 | A kind of preparation method of power type nickel-cobalt lithium manganate cathode material |
| CN106663791A (en) * | 2014-07-25 | 2017-05-10 | 台湾立凯电能科技股份有限公司 | Method for preparing lithium nickel manganese oxide positive battery electrode material, and lithium nickel manganese oxide positive battery electrode material |
| CN108899513A (en) * | 2018-07-03 | 2018-11-27 | 江苏乐能电池股份有限公司 | A kind of preparation method of the trielement composite material containing organic salt |
| CN109360949A (en) * | 2018-09-13 | 2019-02-19 | 德阳威旭锂电科技有限责任公司 | A kind of method that water/solvent-thermal method largely prepares carbon coating iron manganese phosphate for lithium |
| CN110518209B (en) * | 2019-08-27 | 2022-04-22 | 广东风华新能源股份有限公司 | Preparation method of anode material and prepared anode material |
| CN113735187B (en) * | 2020-05-29 | 2023-06-09 | 东莞东阳光科研发有限公司 | Preparation method of nickel cobalt lithium manganate precursor |
| CN113178565B (en) * | 2021-03-29 | 2023-06-16 | 广东邦普循环科技有限公司 | Mixing process for preparing high-nickel anode material and application thereof |
| CN113809319B (en) * | 2021-08-03 | 2022-11-15 | 广东邦普循环科技有限公司 | High-performance lithium nickel cobalt manganese oxide positive electrode material for power battery and preparation method of high-performance lithium nickel cobalt manganese oxide positive electrode material |
| CN114497530A (en) * | 2022-01-11 | 2022-05-13 | 中科锂电新能源有限公司 | Compression type lithium manganese iron phosphate cathode material and production process thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102300806A (en) * | 2008-12-08 | 2011-12-28 | 蒂肖有限公司 | Multicomponent nanoparticle materials and process and apparatus therefor |
| CN102583579A (en) * | 2012-02-14 | 2012-07-18 | 佛山市邦普循环科技有限公司 | Method for modifying rich lithium cobalt lithium manganite cathode material of lithium ion battery |
| CN102956884A (en) * | 2012-11-29 | 2013-03-06 | 四川大学 | Lithium-rich manganese-based material and preparation method thereof |
| CN103000893A (en) * | 2012-12-20 | 2013-03-27 | 中国东方电气集团有限公司 | Method for preparing lithium manganese phosphate positive material of lithium battery by spray pyrolysis |
| CN103094546A (en) * | 2013-01-25 | 2013-05-08 | 湖南邦普循环科技有限公司 | Method for preparing nickel-cobalt lithium aluminate as anode material of lithium ion battery |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5431218B2 (en) * | 2010-03-18 | 2014-03-05 | 三洋電機株式会社 | Non-aqueous electrolyte secondary battery |
| CN103904319B (en) * | 2014-03-04 | 2015-10-07 | 广东邦普循环科技有限公司 | A kind of preparation method of power type nickel-cobalt lithium manganate cathode material |
-
2014
- 2014-03-04 CN CN201410076330.9A patent/CN103904319B/en active Active
-
2015
- 2015-02-10 WO PCT/CN2015/072620 patent/WO2015131745A1/en active Application Filing
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102300806A (en) * | 2008-12-08 | 2011-12-28 | 蒂肖有限公司 | Multicomponent nanoparticle materials and process and apparatus therefor |
| CN102583579A (en) * | 2012-02-14 | 2012-07-18 | 佛山市邦普循环科技有限公司 | Method for modifying rich lithium cobalt lithium manganite cathode material of lithium ion battery |
| CN102956884A (en) * | 2012-11-29 | 2013-03-06 | 四川大学 | Lithium-rich manganese-based material and preparation method thereof |
| CN103000893A (en) * | 2012-12-20 | 2013-03-27 | 中国东方电气集团有限公司 | Method for preparing lithium manganese phosphate positive material of lithium battery by spray pyrolysis |
| CN103094546A (en) * | 2013-01-25 | 2013-05-08 | 湖南邦普循环科技有限公司 | Method for preparing nickel-cobalt lithium aluminate as anode material of lithium ion battery |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2015131745A1 (en) | 2015-09-11 |
| CN103904319A (en) | 2014-07-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103904319B (en) | A kind of preparation method of power type nickel-cobalt lithium manganate cathode material | |
| CN104681795A (en) | Preparation method for lithium ferric manganese phosphate/carbon composite material | |
| CN111261851B (en) | Ternary cathode material of lithium ion battery and preparation method thereof | |
| CN108493435B (en) | Lithium ion battery anode material Li (Ni)0.8Co0.1Mn0.1)1-xYxO2And preparation method | |
| CN108807886A (en) | Double-coating anode material for lithium-ion batteries LiNi0.6Co0.2Mn0.2O2And preparation method thereof | |
| CN104810521A (en) | Preparing method of nickel cobalt lithium manganate ternary positive electrode material | |
| CN103247777A (en) | Cobaltosic oxide multi-shell hollow sphere cathode material for lithium ion battery and preparation method thereof | |
| CN110112388A (en) | The positive electrode and preparation method thereof of porous tungstic acid coating modification | |
| CN112794369B (en) | Preparation method and application of nano lithium cobalt oxide positive electrode material | |
| CN105293458A (en) | Ferrous phosphate, preparation method therefor, lithium iron phosphate positive electrode active material and preparation method therefor | |
| CN108550843A (en) | Preparation method, nickel-cobalt-manganese ternary material, anode material for lithium-ion batteries and the lithium ion battery of nickel-cobalt-manganese ternary material | |
| CN109148878A (en) | A kind of method, positive electrode and lithium ion battery handling the residual lithium in surface containing lithium anode material | |
| CN113991112A (en) | Preparation method of nano-titanium dioxide doped lithium iron phosphate cathode material | |
| CN103833083A (en) | Preparation method of precursor of lithium iron phosphate-lithium vanadium phosphate composite | |
| CN106745251B (en) | A kind of preparation method and application of nanometer vanadic anhydride positive electrode suitable for industrialized production | |
| CN106129409B (en) | A method of lithium iron manganese phosphate anode material is prepared using ethyl cellulose for carbon source | |
| CN103855372A (en) | High-manganese composite cathode material and preparation method thereof | |
| CN113060715B (en) | Method for synthesizing lithium ferric manganese phosphate cathode material | |
| CN105514374A (en) | Graphitized carbon coated manganese-fluorine oxide material and preparation method thereof | |
| CN106159224B (en) | A kind of lithium battery anode active material preparation method | |
| CN108767231A (en) | A kind of LiNixCoyMnl-x-yO2/Li2O·B2O3The preparation method of composite positive pole | |
| CN110165199B (en) | Modified anode material and preparation method thereof | |
| CN110474046A (en) | The rich lithium manganese anode material and preparation method thereof of Spinel LiMn2O4 cladding | |
| CN109346719A (en) | A kind of method that auxiliary agent additive process prepares modified nickel-cobalt lithium manganate cathode material | |
| CN105591096A (en) | Industrial production method of nickel cobalt lithium manganite ternary positive electrode material with cycle life more than 3000 times |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent for invention or patent application | ||
| CB02 | Change of applicant information |
Address after: Water sand village Nanhai District 528200 in Guangdong province Foshan City Industrial Zone Chung Applicant after: GUANGDONG BRUNP RECYCLING TECHNOLOGY CO., LTD. Applicant after: Hunan Brunp Circulation Technology Co., Ltd. Applicant after: HUNAN BRUNP SCRAP CARS RECYCLING CO., LTD. Address before: Water sand village Nanhai District 528200 in Guangdong province Foshan City Industrial Zone Chung Applicant before: GUANGDONG BRUNP RECYCLING TECHNOLOGY CO., LTD. Applicant before: Hunan Brunp Circulation Technology Co., Ltd. Applicant before: HUNAN BRUNP WASTE AND OLD MATERIALS RECOVERY CO., LTD. |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP01 | Change in the name or title of a patent holder | ||
| CP01 | Change in the name or title of a patent holder |
Address after: Water sand village Nanhai District 528200 in Guangdong province Foshan City Industrial Zone Chung Co-patentee after: Hunan brunp automobile recycling Limited Patentee after: GUANGDONG BRUNP RECYCLING TECHNOLOGY CO., LTD. Co-patentee after: Hunan Brunp Circulation Technology Co., Ltd. Address before: Water sand village Nanhai District 528200 in Guangdong province Foshan City Industrial Zone Chung Co-patentee before: Hunan Brunp Circulation Technology Co., Ltd. Patentee before: GUANGDONG BRUNP RECYCLING TECHNOLOGY CO., LTD. Co-patentee before: HUNAN BRUNP SCRAP CARS RECYCLING CO., LTD. |
|
| CP01 | Change in the name or title of a patent holder | ||
| CP01 | Change in the name or title of a patent holder |
Address after: Water sand village Nanhai District 528200 in Guangdong province Foshan City Industrial Zone Chung Co-patentee after: Hunan Brunp Circulation Technology Co., Ltd. Patentee after: GUANGDONG BRUNP RECYCLING TECHNOLOGY CO., LTD. Co-patentee after: Hunan brunp automobile recycling Limited Address before: Water sand village Nanhai District 528200 in Guangdong province Foshan City Industrial Zone Chung Co-patentee before: Hunan Brunp Circulation Technology Co., Ltd. Patentee before: GUANGDONG BRUNP RECYCLING TECHNOLOGY CO., LTD. Co-patentee before: HUNAN BRUNP SCRAP CARS RECYCLING CO., LTD. |
|
| CP02 | Change in the address of a patent holder | ||
| CP02 | Change in the address of a patent holder |
Address after: No.6 Zhixin Avenue, Leping Town, Sanshui District, Foshan City, Guangdong Province Patentee after: GUANGDONG BRUNP RECYCLING TECHNOLOGY Co.,Ltd. Patentee after: HUNAN BRUNP RECYCLING TECHNOLOGY Co.,Ltd. Patentee after: HUNAN BANGPU AUTOMOBILE CIRCULATION Co.,Ltd. Address before: 528200 Lishui Shangsha village shangshayong Industrial Zone, Nanhai District, Foshan City, Guangdong Province Patentee before: GUANGDONG BRUNP RECYCLING TECHNOLOGY Co.,Ltd. Patentee before: HUNAN BRUNP RECYCLING TECHNOLOGY Co.,Ltd. Patentee before: HUNAN BANGPU AUTOMOBILE CIRCULATION Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20210415 Address after: No.6 Zhixin Avenue, Leping Town, Sanshui District, Foshan City, Guangdong Province Patentee after: GUANGDONG BRUNP RECYCLING TECHNOLOGY Co.,Ltd. Patentee after: HUNAN BRUNP RECYCLING TECHNOLOGY Co.,Ltd. Patentee after: HUNAN BANGPU AUTOMOBILE CIRCULATION Co.,Ltd. Patentee after: Ningde Bangpu Recycling Technology Co.,Ltd. Address before: No.6 Zhixin Avenue, Leping Town, Sanshui District, Foshan City, Guangdong Province Patentee before: GUANGDONG BRUNP RECYCLING TECHNOLOGY Co.,Ltd. Patentee before: HUNAN BRUNP RECYCLING TECHNOLOGY Co.,Ltd. Patentee before: HUNAN BANGPU AUTOMOBILE CIRCULATION Co.,Ltd. |