CN103895274B - 陶瓷与塑料的复合体及其制备方法 - Google Patents
陶瓷与塑料的复合体及其制备方法 Download PDFInfo
- Publication number
- CN103895274B CN103895274B CN201210588212.7A CN201210588212A CN103895274B CN 103895274 B CN103895274 B CN 103895274B CN 201210588212 A CN201210588212 A CN 201210588212A CN 103895274 B CN103895274 B CN 103895274B
- Authority
- CN
- China
- Prior art keywords
- plastics
- glue
- complex
- ceramics
- ceramic member
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14311—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles using means for bonding the coating to the articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/005—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B9/045—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B37/00—Joining burned ceramic articles with other burned ceramic articles or other articles by heating
- C04B37/008—Joining burned ceramic articles with other burned ceramic articles or other articles by heating by means of an interlayer consisting of an organic adhesive, e.g. phenol resin or pitch
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/48—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
- B29C65/4805—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the type of adhesives
- B29C65/481—Non-reactive adhesives, e.g. physically hardening adhesives
- B29C65/482—Drying adhesives, e.g. solvent based adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
- C04B2237/30—Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
- C04B2237/32—Ceramic
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
- C04B2237/50—Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
- C04B2237/70—Forming laminates or joined articles comprising layers of a specific, unusual thickness
- C04B2237/708—Forming laminates or joined articles comprising layers of a specific, unusual thickness of one or more of the interlayers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31667—Next to addition polymer from unsaturated monomers, or aldehyde or ketone condensation product
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Laminated Bodies (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Producing Shaped Articles From Materials (AREA)
Abstract
一种陶瓷与塑料的复合体,其包括陶瓷件与塑料件,该塑料件注塑形成于该陶瓷件上,该陶瓷件与塑料件之间设置有胶水层,该胶水层中含有聚醋酸乙烯酯、聚乙烯醇、邻苯二甲酸二丁酯、以及醋酸二丁酯。此外,本发明还提供一种所述陶瓷与塑料的复合体的制备方法。该陶瓷与塑料的复合体中陶瓷件与塑料件的结合牢固,且可有效避免溢胶、结合线不良等问题。
Description
技术领域
本发明涉及一种陶瓷与塑料的复合体及其制备方法。
背景技术
随着制造技术的飞速发展以及日益成熟化,高贵典雅的陶瓷在饰品、3C等行业的应用逐渐增多。但由于陶瓷特殊的物理性能,在组装工艺过程中一直存在很大的挑战。现有的陶瓷与塑料结合的方法通常为:分别成型陶瓷件与塑料件,然后在陶瓷件与塑料件的结合表面涂覆液态胶水,再采用一定的压力将陶瓷件与塑料件组合在一起,由于胶水的粘结作用陶瓷件与塑料件将结合成一体。然而,该种方法通常会产生以下问题:陶瓷件与塑料件的结合处出现溢胶,导致产品外观不良;陶瓷件与塑料件的结合力不够,结合线不良。
发明内容
有鉴于此,有必要提供一种陶瓷与塑料的复合体,该复合体的陶瓷件与塑料件结合牢固,且不会出现溢胶、结合线不良等问题。
另外,还有必要提供一种上述陶瓷与塑料的复合体的制备方法。
一种陶瓷与塑料的复合体,其包括陶瓷件与塑料件,该塑料件注塑形成于该陶瓷件上,该陶瓷件与塑料件之间设置有胶水层,该胶水层中含有聚醋酸乙烯酯、聚乙烯醇、邻苯二甲酸二丁酯、以及醋酸二丁酯。
一种陶瓷与塑料的复合体的制备方法,其包括如下步骤:
提供陶瓷件;
在该陶瓷件后续需与塑料件结合的表面涂覆胶水,该胶水中主要含有聚醋酸乙烯酯、聚乙烯醇、邻苯二甲酸二丁酯、醋酸二丁酯及有机溶剂;
使陶瓷件表面的液体胶水固化形成一胶水层;
将表面具有胶水层的陶瓷件放入一注塑模具中进行注塑成型塑料件,该塑料件将结合于陶瓷件具有胶水层的表面。
本发明的陶瓷与塑料的复合体,通过在陶瓷件涂覆特殊组份的液体胶水并固化形成固体胶水层,再注塑形成塑料件使其与陶瓷件相结合。该陶瓷与塑料的复合体中陶瓷件与塑料件的结合牢固,且可有效避免溢胶、结合线不良等问题。
附图说明
图1为本发明一较佳实施例陶瓷与塑料的复合体的示意图;
图2为沿图1中II-II剖面线剖开的剖面示意图。
主要元件符号说明
陶瓷与塑料的复合体 | 10 |
陶瓷件 | 11 |
塑料件 | 13 |
胶水层 | 15 |
如下具体实施方式将结合上述附图进一步说明本发明。
具体实施方式
请参阅图1,本发明一较佳实施方式的陶瓷与塑料的复合体10,其包括陶瓷件11与塑料件13,该塑料件13注塑形成于该陶瓷件11上成型为一整体。该塑料件13的材质可选自较为常见的注塑树脂,但该注塑树脂的成型温度低于170℃。
请进一步参阅图2,该陶瓷件11与塑料件13之间设置有胶水层15。该胶水层15中含有聚醋酸乙烯酯、聚乙烯醇、邻苯二甲酸二丁酯、以及醋酸二丁酯。该胶水层15为胶水干燥固化形成,该胶水为聚醋酸乙烯酯溶液(质量百分浓度为55%)、聚乙烯醇溶液(质量百分浓度为5%)、邻苯二甲酸二丁酯、醋酸二丁酯按照体积比为1-1.2 :15-17 :0.3-0.5 :2.5-3.0的比例混合制得。该种配方组分的胶水具有良好的粘合功能,可使异质材料粘合牢固。
所述聚醋酸乙烯酯和聚乙烯醇为固体,因此将它们溶于有机溶剂再与邻苯二甲酸二丁酯、醋酸二丁酯混合。该有机溶剂优选为乙醇,但不限于乙醇。此外,该胶水中还选择性的添加有常规的增稠剂、防腐剂及偶联剂。该胶水层15的厚度为20-40μm。
本发明的陶瓷与塑料的复合体10,通过在陶瓷件11涂覆特殊组份的液体胶水并固化形成胶水层15,再注塑形成塑料件13使其与陶瓷件11相结合,因而该陶瓷件11与塑料件13结合牢固,且可有效避免溢胶、结合线不良等问题。
本发明一较佳实施方式的陶瓷与塑料的复合体10的制备方法,其包括如下步骤:
(1)提供烧结好的陶瓷件11。
(2)在该陶瓷件11的一表面涂覆胶水。该胶水为耐高温的液体胶水。该胶水中主要含有聚醋酸乙烯酯、聚乙烯醇、邻苯二甲酸二丁酯、醋酸二丁酯及适量的有机溶剂,该胶水为聚醋酸乙烯酯溶液(质量百分浓度为55%)、聚乙烯醇溶液(质量百分浓度为5%)、邻苯二甲酸二丁酯、醋酸二丁酯按照体积比为1-1.2 :15-17 :0.3-0.5 :2.5-3.0的比例混合制得。所述聚醋酸乙烯酯和聚乙烯醇为固体,因此将它们溶于有机溶剂再与邻苯二甲酸二丁酯、醋酸二丁酯混合。该有机溶剂优选为乙醇,但不限于乙醇。此外,该胶水中还选择性的添加有胶水中常规添加使用的增稠剂、防腐剂及偶联剂。
(3)使陶瓷件11表面的液体胶水固化形成一胶水层15。该胶水层15的厚度为20-40μm。该固化过程的目的使有机溶剂完全挥发,固化过程可在约40℃温度下烘烤约30min,然后放置6h后使用;或自然放置24h使胶水固化后使用。
(4)将表面具有胶水层15的陶瓷件11放入一注塑模具(图未示)中进行注塑成型塑料件13,即制得陶瓷与塑料的复合体10。该塑料件13将结合于陶瓷件11具有胶水层15的表面。该塑料件13的材质可选自较为常见的注塑树脂,但该注塑树脂的成型温度要求低于170℃,以防止注塑过程中胶水因高温而失效。为确保胶水粘接力最佳,注塑成型过程中,该注塑模具温度要求低于170℃。
(5)选择性对该陶瓷与塑料的复合体10进行研磨抛光、喷漆等处理,使该陶瓷与塑料的复合体10外观更加美观。
本发明选取了三个陶瓷与塑料的复合体样品进行了拉拔力测试。每一样品测试6次。具体使用SE精度负载测试仪(SE Precision Load Tester,型号为1220(H)S)进行测试,拉拔力(单位:N)测试结果如下表所示。
样品 | A | B | C | D | E | F | 平均值 |
1 | 260.7 | 261.3 | 289.2 | 281.6 | 259.5 | 262.6 | 269.15 |
2 | 263.1 | 265.4 | 286.7 | 284.3 | 262.3 | 263.4 | 270.87 |
3 | 261.9 | 260.5 | 290.8 | 286.9 | 269.5 | 260.7 | 271.72 |
上述测试结果表明,本发明陶瓷与塑料的复合体10的陶瓷件11和塑料件13之间的拉拔力较大,说明陶瓷件11和塑料件13结合较牢固。
本发明的陶瓷与塑料的复合体10,通过在陶瓷件11表面涂覆特殊组份的液体胶水并固化形成胶水层15,再注塑形成塑料件13使其与陶瓷件11相结合。该陶瓷与塑料的复合体10中陶瓷件11与塑料件13结合牢固,且可有效避免溢胶、结合线不良等问题。
另外,本领域技术人员还可在本发明权利要求公开的范围和精神内做其它形式和细节上的各种修改、添加和替换。当然,这些依据本发明精神所做的各种修改、添加和替换等变化,都应包含在本发明所要求保护的范围之内。
Claims (8)
1.一种陶瓷与塑料的复合体,其包括陶瓷件与塑料件,该塑料件注塑形成于该陶瓷件上,其特征在于:该陶瓷件与塑料件之间设置有胶水层,该胶水层中含有聚醋酸乙烯酯、聚乙烯醇、邻苯二甲酸二丁酯、以及醋酸二丁酯,该胶水层为液态胶水干燥固化形成,该液态胶水为聚醋酸乙烯酯溶于有机溶剂的溶液、聚乙烯醇溶于有机溶剂的溶液、邻苯二甲酸二丁酯、醋酸二丁酯按照体积比为1-1.2:15-17:0.3-0.5:2.5-3.0的比例混合制得,其中聚醋酸乙烯酯溶于有机溶剂的溶液的质量百分浓度为55%,聚乙烯醇溶于有机溶剂的溶液的质量百分浓度为5%。
2.如权利要求1所述的陶瓷与塑料的复合体,其特征在于:该胶水层的厚度为20-40μm。
3.如权利要求1所述的陶瓷与塑料的复合体,其特征在于:该塑料件的材质为成型温度低于170℃的注塑树脂。
4.一种陶瓷与塑料的复合体的制备方法,其包括如下步骤:
提供陶瓷件;
在该陶瓷件的表面涂覆液体胶水,该胶水中主要含有聚醋酸乙烯酯、聚乙烯醇、邻苯二甲酸二丁酯、醋酸二丁酯及有机溶剂;
使陶瓷件表面的液体胶水固化形成一胶水层;
将表面具有胶水层的陶瓷件放入一注塑模具中进行注塑成型塑料件,该塑料件结合于陶瓷件具有胶水层的表面;
该液态胶水为聚醋酸乙烯酯溶于有机溶剂的溶液、聚乙烯醇溶于有机溶剂的溶液、邻苯二甲酸二丁酯、醋酸二丁酯按照体积比为1-1.2:15-17:0.3-0.5:2.5-3.0的比例混合制得,其中聚醋酸乙烯酯溶于有机溶剂的溶液的质量百分浓度为55%,聚乙烯醇溶于有机溶剂的溶液的质量百分浓度为5%。
5.如权利要求4所述陶瓷与塑料的复合体的制备方法,其特征在于:该胶水层的厚度为20-40μm。
6.如权利要求4所述陶瓷与塑料的复合体的制备方法,其特征在于:该胶水固化的方式是在40℃温度下烘烤30min,或自然放置24h。
7.如权利要求4所述陶瓷与塑料的复合体的制备方法,其特征在于:该塑料件的材质为成型温度低于170℃的注塑树脂。
8.如权利要求4所述陶瓷与塑料的复合体的制备方法,其特征在于:注塑成型塑料件的过程中,该注塑模具温度低于170℃。
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210588212.7A CN103895274B (zh) | 2012-12-29 | 2012-12-29 | 陶瓷与塑料的复合体及其制备方法 |
TW102102767A TWI572482B (zh) | 2012-12-29 | 2013-01-25 | 陶瓷與塑膠的複合體及其製備方法 |
US13/864,652 US9855722B2 (en) | 2012-12-29 | 2013-04-17 | Composite article and method for making same |
JP2013268865A JP5956417B2 (ja) | 2012-12-29 | 2013-12-26 | セラミックとプラスチックとの複合体及びその製造方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210588212.7A CN103895274B (zh) | 2012-12-29 | 2012-12-29 | 陶瓷与塑料的复合体及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103895274A CN103895274A (zh) | 2014-07-02 |
CN103895274B true CN103895274B (zh) | 2017-05-03 |
Family
ID=50986997
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201210588212.7A Expired - Fee Related CN103895274B (zh) | 2012-12-29 | 2012-12-29 | 陶瓷与塑料的复合体及其制备方法 |
Country Status (4)
Country | Link |
---|---|
US (1) | US9855722B2 (zh) |
JP (1) | JP5956417B2 (zh) |
CN (1) | CN103895274B (zh) |
TW (1) | TWI572482B (zh) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104589575A (zh) * | 2014-11-27 | 2015-05-06 | 东莞劲胜精密组件股份有限公司 | 陶瓷与塑料复合结构及其制作方法 |
KR101538434B1 (ko) * | 2015-02-03 | 2015-07-23 | 인탑스 주식회사 | 세라믹을 포함하는 성형물 제조방법 |
CN105130449B (zh) * | 2015-07-16 | 2017-08-01 | 深圳市商德先进陶瓷股份有限公司 | 陶瓷与塑料的复合件及其制备方法 |
CN110491720B (zh) * | 2019-03-04 | 2020-09-01 | 娄底市安地亚斯电子陶瓷有限公司 | 一种真空灭弧室及其制备方法和应用 |
CN110357649A (zh) * | 2019-07-05 | 2019-10-22 | 深圳陶陶科技有限公司 | 复合盖板及其制备方法和*** |
JP7462243B2 (ja) | 2020-07-22 | 2024-04-05 | パナソニックIpマネジメント株式会社 | 複合部材 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1033066A (zh) * | 1987-11-13 | 1989-05-24 | 浙江工学院 | 改性聚醋酸乙烯酯乳液 |
CN1022226C (zh) * | 1988-05-25 | 1993-09-29 | 泛塑料株式会社 | ***注模法 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3442845A (en) * | 1966-11-04 | 1969-05-06 | Borden Co | Hot and cold water redispersible polyvinyl acetate adhesives |
US3640791A (en) * | 1969-02-19 | 1972-02-08 | Richard Rosenheim | Process of preparing and applying an improved painting device |
JPS5342251A (en) * | 1976-09-30 | 1978-04-17 | Polyplastics Kk | Method of molding metallic insert |
US5190997A (en) * | 1985-07-10 | 1993-03-02 | Sequa Chemicals, Inc. | Adhesive composition |
US4957677A (en) * | 1987-12-09 | 1990-09-18 | Mitsubishi Yuka Badische Co., Ltd. | Process for producing composite laminate comprising insert part and injection-molded part |
JPH0691694A (ja) * | 1992-07-28 | 1994-04-05 | Nippon Zeon Co Ltd | 成形品とその製造方法 |
US6253655B1 (en) * | 1999-02-18 | 2001-07-03 | Simula, Inc. | Lightweight armor with a durable spall cover |
US6448313B1 (en) * | 2000-02-03 | 2002-09-10 | Henkel Corporation | Temporary protective coating compositions |
JP2003340965A (ja) * | 2002-05-24 | 2003-12-02 | Toppan Printing Co Ltd | 遮光性積層包装材料 |
JP4688411B2 (ja) | 2002-09-26 | 2011-05-25 | 日立化成工業株式会社 | 複合絶縁被膜 |
JP5093976B2 (ja) * | 2004-07-02 | 2012-12-12 | 日立オートモティブシステムズ株式会社 | 複数部材からなる部品の構造及びその製造方法 |
WO2007088736A1 (ja) * | 2006-01-31 | 2007-08-09 | Konica Minolta Opto, Inc. | セルロースエステルフィルム、光拡散フィルム、偏光板及び液晶表示装置 |
US8119048B2 (en) * | 2006-09-22 | 2012-02-21 | Nissha Printing Co., Ltd. | Housing case, method for manufacturing housing case, and glass insert molding die used in same |
CN102844884A (zh) | 2010-04-16 | 2012-12-26 | 旭硝子株式会社 | 太阳能电池模块用背板及太阳能电池模块 |
US8334335B2 (en) * | 2011-02-07 | 2012-12-18 | Nulabel Technologies, Inc. | Fluid activatable adhesives and fluids for activating same for use with liner-free labels |
JP2012245665A (ja) * | 2011-05-26 | 2012-12-13 | Nagase Chemtex Corp | 成形法 |
-
2012
- 2012-12-29 CN CN201210588212.7A patent/CN103895274B/zh not_active Expired - Fee Related
-
2013
- 2013-01-25 TW TW102102767A patent/TWI572482B/zh not_active IP Right Cessation
- 2013-04-17 US US13/864,652 patent/US9855722B2/en not_active Expired - Fee Related
- 2013-12-26 JP JP2013268865A patent/JP5956417B2/ja not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1033066A (zh) * | 1987-11-13 | 1989-05-24 | 浙江工学院 | 改性聚醋酸乙烯酯乳液 |
CN1022226C (zh) * | 1988-05-25 | 1993-09-29 | 泛塑料株式会社 | ***注模法 |
Also Published As
Publication number | Publication date |
---|---|
TWI572482B (zh) | 2017-03-01 |
TW201425019A (zh) | 2014-07-01 |
JP5956417B2 (ja) | 2016-07-27 |
JP2014128975A (ja) | 2014-07-10 |
CN103895274A (zh) | 2014-07-02 |
US20140186616A1 (en) | 2014-07-03 |
US9855722B2 (en) | 2018-01-02 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103895274B (zh) | 陶瓷与塑料的复合体及其制备方法 | |
US10427063B2 (en) | Method for the manufacture of a plastics product and a product made by the method | |
CN104827665B (zh) | 三维打印机的打印方法 | |
WO2009016321A3 (fr) | Composant moulé d'insonorisation, et son procédé de fabrication | |
WO2010144284A1 (en) | Hobby blocks including latently-adhesive surfaces | |
CN104325577A (zh) | 翻边模具、组合模具、成模材料的铺设方法及成模方法 | |
CN103935042A (zh) | 无人飞行器空心旋翼的制造方法及空心旋翼 | |
CN107872998A (zh) | 制造复合结构的方法 | |
CN102226446B (zh) | 一种兆瓦级风机叶片剪腹板及其辅助粘接角的制备方法 | |
CN106166811A (zh) | 一种硅胶模具的生产工艺 | |
CN105400443B (zh) | 一种热膨胀可剥离的压敏胶片材和涂布机 | |
CN110435187B (zh) | 一种lrtm模具及其制作方法 | |
CN108262995A (zh) | 叶片的制作方法及叶片 | |
CN107312482A (zh) | 珠宝首饰制作中环氧树脂ab胶的浇注方法 | |
CN102873816B (zh) | 一体化注塑成型胶水筛选方法 | |
KR100891964B1 (ko) | 점착성 수지가 부착된 흡착패드의 제조 방법 | |
CN100579770C (zh) | 竹制复合材料风力发电机叶片中碳管的制造工艺 | |
CN107000246A (zh) | 制造陶瓷涡轮叶片的工艺 | |
CN108453866B (zh) | 一种半封闭结构陶瓷素坯的制备装置及制备方法 | |
FR2943063A3 (fr) | Element de masse coule a froid | |
CN205443164U (zh) | 一种热膨胀可剥离的压敏胶片材的涂布机 | |
CN103826863A (zh) | 表面转印方法 | |
TWI378130B (zh) | ||
CN105111031A (zh) | 大型***件的脱模方法 | |
CN109719984B (zh) | 一种复合材质的鞋底合成工艺 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20170503 Termination date: 20191229 |