The partial volume screening method for group matching of cylindrical lithium battery
Technical field
The present invention relates to the manufacture method of lithium ion battery, particularly relate to the partial volume screening method for group matching of a kind of cylindrical lithium battery.
Background technology
Lithium ion battery is as environmental protection new forms of energy, and good reliability, safety is high, volume is little, lightweight, be widely used and progressively substitute existing plumbic acid and NI-G Ni-MH battery;Battery technique is more and more ripe, and it is the fiercest that the competition of each producer increasingly comes, and the concordance quality of battery combination is even more important for raising product quality, reduction production cost, and rational partial volume screening method for group matching can improve battery cyclic life-span and security performance.
Summary of the invention
It is an object of the invention to provide a kind of method of the group gas-mixing screening of a kind of capacity for battery, voltage, internal resistance, shorten the production cycle, saved the purpose of production cost and the energy for solving.
For achieving the above object, the technical solution used in the present invention is:
The partial volume screening method for group matching of a kind of cylindrical lithium battery, is characterized in that, the method is carried out in accordance with the following steps:
(1) cell first carries out appearance test, then goes up partial volume test cabinet, shelves;
(2) screening of self discharge voltage, individually indicates undesirable for the voltage undercarriage that carries out;
(3) then self-discharge capacity is screened, constant-current discharge, and electric current 0.5C is discharged to blanking voltage;In this work step, the battery capacity after constant-current discharge should be greater than indicating the 96% of lowest capacity section, and is individually indicated by the undesirable undercarriage that carries out;
(4) charge/discharge capacity screening: constant-current constant-voltage charging, electric current 0.5C, cut-off current 0.01C, charges to full power state and shelves;Constant-current discharge, electric current 0.5C, it is discharged to blanking voltage and shelves;Constant-current constant-voltage charging, electric current 0.5C, charge to half electricity condition;Require qualified battery capacity is carried out segmentation sign according to capacity combo, and carry out lay-down location reason.
Partial volume screening method for group matching according to described cylindrical lithium battery, it is characterized in that: will meet combo capacity required section and shelve complete battery by inner walkway instrument carries out voltage section on request, internal resistance section screen and indicated, the partial volume completing battery screens combo.
It is an advantage of the current invention that technological parameter arranges reasonable standard, shortens the production cycle, effectively saved production cost and the energy;The method is easy to operate, improve cycle performance and the security performance of set of cells, is suitable for batch production, not only ensure that product quality requirement, and cell process test is provided foundation.
Detailed description of the invention
Below by specific embodiment, the invention will be further described:
The partial volume screening method for group matching of a kind of cylindrical lithium battery, is characterized in that, the method is carried out in accordance with the following steps:
(1) cell first carries out appearance test, then goes up partial volume test cabinet, shelves;
(2) screening of self discharge voltage, individually indicates undesirable for the voltage undercarriage that carries out;
(3) then self-discharge capacity is screened, constant-current discharge, and electric current 0.5C is discharged to blanking voltage;In this work step, the battery capacity after constant-current discharge should be greater than indicating the 96% of lowest capacity section, and is individually indicated by the undesirable undercarriage that carries out;
(4) charge/discharge capacity screening: constant-current constant-voltage charging, electric current 0.5C, cut-off current 0.01C, charges to full power state and shelves;Constant-current discharge, electric current 0.5C, it is discharged to blanking voltage and shelves;Constant-current constant-voltage charging, electric current 0.5C, charge to half electricity condition;Require qualified battery capacity is carried out segmentation sign according to capacity combo, and carry out lay-down location reason.
The partial volume screening method for group matching of a kind of cylindrical lithium battery according to claim 1, it is characterized in that: will meet combo capacity required section and shelve complete battery by inner walkway instrument carries out voltage section on request, internal resistance section screen and indicated, the partial volume completing battery screens combo.
Case study on implementation: a kind of 36V12Ah(18650-1500mAh-3.2V 12 goes here and there 8 also) the partial volume screening method for group matching step of cylindrical lithium battery is as follows,
Cell first carries out appearance test, then goes up partial volume test cabinet, and capacity partial volume work step is as follows:
1. shelve 5min;Monomer battery voltage is qualified between 3.33-3.40V;
2. constant-current discharge: electric current 0.5C, blanking voltage 2.5V;Capacity >=1440mAh is qualified;
3. shelve 5min;
4. constant-current constant-voltage charging: electric current 0.5C, charging upper limit voltage 3.65V, cut-off current 0.01C, charging interval 180min;
5. shelve 5min;
6. constant-current discharge: electric current 0.5C, blanking voltage 2.5V;
7. shelve 5min;
8. constant-current constant-voltage charging: electric current 0.5C, charging upper limit voltage 3.65V, charging interval 100min;
9. terminate;
Be battery actual capacity by partial volume work step 6 discharge capacity, according to combo, undercarriage also requires that carrying out every capacity section segmentation within capacity stepping, such as capacity difference 30mAh indicates;30mAh capacity difference 1480-1510mAh, 1510-1540mAh etc..
10. shelve;By battery normal temperature shelf 3*24h complete for capacity stepping, carry out voltage, internal resistance screening combo;
11. internal resistance test device test unit cell voltages, internal resistance also indicate: voltage request at 3.33-3.40V, such as voltage difference 20mV, such as: 3.33-3.34V, 3.35-3.36V;Internal resistance < 60m Ω;Such as internal resistance difference 3m Ω, such as: 37-39m Ω, 40-42m Ω;
According to 36V12Ah(18650-1500mAh-3.2V 12 go here and there 8 and) 12*8=96 props up that battery combo requires that voltage difference, internal resistance be poor, capacity difference is all in the range of same shelves;As: 96 monomer battery voltage scopes are all at 3.35-3.36V;Internal resistance scope is at 37-39m Ω;Range of capacity is in 1510-1540mAh.
Present invention process parameter arranges reasonable standard, has effectively saved production cost and the energy;The method is easy to operate, improve combo concordance, cycle performance and the security performance of set of cells, is suitable for batch production, not only ensure that product quality requirement, and cell process test is provided foundation.
Embodiment described above is only to be described the preferred embodiment of the present invention; not design and protection domain to the present invention are defined; on the premise of without departing from design concept of the present invention; various modification that in this area, technical scheme is made by ordinary skill technical staff and improvement, all should fall into protection scope of the present invention.