CN1038919A - A kind of new liuyangmycin class complex preparation - Google Patents
A kind of new liuyangmycin class complex preparation Download PDFInfo
- Publication number
- CN1038919A CN1038919A CN 88105541 CN88105541A CN1038919A CN 1038919 A CN1038919 A CN 1038919A CN 88105541 CN88105541 CN 88105541 CN 88105541 A CN88105541 A CN 88105541A CN 1038919 A CN1038919 A CN 1038919A
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- CN
- China
- Prior art keywords
- complex preparation
- liuyangmycin
- macro tetrolide
- triphenyl
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
The invention provides a kind of is farm killing mite, the insecticidal complex preparation of active ingredient with macro tetrolide (macro tetrolide) class antibiotic and triphenyl phosphate or triphenyl phosphite, said preparation is not only to people and animals, natural enemy insect safety, non-environmental-pollution effect, and with low cost, effect is remarkable, provides a good model for using public nuisance-free agricultural chemicals.
Description
The present invention is for having following chemical structural formula
(R in the formula
1, R
2, R
3And R
4Be low alkyl group) macro tetrolide (macro tetrolide) class antibiotic and a kind of complex preparation of non-chemical pesticide.
Antibiotic shown in the said structure formula can produce the slightly variant stereoisomers in some resonable chemical property aspect because of the difference of its manufacture method, extraction process for purification.But since these isomeric compounds kill mite, insecticidal activity Fang Mian And does not have very big-difference, so generally can be considered same substance.In the present invention, also above-mentioned isomeric compound is considered as same substance.
In the past, with agricultural chemicals mixing uses different more than two kinds, majority was in order to reduce the medication number of times, to save the labour.Develop increasing, as to have synergistic effect complex preparation afterwards gradually, but still be confined to composite between the agricultural chemicals mostly.Being re-dubbed the preparation with certain synergistic effect with liuyangmycin antibiotics (being designated hereinafter simply as macro tetrolide) and multiple organophosphorous pesticide (clear 45-71417), organo-chlorine pesticide (clear 48-24726), carbamate chemicals for agriculture (clear 48-25488) also once had repeatedly report, still belonged to the first time but be re-dubbed the preparation with notable synergistic effect with non-chemical pesticide and macro tetrolide as described in the present invention.
The object of the present invention is to provide a kind of farm killing mite, disinsection compound preparation that does not contain chemical pesticide,, reduce environmental pollution with the progressively use of substituting chemical pesticide.
Below just the present invention be elaborated.
Macro tetrolide is almost non-toxic to warm blooded animal, also do not have the teratogenesis carcinogenesis, and triphenyl phosphate and triphenyl phosphite is also lower than macro tetrolide to the toxicity of warm blooded animal, and non-stimulated to skin, and The book of Changes skin does not absorb.
Macro tetrolide and triphenyl phosphate or triphenyl phosphite are carried out composite respectively with 1: 1 to 1: 7 Different Weight ratio, the result all has synergistic effect in various degree, is the best with 1: 3 especially wherein.
With macro tetrolide (industrial goods, content are 88.7%) and triphenyl phosphate (chemical pure) is reagent agent, two spotted spider mite is carried out coefficient of synergism measure, and the result is as shown in table 2.
*LC
50It is 50% lethal concentration
Coefficient of synergism=(macro tetrolide LC
50)/(macro tetrolide+triphenyl phosphate LC
50)=14.07
Compound formulation of the present invention can be used purpose and needs are mixed with various preparations according to different, and is wherein comparatively commonly used with emulsion especially.
Used solvent can be benzene, toluene or dimethylbenzene during preparation emulsion.Emulsifier can select to use 0201,0203 or 0204.
Complex preparation of the present invention is made comparisons with medicaments such as the compound macro tetrolide that contains chemical pesticide (complex preparation of macro tetrolide and Rogor) commonly used, dicofols at the described ， And of the following tabulation of test of pesticide effectiveness effect that kills on mite, the desinsection.
In sum, the new complex preparation of liuyangmycin antibiotics provided by the present invention does not only contain chemical pesticide, to people and animals and natural enemy insect safety, non-environmental-pollution danger, can be widely used in edible and medicinal crop, and kill mite insecticidal effect brilliance, residual effect is long, is difficult for bringing out resistance, low price.Complex preparation of the present invention provides a good model for using public nuisance-free agricultural chemicals.
The prescription of embodiment 1 20% macro tetrolide, triphenyl phosphate emulsion
Macro tetrolide 5%
Triphenyl phosphate 15%
Dimethylbenzene 70%
0201 emulsifier 10%
The prescription of embodiment 2 40% macro tetrolides, triphenyl phosphite emulsion
Macro tetrolide 10%
Triphenyl phosphite 30%
Dimethylbenzene 50%
0201 emulsifier 10%
Claims (3)
1, a kind of general expression is
(R in the formula
1, R
2, R
3And R
4Be low alkyl group) macro tetrolide (macrotetrolide) class antibiotic and the complex preparation of other compounds, it is characterized in that described other compounds are triphenyl phosphate or triphenyl phosphite.
2, complex preparation as claimed in claim 1, the weight ratio that it is characterized in that liuyangmycin antibiotics and triphenyl phosphate or triphenyl phosphite were the best with 1: 3 wherein between 1: 1 to 1: 7.
3, a kind of agriculture and garden is characterized in that with killing mite, insecticide contained effective ingredient is the compound of liuyangmycin antibiotics and triphenyl phosphate or triphenyl phosphite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 88105541 CN1026207C (en) | 1988-07-02 | 1988-07-02 | Compound preparation of novel liuyangmeisu (Macro tetrolide ) |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 88105541 CN1026207C (en) | 1988-07-02 | 1988-07-02 | Compound preparation of novel liuyangmeisu (Macro tetrolide ) |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1038919A true CN1038919A (en) | 1990-01-24 |
| CN1026207C CN1026207C (en) | 1994-10-19 |
Family
ID=4833722
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 88105541 Expired - Fee Related CN1026207C (en) | 1988-07-02 | 1988-07-02 | Compound preparation of novel liuyangmeisu (Macro tetrolide ) |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1026207C (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102911227A (en) * | 2008-09-27 | 2013-02-06 | 上海市农药研究所 | Streptomyces diastatochromogenes and fermentation product as well as application thereof |
| CN104322518A (en) * | 2014-11-14 | 2015-02-04 | 济南新起点医药科技有限公司 | Wettable powder containing flucythrinate and application |
| CN104322517A (en) * | 2014-11-14 | 2015-02-04 | 济南新起点医药科技有限公司 | Wettable powder containing ethofenprox and application |
| CN104351240A (en) * | 2014-11-14 | 2015-02-18 | 济南新起点医药科技有限公司 | Cyfluthrin-containing composition and application thereof |
| CN104351220A (en) * | 2014-11-14 | 2015-02-18 | 济南新起点医药科技有限公司 | Brofluthrinate-containing composition and application thereof |
-
1988
- 1988-07-02 CN CN 88105541 patent/CN1026207C/en not_active Expired - Fee Related
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102911227A (en) * | 2008-09-27 | 2013-02-06 | 上海市农药研究所 | Streptomyces diastatochromogenes and fermentation product as well as application thereof |
| CN102911227B (en) * | 2008-09-27 | 2015-08-12 | 上海市农药研究所 | A kind of streptomyces diastatochromogenes, its tunning and application |
| CN104322518A (en) * | 2014-11-14 | 2015-02-04 | 济南新起点医药科技有限公司 | Wettable powder containing flucythrinate and application |
| CN104322517A (en) * | 2014-11-14 | 2015-02-04 | 济南新起点医药科技有限公司 | Wettable powder containing ethofenprox and application |
| CN104351240A (en) * | 2014-11-14 | 2015-02-18 | 济南新起点医药科技有限公司 | Cyfluthrin-containing composition and application thereof |
| CN104351220A (en) * | 2014-11-14 | 2015-02-18 | 济南新起点医药科技有限公司 | Brofluthrinate-containing composition and application thereof |
| CN104322518B (en) * | 2014-11-14 | 2016-02-24 | 徐桂香 | A kind of wetting powder and application containing flucythrinate |
| CN104322517B (en) * | 2014-11-14 | 2016-04-13 | 济南新起点医药科技有限公司 | A kind of wetting powder and application containing ether chrysanthemum ester |
| CN104351220B (en) * | 2014-11-14 | 2016-04-13 | 济南新起点医药科技有限公司 | A kind of composition and application containing brofluthrinate |
| CN104351240B (en) * | 2014-11-14 | 2016-08-24 | 青岛青知企业管理咨询有限公司 | A kind of composition containing cyfloxylate and application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1026207C (en) | 1994-10-19 |
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