CN103884796B - 一种混合型饲料添加剂中总丙酸含量检测方法 - Google Patents
一种混合型饲料添加剂中总丙酸含量检测方法 Download PDFInfo
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- CN103884796B CN103884796B CN201410135214.XA CN201410135214A CN103884796B CN 103884796 B CN103884796 B CN 103884796B CN 201410135214 A CN201410135214 A CN 201410135214A CN 103884796 B CN103884796 B CN 103884796B
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- propionic acid
- propionate
- concentration
- peak area
- detected sample
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- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 title claims abstract description 386
- 235000019260 propionic acid Nutrition 0.000 title claims abstract description 192
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 title claims abstract description 192
- 238000000034 method Methods 0.000 title claims abstract description 25
- 239000003674 animal food additive Substances 0.000 title abstract description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 47
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims abstract description 47
- 239000000706 filtrate Substances 0.000 claims abstract description 24
- 238000001514 detection method Methods 0.000 claims abstract description 19
- 238000012937 correction Methods 0.000 claims abstract description 13
- 239000012528 membrane Substances 0.000 claims abstract description 10
- 150000001875 compounds Chemical class 0.000 claims description 36
- 239000000243 solution Substances 0.000 claims description 32
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 26
- 239000002671 adjuvant Substances 0.000 claims description 17
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims description 16
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 claims description 16
- 239000006228 supernatant Substances 0.000 claims description 15
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 13
- 235000019253 formic acid Nutrition 0.000 claims description 13
- 235000019441 ethanol Nutrition 0.000 claims description 12
- 239000000284 extract Substances 0.000 claims description 12
- 239000012086 standard solution Substances 0.000 claims description 12
- 239000012224 working solution Substances 0.000 claims description 11
- XJMWHXZUIGHOBA-UHFFFAOYSA-N azane;propanoic acid Chemical compound N.CCC(O)=O XJMWHXZUIGHOBA-UHFFFAOYSA-N 0.000 claims description 9
- 238000003965 capillary gas chromatography Methods 0.000 claims description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 125000005909 ethyl alcohol group Chemical group 0.000 claims description 8
- 238000002347 injection Methods 0.000 claims description 5
- 239000007924 injection Substances 0.000 claims description 5
- 229910021529 ammonia Inorganic materials 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 235000012239 silicon dioxide Nutrition 0.000 claims description 4
- 229910052902 vermiculite Inorganic materials 0.000 claims description 4
- 239000010455 vermiculite Substances 0.000 claims description 4
- 235000019354 vermiculite Nutrition 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 230000020477 pH reduction Effects 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 239000003153 chemical reaction reagent Substances 0.000 abstract description 4
- 238000004587 chromatography analysis Methods 0.000 abstract description 3
- 239000011259 mixed solution Substances 0.000 abstract description 3
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- 238000001914 filtration Methods 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 1
- 239000000523 sample Substances 0.000 description 48
- 238000012360 testing method Methods 0.000 description 10
- 230000003449 preventive effect Effects 0.000 description 8
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 4
- 238000002203 pretreatment Methods 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- BCZXFFBUYPCTSJ-UHFFFAOYSA-L Calcium propionate Chemical compound [Ca+2].CCC([O-])=O.CCC([O-])=O BCZXFFBUYPCTSJ-UHFFFAOYSA-L 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 235000010331 calcium propionate Nutrition 0.000 description 3
- 239000004330 calcium propionate Substances 0.000 description 3
- 238000010812 external standard method Methods 0.000 description 3
- 238000010813 internal standard method Methods 0.000 description 3
- BWILYWWHXDGKQA-UHFFFAOYSA-M potassium propanoate Chemical compound [K+].CCC([O-])=O BWILYWWHXDGKQA-UHFFFAOYSA-M 0.000 description 3
- 235000010332 potassium propionate Nutrition 0.000 description 3
- 239000004331 potassium propionate Substances 0.000 description 3
- 239000012488 sample solution Substances 0.000 description 3
- JXKPEJDQGNYQSM-UHFFFAOYSA-M sodium propionate Chemical compound [Na+].CCC([O-])=O JXKPEJDQGNYQSM-UHFFFAOYSA-M 0.000 description 3
- 235000010334 sodium propionate Nutrition 0.000 description 3
- 239000004324 sodium propionate Substances 0.000 description 3
- 229960003212 sodium propionate Drugs 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 238000003822 preparative gas chromatography Methods 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
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CN107367420B (zh) * | 2017-07-13 | 2020-10-30 | 广州品悦生物科技有限公司 | 一种快速联合定量测定丙酸及丙酸铵的方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10134658A1 (de) * | 2001-07-20 | 2003-02-06 | Schmack Biogas Ag | Methode zur VFA Bestimmung in anaeroben Fermentaten |
CN101650347A (zh) * | 2009-09-15 | 2010-02-17 | 安徽泰格生物技术股份有限公司 | 一种同时测定饲用酸化剂中多种有机酸含量的方法 |
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2014
- 2014-04-04 CN CN201410135214.XA patent/CN103884796B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10134658A1 (de) * | 2001-07-20 | 2003-02-06 | Schmack Biogas Ag | Methode zur VFA Bestimmung in anaeroben Fermentaten |
CN101650347A (zh) * | 2009-09-15 | 2010-02-17 | 安徽泰格生物技术股份有限公司 | 一种同时测定饲用酸化剂中多种有机酸含量的方法 |
Non-Patent Citations (5)
Title |
---|
Determination of propionates and propionic acid in bakery products using gas chromatography;1Khaldun M. Al Azzam. 等;《International Food Research Journal》;20101231;第17卷;第1107-1112页 * |
毛细柱气相色谱法测定饲料中的丙酸及丙酸盐;杨晓凤 等;《中国饲料》;20140105(第1期);第39-40+44页 * |
毛细管气相色谱内标法测定防霉剂中丙酸;张凤枰 等;《分析测试技术与仪器》;20070331;第13卷(第1期);第67-70页 * |
气相色谱-质谱法测定腌渍蔬菜中的丙酸及其应用;郝鹏飞 等;《食品研究与开发》;20131231;第34卷(第23期);第98-100页 * |
甲酸萃取-气相色谱测定食品中的丙酸盐防腐剂;梁瑞娥 等;《河北轻化工学院学报》;19910302(第1期);第17-20页 * |
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Address after: 400063 Mintai Road, Jiguan Shilong Industrial Park, Nanan District, Chongqing Patentee after: CHONGQING MINTAI NEW AGROTECH DEVELOPMENT GROUP Co.,Ltd. Address before: 400063 Mintai Road, Jiguan Shilong Industrial Park, Nanan District, Chongqing Patentee before: CHONGQING MINTAI FLAVOR CHEMICAL CO.,LTD. |
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Denomination of invention: A method for determination of total propionic acid in mixed feed additives Effective date of registration: 20210219 Granted publication date: 20150624 Pledgee: Chongqing Branch of China Everbright Bank Co.,Ltd. Pledgor: CHONGQING MINTAI NEW AGROTECH DEVELOPMENT GROUP Co.,Ltd. Registration number: Y2021500000005 |
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Date of cancellation: 20220307 Granted publication date: 20150624 Pledgee: Chongqing Branch of China Everbright Bank Co.,Ltd. Pledgor: CHONGQING MINTAI NEW AGROTECH DEVELOPMENT GROUP Co.,Ltd. Registration number: Y2021500000005 |
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Denomination of invention: A method for detecting the total propionic acid content in a mixed feed additive Granted publication date: 20150624 Pledgee: Chongqing Branch of China Everbright Bank Co.,Ltd. Pledgor: CHONGQING MINTAI NEW AGROTECH DEVELOPMENT GROUP Co.,Ltd. Registration number: Y2024500000032 |
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