CN103875704A - Pesticide granules containing clothianidin and diazinon - Google Patents
Pesticide granules containing clothianidin and diazinon Download PDFInfo
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- CN103875704A CN103875704A CN201410101190.6A CN201410101190A CN103875704A CN 103875704 A CN103875704 A CN 103875704A CN 201410101190 A CN201410101190 A CN 201410101190A CN 103875704 A CN103875704 A CN 103875704A
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- diazinon
- clothianidin
- pesticide
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- pesticide granules
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Abstract
The invention relates to pesticide granules containing clothianidin and diazinon. The effective component is compounded from clothianidin and diazinon in a weight ratio of 1:3:3:1. The granules have obvious compound synergistic effect, can postpone the drug resistance of the single agent, lower the pesticide consumption and save the input cost.
Description
Technical field
The present invention relates to spread fertilizer over the fields the technical field of Agro-chemicals control crop pest, specifically the granular pesticide of a kind of clothianidin-containing and diazinon.
Background technology
Diazinon belongs to organophosphorus insecticides, and it has the advantages such as wide spectrum, efficient, low toxicity, low-residual.Along with high-toxic pesticide thimet limits the use of it the reduction of soil insect preventive effect and nuisanceless production technology, diazinon succeeds in applying aspect the soil insects of the crops such as control wheat, corn, peanut, garlic and cabbage caterpillar, there is every year certain sales volume, but it is not smooth in the popularization that prevents and treats rice hoppers, rice leafhopper, striped rice borer and paddy stem borer, reason is that diazinon cost performance is not high, and there is no interior absorption, the lasting period is short; Aspect control soil insect, the current resistance of diazinon is also developing gradually.
Clothianidin belongs to anabasine insecticide, its highly effective and safe, selectivity is high, be mainly used on paddy rice, vegetables, fruit tree and other crops anti-ly eliminating aphis, Semiptera, coleoptera, diptera and some Lepidoptera class pest such as leafhopper, thrips, plant hopper, there is efficient, wide spectrum, consumption is few, toxicity is low, the drug effect lasting period long, to crop without poisoning, use the advantages such as safety, its novel structure is special, and performance is more excellent compared with traditional nicotinic insecticide.When clothianidin is alone, for part soil insect, as chafer, wireworm etc., effect is remarkable not.
Not yet retrieve at present the open source literature of diazinon and clothianidin compound synergic.
Summary of the invention
Technical problem to be solved by this invention is the defect existing for above-mentioned prior art, and the granular pesticide of the obvious clothianidin-containing of a kind of compound synergic and diazinon is provided.
The present invention solves the problems of the technologies described above taked technical scheme: the granular pesticide of a kind of clothianidin-containing and diazinon, active ingredient is made up of according to the weight ratio of 1:3-3:1 is composite clothianidin and diazinon.
Compared with prior art, compound synergic of the present invention is obvious, can delay the pesticide resistance that single dose is used, and reduces pesticide dosage, saves input cost.
Embodiment
By the following examples technical scheme of the present invention and beneficial effect are described further.
One, indoor joint toxicity measuring test
Clothianidin and diazinon are mixed and are made into binary built agent as No. 5, No. 1-mixture of mixture by active ingredient part by weight 5:1,3:1,1:1,1:3,1:5 respectively, by No. 5, clothianidin and two kinds of single doses of diazinon and No. 1-mixture of mixture from 10ppm according to 8 concentration of the each dilution of geometric ratio gradient, process as blank using clear water.
Laboratory test 1: taking cabbage caterpillar 3 instar larvaes as examination worm, adopt dip method measure, after 24 hours, investigate respectively dead borer population, calculate lethality, lethal in dense and co-toxicity coefficient.
Laboratory test 2: taking sugarcane moth borer 3 instar larvaes as examination worm, adopt dip method measure, after 48 hours, investigate respectively dead borer population, calculate lethality, lethal in dense and co-toxicity coefficient.
Laboratory test 3: taking Brown Planthopper nymph in 3 age as examination worm, adopt rice stem infusion process to measure, after 48 hours, investigate respectively dead borer population, calculate lethality, lethal in dense and co-toxicity coefficient.
The final statistics of above-mentioned three laboratory tests is as shown in the table:
The measurement result of indoor joint toxicity measuring test shows above, when clothianidin and diazinon mixed ratio are 5:1 and 1:5, the coefficient of spending together of cabbage caterpillar, sugarcane moth borer and rice fulgorid is all greater than 80 and is less than 120, performance summation action; And in the time of 3:1,1:1 and 1:3 proportioning, co-toxicity coefficient is all greater than 120, show obvious synergistic effect.
Two, product Preparation Example
Embodiment 1
0.5% clothianidin diazinon granule
Formula: clothianidin 0.25kg, diazinon 0.25kg, calcium lignosulfonate 2kg, lauryl sodium sulfate 2kg, polyvinyl alcohol 2kg, starch 1kg, kaolin complements to 100kg.
Embodiment 2
0.4% clothianidin diazinon granule
Formula: clothianidin 0.3kg, diazinon 0.1kg, sodium lignin sulfonate 2kg, naphthalenesulfonate formaldehyde condensation compound 2kg, lauryl sodium sulfate 2kg, starch 3kg, kaolin complements to 100kg.
Embodiment 3
0.6% clothianidin diazinon granule
Formula: clothianidin 0.15kg, diazinon 0.45kg, calcium lignosulfonate 2kg, naphthalenesulfonate formaldehyde condensation compound 2kg, lauryl sodium sulfate 2kg, polyvinyl alcohol 2kg, bentonite complements to 100kg.
Recipe ingredient described in above-described embodiment 1-3 is mixed, pulverize, stir after adding water-wet, then use screw extruder pelletizer granulation, sieve after dry and obtain the granule of clothianidin-containing and diazinon.
Three, product Application Example
Field experiment 1: embodiment 1-3 products obtained therefrom is carried out to the control of sugarcane moth borer, use in the time that sugarcane is sowed, carry out the sugarcane moth borer investigation of causing harm for after medicine 60 days.
Field experiment 2: embodiment 1-3 products obtained therefrom is carried out to the control of rice hoppers, use after 15 days after rice transplanting, the investigation of causing harm of rice fulgorid when outburst first round.
The final statistics of above-mentioned field experiment is as shown in the table:
As can be known from the above table, the product of the embodiment 1-embodiment 3 of gained of the present invention is all obviously better than clothianidin single dose and diazinon single dose for the preventive effect of sugarcane moth borer and rice fulgorid.
Claims (1)
1. a granular pesticide for clothianidin-containing and diazinon, is characterized in that, active ingredient is made up of according to the weight ratio of 1:3-3:1 is composite clothianidin and diazinon.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410101190.6A CN103875704A (en) | 2014-03-19 | 2014-03-19 | Pesticide granules containing clothianidin and diazinon |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410101190.6A CN103875704A (en) | 2014-03-19 | 2014-03-19 | Pesticide granules containing clothianidin and diazinon |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103875704A true CN103875704A (en) | 2014-06-25 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410101190.6A Pending CN103875704A (en) | 2014-03-19 | 2014-03-19 | Pesticide granules containing clothianidin and diazinon |
Country Status (1)
| Country | Link |
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| CN (1) | CN103875704A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104222145A (en) * | 2014-08-18 | 2014-12-24 | 广东中迅农科股份有限公司 | Insecticide composition containing clothianidin and diazinon |
| CN104255803A (en) * | 2014-09-23 | 2015-01-07 | 谢绪叶 | Pesticide granules containing clothianidin and diazinon |
| CN104286015A (en) * | 2014-09-10 | 2015-01-21 | 广东中迅农科股份有限公司 | Insecticidal composition containing thiamethoxam and diazinon |
| CN104304312A (en) * | 2014-09-15 | 2015-01-28 | 广东中迅农科股份有限公司 | Methylaminoavermectin-diazinon particles |
| CN104430497A (en) * | 2014-12-03 | 2015-03-25 | 联保作物科技有限公司 | Insecticide composition as well as application and preparation thereof |
| CN108684703A (en) * | 2018-04-03 | 2018-10-23 | 瑞隆化工（宿州）有限公司 | A kind of compounding granule containing diazinon, phoxim |
| CN109892337A (en) * | 2017-12-08 | 2019-06-18 | 段绕绕 | A kind of insecticide pesticide formula |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002114612A (en) * | 2000-10-06 | 2002-04-16 | Nippon Nohyaku Co Ltd | Paddy agrochemical composition and method for using the same |
| CN1646017A (en) * | 2002-01-31 | 2005-07-27 | 拜尔农作物科学股份公司 | Synergistic insecticidal mixtures |
| CN103348971A (en) * | 2013-07-31 | 2013-10-16 | 河北博嘉农业有限公司 | Film-spreading oil agent capable of preventing and curing rice planthopper |
| CN103355287A (en) * | 2013-07-30 | 2013-10-23 | 河北博嘉农业有限公司 | Spreading oil for controlling Lissorhoptrus oryzophilus Kuschel |
-
2014
- 2014-03-19 CN CN201410101190.6A patent/CN103875704A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002114612A (en) * | 2000-10-06 | 2002-04-16 | Nippon Nohyaku Co Ltd | Paddy agrochemical composition and method for using the same |
| CN1646017A (en) * | 2002-01-31 | 2005-07-27 | 拜尔农作物科学股份公司 | Synergistic insecticidal mixtures |
| CN103355287A (en) * | 2013-07-30 | 2013-10-23 | 河北博嘉农业有限公司 | Spreading oil for controlling Lissorhoptrus oryzophilus Kuschel |
| CN103348971A (en) * | 2013-07-31 | 2013-10-16 | 河北博嘉农业有限公司 | Film-spreading oil agent capable of preventing and curing rice planthopper |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104222145A (en) * | 2014-08-18 | 2014-12-24 | 广东中迅农科股份有限公司 | Insecticide composition containing clothianidin and diazinon |
| CN104286015A (en) * | 2014-09-10 | 2015-01-21 | 广东中迅农科股份有限公司 | Insecticidal composition containing thiamethoxam and diazinon |
| CN104304312A (en) * | 2014-09-15 | 2015-01-28 | 广东中迅农科股份有限公司 | Methylaminoavermectin-diazinon particles |
| CN104255803A (en) * | 2014-09-23 | 2015-01-07 | 谢绪叶 | Pesticide granules containing clothianidin and diazinon |
| CN104430497A (en) * | 2014-12-03 | 2015-03-25 | 联保作物科技有限公司 | Insecticide composition as well as application and preparation thereof |
| CN109892337A (en) * | 2017-12-08 | 2019-06-18 | 段绕绕 | A kind of insecticide pesticide formula |
| CN108684703A (en) * | 2018-04-03 | 2018-10-23 | 瑞隆化工（宿州）有限公司 | A kind of compounding granule containing diazinon, phoxim |
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Application publication date: 20140625 |