CN103864381A - Cement-based inorganic anchor adhesive and preparation method thereof - Google Patents

Cement-based inorganic anchor adhesive and preparation method thereof Download PDF

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CN103864381A
CN103864381A CN201410105520.9A CN201410105520A CN103864381A CN 103864381 A CN103864381 A CN 103864381A CN 201410105520 A CN201410105520 A CN 201410105520A CN 103864381 A CN103864381 A CN 103864381A
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cement
anchoring adhesive
base inorganic
cement base
inorganic anchoring
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CN103864381B (en
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陈明中
王鸿博
黄坤耀
刘明长
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SHANGHAI FAN'OU BUILDING MATERIAL CO Ltd
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SHANGHAI FAN'OU BUILDING MATERIAL CO Ltd
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Abstract

The invention discloses a cement-based inorganic anchor adhesive. The cement-based inorganic anchor adhesive comprises the following components by mass percent: portland cement, minimum inflation special cement, a volcanic ash material, a super plasticizer, a retarder, a defoaming agent, a water-proofing agent, an antifreezing agent, a corrosion inhibitor and quartz sand. As a high-tech environment-friendly material, the inorganic anchor adhesive has characteristics of ultra high strength, high temperature resistance, antifatigue and very strong durability, can be directly welded, is suitable for operating in water environment, and can be widely used for maintaining buildings and planting a rebar and a bolt in reinforcing. The inorganic anchor adhesive has wider application range, and solves multiple bottleneck problems in anchoring industry, so that the construction operation is not limited by factors like environment any more, construction efficiency and rate are greatly improved, and the engineering cost is lowered.

Description

A kind of cement base inorganic anchoring adhesive and preparation method thereof
Technical field
The invention belongs to building structure strengthening Material Field, relate to the anchoring material that a kind of bar planting is used, specifically a kind of cement base inorganic anchoring adhesive and preparation method thereof.
Background technology
Anchoring adhesive is that in reinforcing, application is comparatively extensive in building structure, and anchoring adhesive is divided into inorganic anchoring adhesive, organic anchoring adhesive conventionally.The bonding reinforcement material of building structure that organic anchoring adhesive is made up of synthetic resins, packing material and chemical assistant.There is the features such as anchor force is strong, construct simple and direct, the cost of material is low, erosion resistance, be applicable to the reinforcement of the connection of new and old buildings thing, reinforcement of building, Equipment Foundations anchoring and brick masonry building structure.The organic anchoring adhesive of main employing in the market, as like sharp obtaining, intelligent fish, Simpson's brand etc.Inorganic anchoring adhesive is made up of inorganic mineral micro mist and inorganic solidification agent aqueous solution two-pack.It is to utilize colloid chemistry, under the effect of the inorganic solidification agent aqueous solution, different active particles produce high efficiency ion-exchange, generate new inorganic bar planting adhesive material, be widely used in concrete, Steel Concrete, geotechnical engineering, house, bridge, tunnel, tunnel, mine, dam, oil well, ocean harbour, ocean platform etc.At present, the application of inorganic anchoring adhesive is not also widelyd popularize, and reason is that people lack understanding and the research to inorganic inserted bar glue material.
Make a concrete analysis of the difference of inorganic anchoring adhesive and organic anchoring adhesive below:
Stressed aspect: single from individual anchor force intensity, organic anchoring adhesive and inorganic anchoring adhesive are substantially suitable to Ribbed Bar bond stress, stressed from system, inorganic anchoring adhesive is better than organic anchoring adhesive, because inorganic anchoring adhesive and former modulus of elasticity of concrete and thermal expansivity are basically identical, the stressed cooperative transformation of system entirety before and after effectively having ensured to reinforce.
Weather resistance aspect: inorganic anchoring adhesive is better than organic anchoring adhesive.Testing circumstance: seawater, freeze-thaw cycle, thermal ageing, hydrothermal aging, 100 DEG C of high temperature.Inorganic anchoring adhesive is strength retention ratio >=100% under each testing circumstance condition, and organic anchoring adhesive strength retention ratio is between 15%~90%.
Practicality aspect: inorganic anchoring adhesive adds water and stirs and can use, construction effect, far above organic anchoring adhesive, has been avoided organic anchoring adhesive because of high-temperature stability and can not have been realized the defective workmanship that welding comes after first glue.
Economy aspect: inorganic anchoring adhesive asepsis environment-protecting, cheap, meet national economic development direction.
Concrete structure after reinforcing is for a long time in the severe environment in humidity or alternation of wetting and drying, and concrete structure reinforcement not only considers to reinforce security and the weather resistance of rear system, also should comply with society's developing direction substantially.In rear-anchorage inserted bar investigation of materials, should form by scientific and reasonable design inserted bar glue material, after novel inorganic anchoring adhesive, anchoring material arises at the historic moment.
Summary of the invention
The object of the present invention is to provide a kind of cement base inorganic anchoring adhesive, this inorganic anchoring adhesive asepsis environment-protecting, good endurance, cheap, performance meets JGJ/T271-2012 " anchoring code after concrete structure engineering inorganic materials " requirement.
Another object of the present invention is to provide a kind of preparation method of cement base inorganic anchoring adhesive.
The present invention is achieved by the following technical solutions:
A kind of cement base inorganic anchoring adhesive, its composition comprises silicate cement, microdilatancy special cement, pozzolanic material, superplasticizer, retardant, defoamer, water-resisting agent, frostproofer, rust inhibitor, quartz sand, described each composition by mass percentage:
Figure BDA0000479497790000031
Preferably, described silicate cement is high early strength silicate cement.
Preferably, described microdilatancy special cement is quick hardening sulphoaluminate cement.
Preferably, described pozzolanic material is SiO 2the activated grammite that effective content is greater than 90%.
Preferably, described superplasticizer is efficient polycarboxylate water-reducer.
Preferably, described retardant is boric acid or citric acid.
Preferably, described defoamer is organosilane defoamer.
Preferably, described water-resisting agent is Zinc Stearate, and described frostproofer is Sodium Nitrite.
Preferably, described rust inhibitor is inorganic alkaline material.
Preferably, described quartz sand is the 30-100 order quartz sand of particle diameter continuous distribution.
A kind of preparation method of cement base inorganic anchoring adhesive, comprise the steps: according to formula rate, be mixed and made into powder by each component mass percent, mixing can adopt artificial mixing or mechanically mixing, add again 13%~14% water of powder amount, adopt mechanical stirring mode that powder and water are stirred to colloidal and get final product bar planting.
Principle of the present invention: the concrete structure after reinforcing is for a long time in the stressed and various rugged environments in complexity, and anchoring adhesive must have good compatibility and matching with former concrete structure, the concrete structure shared external force that combines together before and after making to reinforce.The means that the present invention adopts are to adopt the raw material consistent with former concrete structure material performance, composite good inorganic anchoring adhesive and former concrete structure cohesive strength are high, play mould and thermal expansivity and former concrete structure is basic identical simultaneously, effectively ensured the globality of systems before and after reinforcing.
Anchoring adhesive must meet life requirement simultaneously, after ensureing to reinforce, concrete structure possesses long-term safe application performance, this inorganic anchoring adhesive belongs to pure inorganic materials, make its cohesive strength retention rate under various severe environmental conditions all more than 100%, effectively ensure the safety in utilization of system in various complex environments by various additive complexes.
Beneficial effect: inorganic anchoring adhesive of the present invention is as high-tech ep-type material, have superstrength, high temperature resistant, can directly weld, be applicable to water surrounding operation, antifatigue and the extremely strong feature of weather resistance, can be widely used in building maintenance, the plantation of reinforcing bar and bolt while reinforcing.Adopt inorganic anchoring adhesive of the present invention, subject range is wider, has solved many bottleneck problems of anchoring industry, thereby makes construction operation no longer be subject to the effects limit such as environment, has accelerated widely operating efficiency and speed, has reduced engineering cost simultaneously.
Embodiment
Below embodiments of the invention are elaborated: the present embodiment is implemented under taking technical solution of the present invention as prerequisite, provided detailed embodiment and concrete operating process, but protection scope of the present invention is not limited to following embodiment.
Embodiment 1:
A kind of cement base inorganic anchoring adhesive, its each composition mass percent is as follows:
Figure BDA0000479497790000041
Figure BDA0000479497790000051
Adopt above-mentioned raw materials mass percent to be mixed and made into powder, preparation method is as follows:
Mix and adopt artificial mixing, then add 13% water of powder amount, adopt mechanical stirring mode that powder and water are stirred to colloidal and get final product bar planting.
Embodiment 2:
A kind of cement base inorganic anchoring adhesive, its each composition mass percent is as follows:
Figure BDA0000479497790000052
Adopt above-mentioned raw materials mass percent to be mixed and made into powder, preparation method is as follows:
Mix and adopt mechanically mixing, then add 14% water of powder amount, adopt mechanical stirring mode that powder and water are stirred to colloidal and get final product bar planting.
According to the experimental technique of above two embodiment, select representative inorganic anchoring adhesive and organic anchoring adhesive sample as a comparison on market, under same condition construction, normal curing and testing method, obtain performance data as shown in table 1 below:
Table 1
Figure BDA0000479497790000062
Under same condition construction, different maintenance envrionment conditions, cohesive strength retention rate data are as shown in table 2 below:
Table 2
Figure BDA0000479497790000063
From table 1, table 2, inorganic anchoring adhesive meets JGJ/T271-2012 " anchoring code after concrete structure engineering inorganic materials " code requirement, compare with similar inorganic anchoring adhesive on market, inorganic anchoring adhesive of the present invention has the high microdilatancy advantage of cohesive strength, cohesive strength is substantially approaching compared with organic anchoring adhesive on market, but inorganic anchoring adhesive has compared with clear superiority aspect weather resistance.
That inorganic anchoring adhesive of the present invention has is high-strength, the advantage such as strong, volume stability, high temperature resistant, good endurance early, large to Ribbed Bar bond stress, superior fatigue resistance, can be widely used in the fixing of Bar Anchorage in the engineerings such as water conservancy and hydropower, road and bridge, tunnel and various device and steel construction; The inorganic anchoring adhesive that structural strengthening of the present invention is used not only can meet design requirement, and also has good system compatibility and endurance quality, and operating efficiency is high, is the ideal material that modern architecture is reinforced industry bar planting field.
More than show and described ultimate principle of the present invention and principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; that in above-described embodiment and specification sheets, describes just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.The claimed scope of the present invention is defined by appending claims and equivalent thereof.

Claims (10)

1. a cement base inorganic anchoring adhesive, it is characterized in that, its composition comprises silicate cement, microdilatancy special cement, pozzolanic material, superplasticizer, retardant, defoamer, water-resisting agent, frostproofer, rust inhibitor, quartz sand, described each composition by mass percentage:
2. a kind of cement base inorganic anchoring adhesive according to claim 1, is characterized in that, described silicate cement is high early strength silicate cement, and described microdilatancy special cement is quick hardening sulphoaluminate cement.
3. a kind of cement base inorganic anchoring adhesive according to claim 1, is characterized in that, described pozzolanic material is SiO 2the activated grammite that effective content is greater than 90%.
4. a kind of cement base inorganic anchoring adhesive according to claim 1, is characterized in that, described superplasticizer is efficient polycarboxylate water-reducer.
5. a kind of cement base inorganic anchoring adhesive according to claim 1, is characterized in that, described retardant is boric acid or citric acid.
6. a kind of cement base inorganic anchoring adhesive according to claim 1, is characterized in that, described defoamer is organosilane defoamer.
7. a kind of cement base inorganic anchoring adhesive according to claim 1, is characterized in that, described water-resisting agent is Zinc Stearate, and described frostproofer is Sodium Nitrite.
8. a kind of cement base inorganic anchoring adhesive according to claim 1, is characterized in that, described rust inhibitor is inorganic alkaline material.
9. a kind of cement base inorganic anchoring adhesive according to claim 1, is characterized in that, described quartz sand is the 30-100 order quartz sand of particle diameter continuous distribution.
10. the preparation method of a cement base inorganic anchoring adhesive as claimed in claim 1, it is characterized in that, comprise the steps: according to formula rate, be mixed and made into powder by each component mass percent, mixing can adopt artificial mixing or mechanically mixing, add again 13%~14% water of powder amount, adopt mechanical stirring mode that powder and water are stirred to colloidal and get final product bar planting.
CN201410105520.9A 2014-03-20 2014-03-20 A kind of cement base inorganic anchoring adhesive and preparation method thereof Expired - Fee Related CN103864381B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105604338A (en) * 2015-12-21 2016-05-25 中国铁道科学研究院铁道建筑研究所 Cement-based anchoring glue construction technology
CN106082804A (en) * 2016-06-12 2016-11-09 山东大元实业股份有限公司 A kind of Anchor Agent
CN106396604A (en) * 2016-08-31 2017-02-15 武汉理工大学 Aluminophosphate cement-based steel bar-embedded material and preparation method thereof
CN107324717A (en) * 2017-06-28 2017-11-07 常州市尚泽纺织品有限公司 A kind of inorganic anchoring adhesive and preparation method thereof
CN108726962A (en) * 2018-07-11 2018-11-02 江苏尼高科技有限公司 The inorganic anchoring adhesive of rapid-hardening and mortar depositing construction equipment

Citations (2)

* Cited by examiner, † Cited by third party
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CN101428996A (en) * 2008-11-27 2009-05-13 上海市建筑科学研究院(集团)有限公司 Inorganic rear-anchorage inserted bar glue material
CN102295446A (en) * 2011-06-16 2011-12-28 上海维固工程实业有限公司 High performance structure reinforcement mortar composition and preparation process thereof

Patent Citations (2)

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CN101428996A (en) * 2008-11-27 2009-05-13 上海市建筑科学研究院(集团)有限公司 Inorganic rear-anchorage inserted bar glue material
CN102295446A (en) * 2011-06-16 2011-12-28 上海维固工程实业有限公司 High performance structure reinforcement mortar composition and preparation process thereof

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105604338A (en) * 2015-12-21 2016-05-25 中国铁道科学研究院铁道建筑研究所 Cement-based anchoring glue construction technology
CN106082804A (en) * 2016-06-12 2016-11-09 山东大元实业股份有限公司 A kind of Anchor Agent
CN106082804B (en) * 2016-06-12 2018-05-08 山东大元实业股份有限公司 A kind of Anchor Agent
CN106396604A (en) * 2016-08-31 2017-02-15 武汉理工大学 Aluminophosphate cement-based steel bar-embedded material and preparation method thereof
CN107324717A (en) * 2017-06-28 2017-11-07 常州市尚泽纺织品有限公司 A kind of inorganic anchoring adhesive and preparation method thereof
CN108726962A (en) * 2018-07-11 2018-11-02 江苏尼高科技有限公司 The inorganic anchoring adhesive of rapid-hardening and mortar depositing construction equipment

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