CN103849058A - Coloring master batches for polyethylene and preparation method thereof - Google Patents
Coloring master batches for polyethylene and preparation method thereof Download PDFInfo
- Publication number
- CN103849058A CN103849058A CN201210594731.4A CN201210594731A CN103849058A CN 103849058 A CN103849058 A CN 103849058A CN 201210594731 A CN201210594731 A CN 201210594731A CN 103849058 A CN103849058 A CN 103849058A
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- batch
- pigment
- color master
- polyethylene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/017—Additives being an antistatic agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
Abstract
The invention discloses coloring master batches for polyethylene and a preparation method thereof. The coloring master batches for polyethylene disclosed by the invention comprise the following components in percentage by mass: 70%-90% of pigment, 10%-20% of polyethylene resin, 3%-5% of dispersant, 0.1%-1% of antioxidant and 0.1%-1% of antistatic agent. Compared with the prior art, the coloring master batches for polyethylene have the beneficial effects that the prepared coloring master batches for polyethylene are applied to coloring of polyethylene products, have the characteristics of good dispersibility, uniform coloring, high concentration, little dosage and no influence on the mechanical property of the polyethylene products, and are low in cost, easy to color, convenient to use and capable of saving production time and raw materials and the like.
Description
Technical field
The present invention relates to technical field of polymer materials, specifically a kind of for poly color master-batch and preparation method thereof.
Background technology
(PE) is cheap for polyethylene, and forming process is easy, and has many premium propertiess, thereby the huge market demand, wide application.Along with the development and application of plastics, increasing polyethylene products needs painted processing.Conventionally, polyethylene color method can be divided into: toner is painted, painted three kinds of the painted and Masterbatch of grain is drawn in dyeing.Toner is painted very simple, easily produces color dot, aberration is wayward, environmental pollution is larger shortcoming but exist.It is that pigment is mixed in plastic material that dyeing draws grain painted, and each plastic rubber material is all painted, so it is even to form goods colour stable, but damaged to a certain extent the mechanical property of goods, and cost is high, also needs to store a large amount of coloured raw materials.Masterbatch is painted is that pigment super quantity is attached in resin equably, thereby has greatly improved dispersing property and the coloration efficiency of pigment, has the advantages such as simple to operate, with low cost, environmentally safe.At present, the polyethylene color great majority of prior art are to use universal color master-batch, and its benefit is easy to use, but that shortcoming is the scope of universal color master-batch is very narrow and small, and technical indicator, economic benefit are also poor, are in particular in: the one, and the foresight of coloring effect is poor; The 2nd, may affect the physical strength of goods etc.; The 3rd, cost is relatively high.
Summary of the invention
The object of the present invention is to provide a kind of good dispersity, uniform coloring, addition is few, cost is low and do not affect goods physicals for poly color master-batch and preparation method thereof.
The technical solution adopted for the present invention to solve the technical problems is: for poly color master-batch, its component by mass percent proportioning is: pigment 70%～90%, polyvinyl resin 10%～20%, dispersion agent 3%～5%, oxidation inhibitor 0.1%～1%, static inhibitor 0.1%～1%.
Described pigment is mineral dye or pigment dyestuff, wherein, mineral dye can be selected from one or the arbitrary combination in titanium dioxide (titanium dioxide), carbon black, cadmium yellow, cadmium red, barba hispanica, chromoxide green, and pigment dyestuff can be selected from the one in azo pigment, phthalocyanine pigment and heterocycle pigment.
Described dispersion agent is the one in low molecular weight polyethylene wax, OP wax, Magnesium Stearate, calcium stearate.
Described oxidation inhibitor is the compound of polyphenol antioxidant 1010 and phosphite antioxidant 168.
Described static inhibitor is stearylamide, alkyl phosphate di-alcohol ammonium salt, glycerol monostearate or polyoxyethylene octylphenol ether.
The above-mentioned preparation method for poly color master-batch is: each component is prepared burden by weight proportion, then in high-speed mixer, mix 5～30 minutes, adopt again that twin screw extruder is extruded, after granulation, drying, pack and obtain of the present invention for poly color master-batch.
The invention has the beneficial effects as follows, compared with prior art, adopt the color master-batch prepared of the present invention to be applied to polyethylene products paintedly to there is good dispersity, uniform coloring, concentration is high, consumption is few and on polyethylene products mechanical property without features such as impacts, and cost is low, annesl is easy, easy to use, can save production time and raw material etc.
Embodiment
Further illustrate technical scheme of the present invention below in conjunction with specific embodiment.
Embodiment 1:
A kind of for poly color master-batch, its component by mass percent proportioning is: compound 0.5%, the stearylamide 0.5% of titanium dioxide (titanium dioxide) 80%, polyvinyl resin 15%, low molecular weight polyethylene wax 4%, polyphenol antioxidant 1010 and phosphite antioxidant 168.
Preparation method: each component is prepared burden by weight proportion, then in high-speed mixer, mixes 5～30 minutes, then adopt that twin screw extruder is extruded, after granulation, drying, pack and obtain of the present invention for poly color master-batch.
Embodiment 2:
A kind of for poly color master-batch, its component by mass percent proportioning is: compound 1%, the alkyl phosphate di-alcohol ammonium salt 1% of azo pigment 83%, polyvinyl resin 10%, OP wax 5%, polyphenol antioxidant 1010 and phosphite antioxidant 168.
Preparation method: each component is prepared burden by weight proportion, then in high-speed mixer, mixes 5～30 minutes, then adopt that twin screw extruder is extruded, after granulation, drying, pack and obtain of the present invention for poly color master-batch.
Embodiment 3:
A kind of for poly color master-batch, its component by mass percent proportioning is: compound 1%, the polyoxyethylene octylphenol ether 1% of carbon black 75%, polyvinyl resin 20%, low molecular weight polyethylene wax 3%, polyphenol antioxidant 1010 and phosphite antioxidant 168.
Preparation method: each component is prepared burden by weight proportion, then in high-speed mixer, mixes 5～30 minutes, then adopt that twin screw extruder is extruded, after granulation, drying, pack and obtain of the present invention for poly color master-batch.
Claims (6)
1. for a poly color master-batch, it is characterized in that, its component by mass percent proportioning is: pigment 70%～90%, polyvinyl resin 10%～20%, dispersion agent 3%～5%, oxidation inhibitor 0.1%～1%, static inhibitor 0.1%～1%.
2. according to claim 1 for poly color master-batch, it is characterized in that, described pigment is mineral dye or pigment dyestuff, wherein, mineral dye can be selected from one or the arbitrary combination in titanium dioxide (titanium dioxide), carbon black, cadmium yellow, cadmium red, barba hispanica, chromoxide green, and pigment dyestuff can be selected from the one in azo pigment, phthalocyanine pigment and heterocycle pigment.
3. according to claim 1ly it is characterized in that for poly color master-batch, described dispersion agent is the one in low molecular weight polyethylene wax, OP wax, Magnesium Stearate, calcium stearate.
4. according to claim 1ly it is characterized in that for poly color master-batch, described oxidation inhibitor is polyphenol antioxidant 1010 and the compound of phosphite antioxidant 168.
5. according to claim 1ly it is characterized in that for poly color master-batch, described static inhibitor is stearylamide, alkyl phosphate di-alcohol ammonium salt, glycerol monostearate or polyoxyethylene octylphenol ether.
6. the preparation method for poly color master-batch according to claim 1, it is characterized in that, comprise the following steps: each component is prepared burden by weight proportion, then in high-speed mixer, mix 5～30 minutes, adopt again that twin screw extruder is extruded, after granulation, drying, pack and obtain of the present invention for poly color master-batch.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210594731.4A CN103849058A (en) | 2012-12-04 | 2012-12-04 | Coloring master batches for polyethylene and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210594731.4A CN103849058A (en) | 2012-12-04 | 2012-12-04 | Coloring master batches for polyethylene and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103849058A true CN103849058A (en) | 2014-06-11 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210594731.4A Pending CN103849058A (en) | 2012-12-04 | 2012-12-04 | Coloring master batches for polyethylene and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103849058A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104558799A (en) * | 2014-12-22 | 2015-04-29 | 山东农业大学 | Special anti-ageing dimming green master batch for ginger greenhouse film and preparation method of special anti-ageing dimming green master batch |
| CN104558765A (en) * | 2014-12-22 | 2015-04-29 | 山东农业大学 | Special light-dimming green master batch for ginger mulching film and preparation method of master batch |
| CN105001494A (en) * | 2015-08-04 | 2015-10-28 | 苏州博云塑业有限公司 | Light-resistant color master batch |
| CN108485046A (en) * | 2018-03-23 | 2018-09-04 | 中山市大亮彩塑胶新材料有限公司 | A kind of bright white titanium dioxide color masterbatch composition |
| CN110591204A (en) * | 2019-09-28 | 2019-12-20 | 武汉鑫恒顺科技有限公司 | Antistatic weather-resistant anti-adhesion color master batch for PE (polyethylene) film |
| CN111662466A (en) * | 2020-06-23 | 2020-09-15 | 福建紫牛塑业科技有限责任公司 | Colorant pre-dispersion, preparation method and application thereof, and color master batch |
| CN111875862A (en) * | 2020-07-20 | 2020-11-03 | 余姚市和众塑料有限公司 | Color master batch special for floor heating pipe and preparation method thereof |
| CN113201178A (en) * | 2021-05-11 | 2021-08-03 | 林文丹 | Preparation method of carbon black master batch with improved antistatic capacity |
| CN113337023A (en) * | 2021-05-06 | 2021-09-03 | 淮安腾达色母有限公司 | Masterbatch production process for improving coloring uniformity of plastic masterbatch |
| CN115466449A (en) * | 2022-06-07 | 2022-12-13 | 赤途实业(上海)有限公司 | High-dispersibility polyethylene-based color master batch and preparation method and application thereof |
-
2012
- 2012-12-04 CN CN201210594731.4A patent/CN103849058A/en active Pending
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104558799A (en) * | 2014-12-22 | 2015-04-29 | 山东农业大学 | Special anti-ageing dimming green master batch for ginger greenhouse film and preparation method of special anti-ageing dimming green master batch |
| CN104558765A (en) * | 2014-12-22 | 2015-04-29 | 山东农业大学 | Special light-dimming green master batch for ginger mulching film and preparation method of master batch |
| CN104558765B (en) * | 2014-12-22 | 2016-10-05 | 山东农业大学 | Green master batch of the special light modulation of a kind of Rhizoma Zingiberis Recens mulch film and preparation method thereof |
| CN104558799B (en) * | 2014-12-22 | 2017-06-30 | 山东农业大学 | A kind of special green master batch of anti-aging light modulation of ginger canopy film and preparation method thereof |
| CN105001494A (en) * | 2015-08-04 | 2015-10-28 | 苏州博云塑业有限公司 | Light-resistant color master batch |
| CN108485046A (en) * | 2018-03-23 | 2018-09-04 | 中山市大亮彩塑胶新材料有限公司 | A kind of bright white titanium dioxide color masterbatch composition |
| CN110591204A (en) * | 2019-09-28 | 2019-12-20 | 武汉鑫恒顺科技有限公司 | Antistatic weather-resistant anti-adhesion color master batch for PE (polyethylene) film |
| CN111662466A (en) * | 2020-06-23 | 2020-09-15 | 福建紫牛塑业科技有限责任公司 | Colorant pre-dispersion, preparation method and application thereof, and color master batch |
| CN111875862A (en) * | 2020-07-20 | 2020-11-03 | 余姚市和众塑料有限公司 | Color master batch special for floor heating pipe and preparation method thereof |
| CN111875862B (en) * | 2020-07-20 | 2022-09-13 | 余姚市和众塑料有限公司 | Color master batch special for floor heating pipe and preparation method thereof |
| CN113337023A (en) * | 2021-05-06 | 2021-09-03 | 淮安腾达色母有限公司 | Masterbatch production process for improving coloring uniformity of plastic masterbatch |
| CN113201178A (en) * | 2021-05-11 | 2021-08-03 | 林文丹 | Preparation method of carbon black master batch with improved antistatic capacity |
| CN115466449A (en) * | 2022-06-07 | 2022-12-13 | 赤途实业(上海)有限公司 | High-dispersibility polyethylene-based color master batch and preparation method and application thereof |
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Application publication date: 20140611 |