CN103849032A - Antibacterial antistatic slippery polyethylene masterbatch and preparation method thereof - Google Patents

Antibacterial antistatic slippery polyethylene masterbatch and preparation method thereof Download PDF

Info

Publication number
CN103849032A
CN103849032A CN201210593902.1A CN201210593902A CN103849032A CN 103849032 A CN103849032 A CN 103849032A CN 201210593902 A CN201210593902 A CN 201210593902A CN 103849032 A CN103849032 A CN 103849032A
Authority
CN
China
Prior art keywords
polyethylene
agent
master batch
antistatic
smooth master
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201210593902.1A
Other languages
Chinese (zh)
Inventor
夏伟光
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao Sanli Zhongdemei Water Equipment Co Ltd
Original Assignee
Qingdao Sanli Zhongdemei Water Equipment Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qingdao Sanli Zhongdemei Water Equipment Co Ltd filed Critical Qingdao Sanli Zhongdemei Water Equipment Co Ltd
Priority to CN201210593902.1A priority Critical patent/CN103849032A/en
Publication of CN103849032A publication Critical patent/CN103849032A/en
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00—Making granules
    • B29B9/02—Making granules by dividing preformed material
    • B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/92—Measuring, controlling or regulating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/20—Carboxylic acid amides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/43—Compounds containing sulfur bound to nitrogen
    • C08K5/435—Sulfonamides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/9258—Velocity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/92704—Temperature
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/04—Antistatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses an antibacterial antistatic slippery polyethylene masterbatch and a preparation method thereof. The antibacterial antistatic slippery polyethylene masterbatch disclosed by the invention comprises the components in percentage by mass: 30-70% of carriers, 10-30% of a slipping agent, 5-15% of an antiblocking agent, 10-20% of an antistatic agent, 5-10% of an antibacterial agent, 1-3% of a dispersing agent, 0.5-2% of a coupling agent and 0-1% of other additives. Compared with the prior art, the antibacterial antistatic slippery polyethylene masterbatch is applied to a polyethylene film or film blowing products and has the characteristics of good antiblocking and slippery effects, lasting and stable antibacterial effect, excellent antistatic performance, favorable impact toughness, machinability and the like; in addition, the preparation method is convenient to use, simple in operation, convenient to increase the production efficiency and improve the production environment and relatively good in application prospect.

Description

Antistatic smooth master batch of polyethylene antibiotic and preparation method thereof
Technical field
The present invention relates to technical field of polymer materials, specifically antistatic smooth master batch of a kind of polyethylene antibiotic and preparation method thereof.
Background technology
Polyethylene (PE) has good chemical stability, paracentesis resistance, impact and environment friendly etc., be usually used in film or the blown film packing of the industries such as food, beverage, makeup, electronics, toy, printing, but poly smoothness is poor, and antistatic effect is bad.Simultaneously, along with the raising of people's living standard, the demand of antibacterial polyethylene products is also increased day by day, adding appropriate antiseptic-germicide can give polyethylene products certain antibacterial and sterilizing ability, but shortcoming is that anti-microbial property persistence is poor, but also may cause in production process owing to being subject to thermal response to make goods flavescence, variable color etc.
Summary of the invention
The object of the present invention is to provide a kind of anti-microbial property lasting stability, good, the smooth effect of antistatic property antistatic smooth master batch of polyethylene antibiotic good and easy to use and preparation method thereof that has.
The technical solution adopted for the present invention to solve the technical problems is: the antistatic smooth master batch of polyethylene antibiotic, its component by mass percent proportioning is: polyethylene 30%～70%, slipping agent 10%～30%, opening agent 5%～15%, static inhibitor 10%～20%, antiseptic-germicide 5%～10%, dispersion agent 1%～3%, coupling agent 0.5%～2%, other additive 0～1%.
Described slipping agent is a kind of in amine hydroxybenzene and erucicamide or both mixtures.
Described opening agent is the lightweight synthetic silica of particle diameter between 1～4 μ m.
Described static inhibitor is the one in fatty mono glyceride, fatty acid diglyceride or fatty acid polyglycol ester.
Described antiseptic-germicide is silver-ion antibiotic calcium phosphate or Sulfadiazine Silver.
Described dispersion agent is the one in polyethylene wax, oxidized polyethlene wax (EVA wax) or ethylene bis stearic acid amide (EBS).
Described coupling agent is silane coupling agent.
Other described additive is stablizer and colorant.
The preparation method of the above-mentioned antistatic smooth master batch of polyethylene antibiotic, comprises the following steps:
(1) each component is weighed up stand-by by weight ratio;
(2) add rotating speed in the high-speed mixer of 500～1500 revs/min opening agent and coupling agent, mix 3～5 minutes, in high-speed mixer, add again polyethylene, slipping agent, static inhibitor, antiseptic-germicide, dispersion agent and other additive, at 85 ℃～100 ℃ temperature, mix 5～15 minutes;
(3) the more above-mentioned material mixing is added to the abundant melt blending of twin screw extruder, melt temperature is controlled at 160 ℃～200 ℃, screw speed is 120～300 revs/min, shearing by twin screw extruder, mixing 10～15 minutes, then extrude, cooling, granulation, be drying to obtain the antistatic smooth master batch of polyethylene antibiotic of the present invention.
The invention has the beneficial effects as follows, compared with prior art, the smooth master batch of antibacterial antistatic that the present invention makes is applied in polyethylene film or blown film goods, there is the features such as the good and workability of effective, the antibacterial lasting stability of adhesion-resistant slippery, antistatic property excellence, impelling strength, and easy to use, simple to operate, be convenient to enhance productivity and improve production environment etc., there is good application prospect.
Embodiment
Further illustrate technical scheme of the present invention below in conjunction with specific embodiment.
Embodiment 1:
The antistatic smooth master batch of a kind of polyethylene antibiotic, its component by mass percent proportioning is: polyethylene 45%, amine hydroxybenzene 20%, opening agent 10%, fatty mono glyceride 15%, silver-ion antibiotic calcium phosphate 6%, polyethylene wax 2%, silane coupling agent 1.5%, other additive 0.5%, wherein, described opening agent is the lightweight synthetic silica of particle diameter between 1～4 μ m, and other described additive is stablizer and colorant.
Preparation method: (1) weighs up stand-by by each component by weight ratio; (2) add rotating speed in the high-speed mixer of 500～1500 revs/min opening agent and silane coupling agent, mix 3～5 minutes, in high-speed mixer, add again polyethylene, amine hydroxybenzene, fatty mono glyceride, silver-ion antibiotic calcium phosphate, polyethylene wax and other additive, at 85 ℃～100 ℃ temperature, mix 5～15 minutes; (3) the more above-mentioned material mixing is added to the abundant melt blending of twin screw extruder, melt temperature is controlled at 160 ℃～200 ℃, screw speed is 120～300 revs/min, shearing by twin screw extruder, mixing 10～15 minutes, then extrude, cooling, granulation, be drying to obtain the antistatic smooth master batch of polyethylene antibiotic of the present invention.
Embodiment 2:
The antistatic smooth master batch of a kind of polyethylene antibiotic, its component by mass percent proportioning is: polyethylene 63%, amine hydroxybenzene 10%, opening agent 5%, fatty acid diglyceride 10%, Sulfadiazine Silver 10%, oxidized polyethlene wax (EVA wax) 1%, silane coupling agent 0.5%, other additive 0.5%, wherein, described opening agent is the lightweight synthetic silica of particle diameter between 1～4 μ m, and other described additive is stablizer and colorant.
Preparation method: (1) weighs up stand-by by each component by weight ratio; (2) add rotating speed in the high-speed mixer of 500～1500 revs/min opening agent and silane coupling agent, mix 3～5 minutes, in high-speed mixer, add again polyethylene, amine hydroxybenzene, fatty acid diglyceride, Sulfadiazine Silver, oxidized polyethlene wax (EVA wax) and other additive, at 85 ℃～100 ℃ temperature, mix 5～15 minutes; (3) the more above-mentioned material mixing is added to the abundant melt blending of twin screw extruder, melt temperature is controlled at 160 ℃～200 ℃, screw speed is 120～300 revs/min, shearing by twin screw extruder, mixing 10～15 minutes, then extrude, cooling, granulation, be drying to obtain the antistatic smooth master batch of polyethylene antibiotic of the present invention.
Embodiment 3:
The antistatic smooth master batch of a kind of polyethylene antibiotic, its component by mass percent proportioning is: polyethylene 30%, erucicamide 30%, opening agent 15%, fatty acid polyglycol ester 10%, Sulfadiazine Silver 10%, ethylene bis stearic acid amide (EBS) 3%, silane coupling agent 2%, wherein, described opening agent is the lightweight synthetic silica of particle diameter between 1～4 μ m.
Preparation method: (1) weighs up stand-by by each component by weight ratio; (2) add rotating speed in the high-speed mixer of 500～1500 revs/min opening agent and silane coupling agent, mix 3～5 minutes, in high-speed mixer, add again polyethylene, erucicamide, fatty acid polyglycol ester, Sulfadiazine Silver and ethylene bis stearic acid amide (EBS), at 85 ℃～100 ℃ temperature, mix 5～15 minutes; (3) the more above-mentioned material mixing is added to the abundant melt blending of twin screw extruder, melt temperature is controlled at 160 ℃～200 ℃, screw speed is 120～300 revs/min, shearing by twin screw extruder, mixing 10～15 minutes, then extrude, cooling, granulation, be drying to obtain the antistatic smooth master batch of polyethylene antibiotic of the present invention.

Claims (9)

1. the antistatic smooth master batch of polyethylene antibiotic, it is characterized in that, its component by mass percent proportioning is: polyethylene 30%～70%, slipping agent 10%～30%, opening agent 5%～15%, static inhibitor 10%～20%, antiseptic-germicide 5%～10%, dispersion agent 1%～3%, coupling agent 0.5%～2%, other additive 0～1%.
2. the antistatic smooth master batch of polyethylene antibiotic according to claim 1, is characterized in that, described slipping agent is a kind of in amine hydroxybenzene and erucicamide or both mixtures.
3. the antistatic smooth master batch of polyethylene antibiotic according to claim 1, is characterized in that, described opening agent is the lightweight synthetic silica of particle diameter between 1～4 μ m.
4. the antistatic smooth master batch of polyethylene antibiotic according to claim 1, is characterized in that, described static inhibitor is the one in fatty mono glyceride, fatty acid diglyceride or fatty acid polyglycol ester.
5. the antistatic smooth master batch of polyethylene antibiotic according to claim 1, is characterized in that, described antiseptic-germicide is silver-ion antibiotic calcium phosphate or Sulfadiazine Silver.
6. the antistatic smooth master batch of polyethylene antibiotic according to claim 1, is characterized in that, described dispersion agent is the one in polyethylene wax, oxidized polyethlene wax (EVA wax) or ethylene bis stearic acid amide (EBS).
7. the antistatic smooth master batch of polyethylene antibiotic according to claim 1, is characterized in that, described coupling agent is silane coupling agent.
8. the antistatic smooth master batch of polyethylene antibiotic according to claim 1, is characterized in that, other described additive is stablizer and colorant.
9. the preparation method of the antistatic smooth master batch of polyethylene antibiotic according to claim 1, is characterized in that, comprises the following steps:
(1) each component is weighed up stand-by by weight ratio;
(2) add rotating speed in the high-speed mixer of 500～1500 revs/min opening agent and coupling agent, mix 3～5 minutes, in high-speed mixer, add again polyethylene, slipping agent, static inhibitor, antiseptic-germicide, dispersion agent and other additive, at 85 ℃～100 ℃ temperature, mix 5～15 minutes;
(3) the more above-mentioned material mixing is added to the abundant melt blending of twin screw extruder, melt temperature is controlled at 160 ℃～200 ℃, screw speed is 120～300 revs/min, shearing by twin screw extruder, mixing 10～15 minutes, then extrude, cooling, granulation, be drying to obtain the antistatic smooth master batch of polyethylene antibiotic of the present invention.
CN201210593902.1A 2012-12-04 2012-12-04 Antibacterial antistatic slippery polyethylene masterbatch and preparation method thereof Pending CN103849032A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201210593902.1A CN103849032A (en) 2012-12-04 2012-12-04 Antibacterial antistatic slippery polyethylene masterbatch and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201210593902.1A CN103849032A (en) 2012-12-04 2012-12-04 Antibacterial antistatic slippery polyethylene masterbatch and preparation method thereof

Publications (1)

Publication Number Publication Date
CN103849032A true CN103849032A (en) 2014-06-11

Family

ID=50857173

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201210593902.1A Pending CN103849032A (en) 2012-12-04 2012-12-04 Antibacterial antistatic slippery polyethylene masterbatch and preparation method thereof

Country Status (1)

Country Link
CN (1) CN103849032A (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104277291A (en) * 2014-09-24 2015-01-14 苏州博利迈新材料科技有限公司 Antistatic and antibacterial PE master batch and preparation method thereof
CN105037876A (en) * 2015-07-03 2015-11-11 中山火炬职业技术学院 Polyethylene heat sealing film slippery master batch for solvent-free compounding
CN105237852A (en) * 2015-10-27 2016-01-13 山东鲁燕色母粒有限公司 Novel antiblocking master batch and preparation method
CN106397921A (en) * 2016-09-12 2017-02-15 苏州清丰兴业塑胶有限公司 Opened polyethylene functional master batch
CN106832547A (en) * 2017-01-24 2017-06-13 上海维凯光电新材料有限公司 Opening slipping agent master batch and preparation method thereof
CN108192193A (en) * 2018-02-26 2018-06-22 上海福助工业有限公司 A kind of inorganic antibacterial PE films and preparation method thereof
CN108219258A (en) * 2017-12-29 2018-06-29 上海乘鹰新材料有限公司 Plastic film open agent masterbatch composition and preparation method thereof
CN113462076A (en) * 2021-07-01 2021-10-01 广东普赛夫聚合物有限公司 Antistatic smooth master batch for PP (polypropylene) film and preparation method thereof
CN114196117A (en) * 2022-01-12 2022-03-18 东莞市迪彩塑胶五金有限公司 Antistatic master batch suitable for low-humidity environment and preparation method thereof
CN115093798A (en) * 2022-07-14 2022-09-23 上海展通实业有限公司 Antibacterial and antistatic high-transparency polyethylene protective film and preparation method thereof
CN115725137A (en) * 2022-11-29 2023-03-03 金旸（厦门）新材料科技有限公司 High-efficiency low-haze opening smooth master batch for polyolefin film, preparation method of master batch and polyolefin film

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104277291A (en) * 2014-09-24 2015-01-14 苏州博利迈新材料科技有限公司 Antistatic and antibacterial PE master batch and preparation method thereof
CN105037876A (en) * 2015-07-03 2015-11-11 中山火炬职业技术学院 Polyethylene heat sealing film slippery master batch for solvent-free compounding
CN105237852A (en) * 2015-10-27 2016-01-13 山东鲁燕色母粒有限公司 Novel antiblocking master batch and preparation method
CN106397921A (en) * 2016-09-12 2017-02-15 苏州清丰兴业塑胶有限公司 Opened polyethylene functional master batch
CN106832547A (en) * 2017-01-24 2017-06-13 上海维凯光电新材料有限公司 Opening slipping agent master batch and preparation method thereof
CN108219258A (en) * 2017-12-29 2018-06-29 上海乘鹰新材料有限公司 Plastic film open agent masterbatch composition and preparation method thereof
CN108192193A (en) * 2018-02-26 2018-06-22 上海福助工业有限公司 A kind of inorganic antibacterial PE films and preparation method thereof
CN113462076A (en) * 2021-07-01 2021-10-01 广东普赛夫聚合物有限公司 Antistatic smooth master batch for PP (polypropylene) film and preparation method thereof
CN114196117A (en) * 2022-01-12 2022-03-18 东莞市迪彩塑胶五金有限公司 Antistatic master batch suitable for low-humidity environment and preparation method thereof
CN114196117B (en) * 2022-01-12 2023-08-22 东莞市迪彩塑胶五金有限公司 Antistatic master batch suitable for low-humidity environment and preparation method thereof
CN115093798A (en) * 2022-07-14 2022-09-23 上海展通实业有限公司 Antibacterial and antistatic high-transparency polyethylene protective film and preparation method thereof
CN115725137A (en) * 2022-11-29 2023-03-03 金旸（厦门）新材料科技有限公司 High-efficiency low-haze opening smooth master batch for polyolefin film, preparation method of master batch and polyolefin film
CN115725137B (en) * 2022-11-29 2024-04-26 金旸（厦门）新材料科技有限公司 High-efficiency low-haze open smooth master batch for polyolefin film, preparation method of master batch and polyolefin film

Similar Documents

Publication Publication Date Title
CN103849032A (en) Antibacterial antistatic slippery polyethylene masterbatch and preparation method thereof
CN103849051A (en) Multifunctional smooth master batches for polyethylene films and preparation method thereof
CN101392077B (en) Polypropylene color master-batch with pearlescent interference effect and preparation method thereof
CN103881193A (en) Polyethylene antibacterial mildew-resistant master batch and preparation method thereof
CN101985506B (en) White master batch for high impact polystyrene (HIPS) and preparation method thereof
CN103881199A (en) Antibacterial antistatic reinforcing master batch used for polyethylene and preparation method thereof
CN104558756A (en) Lightweight polymer filling composite material
CN103849033A (en) Polyethylene anti-blocking smooth master batch and preparation method thereof
CN102952326B (en) Modified linear polyethylene resin and preparation method thereof
CN103849031A (en) Polyethylene antistatic smooth color master batch and preparation method thereof
CN102040776A (en) Antibacterial polypropylene material and preparation method thereof
CN104327378A (en) Antistatic and antibacterial color masterbatch and preparation method thereof
CN104804558A (en) Antibacterial powder coating for pipeline
CN101824177A (en) Specific antibacterial PE (polyethylene) preservative film
CN104479336A (en) Colour master batch for TPU film and preparation method thereof
CN103881315A (en) Smooth color master batch used for PET and preparation method thereof
CN103849034A (en) Polyethylene reinforced antistatic smooth masterbatch and preparation method thereof
CN102924809A (en) Polypropylene composite material, and preparation method and application thereof
CN103849026A (en) Antistatic smooth fiber-added polyethylene and preparation method thereof
CN103881322A (en) Antistatic smooth glass-fiber-added polyethylene glycol terephthalate and preparation method thereof
CN102827447A (en) Antimicrobial HIPS (high impact polystyrene) plastic and preparation method thereof
CN103881331A (en) Pet antibacterial antistatic smooth master batch and preparation method thereof
CN104744775A (en) Composite material for polyethylene film and preparation method thereof
CN103881326A (en) Antistatic smooth PET color master batch and preparation method thereof
CN103709662A (en) High-concentration white master batch for polyester, and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20140611