CN103839891A - Semiconductor structure and method for manufacturing semiconductor structure - Google Patents
Semiconductor structure and method for manufacturing semiconductor structure Download PDFInfo
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- CN103839891A CN103839891A CN201210489362.2A CN201210489362A CN103839891A CN 103839891 A CN103839891 A CN 103839891A CN 201210489362 A CN201210489362 A CN 201210489362A CN 103839891 A CN103839891 A CN 103839891A
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- soi substrate
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- 239000004065 semiconductor Substances 0.000 title claims abstract description 44
- 238000000034 method Methods 0.000 title claims abstract description 42
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 21
- 239000000758 substrate Substances 0.000 claims abstract description 35
- 238000000137 annealing Methods 0.000 claims abstract description 12
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims description 40
- 230000004888 barrier function Effects 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 9
- 238000005229 chemical vapour deposition Methods 0.000 claims description 7
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 3
- 238000001947 vapour-phase growth Methods 0.000 claims description 3
- 238000002513 implantation Methods 0.000 claims description 2
- 238000011065 in-situ storage Methods 0.000 claims description 2
- 238000009825 accumulation Methods 0.000 abstract 2
- 239000010410 layer Substances 0.000 description 40
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 229910052710 silicon Inorganic materials 0.000 description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 6
- 239000010703 silicon Substances 0.000 description 6
- 239000002019 doping agent Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229910052732 germanium Inorganic materials 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052581 Si3N4 Inorganic materials 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000005530 etching Methods 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 3
- 229920005591 polysilicon Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 229910010271 silicon carbide Inorganic materials 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229910021332 silicide Inorganic materials 0.000 description 2
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 2
- VLJQDHDVZJXNQL-UHFFFAOYSA-N 4-methyl-n-(oxomethylidene)benzenesulfonamide Chemical compound CC1=CC=C(S(=O)(=O)N=C=O)C=C1 VLJQDHDVZJXNQL-UHFFFAOYSA-N 0.000 description 1
- JBRZTFJDHDCESZ-UHFFFAOYSA-N AsGa Chemical compound [As]#[Ga] JBRZTFJDHDCESZ-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 1
- -1 HfRu Inorganic materials 0.000 description 1
- 229910004129 HfSiO Inorganic materials 0.000 description 1
- 229910000673 Indium arsenide Inorganic materials 0.000 description 1
- GPXJNWSHGFTCBW-UHFFFAOYSA-N Indium phosphide Chemical compound [In]#P GPXJNWSHGFTCBW-UHFFFAOYSA-N 0.000 description 1
- 241000849798 Nita Species 0.000 description 1
- 235000003976 Ruta Nutrition 0.000 description 1
- 240000005746 Ruta graveolens Species 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910004166 TaN Inorganic materials 0.000 description 1
- 229910004200 TaSiN Inorganic materials 0.000 description 1
- 229910010037 TiAlN Inorganic materials 0.000 description 1
- 229910008482 TiSiN Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 229910021419 crystalline silicon Inorganic materials 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001312 dry etching Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- QUZPNFFHZPRKJD-UHFFFAOYSA-N germane Chemical compound [GeH4] QUZPNFFHZPRKJD-UHFFFAOYSA-N 0.000 description 1
- 229910052986 germanium hydride Inorganic materials 0.000 description 1
- RPQDHPTXJYYUPQ-UHFFFAOYSA-N indium arsenide Chemical compound [In]#[As] RPQDHPTXJYYUPQ-UHFFFAOYSA-N 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- QRXWMOHMRWLFEY-UHFFFAOYSA-N isoniazide Chemical compound NNC(=O)C1=CC=NC=C1 QRXWMOHMRWLFEY-UHFFFAOYSA-N 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229910021340 platinum monosilicide Inorganic materials 0.000 description 1
- 238000005036 potential barrier Methods 0.000 description 1
- 235000005806 ruta Nutrition 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/786—Thin film transistors, i.e. transistors with a channel being at least partly a thin film
- H01L29/78606—Thin film transistors, i.e. transistors with a channel being at least partly a thin film with supplementary region or layer in the thin film or in the insulated bulk substrate supporting it for controlling or increasing the safety of the device
- H01L29/78618—Thin film transistors, i.e. transistors with a channel being at least partly a thin film with supplementary region or layer in the thin film or in the insulated bulk substrate supporting it for controlling or increasing the safety of the device characterised by the drain or the source properties, e.g. the doping structure, the composition, the sectional shape or the contact structure
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/77—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate
- H01L21/78—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices
- H01L21/82—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components
- H01L21/822—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components the substrate being a semiconductor, using silicon technology
- H01L21/8232—Field-effect technology
- H01L21/8234—MIS technology, i.e. integration processes of field effect transistors of the conductor-insulator-semiconductor type
- H01L21/8238—Complementary field-effect transistors, e.g. CMOS
- H01L21/823807—Complementary field-effect transistors, e.g. CMOS with a particular manufacturing method of the channel structures, e.g. channel implants, halo or pocket implants, or channel materials
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/77—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate
- H01L21/78—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices
- H01L21/82—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components
- H01L21/822—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components the substrate being a semiconductor, using silicon technology
- H01L21/8232—Field-effect technology
- H01L21/8234—MIS technology, i.e. integration processes of field effect transistors of the conductor-insulator-semiconductor type
- H01L21/8238—Complementary field-effect transistors, e.g. CMOS
- H01L21/823814—Complementary field-effect transistors, e.g. CMOS with a particular manufacturing method of the source or drain structures, e.g. specific source or drain implants or silicided source or drain structures or raised source or drain structures
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- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/66007—Multistep manufacturing processes
- H01L29/66075—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
- H01L29/66227—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
- H01L29/66409—Unipolar field-effect transistors
- H01L29/66477—Unipolar field-effect transistors with an insulated gate, i.e. MISFET
- H01L29/66742—Thin film unipolar transistors
- H01L29/66772—Monocristalline silicon transistors on insulating substrates, e.g. quartz substrates
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- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/786—Thin film transistors, i.e. transistors with a channel being at least partly a thin film
- H01L29/78606—Thin film transistors, i.e. transistors with a channel being at least partly a thin film with supplementary region or layer in the thin film or in the insulated bulk substrate supporting it for controlling or increasing the safety of the device
- H01L29/78618—Thin film transistors, i.e. transistors with a channel being at least partly a thin film with supplementary region or layer in the thin film or in the insulated bulk substrate supporting it for controlling or increasing the safety of the device characterised by the drain or the source properties, e.g. the doping structure, the composition, the sectional shape or the contact structure
- H01L29/78621—Thin film transistors, i.e. transistors with a channel being at least partly a thin film with supplementary region or layer in the thin film or in the insulated bulk substrate supporting it for controlling or increasing the safety of the device characterised by the drain or the source properties, e.g. the doping structure, the composition, the sectional shape or the contact structure with LDD structure or an extension or an offset region or characterised by the doping profile
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- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/786—Thin film transistors, i.e. transistors with a channel being at least partly a thin film
- H01L29/78684—Thin film transistors, i.e. transistors with a channel being at least partly a thin film having a semiconductor body comprising semiconductor materials of Group IV not being silicon, or alloys including an element of the group IV, e.g. Ge, SiN alloys, SiC alloys
- H01L29/78687—Thin film transistors, i.e. transistors with a channel being at least partly a thin film having a semiconductor body comprising semiconductor materials of Group IV not being silicon, or alloys including an element of the group IV, e.g. Ge, SiN alloys, SiC alloys with a multilayer structure or superlattice structure
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Abstract
The invention provides a method for manufacturing a semiconductor structure. The method for manufacturing the semiconductor structure comprises the steps that an SOI substrate is provided, grid accumulation is formed on the SOI substrate, and a side wall is formed in a side wall formed by the grid accumulation; a polycrystal Sil-xGex layer is formed on the SOI substrate; annealing is conducted, and a source/drain area is formed. Correspondingly, the invention further provides a semiconductor structure. According to the semiconductor structure and the method for manufacturing the semiconductor structure, the source/drain area of polycrystal Sil-xGex is formed at lower temperature, influence on doping distribution of channels and source/drain extension areas is reduced, and the performance and reliability of devices are improved.
Description
Technical field
The present invention relates to field of semiconductor manufacture, relate in particular to a kind of semiconductor structure and manufacture method thereof.
Background technology
In order to improve performance and the integrated level of integrated circuit (IC) chip, device feature size constantly dwindles according to Moore's Law, has entered at present nanoscale.Along with dwindling of device volume, power consumption and leakage current become the problem of paying close attention to most.Adopt the cmos device prepared of silicon-on-insulator SOI (Silicon on Insulator) to there is high speed, low-power consumption, high integration, anti-irradiation and without many advantages such as self-locking effects, become the preferred structure of deep-submicron and Nano-MOS transistors.In order further to improve the performance of cmos device, often require the soi structure of very thin si membrane (≤100nm), make device channel in full spent condition, can improve short-channel effect, the Sub-Threshold Characteristic that improves device, the quiescent dissipation that reduces circuit, the elimination kink effects etc. such as DIBL (Drain Induced Barrier Lowering leaks and causes potential barrier reduction) with cmos circuit prepared by this ultra-thin SOI (UTSOI) structure.
But, because the top silicon surface (≤100nm) of ultra-thin SOI is very thin, larger source/drain region series resistance and contact resistance are caused, metal silicide may consume whole silicon fiml, but still be difficult to reduce the impact of source/drain region series resistance and contact resistance, also may cause larger leakage current simultaneously.By forming lifting source/leakage (Raised Source/Drain, RSD), can further reduce the contact resistance of source/drain region, increase the drive current of device, improve device performance.In prior art, forming lifting source/leak conventional method is selective epitaxial monocrystalline silicon, germanium etc., technological temperature is generally more than 650 DEG C, in technical process, easily make the dopant in the source/leakage expansion area, the channel doping district etc. that have formed distribute again, may cause threshold voltage too low, or the problem such as channel punchthrough short circuit.The technological temperature that reduces lifting source/leakage, reduces its impact on dopant profiles, becomes a significant challenge of lifting source/leakage technology.
Summary of the invention
The present invention is intended at least solve above-mentioned technological deficiency, and a kind of manufacture method and structure thereof of semiconductor device is provided, and reduces the technological temperature of lifting source/leakage growth, reduces its impact on semiconductor structure dopant profiles, improves the Performance And Reliability of semiconductor device.
For reaching above-mentioned purpose, the invention provides a kind of manufacture method of semiconductor structure, the method comprises the following steps:
(a) provide SOI substrate, on described SOI substrate, form gate stack, form side wall at the sidewall of described gate stack;
(b) on the SOI substrate exposing, form polycrystalline Si
1-xge
xlayer;
(c) annealing, the polycrystalline Si on SOI substrate
1-xge
xin layer, form source/drain region.
Wherein, form side wall in step (a) before or after, also comprise step:
Taking described gate stack as mask, formation source/drain extension region.
The present invention also proposes a kind of semiconductor structure on the other hand, comprises SOI substrate, gate stack, side wall, source/drain region, wherein:
Described SOI substrate comprises basalis, is positioned at the insulating barrier on described basalis and is positioned at the device layer on described insulating barrier;
Described gate stack is positioned on described SOI substrate;
Described side wall is positioned on the sidewall of described gate stack;
Described source/drain region is formed on described SOI substrate, is positioned at the both sides of described gate stack, and its material is polycrystalline Si
1-xge
x.
According to semiconductor structure provided by the invention and manufacture method thereof, can form at a lower temperature source/drain region, reduce its impact on semiconductor structure dopant profiles, series resistance and the contact resistance of source/drain region are reduced, avoid the problems such as the reduction of threshold of appearance threshold voltage, channel punchthrough short circuit, improve the Performance And Reliability of semiconductor device.
Brief description of the drawings
The present invention above-mentioned and/or additional aspect and advantage will become from the following description of the accompanying drawings of embodiments obviously and easily and understand, wherein:
Fig. 1 is the flow chart of an embodiment of the manufacture method of semiconductor structure, in accordance with the present invention;
Fig. 2 to Fig. 8 is in the cross-sectional view of each fabrication stage according to this semiconductor structure in the method manufacture semiconductor structure process shown in Fig. 1.
Embodiment
Describe embodiments of the invention below in detail, the example of described embodiment is shown in the drawings, and wherein same or similar label represents same or similar element or has the element of identical or similar functions from start to finish.Be exemplary below by the embodiment being described with reference to the drawings, only for explaining the present invention, and can not be interpreted as limitation of the present invention.Disclosing below provides many different embodiment or example to be used for realizing different structure of the present invention.Of the present invention open in order to simplify, hereinafter the parts to specific examples and setting are described.Certainly, they are only example, and object does not lie in restriction the present invention.In addition, the present invention can be in different examples repeat reference numerals and/or letter.This repetition is in order to simplify and object clearly, itself do not indicate the relation between discussed various embodiment and/or setting.In addition, the various specific technique the invention provides and the example of material, but those of ordinary skill in the art can recognize the property of can be applicable to of other techniques and/or the use of other materials.In addition, First Characteristic described below Second Characteristic it " on " structure can comprise that the first and second Characteristics creations are the direct embodiment of contact, also can comprise the embodiment of other Characteristics creation between the first and second features, such the first and second features may not be direct contacts.
Fig. 1 is the flow chart of semiconductor structure, in accordance with the present invention manufacture method, and Fig. 2 to Fig. 8 is according to one embodiment of present invention according to the generalized section in each stage of the semiconductor structure of flow manufacturing shown in Fig. 1.Below in conjunction with Fig. 2 to Fig. 8, the method that forms semiconductor structure in Fig. 1 is described particularly.It should be noted that, the accompanying drawing of the embodiment of the present invention is only the object in order to illustrate, is therefore not necessarily to scale.
Referring to figs. 2 to Fig. 6, in step S101, provide SOI substrate 100, on described SOI substrate 100, form gate stack, form side wall 230 at the sidewall of described gate stack.As shown in Figure 2, described SOI substrate 100 comprises basalis 101, is positioned at the insulating barrier 102 on described basalis 101 and is positioned at the device layer 103 on described insulating barrier 102.
In the present embodiment, described basalis 101 is monocrystalline silicon.In other embodiments, described basalis 101 can also comprise such as germanium of other basic semiconductors, or other compound semiconductors, for example, and carborundum, GaAs, indium arsenide or indium phosphide.Typically, the thickness of described basalis 101 can be about but be not limited to hundreds of micron, the thickness range of for example 0.2mm-1mm.
Described insulating barrier 102 can be SiO
2, silicon nitride, Al
2o
3or other any suitable insulating material, typically, the thickness range of described insulating barrier 102 is 10nm~300nm.
Any in the semiconductor that described device layer 103 can comprise for described basalis 101.In the present embodiment, described device layer 103 is monocrystalline silicon.In other embodiments, described device layer 103 can also comprise other basic semiconductor or compound semiconductors.Typically, the thickness range of described device layer 103 is 10nm~100nm.In the present embodiment, described SOI substrate 100 is ultra-thin SOI (Ultra-Thin SOI, UTSOI) substrate, has device layer as thin as a wafer, and thickness is less than 10nm conventionally, is conducive to control the source/drain region degree of depth, forms super shallow junction, thereby reduces short-channel effect.
Especially, in described SOI substrate 100, form isolated area, for example shallow trench isolation is from (STI) structure 120, so that the continuous semiconductor device of electricity isolation.
Described grid are stacking to be formed on described SOI substrate 100, and it comprises gate dielectric layer 210, grid 220, as shown in Figure 3.Alternatively; described gate stack can also comprise the cover layer (not illustrating in the drawings) covering on described grid; for example, by deposited silicon nitride, silica, silicon oxynitride, carborundum and be combined to form; in order to protect the top area of grid 220, prevent that it is damaged in follow-up technique.Described gate dielectric layer 210 is positioned on SOI substrate 100, can be high K dielectric, for example, and HfO
2, HfSiO, HfSiON, HfTaO, HfTiO, HfZrO, Al
2o
3, La
2o
3, ZrO
2, a kind of or its combination in LaAlO.In another embodiment, can also be thermal oxide layer, comprise silica, silicon oxynitride; The thickness of described gate dielectric layer 210 can be 1nm~10nm, as 5nm or 8nm.Then on described gate dielectric layer 210, form grid 220, described grid 220 can be the heavily doped polysilicon forming by deposition, or first form workfunction layers (for NMOS, for example TaC, TiN, TaTbN, TaErN, TaYbN, TaSiN, HfSiN, MoSiN, RuTa
x, NiTa
xdeng, for PMOS, for example MoN
x, TiSiN, TiCN, TaAlC, TiAlN, TaN, PtSi
x, Ni
3si, Pt, Ru, Ir, Mo, HfRu, RuO
x), its thickness can be 1nm-20nm, as 3nm, 5nm, 8nm, 10nm, 12nm or 15nm, then in described workfunction layers, forms heavily doped polysilicon, Ti, Co, Ni, Al, W or its alloy etc. and formation grid 220.
As shown in Figure 4, described side wall 230 is formed on the stacking sidewall of grid, for separating stacking grid.Side wall 230 can and combine by silicon nitride, silica, silicon oxynitride, carborundum, and/or other suitable materials form.Side wall 230 can have sandwich construction.Side wall 230 can be by comprising that depositing-etching technique forms, and its thickness range can be 10nm~100nm, as 30nm, 50nm or 80nm.
Alternatively, in step S101, after being also included in the described gate stack of formation or after forming described side wall 230, formation source/drain extension region 300.The mode of injecting by low energy forms more shallow source/drain extension region 300 at substrate 100, can in substrate 100, inject P type or N-type alloy or impurity, and for example, for PMOS, source/drain extension region 300 can be the Si of P type doping; For NMOS, source/drain extension region 300 can be the Si of N-type doping.Alternatively, described semiconductor structure is annealed, with the doping in activation of source/drain extension region 300, annealing can adopt and comprise that other suitable methods such as short annealing, spike annealing form thereupon.In some other embodiment of the present invention, annealing operation carries out after also can being placed on and forming source/drain region.Because the thickness of source/drain extension region 300 is more shallow, can effectively suppress short-channel effect.Figure 5 shows that after forming described gate stack, inject taking described gate stack as mask, form the section of structure after described source/drain extension region 300, Figure 6 shows that after forming described side wall 230, form the section of structure after described source/drain extension region 300.
With reference to figure 1 and Fig. 7, execution step S102, on described SOI substrate 100, forms polycrystalline Si
1-xge
xlayer 310.Form described polycrystalline Si
1-xge
xthe method of layer 310 comprises plasma-reinforced chemical vapor deposition (PECVD), low-pressure chemical vapor phase deposition (LPCVD), rapid heat chemical vapour deposition (RTCVD), by gas flow, air pressure, plant capacity etc. are adjusted, can control formation polycrystalline Si
1-xge
xthe technological temperature of layer 310 is below 450 DEG C, and typical technological temperature is 425 DEG C, 400 DEG C.Than selective epitaxial single crystalline Si, Ge (technological temperature>=650 DEG C), chemical vapor deposition forms polycrystalline Si
1-xge
xthe method of layer, less on the existing dopant profiles impact of semiconductor structure, be beneficial to the Performance And Reliability that improves semiconductor device.Typically, generate polycrystalline Si
1-xge
xthe reacting gas of layer 310 is SiH
4, GeH
4, by controlling SiH
4or the gas flow of GeH4 or gas percentage, adjust Si
1-xge
xthe ratio of component of middle Si and Ge.In the present embodiment, the value of x is 0.2~0.7.Described polycrystalline Si
1-xge
xthe thickness of layer 310 can not be higher than the height of described gate stack, and its thickness range is 50nm~200nm.In the present embodiment, by forming described polycrystalline Si
1-xge
xlayer carries out in-situ doped at 310 o'clock, realizes described polycrystalline Si
1-xge
xthe doping of layer 310; In some other embodiment of the present invention, described polycrystalline Si can formed
1-xge
xafter layer 310, then carry out Implantation, realize described polycrystalline Si
1-xge
xthe doping of layer 310.Wherein said polycrystalline Si
1-xge
xdoping content be 10
18~2x10
20cm
-3, for NMOS, Si
1-xge
xthe doping type of layer is N-type; For PMOS, described polycrystalline Si
1-xge
xthe doping type of layer is P type.
With reference to figure 1 and Fig. 8, in step S103, anneal, and graphical described polycrystalline Si
1-xge
xlayer, forms source/drain region 310.Annealing can adopt and comprise other suitable methods such as short annealing, spike annealing, and technological temperature is 450 DEG C~550 DEG C.In step S102, the Si that utilizes the methods such as plasma-reinforced chemical vapor deposition (PECVD), low-pressure chemical vapor phase deposition (LPCVD), rapid heat chemical vapour deposition (RTCVD) to form
1-xge
xlayer is likely amorphous, recovers its crystal structure by annealing, eliminates defect, thereby obtains polycrystalline Si
1-xge
xlayer.On the other hand, activate donor and acceptor's impurity by annealing.Subsequently, by the suitable method such as dry etching RIE to described polycrystalline Si
1-xge
xlayer carries out graphical, at the Si of etching
1-xge
xon layer, form source/drain region 310.
Complete subsequently the manufacture of this semiconductor structure according to the step of conventional semiconductor fabrication process, for example, on source/drain region, form metal silicide; Deposition interlayer dielectric layer is to cover described source/drain region and gate stack; Described in etching, interlayer dielectric layer exposes source/drain region to form contact hole, in described contact hole, fills metal; And the processing step such as follow-up multiple layer metal interconnection.
The present invention also provides a kind of semiconductor structure, and as shown in Figure 8, described semiconductor structure comprises SOI substrate 100, gate stack, side wall 230, source/drain region 310.Wherein said SOI substrate 100 comprises basalis 101, is positioned at the insulating barrier 102 on described basalis 101 and is positioned at the device layer 103 on described insulating barrier 102; Described gate stack is positioned on described SOI substrate 100; Described side wall 230 is positioned on the sidewall of described gate stack; Described source/drain region 310 is formed on described SOI substrate 100, is positioned at the both sides of described gate stack, and its material is polycrystalline Si
1-xge
x.Described polycrystalline Si
1-xge
xthe thickness of source/drain region is 50nm~200nm, and the value of x is 0.2~0.7.Described polycrystalline Si
1-xge
xdoping content be 10
18~2x10
20cm
-3, for NMOS, described polycrystalline Si
1-xge
xthe doping type of layer is N-type; For PMOS, described polycrystalline Si
1-xge
xthe doping type of layer is P type.Described source/drain region 310 is lifting source/drain structure, and the top of source/drain region 310, higher than the bottom of described gate stack, is conducive to reduce series resistance and the contact resistance of source/drain region, polycrystalline Si
1-xge
xthan polysilicon, there is less contact resistance, further improve the current driving ability of semiconductor device.
Alternatively, this semiconductor structure also comprises source/drain extension region 300, and described source/drain extension region 300 is embedded in described device layer 103, is sandwiched between described source/drain region 310 and insulating barrier 102.
Although describe in detail about example embodiment and advantage thereof, be to be understood that the protection range in the case of not departing from spirit of the present invention and claims restriction, can carry out various variations, substitutions and modifications to these embodiment.For other examples, those of ordinary skill in the art should easily understand in keeping in protection range of the present invention, and the order of processing step can change.
In addition, range of application of the present invention is not limited to technique, mechanism, manufacture, material composition, means, method and the step of the specific embodiment of describing in specification.From disclosure of the present invention, to easily understand as those of ordinary skill in the art, for had or be about at present technique, mechanism, manufacture, material composition, means, method or the step developed later, wherein they carry out identical function or the identical result of acquisition cardinal principle of corresponding embodiment cardinal principle of describing with the present invention, can apply them according to the present invention.Therefore, claims of the present invention are intended to these technique, mechanism, manufacture, material composition, means, method or step to be included in its protection range.
Claims (10)
1. a manufacture method for semiconductor structure, the method comprises the following steps:
(a) provide SOI substrate, on described SOI substrate, form gate stack, form side wall at the sidewall of described gate stack;
(b) on the SOI substrate exposing, form polycrystalline Si
1-xge
xlayer;
(c) annealing, the polycrystalline Si on SOI substrate
1-xge
xin layer, form source/drain region.
2. method according to claim 1, in step (b), forms described polycrystalline Si
1-xge
xthe method of layer is plasma-reinforced chemical vapor deposition (PECVD), low-pressure chemical vapor phase deposition (LPCVD), rapid heat chemical vapour deposition (RTCVD).
3. method according to claim 2, wherein said polycrystalline Si
1-xge
xthe thickness of layer is 50nm~200nm, and the value of x is 0.2~0.7.
4. method according to claim 1, wherein in step (b), by the method for in-situ doped or follow-up Implantation, to described polycrystalline Si
1-xge
xlayer adulterates.
5. method according to claim 4, wherein said polycrystalline Si
1-xge
xdoping content be 10
18~2x10
20cm
-3, for NMOS, described polycrystalline Si
1-xge
xthe doping type of layer is N-type; For PMOS, described polycrystalline Si
1-xge
xthe doping type of layer is P type.
6. method according to claim 1, wherein, in step (a), before or after forming side wall, also comprises step:
Taking described gate stack as mask, formation source/drain extension region.
7. a semiconductor structure, this structure comprises SOI substrate, gate stack, side wall, source/drain region, wherein:
Described SOI substrate comprises basalis, is positioned at the insulating barrier on described basalis and is positioned at the device layer on described insulating barrier;
Described gate stack is positioned on described SOI substrate;
Described side wall is positioned on the sidewall of described gate stack;
Described source/drain region is formed on described SOI substrate, is positioned at the both sides of described gate stack, and its material is polycrystalline Si
1-xge
x.
8. semiconductor structure according to claim 7, wherein, described polycrystalline Si
1-xge
xthe thickness of source/drain region is 50nm~200nm, and the value of x is 0.2~0.7.
9. semiconductor structure according to claim 7, wherein, described polycrystalline Si
1-xge
xdoping content be 10
18~2x10
20cm
-3, for NMOS, described polycrystalline Si
1-xge
xthe doping type of layer is N-type; For PMOS, described polycrystalline Si
1-xge
xthe doping type of layer is P type.
10. semiconductor structure according to claim 7, wherein, also comprises source/drain extension region, and described source/drain extension region is embedded in the device layer of described SOI substrate, is sandwiched between described source/drain region and insulating barrier.
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US20030190791A1 (en) * | 2002-04-04 | 2003-10-09 | International Business Machines Corporation | Germanium field effect transistor and method of fabricating the same |
US6909186B2 (en) * | 2003-05-01 | 2005-06-21 | International Business Machines Corporation | High performance FET devices and methods therefor |
US20050156238A1 (en) * | 2004-01-08 | 2005-07-21 | Taiwan Semiconductor Manufacturing Co. | Silicide gate transistors and method of manufacture |
US20050279997A1 (en) * | 2004-06-17 | 2005-12-22 | Samsung Electronics Co., Ltd. | Methods of selectively forming epitaxial semiconductor layer on single crystalline semiconductor and semiconductor devices fabricated using the same |
CN101542697A (en) * | 2006-05-31 | 2009-09-23 | 先进模拟科技公司 | High-voltage bipolar-CMOS-DMOS integrated circuit devices and modular methods of forming the same |
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