CN103834295A - Lemon essential oil added environment-friendly and odorless UV (Ultraviolet)-curable coating material and preparation method thereof - Google Patents
Lemon essential oil added environment-friendly and odorless UV (Ultraviolet)-curable coating material and preparation method thereof Download PDFInfo
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- CN103834295A CN103834295A CN201410075424.4A CN201410075424A CN103834295A CN 103834295 A CN103834295 A CN 103834295A CN 201410075424 A CN201410075424 A CN 201410075424A CN 103834295 A CN103834295 A CN 103834295A
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Abstract
The invention discloses a lemon essential oil added environment-friendly and odorless UV (Ultraviolet)-curable coating material. The coating material is characterized by being prepared from the following raw materials in parts by weight: 30-35 parts of hydroxyethyl methacrylate, 20-24 parts of 102 aromatic polyurethane acrylate resin, 8-11 parts of dipentaerythritol hexaacrylate, 5-8 parts of tripropylene glycol diacrylate, 4-5 parts of 2-hydroxy-2-methyl-1-phenyl-1-propanone, 11-13 parts of glycol diglycidyl ether, 3-4 parts of xylene, 3-4 parts of glycidyl neodecanoate, 1-2 parts of sodium tripolyphosphate, 1-2 parts of titanate coupling agent (TMC-TTS), 1 part of lemon essential oil, 5-7 parts of titanium white, 3-5 parts of nano ceramic powder and 4-5 parts of auxiliaries. According to the coating material, the odor of the coating material is improved through adding the lemon essential oil, so that the coating material is refreshing and pleasant; through adding the nano ceramic powder, the dispersion of the coating material is uniform, and the hardness of a coating film is improved; and the coating material is high in curing speed and is corrosion-resistant, wear-resistant and environment-friendly.
Description
Technical field
The present invention relates to a kind of coating and preparation method thereof, particularly a kind of clean taste UV of environmental protection that adds lemon quintessence oil is coating material solidified and preparation method thereof.
Background technology
The coating material solidified comparatively proven technique that become of UV, particularly, along with the raising of people's environmental consciousness, production and researchist note the development and application that UV is coating material solidified more.UV is coating material solidified is a kind of environmental type coating, it meets " 4E " principle completely, it is thermofixation 1/5 that general UV solidifies energy consumption, and UV is coating material solidified less containing volatiles, pollute little, attract most researchist and developer to be that UV is coating material solidified can reduce raw materials consumption, be conducive to reduce Financial cost.
Current UV solidify material is various, but still in various degree exist some problems, coating material solidified, the generation string stress large through photocuring post-shrinkage ratio of existing UV, cause that film is crisp, sticking power and the shortcoming such as impact resistance is poor and the snappiness of film is poor and hardness is low, not corrosion-resistant, easy xanthochromia is aging, this series of problems all need to continue improvement for different purposes, reduce production costs, expand purposes.
Summary of the invention
The object of this invention is to provide a kind of clean taste UV of environmental protection that adds lemon quintessence oil coating material solidified and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A kind of clean taste UV of environmental protection that adds lemon quintessence oil is coating material solidified, raw material by following weight part is made: hydroxyethyl methylacrylate 30-35, 102 aromatic urethane acrylate resin 20-24, double pentaerythritol methacrylate 8-11, tri (propylene glycol) diacrylate 5-8, 2-hydroxyl-2-methyl isophthalic acid-phenyl-1-acetone 4-5, ethylene glycol diglycidylether 11-13, dimethylbenzene 3-4, neodecanoic acid glycidyl ester 3-4, tripoly phosphate sodium STPP 1-2, titanate coupling agent TMC-TTS 1-2, lemon quintessence oil 1, titanium dioxide 5-7, nano-ceramic powder 3-5, auxiliary agent 4-5,
Described auxiliary agent is made up of the raw material of following weight part: barite 10-13, bamboo charcoal 5-7, nano silicon 5-7, epoxy soybean oil 1-2, lemon quintessence oil 0.1-0.2, lauric acid methacrylic ester 4-6, Hydroxyethyl acrylate 3-5, silane coupling agent KH560 2-3, hydroxyethyl methylacrylate 20-24; Preparation method puts into calcining furnace by barite to calcine 3-4 hour at 520-540 ℃, takes out, and is ground into 50-100 object mixed powder together with bamboo charcoal, nano silicon; All the other remaining components are mixed, be heated to 50-60 ℃, stir and add mixed powder after 30-45 minute, 1-1.5 hour is ground in insulation, to obtain final product.
A kind of clean taste UV of environmental protection that adds lemon quintessence oil of the present invention is coating material solidified, is made up of following concrete steps:
(1) hydroxyethyl methylacrylate, 102 aromatic urethane acrylate resins, double pentaerythritol methacrylate, tri (propylene glycol) diacrylate are put into reactor and stirred, be heated to 75-85 ℃, stir 15-20 minute;
(2) add all the other remaining components except 2-hydroxyl-2-methyl isophthalic acid-phenyl-1-acetone, continue stirring reaction 30-40 minute, make it to be uniformly dispersed;
(3) be finally cooled to 45-55 ℃, add 2-hydroxyl-2-methyl isophthalic acid-phenyl-1-acetone, stirring reaction 20-25 minute, cooling after, grind obtain 20-40 μ m slurry, to obtain final product.
The invention has the beneficial effects as follows: the present invention adds lemon quintessence oil and improved the smell of coating, makes coating pure and fresh pleasant; Adding nano-ceramic powder, is that coating is uniformly dispersed, and has increased the hardness of film; Add auxiliary agent, increased levelling property, coating is even, and sticking power is good, and curing speed is fast, corrosion-resistant, wear-resisting, and production technique is simple, environmentally friendly.
Specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of clean taste UV of environmental protection that adds lemon quintessence oil is coating material solidified, by following weight part (kilogram) raw material make: hydroxyethyl methylacrylate 30,102 aromatic urethane acrylate resins 20, double pentaerythritol methacrylate 8, tri (propylene glycol) diacrylate 5,2-hydroxyl-2-methyl isophthalic acid-phenyl-1-acetone 4, ethylene glycol diglycidylether 11, dimethylbenzene 3, neodecanoic acid glycidyl ester 3, tripoly phosphate sodium STPP 1, titanate coupling agent TMC-TTS 1, lemon quintessence oil 1, titanium dioxide 5, nano-ceramic powder 3, auxiliary agent 4;
Described auxiliary agent by following weight part (kilogram) raw material make: barite 10, bamboo charcoal 5, nano silicon 5, epoxy soybean oil 1, lemon quintessence oil 0.1, lauric acid methacrylic ester 4, Hydroxyethyl acrylate 3, silane coupling agent KH560 2, hydroxyethyl methylacrylate 20; Preparation method puts into calcining furnace by barite to calcine 3-4 hour at 520-540 ℃, takes out, and is ground into 50-100 object mixed powder together with bamboo charcoal, nano silicon; All the other remaining components are mixed, be heated to 50-60 ℃, stir and add mixed powder after 30-45 minute, 1-1.5 hour is ground in insulation, to obtain final product.
A kind of clean taste UV of environmental protection that adds lemon quintessence oil of the present invention is coating material solidified, is made up of following concrete steps:
(1) hydroxyethyl methylacrylate, 102 aromatic urethane acrylate resins, double pentaerythritol methacrylate, tri (propylene glycol) diacrylate are put into reactor and stirred, be heated to 75-85 ℃, stir 15-20 minute;
(2) add all the other remaining components except 2-hydroxyl-2-methyl isophthalic acid-phenyl-1-acetone, continue stirring reaction 30-40 minute, make it to be uniformly dispersed;
(3) be finally cooled to 45-55 ℃, add 2-hydroxyl-2-methyl isophthalic acid-phenyl-1-acetone, stirring reaction 20-25 minute, cooling after, grind obtain 20-40 μ m slurry, to obtain final product.
This coating can adopt the form of construction work of roller coating, showering, spraying to construct.The paint spraying making by above scheme sticking power on plank is all better than secondary, resistance to 75% ethanol is more than 24 hours, alkaline-resisting 24 hours above, acidproof more than 48 hours, the cold cycling that tolerates subzero 40 degree and 40 degree does not ftracture for 10 times, resistance to 15% salt solution is more than 60 hours, hardness can regulate between 3H at 2H, and abrasion resistance index turns above 3800.
Claims (2)
1. the clean taste UV of environmental protection that adds lemon quintessence oil is coating material solidified, it is characterized in that, raw material by following weight part is made: hydroxyethyl methylacrylate 30-35, 102 aromatic urethane acrylate resin 20-24, double pentaerythritol methacrylate 8-11, tri (propylene glycol) diacrylate 5-8, 2-hydroxyl-2-methyl isophthalic acid-phenyl-1-acetone 4-5, ethylene glycol diglycidylether 11-13, dimethylbenzene 3-4, neodecanoic acid glycidyl ester 3-4, tripoly phosphate sodium STPP 1-2, titanate coupling agent TMC-TTS 1-2, lemon quintessence oil 1-2, titanium dioxide 5-7, nano-ceramic powder 3-5, auxiliary agent 4-5,
Described auxiliary agent is made up of the raw material of following weight part: barite 10-13, bamboo charcoal 5-7, nano silicon 5-7, epoxy soybean oil 1-2, lemon quintessence oil 0.1-0.2, lauric acid methacrylic ester 4-6, Hydroxyethyl acrylate 3-5, silane coupling agent KH560 2-3, hydroxyethyl methylacrylate 20-24; Preparation method puts into calcining furnace by barite to calcine 3-4 hour at 520-540 ℃, takes out, and is ground into 50-100 object mixed powder together with bamboo charcoal, nano silicon; All the other remaining components are mixed, be heated to 50-60 ℃, stir and add mixed powder after 30-45 minute, 1-1.5 hour is ground in insulation, to obtain final product.
2. a kind of clean taste UV of environmental protection that adds lemon quintessence oil is coating material solidified according to claim 1, it is characterized in that, is made up of following concrete steps:
(1) hydroxyethyl methylacrylate, 102 aromatic urethane acrylate resins, double pentaerythritol methacrylate, tri (propylene glycol) diacrylate are put into reactor and stirred, be heated to 75-85 ℃, stir 15-20 minute;
(2) add all the other remaining components except 2-hydroxyl-2-methyl isophthalic acid-phenyl-1-acetone, continue stirring reaction 30-40 minute, make it to be uniformly dispersed;
(3) be finally cooled to 45-55 ℃, add 2-hydroxyl-2-methyl isophthalic acid-phenyl-1-acetone, stirring reaction 20-25 minute, cooling after, grind obtain 20-40 μ m slurry, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410075424.4A CN103834295A (en) | 2014-03-04 | 2014-03-04 | Lemon essential oil added environment-friendly and odorless UV (Ultraviolet)-curable coating material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410075424.4A CN103834295A (en) | 2014-03-04 | 2014-03-04 | Lemon essential oil added environment-friendly and odorless UV (Ultraviolet)-curable coating material and preparation method thereof |
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| CN103834295A true CN103834295A (en) | 2014-06-04 |
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| CN201410075424.4A Pending CN103834295A (en) | 2014-03-04 | 2014-03-04 | Lemon essential oil added environment-friendly and odorless UV (Ultraviolet)-curable coating material and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104231803A (en) * | 2014-09-03 | 2014-12-24 | 天长市开林化工有限公司 | Heat insulation and heat preservation latex paint |
| CN105058531A (en) * | 2015-07-16 | 2015-11-18 | 安徽华安达集团工艺品有限公司 | Anti-flame lasting mint fragrance type treating agent for being painted on wicker product surfaces and preparation method for treating agent |
| CN105058532A (en) * | 2015-08-13 | 2015-11-18 | 安徽省舒城华竹实业有限公司 | Antibacterial flexible rose scent type treating agent for surface coating of bamboo-woven handicraft and preparation method of antibacterial flexible rose scent type treating agent |
| CN105082289A (en) * | 2015-07-09 | 2015-11-25 | 安徽省舒城华竹实业有限公司 | Sweet-scented osmanthus fragrance type polyurethane mixed treating agent for surface coating of bamboo weaving artware and a preparation method of treating agent |
| CN107082865A (en) * | 2017-05-23 | 2017-08-22 | 长春富维安道拓汽车饰件***有限公司 | A kind of odor type high-rebound polyurethane moulded foam and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101602917A (en) * | 2009-07-10 | 2009-12-16 | 中国乐凯胶片集团公司 | A kind of ultraviolet-curing paint |
-
2014
- 2014-03-04 CN CN201410075424.4A patent/CN103834295A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101602917A (en) * | 2009-07-10 | 2009-12-16 | 中国乐凯胶片集团公司 | A kind of ultraviolet-curing paint |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104231803A (en) * | 2014-09-03 | 2014-12-24 | 天长市开林化工有限公司 | Heat insulation and heat preservation latex paint |
| CN105082289A (en) * | 2015-07-09 | 2015-11-25 | 安徽省舒城华竹实业有限公司 | Sweet-scented osmanthus fragrance type polyurethane mixed treating agent for surface coating of bamboo weaving artware and a preparation method of treating agent |
| CN105058531A (en) * | 2015-07-16 | 2015-11-18 | 安徽华安达集团工艺品有限公司 | Anti-flame lasting mint fragrance type treating agent for being painted on wicker product surfaces and preparation method for treating agent |
| CN105058532A (en) * | 2015-08-13 | 2015-11-18 | 安徽省舒城华竹实业有限公司 | Antibacterial flexible rose scent type treating agent for surface coating of bamboo-woven handicraft and preparation method of antibacterial flexible rose scent type treating agent |
| CN107082865A (en) * | 2017-05-23 | 2017-08-22 | 长春富维安道拓汽车饰件***有限公司 | A kind of odor type high-rebound polyurethane moulded foam and preparation method thereof |
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Application publication date: 20140604 |
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